a Novel Heterogeneous Catalyst for the Synthesis of

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Oct 27, 2015 - Efficient Synthesis of Indene-Aldehyde Derivatives Catalyzed by Secondary Amine ..... Microwave Dehydration Behaviour of Inderite and Comparison with Thermal ...... Evaluation needs to be continuous process and students should ..... In conclusion, exploration of the mycochemistry of R. roseolus and ...
SAKARYA UNIVERSITY FACULTY OF SCIENCE AND ARTS DEPARTMENT OF CHEMISTRY

INTERNATIONAL TURKIC WORLD CONFERANCE ON CHEMICAL SCIENCES AND TECHNOLOGIES (ITWCCST) 27th OCTOBER-1st NOVEMBER 2015

SARAJEVO BOSNIA-HERZEGOVINA

Chair of the Conference Prof. Dr. Ahmet TUTAR

Congress Secretary Prof. Dr. Ahmet TUTAR Sakarya University Musa Köse Zenith Group D.O.O. Sarajevo, Bosnia and Herzegovina Hana Sarkinovic Zenith Group D.O.O. Sarajevo, Bosnia and Herzegovina İsmet Uzun Zenith Group D.O.O. Sarajevo, Bosnia and Herzegovina



Organization Committee Prof. Dr. Ahmet TUTAR Prof. Dr. Prof. Dr. Mehmet Hakkı ALMA Prof. Dr. Ahmet AYAR Assoc. Prof. Dr. Hüseyin ALTUNDAĞ Assist. Prof. Dr. Mustafa AKÇİL Assist. Prof. Dr. Beytullah EREN Assist. Prof. Dr. Murat TUNA Assist. Prof. Dr. Ertuğrul ALTUNTAŞ Research Assist. Eyyüp KARAOĞUL Research Assist. Tufan SALAN Raşit Fikret YILMAZ İbrahim Halil BAYDİLEK Ömer Faruk TUTAR Research Assist. Yavuz DERİN

Sakarya University, Kahramanmaraş Sütçü Sakarya University Sakarya University Sakarya University Sakarya University Sakarya University Kahramanmaraş Sütçü Kahramanmaraş Sütçü Kahramanmaraş Sütçü Sakarya University Sakarya University Sakarya University Sakarya University



İmam University

İmam University İmam University İmam University



Scientific Committee

Prof. Dr. Abdolali AlEMİ Prof. Dr. Abdurrahim KOÇYİĞİT Prof. Dr. Abel Maharramow Prof. Dr. Ahmed KAYACIER Prof. Dr. Ahmet TUTAR Prof. Dr. Arif DAŞTAN Prof. Dr. Akif AZİZOV Prof. Dr. Bagher EFTEKHARI-SIS Prof. Dr. Bolat URALBEKOV Prof. Dr. Dilgam TAGİYEV Prof. Dr. Erdoğan KÜÇÜKÖNER Prof. Dr. Farid YAMBUŞEV Prof. Dr. Farida KARATAEVA Prof. Dr. Florida KUDASHEVA Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Harun PARLAR Prof. Dr. Hüseyin KARA Prof. Dr. İlyas NİZAMOV Prof. Dr. İsmet KAYA Prof. Dr. Mahammed BABANLİ Prof. Dr. Mehmet Akalin Prof. Dr. Mehmet Hakkı ALMA Prof. Dr. Mehmet SÖNMEZ Prof. Dr. Mohammed Taghi ZAFARANİ-MOATTAR Prof. Dr. Muhammet ARİCİ Prof. Dr. Mustafa SÖZBİLİR Prof. Dr. Naz Mohammed ATABAY Prof. Dr. Osman SAĞDIÇ Prof. Dr. Rinat AKHMETKHANOV Prof. Dr. Rustem AMİROV Prof. Dr. Sluken RAKHMADİEVA Prof. Dr. Tofik NAGİYEV Prof. Dr. Yerdos ONGARBAYEV Prof. Dr. Sharipa JOROBEKOVA Prof. Dr. Vagif ABBASOV Prof. Dr. Vagif FARZALİYEV Prof. Dr. Yücel KADIOĞLU Assoc. Prof. Dr. İsmail Usta Assoc. Prof. Dr. Muhammet Uzun

Tabriz University Bezmialem Vakıf University Bakü State University Bursa Technical University Sakarya University Atatürk University Azerbaijan National Academy of Sciences University of Maragheh El-Farabi Kazak National University Azerbaijan National Academy of Sciences Süleyman Demirel University Kazan Federal University Kazan Federal University Bashkir Government University Kafkas University Munich University Selçuk University Kazan Federal University Çanakkale Onsekiz Mart University Azerbaijan National Academy of Sciences Marmara University Kahramanmaraş Sütçü İmam University Gaziantep University Tabriz University Yıldız Technical University Atatürk University Fatih University Yıldız Technical University Bashkir University Kazan Federal University L.N. Gumilev Eurasia National University Azerbaijan National Academy of Sciences El-Farabi Kazak National University Kirgizstan National Sciences Academia Azerbaijan National Academy of Sciences Azerbaijan National Academy of Sciences Erzincan University Marmara University RWTH Aachen University







Dear Participants I. International Turkic World Conferance on Chemical Sciences and Technologies organized by Sakarya University Faculty of Arts and Science Chemistry Department and Kahraman Maraş Sütçü İmam University and hosted by International University of Sarajevo was held fort he first. We are happy that the conferance was held in this beatiful university and City to which we have many historical relations. On this opportunity I would like to thank to The Rector who opened doors to us and all oficals of Intenational University of Sajevo Chemistry is a scope of science whcih is not only related to fundemantal sciences but also many applied sciences such as Health, Agriculture, Engineering Sciences. Actually Technological and scientific developments removed sharp lines among the sciences. Due to that development in the chemistry effects directly to physicals and natural sciences. in this context Chemisty tend to be one of the interdiciplinary studies. The event we all know and make us proud is Prof Dr Aziz SANCAR who is one of the there people awarded with 2015 nobel chemistry prize besides being medicinal doctor He was awarded because of his studies in Chemistry and exalted Turkic and Islamic world. It is an honour that the date of this conferance held fort he first time is the same year whe Ms. Sancar got Nobel prize.His big succes undouptly will inspire the researches especially youngs. I congratulate and pay my respects to him. We wished this conferance which gathered the scientists and opened new doors to interdiciplinary studies little special. In this respect, we desired that the scienctists in Turkic world come here, meet and creat new projects together. Because this conferance was held for the first time, We couldnt have many people form Turkic World but we hope to reach more people from friendly nations in next the coferances. Scholars form 22 diffent contries especially Turkey and Azerbaijan honored our Conferance586 Scientist, educater, industrialist registrated to attend the conference. 386 abstracts were submitted After Each one was evaluated carefully 353 abstracts were excepted by the scientific committee. 221 and 132 of them took apart in Conference book as poster presentations and oral presentations respectively. I thank to Rector of Sakarya University Prof. Dr. Muzaffer ELMAS who gave us permition for the conferance and moral and material support, to Prof. Dr. Yılmaz DAŞÇIOĞLU Deen of Faculty of Arts and Science, to Prof. Dr. Hakkı ALMA who wished to be with us, to Kahraman Maraş Sütçü İmam University and also I thank to ZENITH Group personals especially Musa KÖSE for preparation of this conferance and to Prof. Dr. Arif DAŞTAN, Prof. Dr. Dilgam TAGIYEV, Prof. Dr. Hacali NECEFOĞLU who made great effort for the conferance and to my dear friend Famil ALİYEV and also All people who came form far distences to join us Prof. Dr. Ahmet TUTAR

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CONTENTS FOREWORD CONTENT POSTER PRESENTATION OR-1 Sulphur-Containing Antioxidants of Combined Action Vagif M. FARZALIYEV OR-2 New Reactions of Acetylenes: An Unexpected Easy Full Cleavage of Polarized C≡C Moiety Under Action of N-Nucleophiles Sergey VASILEVSKY, Maria DAVYDOVA OR-3 Synthesis and Crystal Structure of 4,5,12,13-Tetraaza dibenzo[b,k]chrysene Famil VALIYEV OR-4 Organic Synthesis in Glycerol Based Solvents Adi WOLFSON, Dorith TAVOR OR-5 Photobactericidal and Photochromic Textile Materials Realized by Embedding of Advantageous Dye Using Sol-gel Technology Boris MAHLTIG, Torsten TEXTOR, Perrin AKÇAKOCA KUMBASAR OR-6 An Investigation on Serum Levels of Cu, Zn, Ca, Mg and P in Goats İlker CAMKERTEN, Güzin CAMKERTEN, Osman KARABULUT, Durhasan MUNDAN,Gaye BULUT OR-7 Antioxidant Capacity of Verbascoside Isolated from Teucrium chamaedrys L. subsp. Chamaedrys Mahfuz ELMASTAŞ, Beşir İSNAÇ, Ayşenur TAŞ, Hüseyin AKŞİT, Nusret GENÇ OR-8 Secondary Metabolites from Origanum rotundifolium Boiss. and Antioxidant Activities Ramazan ERENLER, Özkan ŞEN OR-9 Separation and Preconcentration of Palladium on Magnetic Polyhydroxybutyrate-bPolydimethylsiloxane (PHB-b-PDMS) and its Determination in Environmental Samples by Flame Atomic Absorption Spectrometry Mustafa TÜZEN, Yunus Emre ÜNSAL, Mustafa SOYLAK, Baki HAZER OR-10 Conversion Treatment of Thin Chromium Layers Deposited on High Carbon Steels Substrates Younes BENARIOUA OR-11 Evaluation of the Raman Spectroscopy Coupled with Partial Least Squares Regression Analysis for Diagnosis of Hepatitis C. H. NAWAZ, N. RASHID, M. BILAL, M. SALEEM, I. AMIN, M. IGBAL, M. RAHMAN, P. KNIEF, H J BYRNE, S. M. BAIG, M. AHMED OR-12 Kendiliğinden Yerleşen Betonda Rötre Azaltıcı Kimyasal Katkının Dayanıma Olan Etkisi İlhami DEMİR, İlker KALKAN, Ali Payidar AKGÜNGÖR, Özer SEVİM OR-13 Spectroscopic Studies on 9H-Carbazole-9-(4-phenyl) Boronic Acid Pinacol Ester by DFT Method Emine BABUR ŞAŞ, Mustafa KURT, Mustafa CAN, Nesrin HORZUM, Ahmet ATAÇ

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Efficient Synthesis of Indene-Aldehyde Derivatives Catalyzed by Secondary Amine Catalysts Hui MAO, Jung Woon YANGA Synthesis of Multiwall Carbon Nanotube -p-Phenylenediamine - Maleic Anhydride -1Heptene Nanocomposite Elvin MALIKOV, Oktay AKPEROV, Mustafa MURADOV, Goncha EYVAZOVA Design of an Appropriate Semi-Interpenetrating and Full-Interpenetrating Polymer Network Chitosan for Nano Drug Delivery; Review Amilah, Nike Triendah ASIH Preparation of Chitosan-Gum Arabic/N-Eicosane Microcapsules by Complex Coacervation Kasım AKSOY, Cemil ALKAN Removal of Cr(III) and Cr(VI) Ions from Aqueous Solutions Using Modified Cotton Cellulose with Polycarboxylic Acids Nazife KORKMAZ, Sennur ALAY AKSOY, Fethiye GÖDE Oxidative Stress Parameters in Anesthetized with Ketamine-Xylazine the Bozova Greyhounds Güzin CAMKERTEN, İlker CAMKERTEN, Nihat ŞINDAK, GayeBULUT Structural, Electronic, Elastic and Phonon Properties of OsAl in B2 Crystal Structure from First-principles Raşit UMUCU, Mustafa ÖZDURAN Thermal Energy Storage Properties of Poly(methyl methacrylate)/Stearic Acid Micro/Nano Capsules Ahmet SARI,Ayşe Gül KÜÇCÜK, Alper BİÇER, Cemil ALKAN AB Initio Molecular Dynamics Study of Structural Properties of FeF2 as a Function of Pressure Cihan KÜRKÇÜ, Ziya MERDAN, Hülya ÖZTÜRK, Sümeyra YAMÇIÇIER, Çağatay YAMÇIÇIER, Cemile KÜRKÇÜ Developed of Potentiometric Sensitive Sensor to Antipsychotic Risperidone Ömer IŞILDAK, Ayşenur BİRİNCİ Usability and Attenuation Performance of Titanium-Iron Oxide Mineral as Natural Filler for Composite Ionizing Electromagnetic Radiation Shielding Ezgi Eren BELGİN, Gül Asiye AYÇIK, Ayşe KALEMTAŞ Synthesis of Some Natural Bromophenols Including Propane Derivatives Çetin BAYRAK, Abdullah MENZEK From “Dark to light”1-2 to Fluorescence Resonance Energy Transfer: Dual Activator TPE Donor Fused BODIPY Dyes with a Large Stokes Shift and High Quantum Yield Esra ŞEN, Serdar ATILGAN, Kadem MERAL Synthesis of The Topoisomerase-I Inhibitors Isoindolo[2,1-B]-Isoquinolin-7(5H)-one and The Alkaloid Rosettacin Based on Aryl Radical Cyclization and N-Acyliminium Chemistry Lahssen El BLIDI, Adam DAICH, Yousef AL-ZEGHAYER Determination of Structural and Spectroscopic Properties of Methyl-4-bromo-2chloropyrıdine-3-carboxylate Molecule Using FT-IR and NMR Experimental Techniques and DFT Quantum Chemical Calculations Zühre CALIŞIR, Mustafa KURT, Mehmet KARABACAK, Ahmet ATAÇ iv



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A New Approach to Convenient Synthesis of Disubstituted Tacrine Derivatives Makbule EKİZ, Ahmet TUTAR, Salih ÖKTEN Chitosan/Nanoclay/n-Eicosane Microcapsules with Heat Energy Storage Property Ebru GENÇ, Sennur ALAY AKSOY, Kasım AKSOY ab initio Study of Elastic, Electronic and Phonon Properties of SnNCa3 and PNCa3 Compounds Mustafa ÖZDURAN and Raşit UMUCU The Trace Elements (Selenium, Copper, Zink, Iron) Levels in Patients Sera Affected by Bovine Ephemeral Fever Hikmet ÜN, Güzin CAMKERTEN, İker CAMKERTEN, Tekin ŞAHİN, Burcu M. BALKAN, Özcan EREL Comparison of Phenolic Compounds in Commercial Bee Pollen and Pollen Inside the Hive Yaşar GÜLMEZ, Ömer KAYIR, Mahfuz ELMASTAŞ Conductance and Thermodynamic Study of Cobalt (II), Nickel (II) and Copper (II) Complexes with a New Schiff Base Derived from 1,8-Diaminonaphthalene Taher Sh. ABABNEH, Taghreed M. A. JAZZAZI, Tareq M. A. Al SHBOUL, Ziyad A. TAHA Calcination of Galvaniz Ash and Investigation of It’s Resolution in Acid Leaching Solutions Harun YILMAZ Electronic, Elastic, Thermodynamic and Phonon Properties of LaCd and LaCo Compounds in the B2 Phase Osman ÖRNEK, Nihat ARIKAN, Şule UĞUR, Gökay UĞUR Kendiliğinden Yerleşen Betonda Hidratasyon Isısı Azaltıcı Kimyasal Katkının Dayanıma Olan Etkisi İlker KALKAN, İlhami DEMİR, Ali Payidar AKGÜNGÖR, Özer SEVİM Anions Content of Wild Grown Edible Mushrooms Species in Ordu Region, Turkey İbrahim TÜRKEKUL, Ömer IŞILDAK ICG-Conjugated Magnetic Graphene Oxide for Dual Photothermal and Photodynamic Therapy Nuran IŞIKLAN, İsmail ÖÇSOY, Nalan ÖZDEMİR Comparison of Photo Physical Properties of 7-diethylamino-3-thenoyl Coumarin and 7diethylamino Coumarin Dr. Sanjay KUMAR Synthesis and Solid State Self-assembly of Thiosemicarbazones Highlighting Their Potential in Crystal Engineering Muhammad Moazzam NASEER Synthesis of the Efficient Palladium Catalysts for the Cross-coupling Reactions and Hydrogenation by the Direct Loading of Inorganic Supports Using Stable Pd(0) Source Viacheslav I. SOKOLOV, Natalya V. ABRAMOVA Synthesis of Methyl-Substituted Mono- and Di-Methoxy Conduritols Dilek KAPLAN, Latif KELEBEKLİ Structure Activity Relationship Studies of Novel Quinoline Derivatives as Anticancer Agents Salih ÖKTEN, Osman ÇAKMAK, Şaban TEKİN

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The Investigation Of Menthol’s Bioactivity In Blood As Theoritical By Using DFT (Density Functional Theory) Faik GÖKALP Use of Supramolecular Solvents for Liquid Phase Microextraction of Gold(III) from Environmental Sampled ErkanYILMAZ, Mustafa SOYLAK Facile and Large Scale Synthesis of Graphene Tugay ÜSTÜN, Havva Tutar KAHRAMAN, Ahmet AVCI, Erol PEHLİVAN Fabrication of Thermo-regulated PAN/ Myristic asid (MA) Nanofibers by the Electrospinning Process M.Selda TÖZÜM, Sena DEMİRBAĞ, Kasım AKSOY Kendiliğinden Yerleşen Betonda Piriz Hızlandırıcı Kimyasal Katkının Dayanıma Olan Etkisi Ali Payidar AKGÜNGÖR, Özer SEVİM, İlhami DEMİR, İlker KALKAN Density Functional Theory and ab initio Hartree-Fock Calculations of Molecular Structure and Conformational Properties of 4-X-Phenylboronic Acid Derivatives ( X = F, Cl, Br) Güventürk UĞURLU Electronic Structure, Elastic and Phonon Properties of Rh3La Compound: An ab initio Study Nihat ARIKAN, Osman ÖRNEK, Şule UĞUR, Gökay UĞUR Production of Heat Energy Storage PAN/PEG Nanofibers Sena DEMİRBAĞ, Kasım AKSOY, M.Selda TÖZÜM Cost-Effective Graphene Coated Polyurethane Sponge for Oil/Water Separation Havva Tutar KAHRAMAN, Tugay ÜSTÜN, Erol PEHLİVAN, Ahmet AVCI Synthesis and Application of Nano-Metal Catalysts by Metal Vapor Method Vagif AKHMEDOV, Dilgem TAGIYEV Characterisation of Graphene Oxide/Poly(Acrylonitrile-Vinyl Acetate) Nanocomposites Produced by Electrospinning Method Mustafa YAZICI, İsmail TİYEK, M. Hakkı ALMA, Utkay DÖNMEZ, Behzat YILDIRIM, İbrahim KARTERİ, Tufan SALAN, Serhan URUŞ, Şükrü KARATAŞ, M. Sabri ERSOY Supercapacitor Electrode Materials of Novel Synthesized Polymer/Carbon Nanotube Composite Materials Murat ATEŞ, Nesimi ULUDAĞ Linear Pentanuclear Nickel Complex with Pyrazine Modulated N,N’-di(pyrazin-2yl)pyridine-2,6-diamine Ligand Rayyat Huseyn ISMAYILOV, Fuad Famil VALIYEV, Wen-Zhen WANG, GeneHsiang LEE, Shie-Ming PENG Key Magnetic Intermediates in Mo-, W-, Re- based Catalytic Systems for Olefins Metathesis Reactions: Structure and Reactivity Yadigar ABBASOV, Etibar ISMAILOV, Dilgam TAGIYEV Determination Optimum B2O3, KCl and NaOH Molar Ratios in the Synthesis of Potassium Borates Seyhun KIPÇAK, Merve GÜNAL, Sibel ILA, Meral YILDIRIM, Mehmet B. PİŞKİN, Emek MOROYDOR DERUN vi



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Determination of Metal Content in the Water and Sediments Located Around Siirt İbrahim TEGİN, Uyan YÜKSEL Determination of Nitrate, Fluoride and Methyl Tertiary-buty Ether by Aqueous Solution Using Amin Multi Walled Carbon Nanotubes Hamideh YAHYAPOUR, Omid MORADI The Hydrogenation of Carbon Dioxide over Nanostructured Zr/Si Oxide Contacts Shaxla TAGIYEVA, Nushaba ALIYEVA, Lala QASIMOVA, Etibar ISMAILOV Absorbtion Cooling Systems for Ships Mesut TANER Boric Acid Production From Sodium Metaborate With Sulphuric Acid Hilal Seda DEMİREL, Taylan Efe İNCE, Duygu UYSAL, Bekir Zühtü UYSAL Effect of Aqueous Extracts of Leaves, Seeds and Stem Bark of Moringa oleifera on Spme Bacteria and Fungi Isolated From Spoilt Locally Produced Soymilk Abiona Dupe LYDIA, Adegbola Racheal ADEBOLA, Olanrewaju Bernice JEJELOLA Characterization of Biosensor Application By Atomic Force Microscope (AFM): Modification of Gold Screen Surface By Dendrimeric Structures and Biological Molecules Dilek GÜNGÖR Magnetic Properties of Self-Assembled Magnetite Nanoparticles via Spin and Dip Coating Methods Sinem ESİR, Ayşe Demir KORKMAZ, Hüseyin KAVAS Liquifying Slimes and Some Oxidized Lignites Mehmet ÇÖTELİ, Akan GÜLMEZ, Ayşe ERDEM, Mehmet KARAKAŞ, Abdullah ULAŞ, Selami TOPRAK, Emine SÜTÇÜ, Polat CANDAN Synthesis and Investigation of Their Antimicrobial Activities of New Conazole Derivatives Containing Morpholine and Fluorophenilene Rings Hacer BAYRAK, Yıldız UYGUN, Arif MERMER, Serap BAŞOĞLU, Neslihan DEMİRBAŞ, Ahmet DEMİRBAŞ, Şule CEYLAN, Serpil DEMİRCİ Synthesis and Characterization of Green Polyurethanes Using Novel Vegetable Based Polyols Kemal KARADENİZ, Yakup ÇALIKOĞLU Comparison of %1 Nd and %1 Pr Doped %25 TiO2-MMT Composite Photocatalyst Amount on Azo Dye ( Basic Yellow 28) Oxidation Başak OTSUKARCI, Yasemen KALPAKLI The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate Nevin KARAMAHMUT MERMER, Sevil Begüm KARAKAŞ, Müge SARI YILMAZ The Effect of Acid Concentration on the Synthesis of Hydrophobic Silica Based Aerogels Müge SARI YILMAZ, Özgül DERE ÖZDEMİR, Nevin KARAMAHMUT MERMER, Mehmet Burçin PİŞKİN Optimum Conditions for Chromatographic Seperation of N-Nitrosodiphenylamine from Its Intermediates Sinem DEMIR, Murat TORUN, Dilek ŞOLPAN vii



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Extraction, Characterization and Fatty Acid Profile of African Star Apple Seed (Chrysophyllum albidum) Oil Chidimma Emmanuel OMINYI Vesicular Coacervative Microextraction of Pb: Green Alternative to Classical Extraction Strategies Faheem SHAH, Tasneem Gul KAZI, Naeem ULLAH Transformation of Liquefied Gases of Catalytic Cracking in the Presence of PolymerSupported Ionic Liquid Systems Reyhan ALIYEVA, Yeter MAMMADOVA Leaching Kinetics of Zn from Zinc Plant Residue by Atmospheric and High-temperature H2SO4 Leaching Mehmet ERDEM, Mehmet ŞAHİN Fast Oxidation and Optimization of some Lignite Samples by means of Acid Leaching Haydar POLAT, Mehmet ÇÖTELİ, ehmet KARAKAŞ, Ayça YILDIRIM, Polat CANDAN Analytical Investigation of a New Sandwich Type Phthalocyanine and Oncogene Interaction Esra BAĞDA, Ebru YABAŞ, Efkan BAĞDA Turkish Primary Science Teacher Candidates’ Understandings of Some Environmental Problems Fatma AĞGÜL YALÇIN, Mehmet YALÇIN Effects of K+/Mn3+ Addition on Microstructure of SrTiO3 Ceramics Selvin USTABAŞ, Zeki AYDIN, H. Zehra AKBAŞ, Muhammet DEMİREL Solid-Liquid Extraction (Leaching) of Liquorice (Glycyrrhıza Glabra) İrem KARAASLAN, Zeki AYDIN, Ali Coşkun DALIÇ Synthesis and Antimicrobial Evaluation of Nalidixic Acid Based 1,2,4-Triazole Derivatives Şule CEYLAN, Neslihan DEMİRBAŞ, Hacer BAYRAK, Yıldız UYGUN, Serap BAŞOĞLU, Ahmet DEMİRBAŞ Bio-synthesis of Cu- Nanoparticles Using Natural Plant Calotropis Extract as Reducing Agent for Enhanced Antibacterial and Antifungal Activity Muhammad Imran DIN Silver(I)-N-Heterocyclic Carbene Catalyzed Multicomponent One-pot Reactions: A Facile Synthesis of Highly Functionalized Pyrrole-3-carbonitriles Srinivas NERELLA Synthesis and Evaluation of Antitumor Activities of Novel Fused Uracil Derivatives Samar A. EL-KALYOUBI, Eman A. FAYED Comparison of Cold and Hot Esterification Methods of Fatty Acids for GC-MS Analysis Muhammet DEMİREL, Zeki AYDIN, Selvin USTABAŞ Cr(VI) Removal from Aqueous Solutions by Activated Carbon Prepared from Grape Stalk Mehmet ERDEM, Özlem AKÇAKAL, Hatice ERDEM, Mehmet ŞAHİN Utilization of Bergama Gold Tailings as an Additive in the Mortar Kübra KUNT, Meral YILDIRIM, Fatma DUR, Emek MOROYDOR DERUN, Sabriye PİŞKİN The Investigation of the Element Contents in the Turkish Coffees Nigar SELVİ, A.Seyhun KIPÇAK, Funda DEMİR, Özgül D. ÖZDEMİR, Mehmet B. PİŞKİN, Emek M. DERUN viii



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Microwave Dehydration Behaviour of Inderite and Comparison with Thermal Analyses Methods İklim N. OZDOGAN, Yasemen T. AKSOY, F. Tuğçe ŞENBERBER, A. Seyhun KIPÇAK, Mehmet B. PİŞKİN, Emek MOROYDOR DERUN Utilization of Boron Waste as an Additive for Cement Production Kübra KUNT, Fatma DUR, Beril ERTINMAZ, Meral YILDIRIM, Emek MOROYDOR DERUN, Sabriye PİŞKİN New Approach to Modelling of Discontinuous Azeotropic Distillation in NonConventional Configurations Marija STOJKOVIC About Evaluation in Chemistry Education Meliha ZEJNILAGIC-HAIRIC The Use of Mathematical Softwares in Chemistry Education Mehmet YALÇIN, Fatma AĞGÜL YALÇIN, Halil ZEHİR, Kıymet ZEHİR Corrosion Inhibition of Low Carbon Steel by Boron-Containing Ionic Liquids in 0.1 M HCl Hüsnü GERENGİ, H.İbrahim UĞRAŞ, Mine KURTAY, Necip ATAR Investigation Corrosion Effect of KBF4 on Low Carbon Steel by Dynamic Electrochemical Impedance Spectroscopy (DEIS) Hüsnü GERENGİ, H.İbrahim UĞRAŞ, Mine KURTAY Removal of Endocrine Disrupting Chemicals in Aqueous Solutions by Gammairradiation Masoomeh MEHRNIA, Sinem DEMİR, Murat TORUN, Dilek ŞOLPAN Synthesis of Bisbenzoin End-Functionalized Poly(e-Caprolactone) Macrophoto Initiator and Its Use in Miktoarm Star Copolymerization Zafer UYAR, Ülkü ARSLAN, Mustafa DEĞİRMENCİ Synthesis and Photochromic Properties of 4,5-Bisaryl-3(2H)-Pyridazinones Leyla GÜNDOĞDU, Ersin ORHAN, Mahmut KÖSE Antioxidant and Anticholinesterase Activity Evaluation of Various Fraction of Sarcosphaera crassa (santi) Pauzar: A Poisonous Edible Mushroom Zain ULLAH, Mehmet ÖZTÜRK, Mehmet Emin DURU, Yunus ÇETİNTAŞ Biological Activities and Chemical Composition of Essential Oil of Endemic Rhantheriumsuaveolens Desf.from Algerian Sahara Ahmed Elkhalifa CHEMSA, Ebru EROL, Mehmet ÖZTÜRK, Amar ZELLAGUI, Özgür CEYLAN, Noureddine GHERRAF, Mehmet E. DURU Study of Thermal Behavior of Nanocomposite Base on Aniline and Multi Walled Carbon Nanotube: Effect of Size Carbon Nanotube on Thermal Stability Shima moradi SEYMOHAMMADI, Omid MORADI Investigation of Corrosion Behavior of the DP600 Steel and AA5754 Aluminum Alloy Materials Joined Using Friction Stir Welding Method Ramazan SAMUR Catalytic Pyrolysis of Isochrysis Microalgae by Ceria Based Catalysts for Hydrocarbon Production Tevfik AYSU, Aimaro SANNA Proximate, Mineral Composition and Photochemicals Screening of Some Selected Spices Of Ibadan Metropolis, Oyo State, Southwest, Nigeria Adegbola Rachael ADEBOLA, Davies Caleb ADEOSUN, Abiona Dupe LYDIA ix



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AP-TPR-TD-GC/MS Study of Miocene-aged Lignite Humic Acids, Bulgaria Maya STEFANOVA, Lenia GONSALVESH, Stefan MARINOV, Jan CZECH, Robert CARLEER, Jan YPERMAN Rhizopogonroseolus and its Bioassay-guided Mycochemical Investigations Akhtar MUHAMMAD, Mehmet ÖZTÜRK, Mehmet Emin DURU, Aziz TÜRKOĞLU Investigation of Leaching Performance of Wood Materials Colored With Juglans Regia L. Osman GÖKTAŞ, Ertan ÖZEN, Mehmet YENİOCAK, Mehmet ÇOLAK, Mehmet UĞURLU, Sevil YENİOCAK Determination of Vitamin A and E using the High Performance Liquid Chromatography in Medicinal Plants Suat EKİN, Mahire BAYRAMOĞLU, Hatice KIZILTAŞ, Fevzi ÖZGÖKÇE An Experimental Study on the Effect of Sonication Time on Viscosity and Fire Resistance Performance of Nanoclay-based Intumescent Coating Havva Tutar KAHRAMAN, Erol PEHLİVAN, Dilhan M. KALYON Alteration in the Nutritional Components of Trigonella foenum graecum Linn. Seeds During Various Germination Phases Iffat Zareen AHMAD CoxPty Nanoclusters Supported on Magnesia Surface; Preparation, Characterization and the Investigation of the Catalytic Performance in the Dehydrogenation of Aqueous Hydrazine Borane Şerif SAĞLAM, Gökhan YEĞİNER, Mehmet GÜLCAN, Mehmet ZAHMAKIRAN Expedient and Efficient Synthesis of Trifluoroethyl Ethers From Metal Free Reagent 2,4,6-tris-(2,2,2-Trifluoro-Ethoxy)-[1,3,5] Triazene Shrawan Kumar MANGAWA, Satish K. AWASTHI Cobalt Boron Nitride: A Novel Heterogeneous Catalyst for the Synthesis of Medicinally Important α-amino Quinoline Phosphonates Mahalingam SURESKUMAR, Krishnan ANAND, Thangaraj MUTHU, Robert Moonsamy GENGAN Hydrothermal Synthesized Nanocrystalline V2O5 and Electrical Properties Hasan GÖÇMEZ, Mustafa TUNCER, Seher ÇETİN, Faruk EBEOĞLUGİL Optimization of Production of Sodium Pentaborate from Ulexite Ore and Sulfur Dioxide Mehmet Muhtar KOCAKERİM, Vedat Arda KÜÇÜK Propericiazine as a Selective and Sensitive Reagent For The Spectrophotometric Determination of Microgram Amounts of Platinum in Minerals A. Thimme GOWDA Synthesis of Dihydropyrimidine Compounds by Biginelli Reaction and Performing the Eschenmoser Coupling Reaction Esvet AKBAŞ, Erdem ERGAN Selective Separation of Alkyl Tert-alkyl Ethers from Alcohol and Hydrocarbons Containing Azeotropic Mixture by Ionic Liquids Akif AZIZOV, Hamide AZIZBEYLI, Reyhan ALIEVA Purification of Bioactive Fractionations of Industrial Importance from Citrus reticulata Blanco Waste Peel Muhammad Asif HANIF, Rabia IDREES x



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(Oligo)Alkylation of Toluene With Alpha-Olefins in the Presence of Ionic Liquids Khayala SEIDOVA, Akif AZIZOV, Reyhan ALIYEVA, Igrar NAZAROV, Aygun ABDULLAYEVA Polyvinyl Pyrrolidone Coated Iron Oxide Nanoparticles as Contrast Agents for Magnetic Resonance Imaging (MRI) Muhammad Irfan MAJEED Complex Catalytic Systems on Based of Zirconium Phenolates Containing Amino Hydrochloride Substituents for Oligomerization of the Ethylene A.A. KHANMETOV, M.J. KHAMIYEV, A.H. AZIZOV Controlled Radical Polymerization of Some Acrilyc Monomers I.M.GULIYEVA Synthesis, Antimicrobial Activity of New 2- Thioxanthine and Dipyrimidopyridine Derivatives Samar EL-KALYOUBI, Fatmah AGILI, Shaker YOUSSIF Chemical Synthesis of 3,6-bis-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4vinylbenzyl)-9H-carbazole and Polymer Formation Used as Supercapacitor Electrode Material* Nesimi ULUDAG, Murat ATES

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New and Efficient Synthesis of Brominated Diazanaphthalene Derivatives: Key Compounds for Strongly Biologicaly Active Derivatives Sefa UÇAR, Arif DAŞTAN, Erdin DALKILIÇ, Selçuk EŞSİZ Effect of Filler Particle Size on Ionizing Electromagnetic Radiation Shielding Performances of Natural Mineral-Polymer Composite Ezgi Eren BELGIN, Gül Asiye AYÇIK, Ayşe KALEMTAŞ Synthesis and Characterization of Thermal Energy Storage Properties of Polystyrene/(Nonadecane-Octacosane) Micro-Nano Capsules Ahmet SARI, Alper BİÇER, Cemil ALKAN, Çınar KIZIL Preperation and Characterization of Magnetic Featured Horseradish Peroxidase Hybrid Nanoflowers Nalan ÖZDEMİR, İsmail ÖÇSOY, İsmail YILMAZ M/SiO2 (M= Co, Fe, Ru) Type Materials: Synthesis and Catalytic Activities for Hydrogenation of Ketones Nilgun KALAYCIOGLU OZPOZAN, Serkan DAYAN, Sevgi OZTURK Synthesis and Some Reactions of 4-(4-methylbenzoyl)-3-(4-methylphenyl)-1-pyridin-2yl-1H-pyrazole-5-carboxylic Acid Elif KORKUSUZ, İsmail YILDIRIM Synthesis of Ruthenium(0) Stabilized by N-Donor Ligand: Using as Dye In the DyeSensitized Solar Cell (DSSC) Serkan DAYAN, Nilgun KALAYCIOGLU OZPOZAN Magnetic Phosphorus-Containing Polymer for Fast and Selective Solid Phase Extraction of Trace Amounts of Cd(II) and Pb(II) E. YILMAZ, R. M. ALOSMANOV, M. SOYLAK

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Dispersive Liquid-Liquid Micro Extraction of Lead(II) for Preconcentration and xi



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Separation in Environmental Samples Mustafa SOYLAK, M. Karaca A DFT (Density Fuctional Theory) On Sabinene and Isoabienol (the Essential Oils of Juniperus Communis) Faik GÖKALP A DFT Study of Bromoquinolines. Comparison of Experimantal and Theoretical Bioactivities of Bromoquinolines Salih ÖKTEN, Faik GÖKALP The Structural, Elastic and Electronik Properties of Pd2VAl Compound in Heusler Structure Osman ÖRNEK, S. DEMİR, Nihat ARIKAN The First-Principles Study on LuSe Compound in CsCl Structure Nihat ARIKAN, Osman ÖRNEK, Şule UĞUR, Gökay UĞUR Synthesis and in Vitro Antioxidant Properties of New 1-acetyl-3,4-disubstitue-4,5dihydro-1H-1,2,4-triazol-5-ones Özlem GÜRSOY KOL, Haydar YÜKSEK Preparation, Characterization and Antimicrobial Activities of Some New Di-[2-(3alkyl/aryl-4,5-dihydro-1H-1,2,4-Triazol-5-One-4-Yl)-azomethin-6-ethoxyphenyl] isophtalate Derivatives Haydar YÜKSEK, Faruk KARDAŞ, Önder ALBAYRAK, Muzaffer ALKAN,Fevzi AYTEMİZ Synthesis, Spectroscopic and Fluorescence Properties of N,N'-diethylnicotinamide Adducts of 2-bromobenzoates Co(II) and Ni(II) F. Elif ÖZBEK, Mustafa YÜKSEK, Hacali NECEFOĞLU A Review on Crystal Structures of N,N'-diethylnicotinamide Complexes of Metal Arylcarboxylates Hacali NECEFOĞLU, F. Elif ÖZBEK,Mustafa SERTÇELIK The Effect of Boron Compounds on the Levels of L- Carnitine, Leptin, IGF-I and HSP70 in Rat Fed with High-Fat Diet Onur ATAKİŞİ,Kezban YILDIZ DALGINLI,Emine ATAKİŞİ, Ruya KAYA, Canan GÜLMEZ Determination of pKa Values of Some 3-Alkyl(Aryl)-4-[3-(2-Methylbenzoxy)Benzylidenamino]-4,5-Dihydro-1h-1,2,4-Triazol-5-Ones in Non-Aqueus Solvents Songül ULUFER, Özlem GÜRSOY KOL Synthesis and Antimicrobial Properties of Some Novel 3-alkyl(aryl)-4-[3-(3nitrobenzoxy)-4-methoxybenzylidenamino]-4,5-dihydro-1H-1,2,4-triazol-5-ones Fevzi AYTEMİZ, Haydar YÜKSEK, Önder ALBAYRAK, Muzaffer ALKAN Antioxidant Activities of Some 3-Alkyl(Aryl)-4-(3-Cinnamoyloxy-4Methoxybenzylidenamino)-4,5-Dihydro-1H-1,2,4-Triazol-5-Ones with Their Acidic Properties Feyzi Sinan TOKALI, Haydar YÜKSEK, Fevzi AYTEMIZ Spectroscopic Properties of 3-Methyl-4-(4-isopropylbenzylidenamino)-4,5-dihydro-1H1,2,4-Triazol-5-one molecule Gül KOTAN, Haydar YÜKSEK

Synthesis and Investigation of Antioxidant Activities of Novel 3-Alkyl(Aryl)-4-[2-(3xii





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methoxybenzoxy)-benzylidenamino-4,5-dihydro-1H-1,2,4-triazol-5-ones Hilal MEDETALİBEYOĞLU, Haydar YÜKSEK, Özlem GÜRSOY KOL A Study on Theoretical and Experimentical Spectroscopic Properties of 3-N-propyl-4-[3(3,5-dinitrobenzoxy)-benzylidenamino-4,5-dihydro-1H-1,2,4-triazol-5-one Molecule Savaş KARA, Özlem GÜRSOY KOL, Haydar YÜKSEK, Hilal MEDETALİBEYOĞLU Synthesis, Characterization and Antioxidant Activities of {Bis-4-[3-(Alkyl(Aril)-4,5dihydro-1H-1,2,4-Triazol-5-On-4-yl)-azomethin]phenyl} biphenyl-4,4’disulfonates Murat BEYTUR, Haydar YÜKSEK,Özlem GÜRSOY-KOL Synthesis and Antioxidant Activities of N-acetyl Derivatives Having 4,5-dihydro-1H1,2,4-triazol-5-one Ring Muzaffer POLAT, Haydar YÜKSEK,Murat BEYTUR, Özlem GÜRSOY-KOL, Zeynep ZAFER, Savaş KARA Synthesis and in-Vitro Antioxidant Evaluation of New 1-Acetyl-3-alkyl(aryl)-4-(3methoxy-4-acetoxybenzylidenamino-4,5-dihydro-1H-1,2,4-triazol-5-ones Sevda MANAP, Haydar YÜKSEK, Özlem GÜRSOY-KOL Synthesis and Acidic Properties of Some Novel 3-Alkyl(aryl)-4-[3-ethoxy-4-(2methylbenzoxy)-benzylidenamino]-4,5-dihydro-1H-1,2,4-triazol-5-ones Bahar BANKOĞLU, Haydar YÜKSEK,Sevda MANAP GIAO NMR Calculations of 3-Ethyl-4-(3-benzensulfonyloxy-4methoxybenzylidenamino)-4,5-dihydro-1H-1,2,4-triazol-5-one Özlem AKTAŞ YOKUŞ, Haydar YÜKSEK, Gül KOTAN Prophylactic Effect of Beta Carotene on the Diethylnitrosamine-Induced Oxidative Stress in Rabbit Onur ATAKİŞİ, Oğuz MERHAN, Emine ATAKİŞİ, Ayla ÖZCAN, Necati KAYA, Cem ÖZİÇ The Effect of Goji Berry Extract on Liver Enzyme Activity and Antioxidant System in Carbon Tetrachloride Toxicity Ayşe KANICI, Onur ATAKİŞİ, Nurgül ATMACA, Füsun TEMAMOĞULLARI, Yeşim AYDIN, Yonca YILMAZ Synthesis and Non-Aqueus Medium Titrations of Some Novel 3-Alkyl(aryl)-4-[2-(2furylcarbonyloxy)-3-methoxybenzylidenamino)]-4,5-dihydro-1H-1,2,4-triazol-5-ones Muzaffer Alkan, Haydar Yüksek, Abdurrahman Gürbüz Effect of Substrate Temperature on The Functional Properties of Vanadium Oxide Thin Films Grown by Spray Pyrolysis Method Mustafa SAĞLAM, Betül GÜZELDİR Chemical Effect on the Atomic and Molecular Cross Sections of Some Ce Compounds Near the K Edge Rıdvan DURAK, Ferdi AKMAN Magnetically Separable Graphene Oxide-Fe3O4 Nanocomposites for Photocatalytic Degradation of Methylene Blue Under UV Irradiation Tuba Ezgi TÜZEMEN, Kübra BİLMİŞOĞLU, Ayşe Merve ASLANDAŞ, Murat KIRANŞAN, Kadem MERAL A Facile Synthesis of Fluorescent Carbon Dots from Blueberry and Their Performance in Fe3+ Detection Ayşe Merve ASLANDAŞ, Neslihan BALCI, Mustafa ARIK, Halis ŞAKIROĞLU, Yavuz ONGANER, Kadem MERAL Effects of Metal Ions on Binding Constants of Coumarine 35 To BSA and DNA xiii





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Tuğba BAYRAKTUTAN, Yavuz ONGANER The Effect of Organized Surfactant Media on Energy Transfer between Coumarin 120 and Safranine T Molecules Ebru BOZKURT, Kadem MERAL, Yavuz ONGANER

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Interactions between Fluorescein and Safranine T in PC Liposomes Ebru BOZKURT, Tuğba BAYRAKTUTAN, Murat ACAR, Mahmut TOPRAK Synthesis of Halo- and Aminocyclitols Containing Eight-Membered Ring Emine SALAMCI, Ufuk Nusret KARAVAİZOĞLU, Yunus ZOZİK Fabrication and Neutron Dose Rate Measurements of a Ni Based New Super Alloy İncluding W, Cr, and Cu Abdulhalik KARABULUT, Turgay KORKUT, Bünyamin AYGÜN Synthesis of 5-(5-Oxo-pyrrolidin-2-yloxymethyl)-furan-2-carbaldehyde Derivatives Nurhan KİSHALI, Özlem GÜNDOĞDU, Pınar AYDIN, Yunus KARA Synthesis of New Norbornanoid Chiral Compounds via Desymmetrızation of 1, 2-vinyl dibromides Ramazan KOÇAK, Arif DAŞTAN, Giuseppe BORSATO, Ottorino De LUCCHİ An Efficient Synthesis of Substituted Naphthalenes and Anthracenes Esra TURAN AKIN, Musa ERDOĞAN, Ramazan KOÇAK, Nurullah SARAÇOĞLU, Arif DAŞTAN A Regioselective Approach for Functionalization of Indolines/Indoles at the 5-Position Haydar KILIÇ, Berrak ERTUĞRUL, Farrokh LAFZI, Nurullah SARAÇOGLU Purification and Characterization of Glutathione S-Transferase fromLaurel Fruit (Prunus Laurucerasus L.) Research the Effects of Some Metal Ions on Enzyme Activity Fikret TÜRKAN, Neslihan BALCI, Halis ŞAKİROĞLU Molecular Dynamics Studies of the Carboxy Indanone and Tetraline Compounds by NMR Spectroscopy Cavit KAZAZ, Süleyman GÖKSU, Adem ERTÜRK, Barış ANIL,Akın AKINCIOĞLU Effect of Cu and Al Additive on the Functional Properties of Vanadium Oxide Thin Films Grown by Spray Pyrolysis Method Betül GÜZELDİR, Mustafa SAĞLAM Interpretation of the Laterally Inhomogeneous Fecrnic/N-Gaas Contacts by Tung’s Approach Bahattin ABAY Ascorbic Acid (Vitamin C): Important for Human Nutrition Physiology and Health, an Antioxidative & Anticarcinogenic Vitamin Bilgehan POLATOĞLU Investigation of The Inhibition Effect of Kiwifruit (Actinidia Deliciosa) Juice on Human Carbonic Anhydrase-II Metin BÜLBÜL, Gözde İMDAT Synthesis and Characterization of Novel Pyrazole, Thiazole, Thiadiazole and Oxadiazole Derivatives of 1-(3-nitrophenyl)-3-phenyl-1H-pyrazole-4-carbaldehyde Samet MERT, Rahmi KASIMOGULLARI

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Fish (Capoeta Antalyensis) Using Gas Chromatography and Atomic Absorption Spectroscopy Kazım UYSAL, Banu YALIM, Yılmaz EMRE, Özgür AKTAŞ, Gül Nihan ÖZTÜRK Synthesis and Characterization of ZnO Nanostructures via Tartaric Acid Gel Method Mustafa TUNCER Seher ÇETİN, Hasan GÖÇMEZ Purification and Characterization of Glutathione S-Transferase from Laurel Fruit (Prunus Laurucerasus L.) Research the Effects Some Metal Ions on Enzyme Activity Fikret TÜRKAN, Neslihan BALCI, Halis ŞAKİROĞLU Synthesis of Some Benzamide Derivatives and Investigation of Their Crystal Structures Şükriye ÇAKMAK, Halil KÜTÜK, Mustafa ODABAŞOĞLU Synthesis of Some Pyrimidine Derivatives and Investigation of Their Molecular Structures and Spectroscopic Properties Şükriye ÇAKMAK, Halil KÜTÜK, Mustafa ODABAŞOĞLU Solid Phase Extraction of Tartrazine and Determination by UV-VIS Spectrophotometer Aslıhan KARATEPE, Nazan SAYAR Design, Synthesis and Anticancer Activity of Novel Acylthioureas with Pyrimidine Core İrfan KOCA, Muhammet ER, Mehmet GÜMÜŞ, Aykut ÖZGÜR, Yusuf TUTAR Efficient Synthesis of Potential Biactive Molecules: Pyrazole, Thiazole and Coumarine Hybrid Compounds Mehmet GÜMÜŞ, İrfan KOCA, Ali DİŞLİ Synthesis, Characterization and Adsorption Studies of Cationic Dye Adsorbent Masoomeh MEHRNIA, Oya BAL, Murat TORUN, Dilek ŞOLPAN Optimum Conditions for Chromatographic Seperation of N-Nitrosodiphenylamine from Its Intermediate Sinem DEMIR, Murat TORUN, Dilek ŞOLPAN Synthesis and Antimicrobial Evaluation of New 3-Alkyl(aryl)-4-[3-ethoxy-2-(4methoxybenzoxy)-benzylidenamino]-4,5-dihidro-1H-1,2,4-triazol-5-ones Faruk KARDA, Haydar YÜKSEK, Özlem GÜRSOY-KOL, Önder ALBAYRAK, Muzaffer ALKAN Contents and Distributions of Iron Fractions in Bafra, Çarşamba and Suluova Soils and Relationships with Some Soil Properties Havva Sera ŞENDEMİRCİ,Güney AKINOĞLUAhmet KORKMAZ, Ayhan HORUZ, Abdulkadir SÜRÜCÜ Synthesis of Bromo Substituted Indenoquinoline-Amin Derivetives Makbule EKİZ, Ahmet TUTAR, Yadigar ADİLOĞLU Improved Synthesis and Naked –Eye Ag+ Chemosensing Properties of 2,9- Dichloro1,10-phenonthroline Said NADEEM, Mehmet Ali ÖZLER, Muhammad Raza SHAH Antioxidant and Cytotoxic Activity of Ganoderma Resinaceum Boud. Mehmet Emin DURU, Selçuk KÜÇÜKAYDIN, Aziz TÜRKOĞLU, Gülsen TEL, Mehmet ÖZTÜRK Fumigant Toxicity of Essential Oil of Coridathymus Capitatus Against Adults of The Lesser Grain Borer, Rhizopertha Dominica (Coleoptera: Bostrichidae) Fabricius. Selçuk KÜÇÜKAYDIN, Mehmet Emin DURU, Memiş KESDEK, Gülsen TEL, Mehmet ÖZTÜRK. Anticancer and Antioxidant Activity of Porodaedalea Pini (Brot.) Murrill xv





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Ebru DEVECİ, Gülsen TEL ÇAYAN, Mehmet ÖZTÜRK, Selçuk KÜÇÜKAYDIN, Mehmet Emin DURU The Chemical Composition of Essential Oil and Anticholinesterase Inhibition Activity of Various Extracts of Thymus Cilicicus Boiss. & Bal. Selçuk KÜÇÜKAYDIN, Mehmet Emin DURU, Erhan KAPLANER Gülsen TEL, Meltem TAŞ, Gülay ŞAVKINCI Acetazolamide Derivative Novel Acridindione Compounds as Carbonic Anhydrase Inhibitors Ramazan ULUS, Burak ADAY, Muharrem KAYA Efficient Synthesis of Tetrazole Derivatives Catalyzed by Recyclable Platinum Nanoparticles as Heterogeneous Catalyst under the Microwave Irradiation EsmaERKEN, İbrahim ESİRDEN,MuharremKAYA,FatihŞEN Synthesis of 5-Amino-1,3,4-Thiadiazole-2-sulfonamide Based Novel Acridindione Compounds Burak ADAY, Ramazan ULUS, Muharrem KAYA Highly Dispersed Platinum Nanoparticles Supported with Graphene Oxide for the OnePot Synthesis of Acridinedione Derivatives Burak ADAY, Handan PAMUK, Fatih ŞEN, Muharrem KAYA One-Pot, Facile, Highly Efficient, and Clean Synthesis of Acridinedione Derivatives Using Vitamin B1 as a Catalyst Burak ADAY, Ramazan ULUS, Ahmet IŞIK, Muharrem KAYA Synthesis of Thioxanthone Based Water Soluble Copolymeric Macrophotoinitiator and Its Use in Photoinduced Free Radical Polymerization Meral AYDIN, Nüket ÖCAL, Nergis ARSU Ultrasound-Promoted Synthesis of Tetrahydropyridine Derivatives in Presence of M(OTf)X Zühal TURGUT, Emel PELIT, Oğuz Rıdvan DÜRÜST Three- Component, One-Pot Synthesis Of Indeno[1,2-B]quinoline-7-one Derivatives Catalyzed by Triflat Zühal TURGUT, Özlem ELMAS, Kadir TURHAN Biological Activities of Flowers and Peel Oils of Citrus Aurantium L. Growing in Turkey Seda Güreli FERIDUN, Selçuk ALTUN, Ayşe OGAN, Ümit SALAN Investigation of Mechanical Properties of Nonwoven Felt- Polypropylene-Pumice Composite Materials Yalçın BOZTOPRAK, Sabih OVALI, Mahmut KAYAR, Yeşim Müge ŞAHİN Synthesis and Characterization of Novel Metallophthalocyanines Esra KAKI, Nurcan GÖGSU, Bekir SALİH, Özer BEKAROĞLU Investigation of Sound Permeability of Nonwoven Felt- Polypropylene-Pumice Composite Materials Yalçın BOZTOPRAK, Sabih OVALI, Mahmut KAYAR, Yeşim Müge ŞAHİN UV Curable Polyurethane Coating Materials Based Siloxane and Investigation of Their Thermal Properties Mert ÇINAR,Sevim KARATAŞ Synthesis and Characterization of UV Curable Waterborne Polyurethanes Tülin GACAL, Gökhan TOPÇU, Sevim KARATAŞ Synthesis and Characterization of Novel Pyridone Derivative Phthalocyanines xvi





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Şaziye ABDURRAHMANOĞLU, Büşra MIZRAK Synthesis and Characterization of Novel A Structure Co(II) Phthalocyanine Şaziye ABDURRAHMANOĞLU, Büşra MIZRAK Determination of Trace Metals on Some Mushroom Species by ICP-OES After Microwave Digestion Method Muhammet Emre HIŞIR, Esra ALTINTIĞ, Hüseyin ALTUNDAĞ Characterization of Nano Silver Particles Which Are Bonded With Sol- Gel Method to Activated Carbon Esra ALTINTIĞ, Omer Faruk SOYDAN, Sule KIRKIL, Huseyin ALTUNDAĞ Department of Chemistry, Faculty of Art and Science,Sakarya University, TR-54187, Sakarya, Turkey Derivative Spectrophotometric Determination of Ascorbic Acid and N-Acetylcysteine Merve AYHAN, Aysel KÜÇÜK TUNCA Total Phenolics, Total Flavonoids and Cupric Ion Reducing Antioxidant Capacity of Broad-Leaf Dock (Rumex Obtusifolius) Plant Esma Hande ALICI, Gülnur ARABACI Enzymatic Bio-Bleaching of Cotton/PA Fabric Ayşe USLUOĞLU, Gülnur ARABACI Anionic Dye Removal Using Polymer Inclusion Membrane (PIMs) Özlem DEMİRBAŞ, Havva POLAT, Yasemin YILDIZ, Murat TEKER,Aynur MANZAK Application of Polymer Inclusion Membranes (PIMs) Including Aliquate 336 for The Extraction of Humic Acid Cem KURŞUN,Yasemin YILDIZ,Aynur MANZAK,Abdil ÖZDEMİR,Ahmet TUTAR Speciation of Heavy Metals in Food Samples by Ultrasonic Supported Sequential Extraction Method and Microwave Leaching in Using ICP-OES Hüseyin ALTUNDAĞ, Muhammet YıLMAZ, Asude ATEŞ Synthesis, Characterization, Photophysical and Electrochemical Properties of 4,4-Fluoro8-ethyl-3,5-Bis(4'-ethylphenyl)-4-bora-3a,4a-diaza-s-indancene (BODIPY) Raşit Fikret YILMAZ, İbrahim Halil BAYDİLEK, Ömer Faruk TUTAR, Yavuz DERİN, Ahmet TUTAR Synthesis, Characterization, Photophysical and Electrochemical Properties of 4,4-Fluoro8-(4'-bromophenyl-3,5-Bis(4'-trifluoromethoxyphenyl)-4-bora-3a,4a-diaza-s-indancene (BODIPY) Raşit Fikret YILMAZ, İbrahim Halil BAYDİLEK, Ömer Faruk TUTAR, Salih ÖKTEN, Ahmet TUTAR A Facile and Efficient Synthesis of 5-Bromo-2,2-Dihydroxy-1,3-indandione (5bromoninhydrin) from indane Raşit Fikret YILMAZ, İbrahim Halil BAYDİLEK, Ömer Faruk TUTAR, Ahmet TUTAR Synthesis and Antimicrobial Activities of New Conazole and Fluoroquinolones Neslihan DEMİRBAŞ, Serap BAŞOĞLU, Yıldız UYGUN, Arif MERMER, Ahmet DEMIRBAŞ, Serpil DEMİRCİ, Şule CEYLAN Synthesise of Isoxazole and Dehydroisoxazole from Chalcones Nurettin YAYLI, Seda FANDAKLI, and Büşra YAYLI Synthesis and Antimicrobial Activity of Triazole Containing Azole Derivates xvii





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Arif MERMER, Yıldız UYGUN, Serpil DEMİRCİ, Serap BAŞOĞLU, Ahmet DEMİRBAŞ, Neslihan DEMİRBAŞ, Serdar ÜLKER Synthesis and Characterization of New Triazole-Substituted Coumarin Derivatives Nurhan GÜMRÜKÇÜOĞLU Synthesis and Characterization of Novel Heterocyclic Compounds by Reacting Bis Coumarins and Triazole Derivatives Nurhan GÜMRÜKÇÜOĞLU Synthesis of New Triazol Derivatives Containing Several Pharmacophore Groups and Investigation of Their Antimicrobial Activities Ahmet DEMİRBAŞ, Yıldız UYGUN, Serap BAŞOĞLU, Arif MERMER, Hacer BAYRAK, Şule CEYLAN, Neslihan DEMİRBAŞ Synthesis and Characterization of Some New Conazole Derived from Ethylpiperazine Nucleus Serap BAŞOĞLU, Yıldız UYGUN, Hacer BAYRAK, Neslihan DEMİRBAŞ, Arif MERMER, Ahmet DEMIRBAŞ, Şule CEYLAN Synthesis and Antimicrobial Activity Evaluation of New Fluoroquinolone Derivatives Starting from Triptamine Yıldız UYGUN, Serap BAŞOĞLU, Arif MERMER, Hacer BAYRAK, Sule CEYLAN, Ahmet DEMİRBAŞ, Neslian DEMİRBAŞ, Serdar ÜLKER Synthesis and Antimicrobial Activities of Novel Conazoles with Triazol Ring Arif MERMER,Yıldız UYGUN, Serpil DEMİRCİ, Serap BASOGLU, Neslihan DEMİRBAŞ, Serdar ÜLKER Supercapacitor Device Preparation and Equivalent Circuit Model Evaluation of Poly(3,6bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-tosyl-9H-carbazole)/Carbon Nanotube as an Active Material Nesimi ULUDAĞ, Murat ATEŞ Concise Total Synthesis of 20-diethyl-4-dimethyldasycarpidone Nesimi ULUDAĞ, Medet YAKUP Supercapacitor Study of Poly(2-(3,6-bis(-(2,3-dihydrothieno[3,4-B][1,4]dioxin-5-yl)-9hcarbazole-9-yl)ethyl methacrylate)/CarbonNanotube Composite Material Murat ATES,Nesimi ULUDAĞ Synthesis of Mid-Chain Functional Macrophotoinitiators of Poly(D,L-Lactide)-Based Polymers by Rop and Their Use in Photoinitiated Polymerization Mustafa DEĞİRMENCİ,Mustafa DURGUN, Esra BARIM Synthesis, Characterization, Catalytic and Cytotoxic Activities of A Novel Pyridyloxycyclophosphazene Ligand and Its Ru(II) Complex Zafer UYAR, Diğdem ERDENER ÇIRALI, İsmail KOYUNCU Investigation of Properties of Water Soluble 1-[2-(dimethylamino)ethyl]-1H-Tetrazole Substituted Metal-Free and Zinc(II) Monophthalocyanines Ebru YABAŞ, Esra BAĞDA Synthesis and Spectral Charaterization of 4-Nitro-2-(5-chloro/methy-1,3-benzoxazol-2yl)phenols Demet GÜRBÜZ, Adem ÇINARLI, Aydın TAVMAN, Süleyman TANYOLAÇ Synthesis and Spectral Characterization of 1,3-Bis(1H-benzimidazol-2-yl)-2-oxapropane Complexes with Various Zn(II) Salts Aydın TAVMAN, Adem ÇINARLI



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PO-115

The Synthesis and Characterization of Some New S-, S,S- and N,S-Substituted xviii



245

PO-116 PO-117 PO-118 PO-119 PO-120 PO-121 PO-122 PO-123 PO-124 PO-125 PO-126 PO-127 PO-128

Nitrobutadienes F. Serpil GÖKSEL, Elif AYDIN Synthesis of New N-, Substituted 1,4-Benzoquinone Compounds and Their Thio Substituted Derivatives Hakan BAHAR, Sibel ŞAHİNLER AYLA, Funda ÖZKÖK, Cemil İBİŞ Synthesis and Spectroscopic Characterization of Novel N- and N,S-Substituted Naphthoquinone Compounds Sibel ŞAHİNLER AYLA, Hakan BAHAR, Cemil İBİŞ Synthesis and Spectral Characterization of 5-Chloro-2-(5-chloro/methyl-1,3-benzoxazol2-yl)phenols Demet GÜRBÜZ, Adem ÇINARLI, Aydın TAVMAN Determination of Phenolic Acids in Concentrated and Non-Concentrated Apple Juice Made from Denizli by High-Performance Liquid Chromatography DAD Mürüvvet KARAKAPLAN , Mustafa ÖZCAN Hydrogen Generation from Sodium Borohydride Hydrolysis Using Co-B Catalyst on Supported Sepiolite Seda EROL, Mine ÖZDEMİR Adsorption Thermodynamic Parameters of SBA15 and B-SBA-15 Mesoporous Materials by Using Inverse Gas Chromatography Technique Alime ÇITAK, Tuğba CANDAŞ The Synthesis and Characterization of New Oxime Ligands and Their Complexes with Cu(II) Metals Tufan TOPAL, Emin KARAPINAR Characterization of Natural Organic Matter (NOM) by Resin Adsoprtion Method in Drinking Waters Tufan TOPAL, Nazan KARAPINAR, Vedat UYAK Antioxidant Properties of Novel Mixed Ligand Complexes Obtained from Saccharinato Complexes and Azo Dye Ligand (mnppa) Nevin TURAN, Ragıp ADIGÜZEL, Kenan BULDURUN, Ercan BURSAL Synthesis and Catalytic Activity Studies of Ru Complexes Bearing 2-(1H-benzimidazol2-yl)quinoline Derivatives Melek TERCAN, Osman DAYAN, Namık ÖZDEMIR Separation, Optimization and Quantitative Determination of Fruit Acids by New MixedModel Column in HPLC Uyan YÜKSEL, Hayriye ARAL, K.Serdar ÇELİK Quantitative Determination of Phenolic Compounds in Mushroom by New Mixed-Model Column in HPLC K.Serdar ÇELİK, Hayriye ARAL, Uyan YÜKSEL Chemical Compositions of Fatty Acid Obtained from Seeds of Silybum Marianum L. Gaertn (Thistle) by Using Cold Press Eyyüp KARAOĞUL, M. Hakkı ALMA, Ömer ÇİÇEK, Ertuğrul ALTUNTAŞ

246 247 248 249 250 251 252 253 254 255 256 257 258

PO-129

Synthesis and Characterization of Methyl Cellulose Obtained from Cotton Waste: Application in Cement Paste Ali KOÇ, Sümeyye AKARSU, C. Ayhan ZIBA, Mustafa DOLAZ

259

PO-130

Anti-Microbial Activity of Volatile Oils Extracted from Citrus Aurantifolia L. on Several

260

xix



PO-131 PO-132 PO-133 PO-134 PO-135 PO-136 PO-137

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Microorganisms Muharam Yaseen MOHAMMED, Tufan SALAN, Eyyüp KARAOĞUL, M. Hakkı ALMA Determination of Cobalt with Cloud Point Extraction Ümit DİVRİKLİ, Mustafa SOYLAK, Latif ELÇİ Synthesis and Characterization of Imine Polymers Containing Methyl Silane Group İsmet KAYA, Neşe ÇITAKOĞLU Study of Thermal Degradation Kinetic of 7-Amino-4-Hydroxynaphthalene-2-Sulfonic Acid Fatih DOĞAN, Kevser TEMİZKAN, İsmet KAYA Chemical Characterization of Humic Substances Added Wood Plastic Composites Nasir NARLIOGLU, Eyyup KARAOĞUL, M. Hakki ALMA GC/MS Analysis of Essentıal Oil of Salvia Frutıcosa M. and Sideritis Perfoliata L. Ertuğrul ALTUNTAŞ, Eyyüp KARAOĞUL, BETÜL ÇELİK, M. Hakkı ALMA Synthesis of Oil-Based Graft Copolymers via the Combination of Ring Opening Polymerization and Free Radical Polymerization Abdulkadir ALLI, Yurdagül ARI, Sema ALLI, Muharrem GÖKÇEN The Effects of Transplant Age on Element Content Determined by WavelengthDispersive X-Ray Fluorescence Spectrometry of Broccoli (Brassica Oleracea L. Var. İtalica) Cultivars Faika YARALI, HalukÇağlar KAYMAK, İsmail GÜVENÇ, Ali GÜROL Synthesis and Characterization of Pyrimidine-Containing Schiff Base Derived from OVanillin and Its Metal Complexes Mehmet Emin HACIYUSUFOĞLU, Mehmet SÖNMEZ, Benan KILBAŞ, Zülbiye ÖNAL Synthesis of Some Heterofunctionalized Penicillanic Acid, Norfloxacine and Ciprofloxacine Derivatives and Investigation of Their Biological Activities Serpil DEMİRCİ, Meltem YOLAL, Arif MERMER, Neslihan DEMİRBAŞ, Ahmet DEMİRBAŞ A Simple and Sensitive Colorimetric and ‘‘Turn-On’’ Fluorometric Sensor for Arsenic Species in Aqueous Media EsraŞEN, SerdarATILGAN AIE Active Tetraphenylethene: Rapid and Selective Fluorescent “Turn-On” Sensor for Fluoride Ion in Aqueous Media Mine BİNECİ, SerdarATILGAN Synthesis of 2-(2-Chlorophenyl/ 3,4-dichlorophenyl)-5-methyl-1,3-benzoxazole Compounds Adem ÇINARLI, Duygu ÖZATA, Demet GÜRBÜZ Metal Oxide Nanoparticles: An Effective Heterogenous, Recyclable Catalyst for Synthesis of Thio Schiff Bases Aslıhan DALMAZ,Mesut ÖZDİNÇER, Elif AYDINLI, Sefa DURMUŞ Comparative Studies on Conventional & Microwave Synthesis of 2-Aryl Benzothiazoles and Their Antibacterial Activities Aslıhan DALMAZ,Mesut ÖZDİNÇER, Elif AYDINLI, Sefa DURMUŞ Synthesis and Characterization of Pyrimidine-Containing Schiff Base Derived from OVanillin and Its Metal Complexes Mehmet Emin HACIYUSUFOGLU, Mehmet SÖNMEZ, Benan KILBAŞ, Zülbiye ÖNAL xx





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PO-146

PO-147 PO-148 PO-149 PO-150 PO-151 PO-152 PO-153 PO-154

PO-155 PO-156

PO-157 PO-158 PO-159 PO-160 PO-161 PO-162

Synthesis, Characterizational Electrochemical Study A New Heterocyclic Schiff Base and Its Metal Complexes [Co(II), Ni(II), Cu(II), Pd(II)] Mehmet Emin HACIYUSUFOGLU, Mehmet SÖNMEZ, Benan KILBAŞ, Abdulkadir LEVENT Preparation of The Micronize Materials for The Water-Based Paint Esvet AKBAŞ, Aziz SÖKMEN Antimicrobial Agents In Textile Industry Aslı DEMİR, Tülay GÜLÜMSER, Esen ÖZDOĞAN Methods Used for The Surface Modification of Textiles EsenÖZDOĞAN, AslıDEMİR, TülayGÜLÜMSER, Reusebility of the Laccase Incorporated Nanofiber Based Biocomposite Generation with and without Cyclodextrin Addition Hasan Basri SAVAŞ, Mehmet Fatih CANBOLAT, Fatih GÜLTEKİN Experimental Application of Kefir and Acetylsalicylic Acid on Antioxidant Activity in Rats BetülMermiCEYHAN, Hasan BasriSAVAŞ, Altuğ ŞENOL, Gürsel ACARTÜRK Electrochemical Synthesis and Electrochromic Application of A Novel Polymer Based on Carbazole Aysel AydınKOCAEREN Effıciency of Wet and Dry Digestion for Determination of Selected Metals from Coal by FAAS Tidža Muhić ŠARACA, Sadber KASAPOVIĆA, Dejana BRKIĆB Synthesis of Nanostructured Metal - Containing Catalysts and Their Use at Refining of Heavy Oil Residues V.M. ABBASOV, H.J. IBRAHIMOV,G.S.MUKHTAROVA, N.Kh.EFENDIYAVA, R.I.HUSEYNOVA Ionic Liquids on The Basis of Formic Acid and Amines For Selective Purification of Naphthalane Oil V.M. ABBASOV, L.I. ALIYEVA, P.A. MOVSUMOVA, A.E. ALIZADE Investigation of Liquid-Phase Oxidation of Naphthene-Paraffinic Hydrocarbons of Azerbaijan Oils V.M. ABBASOV, L.M. AFANDIYEVA, L.I. ALIYEVA, L.H. NURIYEV, Ch.Q. SALMANOVA, S. F. AHMADBAYOVA, F.N. SEYIDAHMADOVA Investigation of Inhibitory Properties of Salts and Complexes of N- Diethylamine Amides of Oleic Acid of CO2-corrosion V.M. ABBASOV, N.Sh., RZAYEVA S.A. SULEYMANOVA, A.H. TALYBOV Effect Pigments in Multicoatings on Textiles Boris MAHLTIG, Linfei WU,Jieyang ZHANG, Hajo HAASE Demonstration in Teaching Chemistry: the Case of Two High-Schools from Sarajevo Canton Meliha Zejnilagić-HAJRIĆ, Ines NUIĆ Synthesis and Properties of Oligomers of 4-Aminophenol Rena AHMEDOVA, Dilbar ALIYEVA, Bakhtiyar MAMMADOV

276

New Ecologically Water-Diluting Epoxide Telomers Almaz CHALABIYEVA, Nelli ISHENKO Local Catalysts: Synthesis and Application N.Ben TAHAR , H.MIMOUN

291

xxi

277 278 279 280 281 282 283 284

285 286

287 288 289 290

292



PO-163

PO-164 PO-165

PO-166

PO-167 PO-168 PO-169

PO-170

PO-171 PO-172 PO-173 PO-174 PO-175

PO-176

An Efficient Synthesis, Characterization and Anti-Inflammatory of Functionalized Triazoles and Tetrazoles via 1, 3-Dipolar Cycloaddition of 2-Azido-1-(8hydroxyquinolin-5-yl)ethanone Shawkat ABD-ELMOHSEN Improvement of Operational Properties of Combustive-Lubricating Materials by Using Esters of Vicinal Dicarboxylic Acids Maharram Ali MAMMADYAROV, FatmakhanymKheybarALIYEVA Synthesis A Number of Some New Dihydrazones Compounds by Microwave Method Ebtihal Qahtan ABDULLAH, Abdullah Saleem KHAZAL, Amal Qahtan ABDULLAH Chemistry Department , College of Science , Tikrit University,Iraq Superabsorbent Eco-Friendly Cellulose Based Hydrogel as Controlled-Urea Release Packing System Saber IBRAHİM, Maha SULTAN, Zenat A. NAGİEB, Galal A.M. NAWWAR Packaging department, National Research Centre, Elbehoth Street 33, 12622, Dokki, Cairo, Egypt. New Cycloalkyl-Phenol Based Antioxidant for M-8 Engine Oil Çalışkan Mehmet METE , Mirzayev VAGIF , Bağırzade RANA , Mammadov FAHREDDIN , Rasulov ÇINGIZ ANAS Synthesis and Biological Evaluation of Some Benzimidazoles Derivatives. Lamouri HAMMAL, Saliha MEKSEM, Bellara NEDJAR-KOLLI. Determination of Free Amino Acids in Mushrooms from Bosnia Using TLC and Spectophotometric Method Aida ŠAPČANIN, Mirsada SALIHOVIĆ, Amra ALISPAHIĆ, Alema DEDIĆ, Emina RAMIĆ, Ekrem PEHLIĆ

293

Qualitative and Quantative Determination of Different Pesticides in Playground Soils of Sarajevo

300

Aida ŠAPČANIN, Mirsada Čakal, Mirsada SALIHOVIĆ, Ekrem PEHLIĆ Comparison Study between Crude Alkaloid Extracts from Baobab (Adansonia Digitata) Leaves and Some Anti-Malarıa and Antibiotics Abiona Dupe LYDİA, Olaoye Fatimo OLUBUKOLA, Bakare ADETUTU Bezylidene: Synthesis and Reactivity KhaledMESBAH, SalahRHOUATI, Yulian. M VOLOVENKO, Zoya VOITENKO Synthesis of Macrocyclic Polyether’s Based on Alicyclic Dioximes R.N. BUDAGOVA,S.B. ZEYNALOV, N.A. ABDULLAYEVA Features of Phaseformastion in the Tl5Te3(Tl2Te)-Tl9LnTe6-Tl9BVTe6Systems SamiraIMAMALIYEVA, TuranGASANLY, FuadSADYGOV,MahammadBABANLY Anti Tumoral Activity of Hydrazyl Pyrrolidine 2,5-Dione and 2-Thioxo Imidazolidine 4one S. AichoucheBOUZROURA, L. SALHI, Boudjlida, S. BOUGUERRAAOUICHAT, B. NEDJARKOLLI New Approach Synthetic of 4-Thiazolidinones Scaffold. Evaluation of Antimıcrobial Activity Rosa NECHAK,Samia A. BOUZROURA,Bellara N. KOLLI,YaminaBENMALEK,Lydia SALHI, Sophie P. MARTINI,Vincent xxii



294 295

296

297 298 299

301 302 303 304 305

306



PO-177

PO-178 PO-179

PO-180 PO-181

PO-182 PO-183 PO-184 PO-185 PO-186

PO-187

PO-188 PO-189 PO-190 PO-191

MORIZUR,ElisabetDUNACH Thionation of β -Enaminones with Lawesson's Reagent: Synthesis of Pyranopyrazole Derivatives Houria LAKHDARI, Norah BENNAMANE, Brahim CHERFAOUI, Bellara NEDJAR-KOLLI Synthesis and Biological Evaluation of New imidazo[1,2-a]pyridine Derivatives Saléha BAKHTA, Larbi Arslane HAOUCHINE,Bellara NEDJAR-KOLLI New Synthesis and Reactivity of 3-Acetoacetyl-2H-chromen-2-one, Based Condensed Heterocycles Soumaya Ben MOHAMED, Yahia RACHEDI, Maamar HAMDI, Françoise DUMAS, Synthesis and Antibacterial Activity of Some New Bis-1,3,4-Thiadiazole Derivatives Derived from Adipic Acid Mustafa Yawuz JAMAL Crystallization and Phase Transition of Solid Solutions Based on the AI8BIVX6 (AI-Cu, Ag; BIV-Ge, Sn; X-S, Se)Compounds Yusif YUSIBOV, Isfendiyar ALVERDIYEV, Vusala ABBASOVA,Leyla MASHADIYEVA, Dilgam TAGIYEV, Mahammad BABANLY Phase Equilibria in the Systems Tl-X-I (X-S, Se, Te) and Thermodynamic Properties of Thallium Chalcogenide Iodides Dunya BABANLY, Akif ALIYEV, Dilgam TAGIYEV Contribution of the Chromatographic Step in the Uncertaınty of an HPLC Analytıcal Procedure O. DJELLOULI, E. ROZET, H. BENSAOULA, B. DAHMANI, P. HUBERT Synthesis of Novel α -Aminoacids Bearing 1,2,4-Triazinone and Steroidal Moieties As Enzymatic Affects (Cellobaiase Activity) – Part II Dina Abed BAKHOTMAH Synthesis, Spectroscopic Analysis and Electrochemical Study of a New αAminophosphonic Acid. Saleh CHAFAA, Nadjib CHAFAI, Khalissa BENBOUGUERRA Using The Catalytic System Consisted of Seokar-600 and Its Mixture with Halloysite Nanotube for Thermocatalytic Conversion Heavy Gasoil and Its Mixture with Cotton Oil Tarana MAMMADOVA, Elmira ASGAROVA, Nadira HASANKHANOVA, N.V., NATAVAN, Narmin SAFAROVA New Catalytic Systemwith Halloysite Nanotube for Thermocatalytic Conversion Heavy Gasoil and Its Mixture with Cotton Oil Tarana MAMMADOVA, Elmira ASGAROVA, Nadira HASANKHANOVA, N.V., NATAVAN, Narmin SAFAROVA Processing of Pyrolysis Liquid Products with Using of New Catalytic Complex H.J.IBRAHIMOV, M.I.RUSTAMOV, Z.M.IBRAHIMOVA, K.M.GASIMOVA, R.H.AHMADOVA, I.V.KOLCHIKOVA Oxidative Dehydrogenation of Cyclohexanol to Cyclohexanone Over Modified Zeolite A.M. ALIYEV, M.G. ALIYEVA, Z.A. SHABANOVA, G.A. ALIZADE Studies of the Catalytic Activity of The Modified Zeolite in the Oxidative Dehydrogenation of Methylcyclohexane A.M. ALIEV, Z.A. SHABANOVA, A.I. KARIMOV, U.M. NAJAF-GULIYEV Chromatographic Separation of Enantiomers Acids Using Macrocyclic xxiii





307

308 309

310 311

312 313 314 315 316

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318 319 320 321

PO-192 PO-193 PO-194 PO-195 PO-196 PO-197 PO-198 PO-199 PO-200

PO-201 PO-202 PO-204 PO-205 PO-206 PO-207

PO-208 PO-209

Abderrezak HAMDI, N.BOUCHAIR, M.RIGHEZZA Effective Method for Obtaining Methyl Ethyl Ketone Rena AĞAYEVA, Fuad AĞAYEV, Ağadadaş ALIYEV Metal-Containing Nanocomposites on the Basis of Isotactic Polypropylene Nushaba KURBANOVA, Nahida ALIMIRZOYEVA Synthesis of Self-extinction Polyesters on the Basis of Polybromobicyclic Dicarboxylic Acids Raisa ISMAYILOVA, Aga MUSTAFAYEV, Eldar RAMAZANOV Study of Interactions Mixtures (Biodegradable Polymer / Active Ingredient) Obtained by Different Methods of Preparation Rebiha DAMICHE, Baitiche MILAD Selectivity of CDK1 and CDK2 Inhibitors by Heuristic Approach Aleksandar EFTIMOSKI, Mejra BEKTASEVIC, Elvisa HODZIC, Slavica ERIC, Halid MAKIC Diosgenin Bearing Heterocycles Fused to The A-Ring of The Steroid Nucleus Khaled SHAWAKFEH; Hussein AL-MUGHAID Hydroxyalkyl Derivatives of Diethyldithiocarbamic Acid as a Hardener For Polyethylene-Oligomer Compositions Valeh JAFAROV, Alverdi KERIMOV, Nadir ALEKPEROV, Arzu ORUJOVA Synthesis and Characterization of Perylene Derivatives for Liquid Crystal Display Black Matrix of Low Dielectric Constant Woosung LEE, Sim Bum YUK, Jae Pil KIM Modified Activated Carbon for the Removal of Cadmium(II) and Zinc(II) from Wastewater N. BOUCHENAFA-SAÏB, O.MOHAMMEDI, N. MADANI,B. HAMADA, O. CHERIFI. The Hydrogenation of p-Chloronitrobenzene Over Pd-M/C Catalysts N. BOUCHENAFA-SAIB, O.MOHAMMEDI, N. MADANI, B. HAMADA, O. CHERIFI. Reactivity of Quinoline Derivatives Khaled MESBAH, Salah RHOUATI A Novel Synthesis of 7,8-Dihydrocinnoline-5(6H)-ones by Cyclocondensation of BalisHillman Adducts of Arylglyoxals Bagher EFTEKHARI-SIS, Maryam ZIRAK Application of 5,6-Diphenyl-3-(pyridin-2-yl)-1,2,4-triazine as an Efficient Ligands in PdCatalyzed Heck Reaction Bagher EFTEKHARI-SIS, Maryam ZIRAK BiCl3-Catalyzed Three-Component Synthesis of 10-Aryl-7,8-dihydropyrano[3,2b]chromene-4,9(6H,10H)-diones Maryam ZIRAK Selective Oxidation of Sulfides by a Novel İron(III) Complex Containing a N,O- Type Bidentate Oxazoline Ligand Mojtaba AMINI, Reza Masomi JAHANDIZI Novel Thiazoline -Copper and Palladium Complexes as Efficient Antibacterial Agents Reza Masomi JAHANDIZI,Mojtaba AMINI Preparation and Chracteristics of Hemostatic Nanofibrous Sheets Containing Blood Clotting Agents xxiv





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Eun Jung SIM, Sun Jong KIM, Eun Jin KIM, Insu BAEK, and Oh Hyeong KWON Cr-Substituted Ni-Zn Ferrites via Oxalate Decomposition, Structural, Electrical and Magnetic Properties M.A. GABAL , Y.M. AL ANGARI, F.A. AL-AGEL Nature of Steel Substrate Effect on Intermetallic Compounds of Coatings Obtained by Galvanization Younes BENARIOUA, Didier CHICOT Zn-Cr Co-Substitution Effect on the Structural and Magnetic Properties of Nano-Sized CuFe2O4 Synthesized via Oxalates Decomposition Route Mohamed Abdel Fattah GABAL Application of Multivariate Curve Resolution Alternating Least Squares (MCR-ALS) to The Quantitative Analysis of Food Colorants Using Spectrophotometric Acid-Base Titrations Masoumeh HASANI, Masoud SHARIATI-RAD, Elahe BIDAD Spectroscopic Study of Charge Transfer Complexation between Some Benzimidazole Drugs and Picric Acid Ohoud Hassan AL-MOHAMADY Development and Validation of a Stability˗Indicating RP- HPLC Method for Determination of Sofosbuvir in Bulk and Pharmaceutical Dosage Forms Tamer Awad ALI, Gehad G. MOHAMED, Ali A. AGLAN, Fakiha El-Taib HEAKAL Synthesis of New Stable Verdazyl Radical Ekaterina MARTYNKO, Pavel PETUNIN, Pavel POSTNIKOV, Marina TRUSOVA Synthesis, Radical Copolymerization of (P-vinylphenyl)cyclopropyl- Chlorocinnamate with Styrene and Photosensitivity of the Prepared Copolymers Kazim GULIYEV, Afat ALIYEVA, Dilbar NURULLAYEVA, Abasgulu GULIYEV New Polymer Compositions on The Basis of Mineral Fillers with Appreted Polyolefins Sevil BEKTASHI, Gulnara BABAYEVA, Gulnara MUSAYEVA,Valeh JAFAROV Cationic Polymerization of Vinylcyclopropyl Ethers and Photo-Structurization of the Prepared Polymers Rita SHAHNAZARLI, Abasgulu GULIYEV Numerical Study of Natural Convection Heat Transfer Performance in an Inclined Cavity: Nanofluid and Random Temperature Mohamed SI-AMEUR, Hicham SALHI, Nadjib CHAFAI Experimental, DFT Calculation, Biological Activity and Anion Sensing Applications Studies of a New Schiff Base (E)-4-[(pyridin-3-ylimino)methyl]benzene-1,3-diol Hüseyin ÜNVER, Bahadir BOYACİOGLU, Celal Tuğrul ZEYREK, Devrim YOLAL, Mustafa YILDIZ Reactivity of polybromine-cyclopentadienes and their ability to complexation A.M.Mustafayev, S.S.Kerimova

xxv



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351

ORAL PRESENTATIONS





3



OR-1

Sulphur-containing Antioxidants of Combined Action

Vagif M. FARZALIYEV Institute of Chemistry of Additives of Azerbaijan National Academy of Sciences, Az 1029, Beyukshor Highway, Block 2062, Baku, Azerbaijan [email protected] Abstract: Oxidation stability is one of the most important operational properties of lubricants inasmuch as a great many undesirable phenomena, taking place in engines and mechanisms in the process of their operation, are associated with formation of various oxidation products. Therefore the development of highly effective antioxidants is an actual problem of the chemistry of additives. This report deals with the results of recent researches on the synthesis, study ofthe action mechanisms and also the interrelation between the structure and antioxidant efficiency of sulphur-containing derivatives of phenols (phenolsulphides), amines (aminosulphides) and other sulphur-containing organic compounds. It has been established that the compounds mentioned are the antioxidants of combined action, i.e. they terminate the oxidation chain by reacting with peroxy radicals and decompose hydroperoxides. The unique characteristics of the above antioxidants such as ability of the products of their oxidation by hydroperoxides to catalytically decompose hydroperoxides into the molecular products and cause multiple chain termination in the oxidizing hydrocarbons have been found out. A supposition concerning the structures of oxidation products of some antioxidants, affecting the catalytic decomposition of hydroperoxides, has also been made. The kinetic regularities and quantitative characteristics of the reactions of the above antioxidants with cumyl peroxide radicals and cumyl hydroperoxide, and also interrelation between their structure and activity in the reaction have been established. Thus the studied sulphur-containing compounds are the antioxidants of combined action: terminate oxidation chains reacting with peroxide radicals;being oxidized by hydroperoxides form products which catalytically destruct hydroperoxides into molecular products and actively react with peroxide radicals. In inhibiting the oxidation process of hydrocarbons by the antioxidants containing sulphur atom in combination with phenolic or aniline fragment an internal synergism (autosynergism) leading to new effects is observed.

2



OR-2

New Reactions of Acetylenes: An Unexpected Easy Full Cleavageof Polarized C≡C Moiety under Action of N-Nucleophiles a, b

a

Sergey VASILEVSKY , Maria DAVYDOVA Institute of Chemical Kinetics & Combustion, Novosibirsk, Siberian Branch of Russian Academy of Sciences, Novosibirsk. 630090, Russian Federation, b Novosibirsk State University, 2 Pirogova Str., 630090, Novosibirsk, Russian Federation Abstract: The reaction of arylketoalkynes with 1,2-diaminoethane leads to the full scission of the triple bond with the formation of aryl methyl ketone and imidazoline fragments. Similar transformation occurs by interaction of arylketoalkynes with2-aminoethanoles leading to products of full cleavage of substrate: an aryl methyl ketone and corresponding an amide (N-(1-hydroxy-1-R3-2-R2-eth-2-yl)-N-R1arylamide).In both transformations one of the alkyne carbons undergoes formal reduction with the formation of three C-H bonds, whereas the other carbon undergoes formal oxidation via the formation of three C-N bonds (one π and two σ). Computational analysis confirmed that the key fragmentation step proceeds via a six-membered TS in a concerted manner. Activation barriers, reaction energies, and the transition state geometries for fragmentation reaction were calculated and mechanisms for both reactions are suggested. a

O R

R' R2

OH

NH

NH2

H2N

R3

R1 H2O

O

+ R

N

O

R' NH

OH O

+ R3

R

R'

N R2

R1

Scheme1. Products of full cleavage of reactionsofarylketoalkyneswithN-nucleophiles. In summary, we have described new reactions of acetylenes - a cascade transformation that breaks all three C-C bonds in a polarized alkyne moiety under action of N-nucleophiles This work is supported by grant RFBR No. 10-03-00129-a (2013-2015),grant of the Ministry of Education and Science of the Russian Federation (2014-2016). R, = Ar; R' = Alk, Ar, Het

R1, R2, R3 = H, CH3, Ph

References 1. S. Roy, M.P. Davydova, R. Pal, K. Gilmore, G.A. Tolstikov, S.F. Vasilevsky, I. V. Alabugin,J. Org. Chem., 2011, 76, 7482–7490. 2. S.F. Vasilevsky, M.P.Davydova,D.N. Tomilin, L.N. Sobenina, V.I. Mamatuyk, and N.V. Pleshkova. ARKIVOC,2014, 132-144. 3. S. F. Vasilevsky, M. P.Davydova, I. V. Alabugin, Mend Comm.,2015 (in press).

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Synthesis and Crystal Structure of 4,5,12,13-Tetraaza-dibenzo[b,k]chrysene Famil VALIYEV Department of Corrozion protection, “Oilgasscientificresearchproject”Institute, SOCAR, Baku, Azerbaijan, AZ1012, [email protected] Polycyclic and heterocyclic aromatic hydrocarbons are used for active layer of n- and p-channel organic fieldeffect transistors (OFETs), because they can realize a high mobility. Nevertheless, instability or degradation of organic semiconductors under atmospheric conditions causes severe problems for FET performance. The development of the new materials is particularly important for the progress of this field. In this study we introduce new synthetic methodology of fused aromatic hydrocarbons with nitrogen heterocyclic 4,5,12,13Tetraaza-dibenzo[b,k]chrysene (3), where the nitrogen’s are replaced of carbon atoms to maximize the electronic coupling between semiconducting molecules and to enhance stability, solubility and processability. Scheme 1 shows synthetic route of compound 3. Reaction of commersially available 2-bromonicotinaldehyde with ethylene glicol yielded the 2-bromo-3-(1,3-dioxolan-2-yl)pyridine (1) in 95 % yield. Condensation of 1

5

compound 1 with naphthalene-1,5-diamine in the presence of Pd2(dBu)3 catalyst gave in 76 % yield of N ,N bis(3-(1,3-dioxolan-2-yl)pyridin-2-yl)naphthalene-1,5-diamine(2). By cyclization reaction of 2 in acetic acid during 24 hours was obtained target compound 4,5,12,13-Tetraaza-dibenzo[b,k]chrysene in 95% yield.

Scheme1. Synthetic scheme of 4,5,12,13-Tetraaza-dibenzo[b,k]chrysene. 1 13 Compound 3 characterized by H NMR, C NMR, mass and elemental analysis. Slow sublimation provided yellow single crystals of 3 suitable for X-ray analysis. Molecules of 3 are completely planar and form face-toface π-stacking. Distances between fused rings of π- π interactions are 3.346 Å (Figure 1).

Figure1. Molecule structure and crystal packing of compound 3 Compound 3 as a potential candidate for single crystal field effect transistors and high mobility in OFETs can be obtained because of conjugated molecules have strong interactions with neighboring molecules.

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Organic Synthesis in Glycerol-based Solvents Adi Wolfson and Dorith Tavor Green Processes Center, Chemical Engineering Department, Sami Shamoon College of Engineering, Bialik 56, Beer-Sheva, 84100, Israel, [email protected].

Abstract: In the past two decades a variety of green solvents have been proposed, including water, ionic liquids, fluorous solvents, and supercritical fluids. However, their implementation in industrial processes is still limited due to their tedious and non-sustainable synthesis, lack of experimental data and familiarity, as well as operational restrictions and high cost. Several years ago we presented, for the first time, the use of glycerol-based solvents as alternative sustainable reaction mediums in both catalytic and non-catalytic organic synthesis [1-5]. Glycerol is the main by-product from the conversion of oils and fats in oleochemical production. Moreover, in the past decade, its price has substantially decreased due to an increase in supply from the production and use of fatty acid derivatives in the food, cosmetics, and drugs industries and in biofuel synthesis, i.e., biodiesel. The renewable origin, beneficial physicochemical properties and reusability of glycerol-based solvents, enabled improved product yield and selectivity as well as easy product separation and catalyst recycling. Furthermore, their high boiling point and polarity make them perfect candidates for non-conventional heating and mixing techniques such as ultrasound- and microwave-assisted reactions. Finally, in some reactions, such as catalytic transfer-hydrogenation or transesterification, they can also be used simultaneously as both solvent and reactant [6, 7]. In our ongoing efforts to design a viable protocol that will facilitate the acceptance of glycerol and its derivatives as sustainable solvents, pure glycerol and glycerol triacetate (triacetin) as well as various glycerol-triacetin mixtures were tested as sustainable solvents in several representative organic reactions, such as nucleophilic substitution of benzyl chloride to benzyl acetate, Suzuki-Miyaura cross-coupling of iodobenzene and phenylboronic acid, baker’s yeast reduction of ketones, and transfer hydrogenation of olefins [8]. It was found that reaction performance was affected by the glycerol to triacetin ratio, as the solubility of the substrates in the solvent determined product yield. Thereby, employing optimal glycerol to triacetin ratio resulted in maximum product yield. In addition, using glycerol-based solvents enabled easy and successful separation of the products and recycling of the catalysts.

References 1. A. Wolfson, C. Dlugy, Y. Shotland; Environ. Chem. Lett., 2007, 5, 67-71. 2. 3. 4. 5. 6. 7. 8.

A. Wolfson, C. Dlugy, D. Tavor, J. Blumenfeld, Y. Shotland; Tetrahedron: Asymmetry, 2006,17, 2043-2045. A. Wolfson, C. Dlugy; Chem. Papers, 2007, 61, 228-232. A. Wolfson, A. Snezhko, T. Meyouhas, C. Dlugy, D. Tavor; Green Chem. Lett. and Rev., 2012,5, 7-12. A. Wolfson, C. Dlugy, D. Tavor; Trends. in Org. Chem., 2011, 15, 41-50. A. Wolfson, C. Dlugy, Y. Shotland, D. Tavor; Tetrahedron letters, 2009, 50, 5951-5953. A. Wolfson, E. Azran, C. Dlugy, D. Tavor; Lett. in Org. Chem., 2011, 8, 504-508. A. Wolfson, C. Dlugy, I. Mordechaiev, T. Sliman, D. Tavor; Canadian J. of Chem., 2014, 92, 240-242.

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Photobactericidal and photochromic textile materials realized by embedding of advantageous dye using sol-gel technology a

b

c

Boris Mahltig , Torsten Textor , Perrin Akcakoca Kumbasar University of Applied Sciences, Faculty of Textile and Clothing Technology, Webschulstrasse 31, D-41065 Mönchengladbach, Germany b German Textile Research Center North-West, Adlerstrasse 1, D-47798 Krefeld, Germany c Ege University, Faculty of Engineering, Department of Textile Engineering, Izmir, Turkey Abstract: The presented study reports on the application of the dye Rose Bengal for photobactericidal properties and spirooxazine type photochromic dye for photochromic properties onto textiles by using different sol-gel based coating agents. Photochromic dyes changes rapidly and reversibly from colorless form to colored state when activated by ultraviolet irradiation. Color changing technology offers unique design opportunities to the designer and also has an opportunity to obtain camouflage and UV-protective textiles. The obtained phtochromic textiles were tested by means of UPF (Ultraviolet Protection Factor) and ΔE color difference after UV irradiation. UV irradiation photochromic samples showed over +30 UPF and this effect was developed with concentration of the dye. The prepared photobactericidal textiles were investigated by means of UV/Vis-spectroscopy, scanning electron microscopy and by testing the antimicrobial properties against Bacillus subtilis. The purpose of this treatment was to realize photobactericidal materials which enabled antimicrobial properties in case of illumination with visible light. An antimicrobial effect of the Rose Bengal applied fabrics was observed with and without light exposition, however in case of illumination this effect was significantly stronger indicating a certain photobactericidal effect. This photobactericidal effect strongly depended on the kind of sol-gel coating agent used for embedding of the dyestuff onto the textile. a





Bengal Rose







1,3-Dihydro-1,3,3-trimethylspiro[2H-indole-2,3ʹ- [3H]naphth[2,1-b][1,4]oxazine] Figure 1. Chemical structure of the photoactive dye Bengal Rose and spirooksazine type photochromic dye used for current investigations

References 1. B. Mahltig, D. Knittel, E. Schollmeyer, H. Böttcher; Journal of Sol-Gel Science & Technology. 2004, 31, 293. 2. B. Mahltig, T. Textor; Journal of Sol-Gel Science & Technology. 2006, 39, 111.

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An Investigation on Serum Levels of Cu, Zn, Ca, Mg and P in Goats a

b

c

İlker CAMKERTEN , Güzin CAMKERTEN , Osman KARABULUT , d e Durhasan MUNDAN , Gaye BULUT a Department of Internal Medicine, Fakulty of Veterinary Medicine, TR 68100, Aksaray University, Aksaray, TURKEY b Department of Veterinary Laborants, School of Technical Vocational , Aksaray Üniversitesi, Aksaray TURKEY c Department of Biostatistics, Faculty of Veterinary Medicine, TR 68100, Aksaray University, Aksaray, TURKEY, d Department of Zootecnics , Faculty of Veterinary Medicine, TR 63100, Harran University, Aksaray, TURKEY e Department of Gynecology and Obstetrics, Faculty of Veterinary Medicine, TR 68100, Aksaray University, Aksaray, TURKEY

Abstract The aim of this study is the determination of sera Copper (Cu), Zinc (Zn), Calsium (Ca), Magnesium (Mg) ve Potassium (P) levels which are important for animal health and yield. In this study goats (ntotal=117) which are located in the central (n=20) and district of Şanlıurfa were used as the material. Cu, Zn, Ca, Mg and P levels were measured in the serum obtained from the blood samples by ICP-OES at Harran University Center Research Laboratory. The values were given as mg/kg. Tablo1. Goats mineral levels in the Central and district of Şanlıurfa Cu (mg/L) Zn (mg/L) Ca (mg/L) Mg (mg/L) P (mg/L) Şanlıurfa 0,17±0,01a 0,11±0,01 a 19,33±0,90a 4,50±0,12a 10,43±0,45a Suruç 0,17±0,01a 0,10±0,01ab 19,19±0,75a 4,49±0,20a 10,25±0,49a Hilvan 0,18±0,01a 0,09±0,00b 15,98±0,53bc 4,23±0,11a 8,24±0,52b Siverek 0,15±0,01ab 0,09±0,00b 16,42±0,55b 4,17±0,12a 7,98±0,53b Viranşehir 0,13±0,01b 0,06±0,00c 13,72±0,37c 3,58±0,09b 7,90±0,47b Bozova 0,13±0,01b 0,09±0,01b 15,38±1,31bc 3,08±0,26c 10,04±0,89a P ,000 ,000 ,000 ,000 ,002 1 1 2 2 2 Referance 08-1.2 0.8-1.2 92-116 35-52 10-112 All the resulting values were lower than their reference values. The lowest mineral levels were detected in Viranşehir. In conclusion, goats should be carefully examined in terms of yield losses and diseases connected to lack of minerals. Key Words: Şanlıurfa, Goat, Serum, Cu, Zn, Mg, Ca, P References 1. Peter G.G. Jackson, Peter D. Cockcroft. Clinical Examination of Farm Animals – App3, Copyright © 2002 by Blackwell Science Ltd. (04.06.2015) Retrieved from http://onlinelibrary.wiley.com/doi/10.1002/9780470752425.app3/pdf 2. Arif Altıntaş, Ulvi Reha Fidancı. 1993. Evcil Hayvanlarda ve İnsanda Kanın Biyokimyasal Normal Degerleri. A. Ü. Vet. Fak. Derg. 40 (2): 173-186

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Antioxidant Capacity of Verbascoside Isolated from Teucrium chamaedrys L. subsp. chamaedrys a,b

b

b

b

b

Mahfuz ELMASTAŞ , Beşir İsnaç , Ayşenur TAŞ , Hüseyin AKŞİT , Nusret GENÇ Departmen of Chemistryt, Faculty of Arts and Sciences, Gaziosmanpaşa University.TR 60240 Tokat, Turkey. b Plant Research Laboratory, Faculty of Arts and Sciences, Gaziosmanpaşa University.TR 60240 Tokat, Turkey. a

Abstract: Natural antioxidants are extensively studied for their capacity to protect organisms and cells from damage that induced by oxidative stress, the latter being considered a cause of ageing, degenerative diseases (1-3). In this study antioxidant capacity of verbascoside isolated from Teucrium chamaedrys L. subsp. chamaedrys was evaluated. Teucrium chamaedrys L. sups Chamaedrys was collected from Bursa. Methanol/dichloromethane (1/1) extract showed the highest antioxidant capacity than the other solvent systems (hexane/dichloromethane, ethyl acetate/dichloromethane, (1/1)). Therefore methanol/dicloromethane extract of Teucrium chamaedrys L. sups Chamaedrys was used to isolate the verbascoside. Chromatographic techniques including column, flash and PTLC were employed to isolate the compound. The structure was elucidated by 1D-, 2D-NMR and others spectroscopic techniques. In order to determination of antioxidant activity of isolated molecule, the free radical scavenging activity and reducing power antioxidant activities tests were applied. The results showed that isolated molecule has a higher antioxidant activity than synthetic antioxidants (BHA, BHT and Trolox).As a result, verbascoside (C29H36O15) were isolated from Teucrium chamaedrysL. Subsp. chamaedrys and characterized successfullyas antioxidant agent. OH OH

OH

OH

OH OH O

O O

O

OH O O

OH

(E)-((2R,4S,5R,6R)-6-(3,4-dihydroxyphenethoxy)-2-(hydroxymethyl)-5-methyl-4-((2S,3S,4R,5R,6R)3,4,5-trihydroxy-6-methyl-tetrahydro-2H-pyran-2-yloxy)-tetrahydro-2H-pyran-3-yl) 3-(3,4dihydroxyphenyl)acrylate

Figure 1.Isolated compound and its antioxidant activity *This study is supported by a grant (Project Number: 2011/16) from Scientific Research Projects Committeeof Gaziosmanpaşa University.

References 1- L. R. Fukumoto, G. Mazzo;J. Agric. Food Chem.2000,48. 3597–3604. 2- M. H. Gordon;Nat. Prod. Rep.1996. 13, 265–273. 3- A, C, Moffat, Jackson, J. V., Moss M. S., and Widdop, B.,Clarke’s isolation and identification of drugs, The Pharceutical Press, Londra U.K. 1986.

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Secondary Metabolites from Origanum rotundifolium Boiss. and Antioxidant Activities Ramazan Erenler, Ozkan Sen Department of Chemistry, Faculty of Art and Science, Gaziosmanpasa University, 60240 Tokat, Turkey Abstract: Origanumgenus belonging to the Lamiaceae family is represented by 23 species and six hybrids in the flora of Turkey, 14 of 1 which are endemic. Origanum species have been used as folk medicine for treatment of some diseases for years. These species are 2 well known for their essential oils which have been applied in the flavoring of various foods. The plant materials were dried and powdered then extracted with hexane, ethyl acetate, methanol and water. The aqueous part of water extract was partitioned with ethyl acetate to yield the extract exhibited the best antioxidant activities. Therefore, secondary metabolites were isolated from this extract. Apigenin (1), ferulic acid (2), vitexin (3), caprolactam (4), rosmarinic acid (5), globoidnan A (6) were isolated by chromatographic techniques (column chromatography, preparative HPLC) and spectroscopic methods (1D-NMR, 2D-NMR, LCTOF/MS) were used for elucidation of isolated compounds. The antioxidant activities of isolated compounds were carried out using different antioxidant assays, including 1,1-diphenyl-2-picryl-hydrazyl free radical (DPPH) scavenging, 2,2'-azino-bis(3ethylbenzthiazoline-6-sulfonic acid) (ABTS) radical scavenging, reducing power. Butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT) and trolox were used as standards. Compounds(3, 5 and 2) exhibited high DPPH• scavenging activity. 3 and 6 •+ showed the higher ABTS scavenging activity than the standards. The reducing power activity decreased as the order: BHA >globoidnan A> BHT >ferulic acid >Trolox>rosmarinic acid >vitexin> Apigenin >caprolactam. Acknowledgements This work was supported by The Scientific and Technological Research Council of Turkey (TUBITAK, 113Z195). References 1. P. H. Davis, R. R. Mill and K.Tan. Flora of Turkey and the East Aegean Islands. University Press, Edinburgh: 1988. 2. C. Busatta, R. S. Vidal, A. S. Popiolski, A. J. Mossi, C. Dariva, M. R. A. Rodrigues,; F. C Corazza, M. L. Corazza, J. V. Oliveira and R. L Cansian. Food Microbiol. 2008, 25, 207-211.

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Separation and Preconcentration of Palladium on Magnetic Polyhydroxybutyrate-bPolydimethylsiloxane (PHB-b-PDMS) and Its Determination in Environmental Samples by Flame Atomic Absorption Spectrometry Mustafa Tuzena, YunusEmreUnsala, Mustafa Soylakb, BakiHazerc a

GaziosmanpasaUniversity, Faculty of Science and Arts, Chemistry Dept., 60250 Tokat, Turkey b ErciyesUniversity, Faculty of Science, Chemistry Department, 38039 Kayseri, Turkey c BulentEcevitUniversity, Department of Chemistry, 67100 Zonguldak, Turkey E-mail: [email protected]

Polyhydroxyroxybutyrate-b-polydimethylsiloxane is biodegradable polyester block copolymer (1) a new method has been developed for the separation/preconcentration of trace level of palladium usingmagnetic Polyhydroxybutyrate-b-Polydimethylsiloxane (PHB-b-PDMS). The separation of palladium(II) adsorbed as 1nitroso-2-naphthol-3, 6-disulfonic acid chelates on magnetic PHB-b-PDMS from aqueous solution was simply achieved by applying an external magnetic field via a permanent magnet.Various parameters on the separation and preconcentration of palladium ions such as pH, amount of adsorbent, amount of 1-nitroso-2-naphthol-3, 6disulfonic acid, condition of eluting solution, the effects of matrix ions were examined. The detection limit of this method for palladium was 1.1 µg L−1. The relative standard deviation (RSD) was found 5%. The advantages of this new method include rapidity, easy preparation of sorbents and a high concentration factor. The proposed method has been applied to the determination of palladium(II) ions at trace levels in real samples such as waste water, tap water, river water, sea water, vegetable and soil samples by flame atomic absorption spectrometry.

References 1. M. Tuzen, Y.E. Unsal, M. Soylak, Z. Akkirman, B. Hazer,2013,Int. J. Food Sci. Tech.48, 2384-2390.

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Conversion Treatment of Thin Chromium Layers Deposited on High Carbon Steels Substrates* Younes BENARIOUA Département de Génie Mécanique, Faculté de Technologies, Université de M’sila, BP 166 - M'sila 28000, Algérie. Abstract: The use of transition metal carbides as material coatings to improve the mechanical and chemical properties of mechanical parts has shown a large and extensive development[1, 2]. Among these metal compounds, chromium carbides film which has a better chemicals and mechanicals properties can be used as candidate for this purpose. Coatings of chromium carbide films deposited by different deposition techniques including chemical and physical vapor deposition present a low adhesion to their substrates which is considered as disadvantage[3, 4] The aim of the present paper is to obtain chromium carbide thin film having a better mechanical behavior by annealing treatment of chromium films deposited on high carbon steel substrates. In the first step of this study, high carbon steel substrate is covered with a pure chromium thin layer deposited by electrolytic method. In the next step, samples (layer/substrate) were exposed to annealing at different temperatures ranging from 600°C to 1100°C in steep of 100°C. The structure and morphology of the layers were investigated respectively by X-ray diffraction and scanning electronic microscopy. The adhesion and hardness of films were measured by means of a scratch tester and microhardness tester. It was observed that the film was totally, partially or not transformed into chromium carbide, depending on heat treatment temperature. The transformation of chromium layer in chromium carbide takes place firstly at the interface between the film and the substrate, then it expands through the whole film thickness, toward the outer surface, by diffusion of carbon coming from the substrate. As a result, complete transformation of the chromium film in chromium carbide is obtained when an annealing temperature of 1100°C is used. A higher adhesion and hardness, is found for this coating if compared to the one obtained on samples treated at lower temperatures and to other literature data on coatings having similar thickness and composition. * This study is supported by the Thematic Agency Research of Science and Technology (ATRST) of Algeria under research contract of thematic project 100/2015,

References 1. S.C. Kwon, M. Kim, S.U. Park, D.Y. Kim, D. Kim, K.S. Nam, Y. Choi, Surf. Coat.Technol. 183, 2004, 151. 2. K. Nakaniahi, H. Takeda, H. Tachikawa, T. Arai, The 8th International Congress on Heat Treatment of Metals, Kyoto, Japan, Nov. 17-20,1992, p. 507. 3. C.Y. Wei, F.S. Chen, Mater. Chem. Phys. 91, 2005, 192. 4. Y. Benarioua , R. Boubaaya , J. Lesage, D. Chicot; Surface & Coatings Technology,227, 2013, 65–69

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Evaluation of the Raman Spectroscopy Coupled with Partial Least Squares Regression Analysis for Diagnosis of Hepatitis C. a

a

b

b

e

a

a

c

d

a

b

H. Nawaz , N. Rashid , M. Bilal , M. Saleem ,I. Amin , M. Iqbal , M. Rahman , P. Knief ,H J Byrne , S. M.Baig, M. Ahmed a

National Institute for Biotechnology and Genetic Engineering (NIBGE), P.O.Box 577, Jhang Road Faisalabad, Pakistan. b. National Institute of Lasers and Optronics (NILOP), Islamabad, Pakistan. c . Royal College of Surgeons Ireland (RCSI), Dublin 2, Ireland. d . FOCAS Research Institute, Dublin Institute of Technology, Kevin Street, Dublin 8, Ireland. e. PINUM Hospital, Faisalabad, Pakistan. *Corresponding Author: Dr. Haq Nawaz E-mail: [email protected]

Abstract: Raman spectroscopy has been used to identify the biochemical changes associated with the presenceof the Hepatitis C virus (HCV) in infected human blood plasma samples as compared to healthy samples as control, in an effort to establish the Raman spectral markers of hepatitis infection, which could be used for diagnostic purposes. Moreover, multivariate data analysis techniques, including Principal Component Analysis (PCA) and Partial Least Square Regression (PLSR) are employedto further analyse the biochemical origin of the spectral markers of HCV infection and a PLSR modelisdeveloped to predict the viral loads of the HCV infected plasma on the basis of the biochemical changes caused by the viral infection. Raman spectral features related to RNA/DNA -1

-1

bases, including those at 1247 cm and 1322 cm , are observed only in the plasma of diseased samples as compared to control, indicating their association with the HCV. In addition,spectral changes related to lipids are also observed which can be associated with their involvement in the replication process of the virus after infection. PCA differentiated the “normal” and “HCV” groups of the Raman spectra and the PC loadings highlight the biochemical origin of the spectral changes associated with HCV infection. PLSR modelling was found to be 93.8 % accurate in predicting the viral loads of the HCV samples on the basis of the Raman spectral changes caused by the virus during the process of the development of Hepatitis C.

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Kendiliğinden Yerleşen Betonda Rötre Azaltici KimyasalKatkinin Dayanima Olan Etkisi İlhami Demir, İlker Kalkan, Ali Payidar Akgüngör, Özer Sevim Kırıkkale Üniversitesi, Mühendislik Fakültesi, İnşaat Mühendisliği, Yahşihan, Kırıkkale, Türkiye Özet: Kendiliğinden yerleşen beton (KYB) özellikle hazır-beton sektörü, onarım güçlendirme işleri ve prefabrik inşaat sektörü başta olmak üzere yapıların beton ile ilgili tümdallarında giderek daha fazla uygulama alanı bulmaktadır. Vibratör gerektirmeden yerleşmesi, yüksek dayanım özelliği gibi nedenlerle yüksek performanslı beton üretimine olanak vermektedir. Günümüzde en çok kullanılan özel beton çeşitlerinden biri kendiliğinden yerleşen betondur. Kendiliğinden yerleşen betonun davranış özelliklerini bilmek için öncelikle kendiliğinden yerleşen betonun (KYB) yapısının iyi analiz edilmesi gerekir. Bu nedenle de KYB’nin fiziksel ve kimyasal yapısının, onu oluşturan yapı malzemelerinin ve bu malzemelerin birbirleriyle uyumlu çalışmalarının bilinmesi gerekir. Son yıllarda düşük su/bağlayıcı oranına sahip ve çatlak oluşumuna daha eğilimli yüksek kalitedeki betonların üretimi ile birlikte durabilite konusunda çatlak oluşumunun oynadığı zararlı rol, rötre ve erken yaş çatlakları konusuna duyulan ilginin yeniden artmasına yol açmıştır. Bu modern betonların sahip oldukları çatlak duyarlığı sahip oldukları yüksek çimento dozajı ile düşük su/bağlayıcı oranının neden olduğu otojen rötreye bağlı etkilerle ilişkili olmaktadır. Bu çalışmada rötre azaltıcı katkının kendiliğinden yerleşen beton (KYB) karışımların taze haldeki özellikleri ile yarmada çekme dayanımı ve basınç dayanımı irdelenmiştir. Anahatar Kelimeler: Kendiliğinden Yerleşen Beton, Rötre, Rötre Azaltıcı, Eğilme ve Basınç Dayanımı



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Spectroscopic Studies on 9H-Carbazole-9-(4-phenyl) Boronic Acid Pinacol Ester by DFT Method a a b b c Emine BABUR SAS , Mustafa KURT , Mustafa CAN , Nesrin HORZUM , Ahmet ATAC a

b

Department of Physics, Ahi Evran University,TR-40100, Kirsehir, Turkey, [email protected], [email protected]

Department of Engineering Sciences, Faculty of Engineering, Izmir Katip Celebi University, TR-35620 Izmir, Turkey, [email protected], [email protected] c Department of Physics, Celal Bayar University,TR-45100, Manisa, Turkey, [email protected]

Abstract: 9H-Carbazole-9-(4-phenyl)boronic acid pinacol ester (9-CPBAPE) molecule was investigated by FT-IR, 1H and 13C NMR spectra. FT-IR 1 13 spectrum was recorded in the solid phase. H, C-NMR spectra were recorded in dimethyl sulfoxide (DMSO) solution. The results of theoretical calculations for the spectra of the title molecule were compared with the observed spectra. The theoretical calculations for the molecular structure and spectroscopic studies were performed with DFT (B3LYP) and 6-311G (d,p) basis set calculations using the Gaussian 09 program. The complete assignments are performed on the basis of the potential energy distribution (PED).

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Efficient Synthesis ofIndene-Aldehyde Derivatives Catalyzed by Secondary Amine Catalysts a

HuiMaoa, Jung WoonYanga Department of Energy Science, Sungkyunkwan University, Suwon 440-746, Republic of Korea

Abstract: Substituted indene derivatives are valuable synthetic targets in organic and medicinal chemistry because of their important biological activities and applications in functional materials. These indene-based materials have shown a wide range of biological activities such as antineoplastic, anti-inflammatory, aromatase inhibitory, and cytotoxic activities. A variety of effective approaches were already reported for indene synthesis. However, many of these existing methods suffer from shortcomings includinglow tolerance of functionality, the necessity of expensive transition metal catalysts and harsh reaction conditions. Herein, we describe a novel method for the synthesis of various substituted indene aldehydes using secondary amine catalystsunder mild reaction conditions.

Scheme1.Formation of indene aldehyde derivativescatalyzed by secondary amine catalysts





References 1. Y. Huang, A. M. Walji, C. H. Larsen, D. W. C. MacMillan, J. Am. Chem. Soc.,2005, 127, 15051-15053. 2. K. B. S. Magar, Y. R. Lee, Org. Lett.,2013, 15(17), 4288-4291.

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OR-15

Synthesis of Multiwall Carbon Nanotube - p-Phenylenediamine - Maleic Anhydride - 1Heptene Nanocomposite a

a

b

b

Elvin MALIKOV , Oktay AKPEROV , Mustafa MURADOV , Goncha EYVAZOVA Department of Chemistry, High Molecular Compounds chemistry sub-department,Baku State University, AZ 1148, Z.Khalilov str.,23, Baku, Azerbaijan b Department of Physics, Sub-department of Chemical Physics of Nanomaterials,Baku State University, AZ 1148, Z.Khalilov str.,23, Baku, Azerbaijan Abstract: Carbon nanotubes (CNTs) have received considerable attention recently owing to their unique electronic and mechanical properties that are expected to lead to breakthrough industrial applications [1]. CNTs exhibit a well-known tendency to form agglomerates due to van der Waals forces, which makes them extremely difficult to disperse and align in a polymer matrix. The functionalization of CNTs is an effective way to prevent nanotube aggregation, which helps in dispersing and stabilizing carbon nanotubes within a polymer matrix. The two main pathways suggested for the covalent grafting of polymers to CNTs are the “grafting from” and the “grafting to” approaches [2-4]. In this paper multiwall carbon nanotubes (MWCNTs) synthesized by CVD from acetylene over an Fe,Co/alumina catalyst were oxidized by KMnO4 solution to form functionalities on wall defects and end caps. The “grafting to” approach was used to graft maleic anhydride-1-heptene copolymer (MAHP) to oxidized-MWCNTs using p-Phenylenediamine (PPDA) bridge. First of all PPDA was added to the oxidized-MWCNTs to form a salt. Then this salt was reacted with MAHP to form a grafted structure. The proof of completion of the “grafting to” process was obtained by XRD, Raman and FTIR methods. FTIR also confirmed the presence of the characteristic peaks of the anticipated zwitterion and amine-amide conversion. TEM and SEM revealed that the nanotubes are uniformly covered with the polymer which shows the effectiveness of the method. The solubility of the MWCNTs was improved by the functionalization because, grafting MWCNTs to MAHP helps in reducing the nanotube-nanotube adhesion and the tendency to form entangled stacks, which generally make MWCNTs unusable for manufacturing advanced plastic materials. The novelty of this work is that MAHP macromolecules are attached to oxidized-MWCNT using PPDA bridge via the “grafting to” approach for the first time at room conditions. The long copolymer chains in the resulting material are able to screen and protect the nanotubes from entanglement during dispersion. The suggested process was carried out at room conditions and therefore it can be considered as a feasible alternative for carbon nanotube functionalization targeted at polymer composite applications. a

References 1. X. Wang, Q. Li, J. Xie, Z. Jin, J. Wang, Y. Li, K. Jiang, S.S. Fan;Nano Lett.2009, 9(9), 3137-3141. 2. N.G. Sahoo, S. Rana, J.W. Cho, L. Li, S.H. Chan;Prog Polym Sci.2010, 35, 837-867. 3. E.Y. Malikov, M.C. Altay, M.B. Muradov, O.H. Akperov, G.M. Eyvazova, R. Puskás, D. Madarász, Á. Kukovecz, Z. Kónya;Physica E. 2015, 69, 212-218. 4. E.Y. Malikov, M.B. Muradov, O.H. Akperov, G.M. Eyvazova, R. Puskás, D. Madarász, L. Nagy, Á. Kukovecz, Z. Kónya;Physica E.2014, 61, 129-134.

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Design of an Appropriate Semi-Interpenetrating and Full-Interpenetrating Polymer Network Chitosan for Nano Drug Delivery Amilah*, Nike TriendahAsih** *) Chemistry Department, Faculty of Mathematics and Natural Science, University of Indonesia Phone: +62-852-7413-4736 E-mail: [email protected] **) Chemistry Department, Faculty of Mathematics and Natural Science, Indonesia University Phone: +62-858-1719-6070 E-mail: [email protected] Chitosan is a non-toxic biocompatible polysaccharide thathas been widely explored for drug delivery agent, tissue engineer and cosmetic. Chitosan is among of the most exploredpolysaccharides in biomedical science. It has many advantages that are not availablein most natural polysaccharides. However, chitosan has few disadvantages like as have weak mechanical strength and swelling/deswelling respone. Because of these disadvantages, chitosan requires further development to achieve the targeted efficiency results desired. To overcome some of the disadvantages of a pristine chitosan, it is most imperative to functionalize pristine chitosan with suitable functional groups. These functional groups include the primary hydroxyl group, and amide group that are located in backbone of chitosan, in which they act as a site of chemical modification, and are responsible for the polymer’s reactivity. Chitosan has limitation as a nano-drug delivery because of the limitation in it’s chemical modification. Modification of chitosan is very important to carry out it’s purpose as a nano-drug delivery. The stability of the nano-drug delivery is an important parameter for a successful passive targeting. If the particles circulated in the blood-streams for a longer period of time, therefore the particles can reach the target sites more effectively. Thus, it is highly desirable to understand the design of the Interpenetrating Polymer Network (IPN) base on polysaccharides in order tosynthesizea polymer that can be applied as nano-drug delivery. The purpose of this review is to give an overview of the strategy and design foran appropriate Semi- Interpenetrating Polymer Network (Semi-IPN)

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Preparation ofChitosan-Gum Arabic/n-eicosane Microcapsules byComplex Coacervation Kasım AKSOYa, Cemil ALKANb a

Süleyman Demirel University, Technical Sciences Vocational School, Biomedical Device Technology Program, Isparta, TURKEY b Gaziosmanpaşa University, Department of Chemistry, Tokat, TURKEY [email protected]

In this study, microencapsulated n-eicosane as phase change heat energy storage material was prepared by complex coacervation method. In the complex coacervation method, oppositely charged polymers were used to form microcapsule shell. Polymer complex formed at suitable pH value between the positive and negative charged polymer chains is deposited on microcapsule core material in emulsion system. In the system, pH is adjusted to the value that two polymers are oppositely charged. Finally, complex macromolecular structure formed between the polyanion and polycation polymers in the emulsion system were cross-linked by a crosslinker agent to increase thermal, chemical and mechanical stability of prepared microcapsules. In this study, chitosan and gum Arabic polymers were used as polycation and polyanion polymers, respectively. Span 20 with 8.6 of HLB value was used as surfactant. Core/shell and polycation polymer:polyanion polymer ratios were determined as 1:1,5 and 1:1, respectively according to the finding from our previous studies [1,2]. The particle size, morphology, chemical structure and thermal properties such as melting and crystallization temperature and enthalpy were analyzed by particle size analyzer, SEM, FT-IR spectroscopy and DSC methods, respectively. The results showed that microcapsules have spherical shape with particle sizes between 15.49 µm and 65.92 µm.Microencapsulated n-eicosane have70.35 J/g melting enthalpy at 33.3 oC and -71.35 J/g crystallization enthalpy at 33.8 oC. Key Word: Microcapsules, complex coacervation, phase change material, n-eicosane, chitosan and gum arabic.

References [1] K.Aksoy and C.Alkan,2013,8th International Conference Textile Science-TEXSCI 2013, 50-51,September 2325,Liberec,Czech Republic. [2] K.Aksoy, C.Alkan,2014,V. Ulusal Polimer Bilim Ve Teknolojisi Kongresi,26-27,Eylül 1-4,Tokat, Türkiye.

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Removal of Cr(III) and Cr(VI) Ions from Aqueous Solutions Using Modified Cotton Cellulose with Polycarboxylic Acids a

a

a

b

Nazife Korkmaz , Sennur Alay Aksoy , Fethiye Göde Süleyman Demirel University, Textile Engineering Department, Isparta, Turkey. b Süleyman Demirel University, Department of Chemistry, Isparta, Turkey. [email protected]

Abstract Pollution of ground water and surface water by heavy metals such as lead, cadmium, copper, chromiumand mercury is one of the most serious environmental problems due to their toxic nature and other adverse effects (1). These heavy metals are not biodegradable and tend to accumulate in living organisms. They can cause various diseases and disorders which represent a serious threat for human population as well as the fauna and flora of receiving water bodies as discharges in waste water. Hence, the removal of heavy metal ions from aqueous solution before discharge is essential. Among these heavy metal ions, chromium especially in its hexavalent form has toxic effects. At high exposure levels, Cr (VI) causes respiratory cancers (2).Most of conventional methodssuch as chemical precipitation, electrolysis, membrane separation, ion exchange, reverse osmosis and biosorption suffer from some drawback such as high capital or high operating cost or disposal of resulting solid waste. On the other hand, adsorption using sorbents is one of the most popular and effective processes for the removal of heavy metals from wastewater because of the flexibility in design and operation and environmental friendly behavior. In recent years, the investigation of low-cost materials such as agricultural by products, industrial wastes and biological materials as adsorbents for the removal of heavy metal from industrial wastewater has been considered. According to the findings, the heavy metal adsorption capacities ofthe modified cellulose by forming an ester linkage were significant and levels of uptake were comparable to commercial ion exchange type resins (3). In this study, the Cr(III) and Cr(VI) ions sorption ability of cross-linked cotton cellulose with different polycarboxylic acids by forming ester linkage were investigated. Butane tetra carboxylic acid (BTCA) and maleic acid (MA) catalyzed by sodium hypophosphite were cross-linked to cellulose by esterification reaction. Fourier transform infrared spectrometer (FT-IR) was used to verify the presence of functional carboxylic acid groups in cross-linked cellulose. The morphology of the modified cotton cellulose was studied by scanning electron microscope (SEM). Furthermore, the adsorption mechanism was systematically investigated. The percentages of Cr(III) adsorbed on the 0.1 g adsorbent which modified cotton cellulose with MA and BTCA were 69.94 %and 62.23 %, respectively. Besides, the percentages of Cr(VI) adsorbed on the 0.1 g adsorbent which modified cotton cellulose with MA and BTCA were 66.54 % and 66.04%, respectively. It was concluded that modified cotton cellulose with BTCA and MA by forming ester linkage could be used for the removal of Cr(III) and Cr(VI) ions from the waste water. References 1. X. Yu, S. Tong, M. Ge1, L. Wu, J. Zuo, C. Cao, W. Song, Journal of Enviromental Sciences, 2013, 933-943 2. IARC, 1990. Monograph on the Evaluation of Carcinogenic Risk to Humans, vol. 49, Chromium, Nickel and Welding. International Agency for Research on Cancer, Lyon. 3. D.W. O’Connell , C. Birkinshaw , T. F. O’Dwyer, Bioresource Technology, 2008,99, 6709-6724.

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Oxidative Stress Parameters in Anesthetized with Ketamine-Xylazinethe Bozova Greyhounds

Güzin CAMKERTENa, İlker CAMKERTENb, Nihat ŞINDAKc, Gaye BULUTd Department of Veterinary,Vocational-Technical School, Laboratory and Veterinary Health Program,Aksaray University, TR-68100, Aksaray, Turkey b Department of Internal Medicine, Faculty of Veterinary Medicine, Aksaray University, TR-68100, Aksaray, Turkey c Department of Surgery, Veterinary Medicine, Siirt University, TR-56100, Siirt, Turkey d Department of Gynecology and Obstetrics, Faculty of Veterinary Medicine, Aksaray University, TR-68100, Aksaray, Turkey

a

Abstract Background:The combination of ketamine HCl and xylazineHCl anesthesia is very useful and safe in dog. “Bozova Greyhounds” were raised villages of around Bozova town of Sanliurfa city in Turkey and they were used to hunting. To our knowledge, it is only a few article reported on ketamine and xylazin anesthesia effects of clinical parameters but not about oxidative stress parameters on the greyhounds and no study has been reported anesthesia on Bozova Greyhounds. Therefore, the purpose of this study is to evaluate the oxidative stress parameters in anesthetized with ketamine-xylazineBozova greyhounds. Materials and methods:In this study eight greyhounds which were in different age, body weight and sex were used as the material. The animals which were came in clinic with different complaints injected with the ketamine (10 mg/kg) and xylazine (1 mg/kg) intramuscularly. The findings were recorded before and 30 minute of anesthesia. Blood samples were collected from the vena cephalicaantebrachii into two tubes with and without coagulant. Erythrocyte Superoxide dismutase (SOD), glutathione peroxidase (GPx), malondialdehyde (MDA) and plasma catalase (CAT) were measured by validated standard methods.Serum copper, zinc, manganese levels were determined by an ICP-OES. Results: Table 1.Oxidative stress paremeters before and after anestezia in greyhounds ntotal = 8 Sod Cat Gpx Mda Cu (Mg/L) Zn (Mg/L) Mn (Mg/L)

Before Anestezia mean 361,4 245,4 9561 8,02 1,70 2,70 0,20

After Anestezia

SE 31,4 27,2 2103 2,20 0,06 0,90 0,06

mean 237,3 276,9 9676 3,67 1,69 5,79 0,32

SE 40,8 31,8 1951 0,16 0,06 1,42 0,08

P < 0.05 -

Discussion:The SOD Activity is increased in tissues that are much using oxygen and with the rise of tissue pO2. The first 30 minutes of anesthesia, partial oxygen pressure (PaO2) usually decreases. During anesthesia,the drop of PaO2 is causes a reduction in the SOD activity. As a result, the using of ketaminexylazine anesthetics in dogs (especially Bozova Greyhounds) can be said that in terms of sera Cu, Zn, Mn trace elements and oxidative stres are highly secure and available. Key Words:Bozova Greyhounds, oxidative stress, SOD, CAT, GPx, MDA

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Structural, Electronic, Elasticand Phonon Properties of OsAl in B2 Crystal Structurefrom First-principles Raşit UMUCUaand Mustafa ÖZDURANa a

A

Department of Physics,Faculty of Art and Science, Ahi Evran University, Bağbaşı-TR-40200 Kırşehir, Turkey

theoreticalstudy

presentedbyperforming

of

structural, ab

wavepseudopotentialmethod.

electronic,

elasticandphononproperties

initiocalculationsbased

on

of

OsAlcompound

is

thedensity-functionaltheoryusingtheplane-

Thegeneralized-gradientapproximation

(GGA)

is

chosenfortheexchange–

correlationenergy. Thecalculatedstructuralparameters, such as thelatticeconstant, bulkmodulus, secondorderelasticconstants,

electronicbandstructuresandtherelated

total

density

of

statesarepresented.

OurcalculationspredictthatOsAl is a metal in CsClstructure. Theelasticconstantswerederivedfromthestress– strainrelation.

Phonon-dispersioncurveswereobtainedusingthefirstprincipleslinear-responseapproach

thedensity-functionalperturbationtheory.



REFERENCES [1] J.J. Spokas, C.H. Sowers, D.O. Van Ostenburg, and H.G. HoevePhys. Rev. B, 1, 2523 (1970). [2] D. Nguyen-Manh, D.G. Pettifor, Intermetallics, 7, 1095-1106 (1999).

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Thermal energy storage properties of poly(methyl methacrylate)/stearic acid micro/nano capsules* *

Ahmet SARI ,Ayşe Gül KÜÇCÜK, Alper BİÇER, Cemil ALKAN Department of Chemistry, Gaziosmanpaşa University, 60240, Tokat, Turkey *[email protected] Fatty acids categorized as solid-liquid organic PCMs have attractive thermal energy storage (TES) properties like reversible phase change, high thermal durability and goodchemical stability with different environmental matters [1]. However, the fatty acids need packaging materials to hold them in liquid or solid state in order to avoid their contact with near surrounding [2]. The micro or nano encapsulation of PCM can prevent its seepage from the structure, lessen the interference with its close environment, resist its volume change and improve enlarge its heat-transfer area, light permeability, controlled releasing, and thermal stability properties [3]. Therefore, in recent years, the encapsulated PCMs have been prepared to use them in the fabrication of thermal regulating fibers, fabrics, coatings and foams [4], insulation panels, the exterior walls of buildings [5] and electronic equipments [6]. In this study, it is aimed to prepare, characterize and determine the latent heat thermal energy storage properties of micro/nano encapsulated stearic acid (SA) with polymethylmethacrylate(PMMA) shell. The micro/nano capsules were prepared effectively as novel encapsulated phase change material(EPCM) via emulsion polymerization. The fourier transform infrared (FTIR) spectroscopy analysis confirmed that the polymerization reaction was carried out successfully. The polarized optical microscopy (POM), scanning electron microscopy (SEM) and particle size distribution (PSD) analysis showed that the prepared PMMA/SA micro/nano capsules with 1:1 styrene/SA ratio had spherical shape-appearances with micro/nano sizes. The differential scanning calorimetry (DSC) measurements revealed that the micro/nano capsules containing the highest paraffin content had melting temperature of 64.58°C and latent heat storage capacity of 124.98 J/g. Thermogravimetry analysis (TGA) results verified that the encapsulated PMMA/SA(1:1) had good thermal reliability and chemical stability after repeated melting/freezing cycles for 5000 times. Furthermore, the synthesized PMMA/SA(1:1) micro/nano capsules had conceivable thermal conductivity values and reversible phase change behaviors. Based on all results it can be also concluded that the prepared PMMA/SA(1:1) micro/nano capsules had good thermal energy storage potential for low temperature-solar passive TES purposes especially for buildings and thermal regulating of textile materials. *The author would like to acknowledge by Scientific and Technological Research Council of Turkey (TÜBİTAK) for financial support (Project No:112T864). References: [1] Hadjieva M, Kanev St, Argirov J, Solar Energy Material and Solar Cells 1992; 27:181–187. [2] Zhao CY, Zhang GH. Renewable and Sustainable Energy Reviews 2011;15:3813–32. [3] Hawlader MNA, Uddin MS, Khin MM. Applied Energy 2003;74:195–202 [4] Sarı A, Alkan C, Karaipekli A. Applied Energy 2010; 87:1529-1534. [5] Jeong SG, Jeon J, Seo J, Lee JH, Kim S. Energy Conversion and Management 2012; 64:516-521. [6] Su JF, XY, Wang SB, Wang YH, Zhao, ZH, Energy Conversion and Management 2012; 55:101-107. [7] Jackson WB,Gould RD, Mulligan JC.8th AIAA/ASME Joint Thermophysics and Heat Transfer Conference, 24-26 June 2002.

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AB Initio Molecular Dynamics Study OF Structural Properties OF FeF2as aFunction ofPressure *

**

*

***

Cihan KÜRKÇÜ ,Ziya MERDAN , Hülya ÖZTÜRK , Sümeyra YAMÇIÇIER , * Çağatay YAMÇIÇIER and Cemile KÜRKÇÜ * Department of Physics, Faculty of Arts and Sciences, Ahi Evran University, TR-40200, Kirsehir, Turkey. [email protected], [email protected], [email protected] ** Department of Physics, Science Faculty, Gazi University, TR-06500, Ankara, Turkey. [email protected] *** Vocational School of Health Services, Ahi Evran University, TR-40100, Kirsehir, Turkey. [email protected], [email protected] Abstract: We have studied the structural properties of the antiferromagnetic FeF2 using density functional theory (DFT) methods under rapid hydrostatic pressure up to 300 GPa. FeF2 crystallizes in tetragonal rutile-type structure with space group P42/mnm at ambient conditions. FeF2 undergoes a phase transformation from the tetragonal structure to CaCl2-type orthorhombic structure with space group Pnnm at 136 GPa. This phase transformation is in good agreement with other theoretical and experimental studies. This phase transformation is also studied by total energy and enthalpy calculations.

Scheme1.(Color on-line)Crystal Structures with polyhedral views of FeF2. (top) at zero pressure and (bottom) at 136 GPa.

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Developed of PotentiometricSensitive Sensorto Antipsychotic Risperidone Ömer IŞILDAKa, Ayşenur BİRİNCİa

a

GaziosmanpasaÜniversity, Faculty of Science and Education, Department of Chemistry, Tokat, Turkey [email protected] Abstract: A drug with a antipsychotic risperidone can be analyzed by liquid chromatographic techniques (LC) using uvvisible and flourosans detectors. However all developed methods based on LC are expensive, time consuming due to pre-and post-column reaction, and also not very selective and sensitive. In this planned work, preparation of micro sized composite risperidone-sensitive sensor, development of prepared composite risperidone-sensitive electrodes, and investigation of suitability as a detector in flowinjection analysis system are aimed. For this aim, risperidone-sensitive censor membrane was prepared by coating composite cocktail on the surface of contact transducer in solid state. Risperidone-sensitive censor was not constitute internal reference electrode or solution. The potensiometric performance of risperidone-sensitive chemical censor (selectivity constant, liner working interval, detection limit, response time, pH working interval, repeatability, lifetime, and time dependent potential decay) was determined using computer controlled measurement system in static conditions. Because micro sized sensors will be developed in the present project study proposed are composite material, the fabrication of flow-through cells in nano-liter dead volume can be produced for the use as detectors in LC of risperidone that could be efficiently determined.

(b) (b) Figure 1.The response and linearity to exhibits of the all solid-state membrane electrodeagainst 1x10-1-5x10-5 Mrisperidoneconcentration change. *The study was supported by The Scientific and Technological Research Council of Turkey, TUBITAK, project no. 114Z033

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Usability and Attenuation Performance of Titanium-Iron Oxide Mineral as Natural Filler for Composite Ionizing Electromagnetic Radiation Shielding 1

1

2

Ezgi Eren Belgin , Gül Asiye Ayçık , Ayşe Kalemtas Mugla Sitki Kocman University, Faculty of Science, Department of Chemistry, Mugla, Turkey, [email protected] 2 Bursa Technical University, Faculty of Natural Sciences, Architecture and Engineering, Department of Metallurgical and Materials Engineering, Bursa, Turkey Abstract: 1

Appropriate shielding materials are used to protect human and environment from harmful effects of high energy ionizing radiation. In the present, generally aggregated concretes and/or lead are used as electromagnetic radiation shielding materials. Concrete is a heavy material and can only be used for stationary applications while lead is heavy, not flexible, has low chemical and mechanic stability and hard workable specifications. Lead is also ranked as number two on the U.S. Government's Top 100 Hazardous Substances Priority List, which means that lead (#2) poses a bigger risk to human health than mercury (#3), chloroform (#11), cyanide (#35) and asbestos (#94) [1]. As the technology develops usage and production of radiation sources increases and need of novel shielding materials for different application areas increases, too. Thus the studies about production of new shielding materials with more desirable properties than lead and developing properties of conventional shielding materials rise during the recent years. In this study, natural mineral-polymer composites were produced and their electromagnetic radiation shielding effects were investigated. Ilmenite (natural mineral of titanium and iron oxide) was used as reinforcement material and isophytalitic polyester unsaturated resin was used as composite base. After production, ionizing radiation attenuation properties of the composites were investigated by using HPGe detector and shielding properties of the produced composites were compared with the conventional shielding materials. The composites showed about %30 of the attenuation properties of lead and 4-5 times greater attenuation properties from the composite base polyester for electromagnetic radiation with low-intermediate and high energy. Thus this non-toxic and light weight novel material could be an alternative for lead shieldings. This shield could be used for both stationary applications as reactor shielding and also mobile applications because of its light weight. Light weight and comfortable clothing shield materials could be produced for radiation workers by using this material. The results showed that this material can be effectively usable by ionising-radiation workers and by the comfort of general population.

References 1. USA Agency of Toxic Substances&Disease Registry, http://www.atsdr.cdc.gov/ spl.index.htm

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Synthesis of Some Natural Bromophenols Including Propane Derivatives* Çetin BAYRAK, Abdullah MENZEK Department of Chemistry, Faculty of Science, Atatürk University, 25240 - Erzurum, Turkey Abstract: Natural bromophenols are frequently isolated from marina life. This and similar compounds to it have biological activities such as 1 enzyme inhibition , cytotoxicity, anticancer, antioxidant and microbial activities.



Vanillin was used as starting material, and their reactions with acetone and propanal were performed. In the reactions, OH group of vanillin was protected as OMe and OMOM (methoxymethyl). After products were purified, protected groups in the products were removed and natural bromophenols 5, 6, 7 and 8 were obtained.



Synthesized products from the reactions were purified by chromatographic methods and their structures were determined by spectroscopic methods. *This study is supported by a grant (Project Number: 113Z702) from TÜBİTAK.

References 1. a) D. Shi, J. Li, S. Guo, H. Su, X. Fan, Chin. J. Ocean Lim, 2009,27, 277–282. b) Paul S, Gupta M. Synth. Commun.,2005, 35, 213-222. c) H.T. Balaydın, İ. Gülçin, A. Menzek, S. Göksu, E. Şahin, J. Enzym. Inhib. Med. Chem.,2010, 25, 685-695. d) H.T. Balaydın, M. Şentürk, S. Göksu, A. Menzek,Eur. Med. Chem., 2012,54, 423-428.

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From “Dark to light”1-2 to Fluorescence Resonance Energy Transfer: Dual Activator TPE Donor Fused BODIPY Dyes with a Large Stokes Shift and High Quantum Yield

Esra Şen, Serdar Atılgan Department of Chemistry, Suleyman Demirel University, 32000, Isparta, Turkey, Fluorescent molecules, providing insights into the solutions of current challenges towards widespread applications and expanding the horizons of many processes with their judiciously designed architecture, is an attractive sub-discipline in the broader field of supramolecular chemistry. This is mostly due to its many potential medicinal and bioimaging applications as well as material science. 1 Fluorescence resonance energy transfer (FRET), is the one attractive spectroscopic technique that is used in these supramolecular architectures. FRET is explained as a process which describes the energy transfer between excited state donor fluorophore and ground state acceptor fluorophore linked together by a non-conjugated spacer. In this study, we are presenting a novel strategy combining the advantageous of aggregation induced emission (AIE) methodology with energy transfer systems to improve energy transfer efficiency and thus increase adaptability of energy transfer systems to different applications. The strategy developed in this work provides a more promising approach for making full use of energy transfer systems in both organic and aqueous media with one donor-acceptor interaction. a

References 1. Su, D., Oh, J., Lee, S.-C., Lim, J.M., Sahu, S., Yu, X., Kim, D., Chang, Y.-T. (2014) Chemical Science, 5 (12), pp. 4812-4818 2. E Aydin, B Nisanci, M Acar, A Dastan, ÖA Bozdemir New Journal of Chemistry 39 (1), 548-554

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Synthesis of The Topoisomerase-I Inhibitors Isoindolo[2,1-B]-Isoquinolin7(5h)-One and the Alkaloid Rosettacin Based on Aryl Radical Cyclization and N-Acyliminium Chemistry 1

Lahssen El blidi 1 , Adam Daich 2 , Yousef Al-Zeghayer 1

Chemical Engineering Department, King Saud University, Riyadh, Saudi Arabia 2

Laboratoire de Chimie URCOM, INC3M CNRS-FR 3038, Université du Havre, France [email protected]

Camptothecin 1a and his analogues with lactone-free ring such as the alkaloid luotonin-A (2), rosettacin (3a), acuminatine (3b), and 22-hydroxyacuminatine (3c) belonging to the named aromathecin family (ART), act as a selective poison of DNATop1.1 Taking into account these biological considerations with high importance, many synthetic approaches including QSAR studies have been conducted over the last 10 years to provide these aromathecins including the Top1 poison rosettacin (3a).2



In connection with our project aimed at the synthesis of aromathecins, herein we present a short and effective approach for the synthesis of the topoisomerase-I inhibitors isoindolo[2,1-b]isoquinolin-7(5H)-one and the alkaloid rosettacin belonging to the aromathecin family. The key step of this sequence which resulted in the formation of five-membered ring was the aryl radical cyclization3 of enamides generated by using the N-acyliminium chemistry.

[1] (a) Pommier, Y. Chem. Rev. 2009, 109, 2894–2902. (b) Khadka, D. B.; Cho,W.-J. Bioorg. Med. Chem.2011, 19, 724– 734; and the references therein. [2] Cinelli, M. A.; Morrell, A. E.; Dexheimer, T. S.; Agama, K.; Agrawal, S.; Pommier, Y.; Cushman, M. Bioorg. Med. Chem.2010, 18, 5535–5552. [3]Wakchaure, P. B.; Easwar, S.; Argade, N. P. Synthesis2009, 10, 1667–1672.

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Determination of Structural and Spectroscopic Properties of Methyl-4-bromo-2chloropyrıdine-3-carboxylate Molecule using FT-IR and NMR Experimental Techniques and DFT Quantum Chemical Calculations a

a

a

b

Zuhre CALISIR , Mustafa KURT , Mehmet KARABACAK , Ahmet ATAC

c

Department of Physics, Ahi Evran University,TR-40100, Kırsehir, Turkey [email protected],[email protected] b Department of Mechatronics Engineering, H.F.T. Technology Faculty, Celal Bayar University,TR45400, Turgutlu, Manisa, Turkey,[email protected] c Department of Physics, Celal Bayar University,TR-45100, Manisa, Turkey, [email protected] Abstract: The theoretical and experimental vibrational spectra of methyl-4-bromo-2-chloropyridine-3-carboxylate molecule were studied. The geometrical parameters and vibrational wavenumbers of methyl-4-bromo-2-chloropyridine-3-carboxylate molecule were calculated using the density functional method (B3LYP with 6-311++G(d,p) basis set). For this molecule, theoretical calculations were performed by using Gaussview and GAUSSIAN09 package program on the personal computer. Fourier Transform Infrared (FT-IR) 1 13 spectrum of the studied molecule was recorded in the solid phase. H and C NMR spectra were recorded in DMSO solution. As a conclusion, the calculation results were applied to the simulated infrared and NMR spectra of the title compound, with the observed spectra.

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New Approach to Convenient Synthesis of Disubstituted Tacrin Derivatives a,b

b

c

Makbule EKİZ , Ahmet TUTAR , Salih ÖKTEN a Department of Chemistry,Faculty of Art and Science, Düzce University, TR-81620, Düzce b Department of Chemistry, Faculty of Art and Science,Sakarya University, TR-54187, Sakarya c Department of Primary Education, Division of Science Education, Faculty of Education, Kırıkkale University,TR-71450, Kırıkkale [email protected], [email protected] Abstract: Tacrine derivatives have received attention due to pharmacological properties. Tacrines have been used to cure for alzhemier disease for years. The aim of this study is described a convenient route for 5,7-disubstituted tacrine derivatives via substitution reactions. Cupper promoted reactions gave methoxy ve cyanide tacrine compounds. Several 5,7-disubstituted tacrines were obtanined by treatment of 5,7-dibomotacrine with n-BuLi followed by trapping with electrophile [Si(Me)3Cl, S2(Me)2,and DMF].

Figure 1.Synthesis of tacrine derivatives *This study is supported by a grant (Project Number 2014-02-04-008 and 2014-50-02-025) from Scientific Research Projects Committeeof Sakarya University.

References 1. M.T. McKenna, G.R. Proctor, L.C. Young, A.L. Harvey, J.Med. Chem., 1997, 40, 3516-3523. 2. G.R. Proctor, A.L. Harvey, Cur. Med. Chem., 2000, 7, 295-302.

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OR-31

Chitosan/Nanoclay/n-Eicosane Microcapsules with Heat Energy Storage Property a

a

b

Ebru Genç , Sennur Alay Aksoy , Kasım Aksoy Süleyman Demirel University, Textile Engineering Department, Isparta, Turkey b Department of Electronics and Automation, Technical Sciences Vocational School, Süleyman Demirel University, TR-32260, Isparta, Turkey [email protected] Abstract Microencapsulated PCMsrefer to PCMs encapsulated in micron-sized shellto avoid the possible interaction between the PCM and matrix and the PCM leakage. Paraffins like n-eicosane, n-octadecane, n-hexadecane are common PCMs used as the core material of microcapsules because of their appropriate phase transition temperature, large latent heat of fusion, and chemical stability (1). This study focuses on the preparation of microencapsulated phase change materials (MEPCMs), consisting of n-eicosane core within a chitosan/nano clay shell, using a complex coacervation method. The MEPCMs were prepared using two different weight ratios of chitosan/nan clay that are 1:1 and 1:1.5. The effects of the type ofthe surfactant on the encapsulation characteristics and thermal properties of the MEPCMs have been investigated. The analysis results show that the MEPCMs were prepared successfully. The thermal characteristics of MEPCMs prepared with various ratios by surfactant type. When the surfactant Span 80 was used the heat of melting of MEPCMs was higher. The melting temperature and latent heat of the MEPCMs were in the range of 35.43-36.59 °C and 94.11-120.51 J/g, respectively. According to the optical microscopy analysis results, microcapsules were spherically shaped. Acknowledgement: This work was financially supported by the Süleyman Demirel University (Project No. 4288-YL1-15). References 1. C.Fangyu,Y. Bao, Applied Energy, 2014,113, 1512–1518. a

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OR-32

ab InitioStudy of Elastic, Electronic and Phonon Properties of SnNCa3and PNCa3Compounds

a

Mustafa ÖZDURANa and RaşitUMUCUa Department of Physics,Faculty of Art and Science, Ahi Evran University, Bağbaşı-TR-40200 Kırşehir, Turkey

The structural, elastic, electronic and phonon properties of SnNCa3 and PNCa3 compounds with a cubic antiperovskitestructure are studied by employing an ab initio pseudopotential method and a linear-response technique within a generalized gradient approximation (GGA) of the density-functional theory (DFT) scheme. The calculated structural properties, lattice constants, bulk modulus and its pressure derivatives are in good agreement with available experimental and theoretical results. The calculations of the elastic constants have been

used

to

calculate

C11,

C12,

and

C44

for

SnNCa3

and

PNCa3.

Thesecalculatedelasticconstantssatisfythemechanicalstabilitycriterion, andtheductility of SnNCa3 and PNCa3 is predictedbyPugh’scriterion. The electronic band structures show that SnNCa3 compound has metallic character while PNCa3 is direct band gap semiconductor. The phonon-dispersion curves and phonon total and partial density of states based on the linear-response method have been investigated for both materials.Thephonon spectra

of

SnNCa3

and

PNCa3

indicatethatthesecompoundsare

not

dynamicallystable,

thereareimaginaryphononfrequenciesalongthe M-R and G-X forSnNCa3 and PNCa3, respectively. REFERENCES [1] K. Haddadi, A. Bouhemadou, L. Louail, Y. Medkour, Solid State Communications 149 619-624 (2009). [2] K. Haddadi, A. Bouhemadou, L. Louail, S. Maabed, D. Maouche, PhysicsLetters A, 373 1777–1781 (2009). [3] M. Bilal, I. Ahmad, S.J. Asadabadi, R. Ahmad, and M. Maqbool, Electron. Mater. Lett., 11 466-480 (2015). [4] P. R. Vansant, P.E. Van Camp, V.E. Van Doren, and J.L. Martins, Phys. Rev. B 57 7615 (1998).

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as



OR-33

The Trace Elements (Selenium, Copper, Zink, Iron) Levels in Patients Sera Affected by Bovine Ephemeral Fever 1

2

3

4

5

6

Hikmet Ün , Guzin Camkerten , Ilker Camkerten , Tekin Sahin , Burcu M. Balkan , Özcan Erel , 1



Aksaray University, Faculty of Veterinary Medicine, Dept. of Virology, Aksaray- Turkey 3 Aksaray University, Faculty of Veterinary Medicine, Dept. of Biochemistry, Aksaray-Turkey Aksaray University, Faculty of Veterinary Medicine, Dept. of Internal Medicine, Aksaray- Turkey 4 Bingöl University, Faculty of Veterinary Medicine, Dept. of Internal Medicine, Bingol -Turkey 5 Mehmet Akif Ersoy University, Faculty of Veterinary Medicine, Dept. of Biochemistry Burdur-Turkey 6 Yıldırım Beyazıt University, Faculty of Health, Department of Biochemistry, Ankara- Turkey [email protected] Abstract: Bovine ephemeral fever (BEF) transmitted by vectors and observed seasonal, is a disease of cattle and buffalo. The disease is an arboviral infection that observed in the tropic and sub-tropic zone of Asia, Australia, Middle East and Africa. The epidemics occur due to excessive population growth of the culicine and anopheline biting flies. The agent is a virus carrying the same name which is located in the Rhabdoviridae family, genus Ephemerovirus. It has got an economic importance due to the temporary or permanent loss of milk production during disease. The disease is characterized by high fever (40-41.5 ° C), muscle stiffness, incoordination, lameness, muscle tremors, severe respiratory distress oedema and swelling of the lymph nodes under the skin. It is known to be characteristic changes in biochemical and haematologic parameters in the affected animals. Starting from this point, it was aimed to determine the serum levels of trace elements (Selenium, Copper, Zink, Iron) in this study. The trace element levels were determined in the control group consisted of healthy animals (n = 15) and patients (n = 17), and recovering from illness (n = 17) and results were compared with the control group.Compared with the control group, statistically significant differences in serum selenium and iron levels (p