Application of Mie theory and fractal models to ...

7 downloads 0 Views 1MB Size Report
Jul 4, 2017 - Department of Physics, Motilal Nehru National Institute of Technology, Allahabad, UP 211004,. India. 3. Department of Physics, University of ...

See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/317599071

Application of Mie theory and fractal models to determine the optical and surface roughness of Ag–Cu thin films Article in Optical and Quantum Electronics · June 2017 DOI: 10.1007/s11082-017-1079-3

CITATIONS

READS

0

39

14 authors, including: Ştefan Ţălu

Amine ACHOUR

Universitatea Tehnica Cluj-Napoca

Laboratoire d’Analyse et d’Architecture des S…

349 PUBLICATIONS 817 CITATIONS

36 PUBLICATIONS 216 CITATIONS

SEE PROFILE

SEE PROFILE

Carlos Luna

Gabriel Trejo

Autonomous University of Nuevo León

Centro De Investigación Y Desarrollo Tecnoló…

68 PUBLICATIONS 604 CITATIONS

58 PUBLICATIONS 814 CITATIONS

SEE PROFILE

SEE PROFILE

Some of the authors of this publication are also working on these related projects:

Structural, optical and thermal properties of silver colloidal nanoparticles View project

Engineering magnetic nanowires for green technologies View project

All content following this page was uploaded by Shahram Solaymani on 04 July 2017.

The user has requested enhancement of the downloaded file.

Opt Quant Electron (2017)49:256 DOI 10.1007/s11082-017-1079-3

Application of Mie theory and fractal models to determine the optical and surface roughness of Ag–Cu thin films Ștefan Țălu1 · Ram Pratap Yadav2 · Ashok Kumar Mittal3 · Amine Achour4 · Carlos Luna5 · Mohsen Mardani6 · Shahram Solaymani7 · Ali Arman6 · Fatemeh Hafezi6 · Azin Ahmadpourian8 · Sirvan Naderi9 · Khalil Saghi6 · Alia Méndez10 · Gabriel Trejo11

Received: 22 March 2017 / Accepted: 12 June 2017 © Springer Science+Business Media, LLC 2017

Abstract Thin films of Ag/Cu were deposited by reactive DC magnetron sputtering on (001)-oriented Si and glass substrates for various deposition times (4–24 min). These films were characterized by atomic force microscopy (AFM), and a power law scaling was performed on the obtained micrographs to investigate the self-affine nature of the sample morphology, which is indicative of a fractal structure. We applied the Higuchi’s algorithm to the AFM data to determine the fractal dimension of each sample, and the Hurst exponents were computed. The deposition time dependences of these parameters and the grain size distributions estimated from the UV–visible spectra using the Mie theory, & Ali Arman [email protected] 1

Discipline of Descriptive Geometry and Engineering Graphics, Department of AET, Faculty of Mechanical Engineering, Technical University of Cluj-Napoca, 103-105 B-dul Muncii St., 400641 Cluj-Napoca, Romania

2

Department of Physics, Motilal Nehru National Institute of Technology, Allahabad, UP 211004, India

3

Department of Physics, University of Allahabad, Allahabad, UP 211002, India

4

Institut National de la Recherche Scientifique (INRS), 1650 Boulevard Lionel-Boulet, Varennes, QC J3X 1P7, Canada

5

Facultad de Ciencias Fı´sico Matema´ticas, Universidad Auto´noma de Nuevo Leo´n, Av. Universidad s/n, San Nicola´s de los Garza, Nuevo Leo´n 66455, Mexico

6

Vacuum Technology Group, ACECR, Sharif Branch, Tehran, Iran

7

Department of Physics, Science and Research Branch, Islamic Azad University, Tehran, Iran

8

Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran

9

Young Researchers and Elite Club, Kermanshah Branch, Islamic Azad University, Kermanshah, Iran

10

Centro de Quı´mica-ICUAP Beneme´rita Universidad Auto´noma de Puebla, Ciudad Universitaria Puebla, Puebla 72530, Mexico

11

Center of Research and Technological Development in Electrochemistry (CIDETEQ), Parque Tecnolo´gico Sanfandila, A.P. 064, Pedro Escobedo C.P. 76703, Quere´taro, Mexico

123

256 Page 2 of 15

Ș. Țălu et al.

allowed us to describe a particle formation mechanism during the deposition process, in which the length of continuous paths of conductive particles increases as the deposition time is increased. In agreement with this explanation, the electrical resistance decreased with the increment of the deposition time. Keywords Ag–Cu thin films · AFM · Fractal analysis · Surface topography

1 Introduction The remarkable progress in the research fields related to low dimensional materials have allowed the exploration of new physical phenomena and have opened up promising avenues to develop astonishing and innovative technologies (Ferrari et al. 2015; Lhuillier et al. 2015; Jariwala et al. 2014); giant magnetoresistance (Yuasa et al. 2004; Ghodselahi and Arman 2015), emission of spin waves (Berger 1996), new sources of magnetic anisotropy (Skumryev et al. 2003), superparamagnetism and its combination with luminescent properties (Evans et al. 2010), engineered photocatalytic activities (Oveisi et al. 2010; Ouldhamadouche et al. 2017) and the surface enhanced Raman scattering effect (Bader and Parkin 2010) are only few examples of the astonishing physicochemical behaviors uniquely related to these materials. Such phenomena display a great potential in a variety of technological applications such as spintronics (Bader and Parkin 2010), sensor technologies (Stewart et al. 2008), energy storage (Achour et al. 2017), environmental remediation (Mohamed and Salam 2014) and nanomedicine (Luna et al. 2015; Nafiujjaman et al. 2015). Confinement and surface effects arising from the nanometer-scale dimensions govern the unique properties of low dimensional materials (Luo et al. 2013; T¸a˘lu 2015; Luna et al. 2016); consequently, descriptive parameterizations are required for the accurately quantification of the material dimensions and surface topography. Specifically, the comprehensive description of the surface roughness of these materials is an intriguing and crucial challenge necessary for the understanding of their properties and their potential technological exploitation (T¸a˘lu et al. 2014). Atomic force microscopy (AFM) represents an outstanding imaging tool for the examination and analysis of nanostructures and surfaces (T¸a˘lu et al. 2014, 2015, 2016), especially in thin films deposited by sputtering techniques (Kalb et al. 2004; Gelali et al. 2012; Stach et al. 2015; Arman et al. 2015). The three-dimensional (3D) surface topography of these materials can be engineered controlling the deposition variables, such as the deposition time (Ahmadpourian et al. 2016), DC power (Ghobadi et al. 2016a), deposition pressure (Assuncao et al. 2003; Molamohammadi et al. 2015) and substrate temperature (Ghobadi et al. 2016b), among others, and its study by AFM have generated crucial information about the nature of surfaces (Reyes-Vidal et al. 2015; Stach et al. 2017; Elenkova et al. 2015). In this regards, it has been pointed out that surfaces are not generally random or stationary processes due to surface parameters depend on the scan length and on the measuring instrument (Molamohammadi et al. 2015; Ramazanov et al. 2015; Arman et al. 2015). In consequence, new models for surface roughness measure have been proposed to determine its properties at all scales using scale-independent parameters. In this regards,

123

Application of Mie theory and Fractal models to determine…

Page 3 of 15 256

several recent studies have shown that natural and fabricated surfaces display self-affine features, therefore their topography can be described using scale-independent parameters by fractal (T¸a˘lu et al. 2014, 2015a, b, 2016a, b; Stach et al. 2015; Arman et al. 2015; Me´ndez et al. 2015; Singh et al. 2016; Yadav et al. 2012, 2014a, b, 2015a, b) or multifractal (T¸a˘lu et al. 2014, 2015; Yadav et al. 2012, 2014, 2015) analyses of the AFM images. Fractal analysis provides surface information different from traditional analysis, and it helps to understand the nature of the surface geometry (Yadav et al. 2015). The physical properties of the system are affected by it; hence, fractal approaches are appropriate tools to determine the complexity and irregularity of thin films (Yadav et al. 2012, 2014a, b, 2015a, b; Singh et al. 2016) and understanding surface morphology(Singh et al. 2016; Yadav et al. 2012, 2014). In the present study, the 3D surface morphology of Ag/Cu thin films synthesized by direct-current magnetron sputtering varying the deposition time from 4 to 24 min have been investigated by AFM imaging, and a fractal approach has been implemented for the analysis of the obtained 3D AFM images. In addition, the UV–visible absorption and the electrical resistance of these samples have been studied as functions of the deposition time and the complexity/irregularity of the samples.

2 Experimental procedure 2.1 Cleaning of the thin film supports Prior to thin film deposition and in order to avoid any contamination of surfaces, glass and silicon substrates (1 cm 9 1 cm in dimensions) were carefully washed with soap and water, followed by ultra-sonication during 5 min in acetone without heating. After washing the silicon and glass substrates, they were dried using a nitrogen gun.

2.2 Preparation of sample deposition Thin films of Ag/Cu were deposited by reactive DC magnetron sputtering on (001)oriented Si and glass substrates using a silver/copper target with 99.99% purity. The silver/copper atomic ratio of the target was equal to 0.639, as it was confirmed by the energy-dispersive X-ray spectroscopy analysis shown in reference Ahmadpourian et al. (2016). The deposition chamber was equipped by two (rotary) mechanical pumps that achieved a pressure of 10−3 torr, and another turbo (diffusion) pump that achieved a base pressure of 10−5 torr. The distance between the target and substrate holder was fixed at 5 cm. The thin films were deposited at constant power of 20 W without intentional heating. The deposition time was varied from 4 to 24 min with a time step of 4 min. Table 1 summarizes the experimental parameters used during film deposition.

2.3 Sample characterization The nanostructured surface morphology of the films was investigated by tapping mode (TM) atomic force microscopy (AFM). The average grain size and the surface roughness of each sample were determined from the corresponding AFM data using the WSxM software (version 5.0). The optical properties of layers were studied using UV–visible spectroscopy

123

Ș. Țălu et al.

256 Page 4 of 15

Table 1 Interface width (w), grain size, Hurst exponent (H), Fractal dimension (Df) and electrical resistance of sputtered Ag–Cu thin films deposited at different times Deposition time (min)

Interface width (w) nm

Grain size [nm]

Fractal dimension (Df)

Hurst exponent (H)

Resistance (Ω)

4

1.57

19.29

1.44 ± 0.05

0.56 ± 0.05

4000

8

2.65

44.37

1.28 ± 0.05

0.72 ± 0.05

500

12

2.84

47.23

1.50 ± 0.05

0.50 ± 0.05

160

16

2.27

54.26

1.51 ± 0.04

0.49 ± 0.04

115

20

1.62

36.85

1.48 ± 0.05

0.52 ± 0.05

80

24

1.60

47.43

1.26 ± 0.05

0.75 ± 0.05

40

and the particle size distribution was calculated from the obtained spectra using the Mie theory and compared with AFM results (Bohren and Huffman 1998; Naderi et al. 2012; Dalouji et al. 2016; Balan et al. 2007; Christian and O’Reilly 1986).

2.4 Mie theory The absorption cross section obtained from Mie theory using the dipole Plasmon approximation for spherical particles is given by the following expression (Bohren and Huffman 1998; Naderi et al. 2012): ( ) 18pVe3=2 e00 m ð1Þ Qabs ðkÞ ¼ k ðe0 þ 2em Þ2 þ e002 where V is the volume of the spherical particles, λ is the radiation wavelength, em is the medium dielectric constant, and e0 is the real part of the dielectric function. When the denominator reaches its minimum, i.e. e0 ¼ 2em , resonant conditions are satisfied and the absorption reaches its maximum value. The imaginary part of the dielectric function e00 is: (Naderi et al. 2012; Dalouji et al. 2016; Balan et al. 2007) e00 ðx; ri Þ ¼ e00bulk þ

3x2p vF 4x3 ri

ð2Þ

where νF is the Fermi velocity and ωp is the Plasmon frequency. The Plasmon frequency of metallic nanoparticles is: xp;b xp ¼ pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi 1 þ 2em

ð3Þ

where xp;b is the volume plasmon frequency (Balan et al. 2007; Christian and O’Reilly 1986). The particle size distribution was calculated from the experimental absorption spectrum by fitting the absorption cross section obtained from Mie theory with the experimental absorption spectrum of Ag/Cu samples (Ahmadpourian et al. 2016).

123

Application of Mie theory and Fractal models to determine…

Page 5 of 15 256

3 Methods 3.1 Surface roughness A random rough surface can be described mathematically as h(i, j), where h(i, j) is the rough surface height distribution at point (i, j). For the rough surfaces, we assume that the height fluctuation is a random field with respect to the position. Root mean square (RMS) roughness is one of the most important parameters needed to characterize such surface. Analytically, it can be estimated as: (Yadav et al. 2015) 2 L L 312 Z Z 1 ð4Þ wL ¼ 4 fhði; jÞ  hhði; jÞigdxdy5 L 0

0

where L is the length of the measure surface and hhði; jÞi is the average surface height that it can be analytically expressed as: (Yadav et al. 2015) 1 hhði; jÞi ¼ 2 L

ZL Z L hði; jÞdxdy 0

ð5Þ

0

These parameters are real and impose certain restrictions on the mathematical description of the random rough surface. An accurate estimation is important to understand the surface roughness because it provides the basic information about the surface texture. Our knowledge of surface roughness depends on the range of measurement and the instrumental resolution. On the other hand, the concept of fractal is very useful for describing rough surfaces. The idea of the fractal geometry is closely associated with the properties of invariance under a change of scale. The simplest fractal object is a selfsimilar object that is invariant under similarity transformations.

3.2 Higuchi’s Fractal dimension Higuchi’s algorithm (Higuchi 1988) computes the fractal dimension of a vertical section of the surface from the discrete height data that is obtained by AFM, for example. The height data of the vertical section can be denoted by X (1), X (2)…X (N). The Higuchi’s algorithm constructs sub-sequences: (Higuchi 1988) Xkm : XðmÞ; Xðm þ kÞ; Xðm þ 2kÞ. . .Xðm þ pkÞ   ðN  MÞ for m ¼ 1; 2; 3. . .k; where p ¼ int k The ‘length’ Lm(k) of each segment Xmk is then calculated as: ( ) ! p X N1 =k Lm ðkÞ ¼ jXðm þ ikÞ  Xðm þ ði  1ÞkÞj pk i¼1

ð6Þ ð7Þ

ð8Þ

where N is the total number of sample points and N1 pk denotes the normalization constant. Lm(k) is not a ‘length’ in Euclidean sense. It represents the normalize sum of absolute values of difference in pair of points at distance k with initial point m.

123

Ș. Țălu et al.

256 Page 6 of 15

Therefore the length of curve is given by: Pk Lm ðkÞ LðkÞ ¼ m¼1 k

ð9Þ

Higuchi’s algorithm for determining the fractal dimension is based on how the length L (k) of the curve, which represents the series of k samples as a unit, scales with k as: L ðkÞ  K Df

ð10Þ

where Df is the fractal dimension and characterizes the complexity/irregularity of the surface. Df is calculated by the least square linear best fit procedure in the linear regression of the log–log representation using Eq. (10): y ¼ ax þ b with a = Df according to following relation: P P P n ðxk yk Þ  xk yk Df ¼ P P n ðx2k Þ  n ðxk Þ2

ð11Þ

ð12Þ

where yk ¼ ln L ðkÞ; xk ¼ ln k, k = k1,k2,………kmax and n denotes the number of k values for which the linear regression is calculated. The standard deviation of Df is estimated as: sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi P P P ffi xk yk  b yk n y2k  Df  P P 2  SDf ¼ ð13Þ xk ðn  2Þ n x2k  P P here b ¼ 1n ð yk  Df xk Þ with standard deviation rffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi X 1 S Df x2k Sb ¼ ð14Þ n Finally, we computed the Hurst exponent from the fractal dimension using the relation (Yadav et al. 2015) H ¼ 2  Df

ð15Þ

4 Results and discussion Figure 1 depicts the UV–visible absorption spectra of the six studied samples and the best fitted curves using Eq. (1). The particle size distributions obtained from these fittings are shown in Fig. 2. From AFM images (Fig. 3), the average particle diameters obtained for the samples 1–6 are 19.29, 44.37, 47.23, 54.26, 36.85 and 47.43 nm, respectively (Table 1). We observe that the particle size distributions obtained from the fitting of the UV– visible absorption are in good agreement with the AFM results for samples 1–5. However, for sample 6 the average diameter calculated from the optical properties is about 5 times smaller than the value determined by AFM. This difference is probably due to the limitations of the AFM lateral resolution to study nanoparticles of few nanometers in size.

123

Application of Mie theory and Fractal models to determine…

Page 7 of 15 256

Fig. 1 UV–visible spectra of the six studied samples (dots) and the corresponding fitting curves (solid lines) obtained using the dipole Plasmon approximation model

Figure 3 shows AFM images of Ag/Cu thin films deposited by reactive DC magnetron sputtering on (001)-oriented Si and glass substrates at different deposition time (4, 8, 12, 16, 20 and 24 min respectively). These images indicate that the surface structures and surface roughness of samples are significantly modified when the deposition time is varied. We notice that granules of various sizes, irregular shapes and separations are present in the films. The values of interface width (w) of thin films were measured using the method described in Sect. 3.1. The obtained values are summarized in Table 1. From this table, it can be seen that the surface roughness of the films does not vary monotonically with increasing deposition

123

256 Page 8 of 15

Ș. Țălu et al.

Fig. 2 Particle size distributions estimated from the fits of Eq. (1) to the UV–visible spectra

time: it increases for deposition times from 4 to 12 min and then, it decreases for larger deposition times, being the film obtained after a deposition time equal to 12 min the film with greater roughness. This tendency can be explained as follows. During the first minutes of deposition, grains and inter-grain valleys appear. Then, at larger deposition times, the valleys are filled and the surface roughness is reduced. Afterwards, the progressive agglomeration of particles and the formation of new islands yield to the increment of the surface roughness (Yadav et al. 2012).

123

Application of Mie theory and Fractal models to determine…

Page 9 of 15 256

Fig. 3 AFM images of Ag/Cu thin films deposited by reactive DC magnetron sputtering on (001)-oriented Si and glass substrates at different deposition time: 4, 8, 12, 16, 20 and 24 min, respectively

In addition, it is important to highlight the evolution of the grown crystalline phases during the deposition process. X-ray diffraction (XRD) studies of these Ag/Cu thin films, carried out in a previous work (Kalb et al. 2004), reveal a complex evolution of the crystallized phases as the deposition time is increased. XRD results showed that the Ag and Cu tend to grow as separated phases with nanometric sizes due to the immiscible character of these elements, and the Cu appeared partially oxidized. However, samples prepared with low deposition times (specifically, 4 and 8 min) presented additional face centered cubic nanocrystals with a preferable crystallization orientation along the [111] direction. Interface width (w) only characterizes the large-scale properties of the surface height fluctuations and it is only sensitive to peak values of surface profile (Singh et al. 2016; Yadav et al. 2012, 2014) . Also, it provides only vertical information and misses out important characteristics of the surface profile. Thin film evolution under non-equilibrium conditions is expected to produce a selfaffine surface following a power law scaling (Lhuillier et al. 2015; Yadav et al. 2012, 2014a, b, 2015; Singh et al. 2016) .These characteristics are investigated using fractal analysis that gives the information about irregularity/complexity of a surface (Singh et al. 2016; Yadav et al. 2012, 2014a, b) . For this reason fractal analysis is highly needed for thin films surface assessment. In order to distinguish the microstructure of Ag/Cu thin films surfaces for various deposition times, we estimated the fractal dimension and Hurst exponents from the AFM images. For this purpose the method described in Sect. 3.2 is applied to the height data of 256 linear traces in fast scan.

123

256 Page 10 of 15

Ș. Țălu et al.

Fig. 4 log L(k) as function of log k The red solid line is the best-fit curve, whose slope gives the value of fractal dimension. (Color figure online)

A graph is plotted between the average value of curve length L(k) and k at double logarithmic scale. Figure 4 depicts the plot between L(k) and k at double logarithmic scale for the film deposited during 4 min. The curves for the rest of the films are not shown here. The solid red line corresponds to the least square fit to the data, whose slope gives the value of fractal dimension (Df). The average value of Df for each film gives an idea about the change of surface morphology (Table 1). A larger value of Df corresponds to a more jagged morphological structure, while smaller one indicates a smoother structure (Yadav et al. 2015). The measure values of Df versus pixels for each thin film deposited for various time is shown in Fig. 5. The Hurst exponent (H) of each surface is computed by Eq. (12). The plot between H versus pixels for each surface is depicted in Fig. 6, and the average value of H for each thin film is listed in Table 1. Values of H varying between 0 \ H \ 1 illustrate the fractal characteristics of the system (Yadav et al. 2015). From this data, we observe that H lies between 0.5 and 1 for all samples. The greater fractal dimension and lower Hurst exponent value is obtained for the thin film deposition time of 16 min. Values H [ 0.5 indicate that a long-term memory effect occurs during deposition and a persistence behavior exists. Average fractal dimension, average Hurst exponent and electrical resistance are plotted as a function of deposition time in Fig. 7. The average fractal dimension and the average Hurst exponent exhibit a non-monotonic dependence on deposition time probably due to the complex above-discussed growth mechanism of the films. Also, from this figure it is observed that the electrical resistance decreases as the deposition time increases. The thin film with deposition time of 4 min has the highest electrical resistance, which is around 4000 Ω, and it gradually decreases with the increment of the deposition time. This may be due to the fact that size of particles increases with increasing deposition time; thus, the contact between particles is more frequent for larger deposition times. It yields to the formation of continuous paths of conductive particles, and in consequence, the electrical resistance is reduced.

123

Application of Mie theory and Fractal models to determine…

Page 11 of 15 256

Fig. 5 Fractal dimensions as a function of the analyzed linear traces (256) for each film prepared at different deposition time

Fig. 6 Hurst exponents for different horizontal sections of each thin film surface profile

5 Conclusions A fractal approach has been performed to investigate the complexity and irregularity of Ag/Cu thin films deposited by reactive DC magnetron sputtering at different deposition time (from 4 to 24 min). The found describing parameters were estimated and correlated with the deposition time. Also, optical and electrical properties were measured.

123

256 Page 12 of 15

Ș. Țălu et al.

Fig. 7 Fractal dimension, Df (upper panel), Hurst exponent, H (middle panel) and electrical resistance, Ω (lower panel) graph for sputtered Ag–Cu thin films deposited at different times

It was found that the interface width exhibited a maximum for a deposition time of 12 min, and the fractal dimension computed using the Higuchi´s algorithm and Hurst exponent exhibited complex non-monotonic dependences on the deposition time. These behaviors have been explained with the initial occurrence of inter-grain valleys at the first minutes of deposition, and their subsequent filling and particle agglomeration produced at larger deposition times. In agreement with this hypothesis, the electrical resistance decreased as the deposition time increased, suggesting the increment of the contacts between particles as the deposition time increases. On the other hand, the UV–visible spectra were measured and analyzed using the Mie theory with the dipole Plasmon approximation, obtaining particle size distributions in agreement with the AFM observations with the exception of the sample obtained at largest deposition time, probably due to limitations of the AFM lateral resolution to study nanoparticles of few nanometers in size. Funding Neither author has a financial or proprietary interest in any material or method mentioned. Compliance with ethical standards Conflict of interest The authors declare that they have no competing interests.

References Achour, A., Lucio-Porto, R., Chaker, M., Arman, A., Ahmadpourian, A., Soussou, M.A., Boujtita, M., Le Brizoual, L., Djouadi, M.A., Brousse, T.: Titanium vanadium nitride electrode for micro-supercapacitors. Electrochem. Commun. 77, 40–43 (2017) Ahmadpourian, A., Luna, C., Boochani, A., Arman, A., Achour, A., Rezaee, S., Naderi, S.: The effects of deposition time on surface morphology, structural, electrical and optical properties of sputtered Ag–Cu thin films. Eur. Phys. J. Plus 131(10), 381 (2016)

123

Application of Mie theory and Fractal models to determine…

Page 13 of 15 256

Arman, A., Ghodselahi, T., Molamohammadi, M., Solaymani, S., Zahrabi, H., Ahmadpourian, A.: Microstructure and optical properties of [email protected] Ni nanoparticles embedded in aC: H. Prot. Met. Phys. Chem. Surf. 51(4), 575–578 (2015a) Arman, A., T¸a˘lu, S¸., Luna, C., Ahmadpourian, A., Naseri, M., Molamohammadi, M.: Micromorphology characterization of copper thin films by AFM and fractal analysis. J. Mater. Sci. Mater. Electron. 26 (12), 9630–9639 (2015b) Assuncao, V., Fortunato, E., Marques, A., Aguas, H., Ferreira, I., Costa, M.E.V., Martins, R.: Influence of the deposition pressure on the properties of transparent and conductive ZnO: Ga thin-film produced by rf sputtering at room temperature. Thin Solid Films 427(1), 401–405 (2003) Bader, S.D., Parkin, S.S.P.: Spintronics. Annu. Rev. Condens. Matter Phys. 1(1), 71–88 (2010) Balan, L., Malval, J., Schneider, R., Burget, D.: Silver nanoparticles: new synthesis, characterization and photophysical properties. J. Mater. Chem. Phys. 104(2, 3), 417–421 (2007) Berger, L.: Emission of spin waves by a magnetic multilayer traversed by a current. Phys. Rev. B 54(13), 9353 (1996) Bohren, C.F., Huffman, D.R.: Absorption and Scattering of Light by Small Particles. John Wiley and Sons, Chichester (1998) Christian, G.D., O’Reilly, J.E.: Instrumental Analysis. Prentice-Hall, New Jersey (1986) Dalouji, V., Elahi, S.M., Naderi, S.: Surface plasmon resonance and electrical properties of RF: magnetron sputtered carbon–nickel composite films at different annealing temperatures. Rare Met. 35(11), 863– 869 (2016) Elenkova, D., Zaharieva, J., Getsova, M., Manolov, I., Milanova, M., Stach, S., T¸a˘lu, S¸.: Morphology and optical properties of SiO2-based composite thin films with immobilized terbium(III) complex with a biscoumarin derivative. Int. J. Polym. Anal. Charact. 20(1), 42–56 (2015) Evans, C.W., Raston, C.L., Iyer, K.S.: Nanosized luminescent superparamagnetic hybrids. Green Chem. 12 (7), 1175–1179 (2010) Ferrari, A.C., Bonaccorso, F., Fal’Ko, V., Novoselov, K.S., Roche, S., Bøggild, P., Garrido, J.A.: Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems. Nanoscale 7(11), 4598–4810 (2015) Gelali, A., Ahmadpourian, A., Bavadi, R., Hantehzadeh, M.R., Ahmadpourian, A.: Characterization of microroughness parameters in titanium nitride thin films grown by DC magnetron sputtering. J. Fusion Energy 31(6), 586–590 (2012) Ghobadi, N., Ganji, M., Luna, C., Ahmadpourian, A., Arman, A.: The effects of DC power on the physical properties and surface topography of sputtered TiN nanostructured thin films. Opt. Quantum Electron. 48(10), 467 (2016a) Ghobadi, N., Ganji, M., Luna, C., Arman, A., Ahmadpourian, A.: Effects of substrate temperature on the properties of sputtered TiN thin films. J. Mater. Sci. Mater. Electron. 27(3), 2800–2808 (2016b) Ghodselahi, T., Arman, A.: Magnetoresistance of Cu–Ni nanoparticles in hydrogenated amorphous carbon thin films. J. Mater. Sci. Mater. Electron. 26(6), 4193–4197 (2015) Higuchi, T.: Approach to an irregular time series on the basis of the fractal theory. Phys. D 31(2), 277–283 (1988) Jariwala, D., Sangwan, V.K., Lauhon, L.J., Marks, T.J., Hersam, M.C.: Emerging device applications for semiconducting two-dimensional transition metal dichalcogenides. ACS Nano 8(2), 1102–1120 (2014) Kalb, J., Spaepen, F., Wuttig, M.: Atomic force microscopy measurements of crystal nucleation and growth rates in thin films of amorphous Te alloys. Appl. Phys. Lett. 84(25), 5240–5242 (2004) Lhuillier, E., Pedetti, S., Ithurria, S., Nadal, B., Heuclin, H., Dubertret, B.: Two-dimensional colloidal metal chalcogenides semiconductors: synthesis, spectroscopy, and applications. Acc. Chem. Res. 48(1), 22– 30 (2015) Luna, C., Ortega, S.V., Barriga-Castro, E.D., Mendoza-Rese´ndez, R., Go´mez-Trevin˜o, A.: Synthesis, characterization, and magnetically guided antiproliferative activity studies of drug-loaded superparamagnetic nanovectors. J. Appl. Phys. 117(17), 174308 (2015) Luna, C., Cuan-Guerra, A.D., Barriga-Castro, E.D., Nu´n˜ez, N.O., Mendoza-Rese´ndez, R.: Confinement and surface effects on the physical properties of rhombohedral-shape hematite (α-Fe2O3) nanocrystals. Mater. Res. Bull. 80, 44–52 (2016) Luo, X., Zhao, Y., Zhang, J., Xiong, Q., Quek, S.Y.: Anomalous frequency trends in MoS2 thin films attributed to surface effects. Phys. Rev. B 88(7), 075320 (2013) Me´ndez, A., Reyes, Y., Trejo, G., Ste˛pien´, K., T¸a˘lu, S¸.: Micromorphological characterization of zinc/silver particle composite coatings. Microsc. Res. Tech. 78, 1082–1089 (2015). doi:10.1002/jemt.22588 Mohamed, R.M., Salam, M.A.: Photocatalytic reduction of aqueous mercury (II) using multi-walled carbon nanotubes/Pd–ZnO nanocomposite. Mater. Res. Bull. 50, 85–90 (2014)

123

256 Page 14 of 15

Ș. Țălu et al.

Molamohammadi, M., Arman, A., Achour, A., Astinchap, B., Ahmadpourian, A., Boochani, A., Naderi, S., Ahmadpourian, A.: Microstructure and optical properties of cobalt–carbon nanocomposites prepared by RF-sputtering. J. Mater. Sci. Mater. Electron. 26(8), 5964–5969 (2015a) Molamohammadi, M., Luna, C., Arman, A., Solaymani, S., Boochani, A., Ahmadpourian, A., Shafiekhani, A.: Preparation and magnetoresistance behavior of nickel nanoparticles embedded in hydrogenated carbon film. J. Mater. Sci. Mater. Electron. 26(9), 6814–6818 (2015b) Naderi, S., Ghaderi, A., Solaymani, S., Golzan, M.M.: Structural, optical and thermal properties of silver colloidal nanoparticles. Eur. Phys. J. Appl. Phys. 58(2), 20401 (2012) Nafiujjaman, M., Revuri, V., Nurunnabi, M., Cho, K.J., Lee, Y.: Photosensitizer conjugated iron oxide nanoparticles for simultaneous in vitro magneto-fluorescent imaging guided photodynamic therapy. Chem. Commun. 51(26), 5687–5690 (2015) Ouldhamadouche, N., Achour, A., Ait Aissa, K., Islam, M., Ahmadpourian, A., Arman, A., Soussou, M.A., Chaker, M., Le Brizoual, L., Djouadi, M.A.: AlN film thickness effect on photoluminescence properties of AlN/carbon nanotubes shell/core nanostructures for deep ultra-violet optoelectronic devices. Thin Solid Films 622, 23–28 (2017) Oveisi, H., Suzuki, N., Beitollahi, A., Yamauchi, Y.: Aerosol-assisted fabrication of mesoporous titania spheres with crystallized anatase structures and investigation of their photocatalitic properties. J. SolGel Sci. Technol. 56(2), 212–218 (2010) Ramazanov, S., T¸a˘lu, S¸., Sobola, D., Stach, S., Ramazanov, G.: Epitaxy of silicon carbide on silicon: micromorphological analysis of growth surface evolution. Superlattices Microstruct. 86, 395–402 (2015). doi:10.1016/j.spmi.2015.08.007 Reyes-Vidal, Y., Suarez-Rojas, R., Ruiz, C., Torres, J., T¸a˘lu, S¸., Me´ndez, A., Trejo, G.: Electrodeposition, characterization, and antibacterial activity of zinc/silver particle composite coatings. Appl. Surf. Sci. 342, 34–41 (2015) Singh, U.B., Yadav, R.P., Pandey, R.K., Agarwal, D.C., Pannu, C., Mittal, A.K.: Insight mechanisms of surface structuring and wettability of ion-treated Ag thin films. J. Phys. Chem. C 120(10), 5755–5763 (2016) Skumryev, V., Stoyanov, S., Zhang, Y., Hadjipanayis, G., Givord, D., Nogue´s, J.: Beating the superparamagnetic limit with exchange bias. Nature 423(6942), 850–853 (2003) Stach, S., Dallaeva, D., T¸a˘lu, S¸., Kaspar, P., Toma´nek, P., Giovanzana, S., Grmela, L.: Morphological features in aluminum nitride epilayers prepared by magnetron sputtering. Mater. Sci. Pol. 33(1), 175– 184 (2015). doi:10.1515/msp-2015-0036 Stach, S., Sapota, W., T¸a˘lu, S¸., Ahmadpourian, A., Luna, C., Ghobadi, N., Arman, A., Ganji, M.: 3-D surface stereometry studies of sputtered TiN thin films obtained at different substrate temperatures. J. Mater. Sci. Mater. Electron. 28(2), 2113–2122 (2017) Stewart, M.E., Anderton, C.R., Thompson, L.B., Maria, J., Gray, S.K., Rogers, J.A., Nuzzo, R.G.: Nanostructured plasmonic sensors. Chem. Rev. 108(2), 494–521 (2008) T¸a˘lu, S¸.: Micro and Nanoscale Characterization of Three Dimensional Surfaces. Basics and Applications. Napoca Star Publishing House, Cluj-Napoca (2015) T¸a˘lu, S¸., Stach, S., Zaharieva, J., Milanova, M., Todorovsky, D., Giovanzana, S.: Surface roughness characterization of poly(methylmethacrylate) films with immobilized Eu(III) β-Diketonates by fractal analysis. Int. J. Polym. Anal. Charact. 19(5), 404–421 (2014a) T¸a˘lu, S¸., Stach, S., Me´ndez, A., Trejo, G., T¸a˘lu, M.: Multifractal characterization of nanostructure surfaces of electrodeposited Ni–P coatings. J. Electrochem. Soc. 161(1), D44–D47 (2014b) T¸a˘lu, S¸., Stach, S., Raoufi, D., Hosseinpanahi, F.: Film thickness efect on fractality of tin-doped In2O3 thin films. Electron. Mater. Lett. 11(5), 749–757 (2015a). doi:10.1007/s13391-015-4280-1 T¸a˘lu, S¸., Stach, S., Valedbagi, S., Bavadi, R., Elahi, S.M., T¸a˘lu, M.: Multifractal characteristics of titanium nitride thin films. Mater. Sci. Pol. 33(3), 541–548 (2015b). doi:10.1515/msp-2015-0086 T¸a˘lu, S¸., Bramowicz, M., Kulesza, S., Solaymani, S., Shafikhani, A., Ghaderi, A., Ahmadirad, M.: Gold nanoparticles embedded in carbon film: micromorphology analysis. J. Ind. Eng. Chem. 35, 158–166 (2016a). doi:10.1016/j.jiec.2015.12.029 T¸a˘lu, S¸., Luna, C., Ahmadpourian, A., Achour, A., Arman, A., Naderi, S., Ghobadi, N., Stach, S., Safibonab, B.: Micromorphology and fractal analysis of nickel–carbon composite thin films. J. Mater. Sci. Mater. Electron. 27(11), 11425–11431 (2016b) Yadav, R.P., Dwivedi, S., Mittal, A.K., Kumar, M., Pandey, A.C.: Fractal and multifractal analysis of LiF thin film surface. Appl. Surf. Sci. 261, 547–553 (2012) Yadav, R.P., Kumar, M., Mittal, A.K., Dwivedi, S., Pandey, A.C.: On the scaling law analysis of nanodimensional LiF thin film surfaces. Mater. Lett. 126, 123–125 (2014a) Yadav, R.P., Dwivedi, S., Mittal, A.K., Kumar, M., Pandey, A.C.: Analyzing the LiF thin films deposited at different substrate temperatures using multifractal technique. Thin Solid Films 562, 126–131 (2014b)

123

Application of Mie theory and Fractal models to determine…

Page 15 of 15 256

Yadav, R.P., Kumar, M., Mittal, A.K., Pandey, A.C.: Fractal and multifractal characteristics of swift heavy ion induced self-affine nanostructured BaF2 thin film surfaces. Chaos 25(8), 083115 (2015a) Yadav, R.P., Pandey, R.K., Mittal, A.K., Kumar, M., Pandey, A.C.: Surface roughness and fractal study of CaF2 thin films. Mater. Focus 4, 403–408 (2015b) Yuasa, S., Nagahama, T., Fukushima, A., Suzuki, Y., Ando, K.: Giant room-temperature magnetoresistance in single-crystal Fe/MgO/Fe magnetic tunnel junctions. Nat. Mater. 3(12), 868–871 (2004)

123 View publication stats

Suggest Documents