Changing Scopes in Mineral Processing

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MEHMET CANBAZOGLU. Cumhuriyet University, Mining Engineering Department, Sivas, Turkey. UNIVERSITATSBIBLIOTHEK. HANNOVER. TECHNISCHE.
PROCEEDINGS OF THE 6TH INTERNATIONAL MINERAL PROCESSING SYMPOSIUM KUSADASI/ TURKEY/ 24-26 SEPTEMBER 1996

Changing Scopes in Mineral Processing Edited by MEVLUT KEMAL, VEDAT ARSLAN & ALIAKAR Dokuz Eyliil University, Mining Engineering Department, Izmir, Turkey MEHMET CANBAZOGLU Cumhuriyet University, Mining Engineering Department, Sivas, Turkey

UNIVERSITATSBIBLIOTHEK HANNOVER TECHNISCHE INFORMATIONSBIBLIOTHEK

A. A. BALKEMA/ROTTERDAM/BROOKPIELD/1996

Changing Scopes in Mineral Processing, Kemal, Arslan, Akar & Canbazoglu (eds) CO 1996Balkema, Rotterdam. ISBN 90 54108290

Table of contents

Foreword

XIII

1 Comminution and classification Mechanical activation enthalpy of different minerals M. Petrov & S. Milosevic

3

Grinding behaviours of minerals mixtures

9

CTurgut&AIArol The interrelationships between Bond grindability of coals and Impact strength index (I. S. I.), Point load index (Is) and Friability index (FD) V.Deniz, G.Balta & AYamik

15

Mobile primary crushers in mining

21

M. Fjcestad

Modern grinding mill designs S. M.Jones, Jr &K.L. Holmberg

29

Vibration attrition pulverizing LV.Kuzev, S.G.Seksenov & R.I.Kuzeva

37

Shape of finely ground mineral particles: A preliminary study G.Alfano, M.Surracco, M.Dondi & P.Saba

41

Particle shape characterization using an image analysis technique E. Kaya, S. R. Kumar & R. Hogg

47

3-Dimensional measurements of morphological properties of particles C. Hicyilmaz & S. Bilgen

53

Contributions to the development of an instrument for powder particle size analysis by laser light diffraction method N.Boia, C.Boia, C.Matros & G.Georgescu

57

Performance improvement by two stage classification LBayraktar & S.Ersayin

71

A simple, low cost wet classifier G.Alfano, M.Ghiani, R.Peretti & AZucca

77

2 Gravity, magnetic, and electrostatic separation Microfractures and structural characteristics and their influence in beneficiation of an olivine chromium ore S.Mati

85

Factorial experiments and principal component analysis in the optimization study of a multi gravity separator F.Vegilo,P.Forlano, G.Belardi & N.Sheau

91

Coal desulphurisation with the Mozley Multi-Gravity-Separator F.Goktepe, FD.Pooley, K.P.Williams, GJ.Wise & R.Trillo-Soto

97

Processing of thickener underflow from celestite concentrator by Multi Gravity Separator N.Asian & M. Canbazoglu

103

Recycle of tailing of the Chromium Dressing Plant of Bulqiza S. Boci, O. Kondi, G. Demi & S. Mali

107

The effects of operating parameters on the performance of a pinched sluice LErgiin, O.Giilsoy, B.Aksani & S.Ersayin

111

Recovery of precious metals from military electronic components LH.Gundiler, J.D.Lutz & P.G.Neiswander

119

Treatment of chromium ores with high percentage of olivine S.Mati, G.Demi, S.Boci & O.Kondi

125

Upgrading of raw perlite by a dry magnetic technique D.Herskovitch & I.J.Lin

131

Upgrading of a low-rank semicoked lignite by high intensity dry magnetic separator i.Yildinm,H.Yiice, G.Onal &M.S.Celik

137

Beneficiation of Emet tailings by water absorption + mechanical attrition + magnetic separation E.Sonmez, H.Ozdag & M.Savas

143

The recovery of chromite fines from the tailings of Uckoprii chromium plant using HIWMS AGiiney, AASirkeci, V.Gurkan & G.Onal

149

Removal of iron-minerals from Aydin-Cine Feldspar by magnetic separation I.Cocen, T.Cigek & Y.Cilingir

155

Upgrading of phosphate ores by electrostatic separation A Z MAbouzeid, A E. Khazback &S.A Hassan

161

Magnesite processing using high-force® magnetic separators B.RArvidson & B.Dille

171

3 Flotation fundamentals The action of collector forms sorption in mineral

flotation

AAAbramov

VI

181

Effect of temperature on collector adsorption and K.Hussin, J.Hisham & PR. Khangaonkar

flotation

187

The role of zeta potential and hydrophobicity on shear flocculation of fine particles U.Akdemir & C.Hicyilmaz

193

Electrochemical behaviour and collectorless flotation of pyrite Z Ekmekci & H. Demirel

197

Wettability characteristics of sparingly-soluble minerals: Fluorite, calcite and apatite M.Yekeler & B.Yarar

203

Wetting properties of an Egyptian coal and their relation to its flotation behavior A A S. Seifelnassr

209

Adsorption of model collector colloids at the surface of colemanite as characterized by optical 215 and atomic force microscopy S. Veeramasuneni, M. R. Yalamanchili, J. D. Miller & M. S. Celik Laser interferometry to determine absorption kinetics of flotation collector reagents on sulfides R. Todoran, I. Pop & I. Sharkany

221

Difficulties in separating copper and lead sulphides by xanthate flotation: Negative role of contact of particles in the presence of depressants J.Drzymala, T.Chmielewski & ALuszczkiewicz

225

Flotation behavior of galena and pyrite B.Toka & U.Atalay

229

Elimination of depressants in flotation of lead-zinc sulfides using cationic resins AAkar & Y.B.Cevikmen

235

Effect of dissolved copper on ethylxanthate adsorption on pyrite D.R.Vucinic, S.R.Popov & R.ATomanec

241

Cyanideless depression of galena and sphalerite N. M. Calk, S. R. Popov, D. R. Vucinic & D. D. Draskic

249

Effect of SO2 addition on flotation and pulp potential of pure sulphide minerals and a Turkish complex sulphide ore F.Goktepe & K.P.Williams

255

The effect of inorganic agents on the flotation of barite and C.Hicydmaz & M.Ghaemi

261

fluorite

Flotation of carrollite and chalcopyrite in the presence of potassium ethyl xanthate (KEX) and Mercapton-Benzo-Oxazole (MBO)

265

LKWitika&BDobias Application of tube hydrodynamical sound-generator for water treatment in the process S.D.Djendova & V. K. Kovatcheva Effect of simultaneous ultrasonic treatment on colemanite §.G.Ozkan & T.J.Veasey VII

flotation

flotation

271

277

4 Flotation technology Results from a Copper-Pyrite selection made by means of an electrochemical treatment V.T.Panayotov, K.Kovachev & St.I.Stamenov

285

Recovery enhancement of gold and silver in chalcopyrite flotation Bucim - Macedonia applying new collectors S.Iliev, G.Konzulov, ZGocev, B.Krstev & B.Golomeov

289

Metal ion characterization of monoclinic pyrrhotite from nickel-copper ores using EDTA extraction $.Kelebek, P.F.Weils & G.W.Heinrich

295

Recovery of copper and tin from copper fire-refining slags KGiray, G.Onal, F.Arslan & V.Gurkan

301

Lahanos copper-zinc concentrator: An innovative way to improve plant performance S.Bulatovic, i.Bayraktar, O.Tecen & MAgytiz

307

Concentration of Kure-Bakibaba ore by G.Bulut, U.Savas & SAtak

315

flotation

The distribution of precious and rare metals in the flotation products of Kiire copper ore AASirkeci, SAtak, V.Gurkan & S.Yalcin

319

The application of the selective-collective flowsheet by the galena-sphalerite on the Zletovo concentration plant - Probistip M.Nikolovski

325

flotation

Constructions, automation and utilisation of column cells at CEPROMIN Deva /. Lupulescu & M. Herban

329

Entrainment of fine gangue particles in column flotation with negative bias B.6teyaka, Y.Ugbas, K.Bilir &HOzdag

333

Parameters affecting mineral behavior in the froth zone of a laboratory flotation column BAksani & H. Demirel

337

Development, design, simulation and operation of multisectional flotation columns J.B. Rubinstein & SJ.Hall

343

Column flotation parameters and their influence upon rutile and zircon concentrates purification /. Coldea, D. Georgescu & A Sporea

349

Optimisation of enrichment conditions of Zonguldak hardcoal with column O.Dalahmetoglu & M.Kemal

355

Upgrading of bulk concentrate of Murgul Flotation Plant by column AGUney,AGul, M.ZDogan & G.Onal New flotation cell for precious metal recovery J. R. Parga, H. Mercado, H. Ojeda & A Salazar

VIII

flotation flotation

361 365

5 Industrial minerals A new approach to borax pentahydrate production HCebi, S.Delice, S.G.Ozkan, V.Neslioglu, K.Poslu & ED emircan

373

Effect of temperature on anhydrous Borax compaction S.Kocaku§ak, M.Koral, H.J.Koroglu, O.T.Savasci & R.Tolun

377

Stagewise dehydration, a new concept on anhydrous borax production S.Kocakusak, KAkcay, T.Ayok, H.J.Koroglu, M.Koral, FJsbilir, T.Savasa & R.Tolun

383

Processing of tincal and colemanite ores by decrepitation method and comparison with wet method in terms of production cost MAkdag, T.Batar, U.ipekoglu & M.Polat

389

Froth flotation of ultrafine Egyptian kaolin ore N.AAbdel-Khalek, M.AArafa & F.Hassan

395

Production of SrCO3 by black ash process: Determination of reductive roasting parameters M. Erdemoglu & M. Canbazoglu

401

Technological evaluation of Turkish sepiolites H. Kurama, D.Oz & M Kaya

407

The recovery studies of pure mica for paint industry BJpekoglu & RAsmatiilu

415

Concentration of waste gypsum by column / Toroglu, L Buzkan & N. Bayrak

flotation

A new technology for mineral processing: 'Converting method' X. Shangbin

421 427

6 Coal processing Observations and studies of float and sink centrifugation of fine coal at Nottingham University S. Kizgut, D. Rhodes & N.J. Miles

435

Cleaning of Seyitomer lignites by otisca process H. Koca & M. Kaya

441

The oxidation properties of imported hard coals by the Turkish iron and steel association GAtesok, A A Sirkeci & M.ilhan

449

The investigation of effects of some parameters on the performance of selective agglomeration of lignites Y.Cebeci

455

Mechanism of coal flotation by insoluble collectors in the presence of PEO/ PPO triblock co-polymers 5. Chander, H. Polat & M. Polat

461

Separation of coal particles from Soma fly ash by O. Bayat & O.Y.Toraman

469

IX

flotation

Flotation and oil agglomeration studies for beneficiation of-0.5 mm coal of Zonguldak washery D.C-uhadaroglu & H.Ozdag

475

Co-pyrolysis of lignites with oil-products I.Mustafaev, G.Onal, M.Z.Dogan & LYddirim

481

CO2 neutral carbon production from biomass by carbonization W.Klose & WWiest

485

Desulphurization of Turkish lignites by NaOH leaching D.Renda, G.Onal, H.Yiice & M.ZDogan

489

7 Hydrometallurgy Metal ions catalysis in acidic leaching of metal sulfides W.Mulak

495

Utilization of electrochemical methods for the production and purification of tellurium L. YAgapova, E.I. Ponomareva & Z SAbisheva

499

Gallium recovering from unconventional sources of raw materials Z SAbisheva, A N. Zagorodnyaya, I. N. Parshina & B. B. Beisembaev

503

Benefication of ilmenite by chemical treatment ASporea, D.Georgescu & I.Coldea

509

Recovery of rare metals from sulfidic concentrates FArslan, AUzunoglu, V.Gurkan & G.Onal

513

Recovery of rare-earths from bastnaesite flotation pre-concentrate with hydrochloric acid i.Girgin & M.Gundu'z

519

Oxidative pressure leaching of Cayeli zinc sulphide concentrate N.Guresin, Y.Topkaya & AGeveci

525

8 Gold and silver Particle characterisation and selective separation process of complex auriferous minerals R.ATomanec & P.M.Lazic

533

Heap leaching practices applied to some clayee gold bearing ores and secondary resources P. Ilie, I.Vida & N. Sdsdran

539

Heap leaching of precious metals from Rosia Montana ore I.Giurca & D.Turcu

543

Recovery of gold and silver from sulfide refractory gold ore V.Cvetkovski, LJovanovic,N.Mitevska &M.Vukovic

549

Extraction of low grade gold using thiourea Y.B.Cevikmen, AAkar & VArslan

553

Gold recovery from finely disseminated ore by use of cyanidation and thioureation SUbaldini,R.Massidda, CAbbruzzese, F.Veglid <oro

559

A technology for thiosulphate leaching of Au and Ag from Pyrite concentrates V.T. Panayotov

563

Leaching of Ovacik gold ore with cyanide and thiourea C.Tiikel, H.Qelik, U.ipekoglu, M.Tanriverdi & H.Mordogan

567

Increasing the recovery of gold from sulphide copper ores A Boteva

573

Coal-gold-agglomeration of alluvial gold St.Gaidarjiev, St.Stoev & R.Kireva

577

Microbial leaching of a gold-bearing pyrite concentrate S.N.Groudev, I.I.Spasova & I.M.Ivanov

583

New approach for capacity and recovery increases on Etibank silver cyanidation plant NAcarkan, G.Onal & AE.Yiice

587

Possibilities of treatment of residual waters containing cyanide and its recovery in a cyanidation plant from Regia Autonoma a Cuprului Deva SCopaescu, G Fodor, G. Bota, L. Popa & A. Pescaru

591

Ozone treatment of cyanides from waste streams of nonferrous minerals processing P. Hie, D.Baciu & N.Sdsdran

599

Natural degradation, chemical destruction and regeneration process of cyanide N.Gonen, E.Demir, H.M.Kose & G.Ozdil

603

9 Modeling, simulation and control Two forms of Rayleigh law in separating solid particles in pulp under sinusoidal vibrations LV.Kuzev

609

Mass balance calculation for a complex grinding circuit P.Zoga, K.Fetahu & K.Markollari

613

Determination of breakage parameters in laboratory scale ball mill and scale-up of ball milling B.Sonmez & H.Demirel

617

Simulation of a full scale cement grinding circuit H. Ergin & A CApling

623

A new approach to kinetic characterization of semi batch flotation tests O.Y.Giilsoy & SErsayin

629

Towards an intelligent control of technological flotation processes D.G.Cojocariu

635

10 Dewatering Investigation of tailings disposal problems of Etibank Bigadic Mines SDelice, K.Poslu, S.G.6zkan & U.ipekoglu

XI

643

Comparison of polyethylene oxide and polyacrylamides as flocculating agent for the flocculation of tincal slimes G.Gur, STurkay & AN. Bulutcu

649

Filtration behavior of flocculated kaolin slurries O.San &C.Hosten

655

Flocculation behavior of fine albite concentrate with various polymers I.Kursun, Y.Kaytaz, B.ipekoglu & M.S.^elik

661

Dewatering of fine particle waste using the derrick dewatering system O.N.Guven&C.P.Kelley

667

Wastewater treatment in marble industry LBayraktar, M.Oner, N. Karapinar & S. Saklar

673

11 Agglomeration Spherical agglomeration of flotation tailings Z Sadowski

681

Concentration of magnesite fines by magnetic separation and selective agglomeration Y.Ucbas&H.Ozdag

687

Oil agglomeration using water jets P.Carbini, R.Ciccu, M.Ghiani, F.Satta & C.Tilocca

693

Effect of bentonite addition on physical properties and reducibility of mill scale pellets M. H. Khedr, Y. M. Z Ahmed, O.A Mohamed & M. E H. Shalabi

699

The optimum conditions of pelletization of chromite concentrate required for the production of ferrochrome silicon alloys H. S. R. El-Faramawy, M. H. Khedr, F. M. Mohamed, O.A Mohamed & M. E. H. Shalabi

707

Author index

715

XII