Degradation state of carbon in groundwaters ...

14 downloads 4331 Views 4MB Size Report
DOC. CDOM. Anschutz et al 2010. Kim et al. 2013. +++++. Coastal ocean ? Still large ... Zone A : seawater signature. Specific ... Zone B : Freshwater signature.
Degradation state of carbon in groundwaters discharging through a sandy beach Mathilde Couturier1, Fréderike Lemay-Borduas1, Christian Nozais2, Gwénaëlle Chaillou1

1Canada

Research Chair in the Geochemistry of Coastal Hydrogeosystem, 2Biology, Geography and Chemistry Department Université du Québec à Rimouski

Subterranean estuary Groundwater

?

DOC CDOM

Porewater DOM Remineralisation

Anschutz et al 2010 Kim et al. 2013 +++++ Seawater DOC CDOM

Biogeochemical products

Coastal ocean

Still large unkowns concerning the source and the behavior of DOM

2

DOM in subterranean estuaries

3 CDOM Cycling carbon Trace elements Biological activity

Component of DOM that absorbs light

Opticals indexes Amount of CDOM absorption coefficient Quality ratio 254.375 Origin Biological Index and Fluorescence Index

Subterranean estuary Groundwater DOC CDOM

Porewater DOM Remineralisation Biogeochemical products

Seawater DOC CDOM

DOM in subterranean estuaries

Objectives 1)  Determine the origin of DOM sources 2)  Evaluate the degradation state of the potential DOM exported to coastal ocean

Determine the quality and reactivity of Carbone in the coastal ocean

4

Study site: Magdalen Island, Quebec

5

ø = 300µm

Magdalen Island

ø = 100µm

Chaillou et al., 2014

Study site: Magdalen Island, Quebec

M1

6

M2

M3

M4 M5 M6

M7

seawater

Groundwater 35 m

Multi-level samplers

Seawater

Groundwater Porewater

Sandy beach: pore water characteristics

7

Iron (µM)

Specific Conductivity (mS.cm-1)

!"#;(%8"+