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Jul 10, 1984 - and Lundquist, 1982; Nicolas and Violette,. 1982]. Olivine and ..... Anderson, R. N., J. Honnorez, K. Becker, A. C.. Adamson, J.C. Alt, R.
JOURNALOF GEOPHYSICALRESEARCH,VOL. 89, NO. B7, PAGES 6126-6138,

JULY 10,

1984

GEOLOGIC AND SEISMIC VELOCITY STRUCTURE OF THE CRUST/MANTLE TRANSITION IN

THE BAY OF ISLANDS J.

A.

Karson

and

OPHIOLITE J.

A.

COMPLEX

Collins

Department of Geology and Geophysics, WoodsHole OceanographicInstitution J.

F.

Casey

Department of Geosciences, University corrections

Abstract. Geological investigations of the Bay of Islands Ophiolite Complex show that while a typical layered ophiolite suite is present, the thickness of major lithologic units is extremely variable from place to place. The composition

and internal

structure

tions

("Moho")

transition

reconstructed

plex internal transition

for

seismic structure.

from mafic

meters)

terrane

com-

Recent

results

over

lateral

from well

distances

exposures of ancient

oceanic

that conside.rable variations

lithologies

thicknesses

from a sharp geologic

discontinuity

structural

varia-

controlled

of

tens

of kilo-

meters regardless of spreading rate or age [Purdy, 1982, 1983; Bratt and Purdy, in press, !984]. Alternatively, studies of ophiolites, subaerial

The crust/mantle

to ultramafic

varies across the ophiolite and seismic velocity

this

suggest an extremely

two-dimensional

seismic refraction experiments suggest that the seismic structure of oceanic crust is laterally homogeneous on the seismic scale (a few kilo-

of map-scale (kilometers

lithosphere

for

in sediment thickness and basement topo-

graphy.

across) lithologic units as well as the contacts that bound them are laterally variable. Inferred velocity-depth functions of the crust/mantle as oceanic

of Houston

on scales

lithosphere,

in lithologic

of centimeters

suggest

unit

to kilometers

may b• present in contemporary oceanic crust.

to a complexly

Reconstructions

of the velocity

structure

of

interlayered transition zone as muchas 3 km thick. The mafic/ultramafic transition is charac-

ophiolites have been used to help interpret the seismic structure of oceanic regions [Peterson et

terized

al., 1974; Salisbury and Christensen, 1978; Spudich and Orcutt, 1980; Nichols et al., 1980; Hale et al., 1982; Kempher and Gettrust, 1982a,

units

by laterally on

the

kilometers

long.

order

thick

discontinuous of

hundreds

of

lithologic meters

and up to several

to

a few

kilometers

These units (megalenses) may be composed

b]. The ophiolite analogy must be applied cautiously, however, because there is a disparity in

of lithologies with higher or lower seismic velocities than those of the surrounding units. Solid-state deformation has produced seismically anisotropic materials in the upper mantle and lower

crustal

units.

Substantial

slopes of up to at least

relief

12ø over lateral

the

and

to the understanding

and are signifi-

of crustal

observation

used

in

seismic

studies

averages

over

lateral

distances

on the scale of the seismic experiment, typically tens of kilometers, whereas laboratory measurements of rock velocities are usually carried out on cylindrical samples only several centimeters long and 1-2 cm in diameter. Cracking of the upper oceanic crust on scales larger than the

geologic unit contacts. Although these types of geological features are striking to the field cant

of

ments represent

dis-

tances of about 10 km occur on the top of the crust/mantle transition zone as well as other

geologist working in ophiolites

scales

and those used in field and laboratory studies of ophiolites. Seismic refraction velocity measure-

accretion

scale

processes, many of them occur on such a small

of laboratory

samples results

in seismic

velocities of the shallow crust being significantly lower than laboratory values measured at the appropriate confining pressure [Schreiber and Fox, 1977; Kirkpatrick, 1979; Salisbury et al.,

scale that they might go undetected in different types of seismic experiments in contemporary oceanic lithosphere.

•979]. Introduction

However, at crustal depths greater than a few kilometers, where increased lithostatic pressure results in crack closure, the mineralogy and texture of the various rock units present are considered to be the dominant factors controlling the velocity structure. Laboratory measured velocities of lithologies expected at deep crustal and upper mantle levels are similar to the seismic velocities reported for the deep crust and upper

Our understanding of the seismic structure of the oceanic crust has evolved from constant veloc-

ity,

"layer

cake" models to more complex models

involving velocity and lateral-velocity

Spudich and Orcutt,

gradients, low-velocity zones, heterogeneities [e.g.,

1980].

Purdy [1982, 1983],

however, has pointed out that our knowledge of the lateral variability of seismic structure on scales of tens of kilometers has not kept pace with

the

above

advances.

He has

cautioned

mantle [e.g., Spudich and Orcutt, 1980; Fox and Stroup, 1981]. Thus the geological and velocity structure of the middle crustal to upper mantle portions of ophiolites may serve as a useful guide in revealing the type of seismic structure that should be expected in marine seismic experiments. In a general sense, the crust/mantle transition or Moho must correspond to the depth at which mafic lithologies with crustal velocities (less than 48.0 km/s) give way to ultramafic litho-

that

apparent lateral variability might well be an artifact of poor experiment location in relation to fracture zones and incomplete knowledge of

Copyright

1984 by the American Geophysical Union.

Paper number 4B0522. 0148-0227 / 84 / 004B-0522 •05.00

logies with upper mantle velocities 6126

(generally

Karson

et al.:

Structure

of the

>8.0 kin/s). The geological expression of the Moho as seen in ophiolites indicates that the crust/mantle transition is far from a simple lithologic contact. In this paper, we present

evidence for complex lateral and vertical variability in the geologic and seismic velocity structure

at the fossil

crust/mantle

transition

(Moho) preserved in the Bay of Islands Ophiolite. We first present a description of the Bay of Islands Ophiolite with emphasis on geologic features which may influence seismic velocity structure

in the lower crust

and upper mantle.

Rock

velocity data are then used to define the seismic

Crust/Mantle

initially

detached from a ridge-transform

farther Massif

the Coastal Complex. Structural continuously and systematically nants of the ophiolite slab and the context of the preobduction temporal and spatial variations

logy and seismic velocities at the crust/mantle

Vertical

transition

the Ophiolite

structure

of oceanic

inter-

from the fracture zone. The Lewis Hills contains the contact between the BOIC and

of this

of the seismic

6127

section along the inactive portion of a fracture zone. The lithosphere within the slab becomes progressively older from SW to NE. The geology of the individual massifs and the apparent displacements across major tear faults suggest that from SW to NE the massifs come from progressively

velocity structure at different points in the ophiolite. Finally, we discuss the possible implications of the observed variability im geofor the interpretation

Transition

slab

of oceanic

Section

variations occur across the remwhen viewed in geometry, reflect in the evolution

lithosphere.

Through

Complex

lithosphere.

In general, the BOIC has a relatively Geology of the Bay of Islands

Complex

stratiform

internal

structure

well-developed ophiolite

simple

that is typical

of

complexes. From base to

top, the layered sequemceconsists of layered

Geologic Settimg

ultramafic

TheBayof IslandsOphioliteComplex (BOIC)is

tectonites

(mostly harzburgite),

layeredultramaficcumulates (dunites,wehrlites,

oneof the world'sbest exposed,complete sections clinopyroxemites, etc.), interlayeredmaficand of ancientoceaniclithosphere[Church and ultramaficcumulates (locally referred to as the

Stevens,1971;Dewey andBird, 1971;Williams, "mafic/ultramafic transitionzone"whereit 1973;Casey et al., 1981;Casey andKarson,1981]. represents an intervalgrading downward from100%

The BOIChas excellent outcrops of the entire

to 100%ultramafic rocks), layered mafic cumulates

dikes, isotropic and layered cumulategabbroic rocks, layered cumulateultramafic rocks, and

metagabbro,etc.); variably metamorphosed sheeted diabasedikes; andvariably altered basaltic

in a continuous

lower parts of the cumulate units are variably

sequence of lithologic units that constitutethe ophiolite suite' pillow lavas, sheeteddiabase residual ultramafic tectonites. stratiform

recognized in ophiolites Conferemce Participants,

These units occur

succession

that

is

worldwide [Penrose 1972]. The BOIC crops

(gabbro,olivine-gabbro,troctolite, etc.); nonlayeredgabbroicrocks(gabbro,hornblende-gabbro,

pillow lavas and minor sediments (Figure 3). tectonized conditions

out in a series of allochthonous klippen which represent the dissected remnants of a once continuous slab of oceanic lithosphere at least 100 km long and 20 km wide (Figure 1), and is a highlevel nappe in the Taconic Humber Arm Allochthon

al.,

of the western Newfoundland Appalachians. It lies structurally above a compressionally telescoped

parallel contacts

Cambro-Ordovicianrifted

(Atlantic

type) conti-

The

under anhydrous, high-temperature [Karson, 1977; Casey, 1980; Casey et

1981].

Im the reconstructions

presented

assumptions have been made. First,

here,

two

undeformed

diabase dikes in the complex are assumed to have formed in a vertical attitude approximately

to a spreadimg ridge axis. Second, between major rock umits in the BOIC are

taken as approximately horizontal over short

nental margin [Williams, 1973, 1975]. The age of the ophiolite is determined by isotopic dates on zircons from the gabbroic units at 485 + 2 Ma

distances (about 100-300 m) in order to construct columnar sections. The fracture zone assemblage formed in an approximately vertical, dextral

[DunningandKrogh, 1983] althoughsomewhat older ages (4504 Ma) have also been reported [Mattinson,

shear-zoneprior to the formation of adjacent parts of the BOICalong its eastern edge (Figure

1976; Jacobsenand Wasserburg,1979].

A basal

2; Karson [1977], Karson and Dewey[1978], and

metamorphic aureoledatedat 470+ 5 Maby 40Ar/

Karson[1984]).

marks the approximate age of obduction of the complex. Within the ophiolite slab a steeply dipping

ed through recent 1:15,000 scale mapping of the ophiolite allochthon and related structural studies [Karson, 1977, 1982; Casey, 1980; Casey

39Ar techniques [Dallmeyer and Williams, 1975]

These geometrical relations have been establish-

linear belt of variably deformedand metamorphosed and Karson, 1981; Casey et al., 1981, 1983]. They ophiolitic lithologies, called the Coastal Comdiffer from someassumptionsused by previous plex, is interpreted as a fossil oceanic fracture zone that transects the ophiolite allochthon [Karson and Dewey, 1978; Karson, 1982, 1984;

workers [Salisbury and Christensen, 1978; Christensen and Salisbury, 1982] that have been shown to be in error due to lack of geological

Karson et al.,

1983]. The geometric relationships

control [Casey et al.,

of structures

in the Coastal Complex and BOIC help

1979; Caseyand Karson,

1981; J. F. Casey et al.,

unpublished manuscript,

provide someimportant constraints on the evolution of this terrane as well as the time/space

1984]. The present reconstruction of the crust/ mantle transition (shown in preliminary form in

relations amongthe separate outcrop areas during formation (Figure 2; Karson [1977,1984], Casey and

the work of Casey et al. [1981]) reveals a much more complex structure than that indicated by earlier studies.

Karson [1981], amdCasey et al. [1983]). From the internal geometric relations of the

ophiolite it appearsthat the ophiolite slab was

The middle crustal to upper mantle sections of the oceanic lithosphere are preserved across the

6128

Karson et al.:

Structure of the Crust/Mantle Transition

EXPLANATION

PARA-ALLOCHTHONOUS SEDIMENTARYROCKS

)'.•

Shale, Sandstone, M•lange

BAY OF ISLANDS OPHIOLITE COMPLEX



BasalhcPillowLavas



Sheeted Dlabase Dike Complex (hnes show mean dike trends)

•--_• Non-layered Gabbrolc Rocks --E• LayeredGabbrmc Rocks



Interlayered Maflc/Ultramafic Cumulates ('Transition Zone')

• Massive Dumte Cumulates :.[•'•-] ß Layered UltramaficCumulates qL--•']Harzburglte Tectomtes COASTAL



MOUNTAIN

COMPLEX

Amph•bolHe, Metagabbro, Quartz-D•or•te, Serpentlnlte, Dlabase, Basalt ALLOCHTHONOUSAND PARA-AUTOCHTHONOUS

SEDIMENTARY

[•

ROCKS

ARM

Sandstone, Shale,Limestone

• •

H•gh-Angle Fault Thrust Fault

½

BasalMetamorphic Aureole



UnconformHy

.

o ---_.J

5

BAY

OF

I SL

A AID $

io ß

KM

BLOW ME DOWN MOUNTAIN

LEWIS HILLS

Fig. 1. entire

Generalized geological mapof the Bay of Islands Ophiolite Complex.

length of the BOIC. The upper parts of

the section have been removed by erosion in some places. In order to reconstruct the geologic

structure in various places it is necessary to assume some average

upper lithologic restored

parts

crustal

units of

the

structure

where

have been lost. sections

the

The

determine

the

crustal depth assigned throughout each vertical section and therefore the lithostatic pressure at any given point. In order to do this we have attempted to estimate the missing portions of the

sections by assuminga similar geologic structure to nearby exposures.

It

is possible

that

changes in lithostatic pressure do not cause significant variations in seismic velocity for rocks at pressures corresponding to middle to deep crustal levels (i.e., >100 MPa).

the

contacts between the missing upper crustal units had relief that has not been recognized, resulting

in errors in estimates of crustal thickness in the incompletesections. Small errors in these

reconstructions makelittle difference in confin-

ing pressure(43 MPaper 100m) andsuchminor

Lateral

Variation

in

the

Internal

Structure of the 0phiolite

The geologic contacts shownin Figures 1 and 3 are not as simple as they appear.

Some contacts

tend to be sharp (occuring over less than a meter) whereas others are gradational (ocurring over tens to hundreds of meters). In most cases, individual contacts vary in style and may change character over distances as small as a few tens of meters along strike. Discontinuousminor units, not

shownhere becauseof their small scale (less than

a few tens of metersthick), pinchout andswell

alongsome contacts. Complex interlayeringof

Karson et al.:

Structure

of the Crust/Mantle

/

6129

result of unevenly distributed layering, minor intrusive bodies, ductile shear zones, and mineralogic variations. Thus even the mappable

lithologic their

0

Transition

50km ,/•/

units referred to here are variable in

internal

structure

and composition.

Even the most laterally continuous map units tend to pinch and swell across the ophiolite allochthon. +1.0

Thickness

km and

more

variations

occur

both

on the

across

order

massifs and on a broader scale with proximity the Coastal Complex fracture zone assemblage. Thus thickness

/

It

/ ,/ / 2.

tectonic

both

along

and

1981].

is not clear

which,

if

any,

of the contacts

mappedthrough the BOIC can be used as a horizontal

datum.

Here

we have

chosen

to use the

of the depleted upper mantle (harzburgite)



Schematic map representation

obduction

occur

to

across the spreading direction. This implies that the individual geological units, although usually laterally continuous, have complex, laterally variable, undulating upper and lower surfaces

[Casey et al.,

Fig.

variations

of

individual

setting

top

sec-

of the pre-

of the Bay of Islands

SPFe. E'ADING DIF•E'CT/ON

Ophiolite Complex [after Karson and Dewey, 1978; Karson, 1983; Casey et al., 1983]. The BOIC is a comparatively simple stratifo• ophiolite sequence.

The adjacent

CC is a variably

deformed

INTRUSIVE/EXTRUSIVE CARAPACE

and metamorphosedophiolite suite that is interpreted to be derived from an oceanic fracture

(MogmoChomberRoof)

zone,

lithologies

(Figure 4) occurs at the contacts

between the lower crustal mantle

(ultramafic)

units,

between major lithologic

(gabbroic)

- MAGMATIC

and upper

and the contacts

PLUTONIC

units are defined by the

Wells ond Floor)

points at which greater than 90%of a single lithology is present. In the case of the mafic/ ultramafic transition contacts are defined

COMPLEX

(MegmeChomberCeding,

zone, the upper and lower by the points at which the

proportionof maficto ultramaficrocksis 90% and 10% respectively. From the map (Figure 1) and sections it is

obvious that while a particular lithologic unit

RESIDUAL UPPER MANTLE

may represent a largepartof thesection in some

places, itmay be entirely absent inothers. discontinuous units pinch out gradually along

Typically, at deep crustal levels these laterally

BASAL

- METAMORPHIC

strike (both parallel and perpendicular to the inferred spreading direction) and tend to pinch

out near their in

upper or lower contacts

the middle

of another

rather

than

unit.

Within someof the major units,

AUREOLE

large-scale

Fig. 3. Generalized columnar section of the BOIC showingthe usual succession of lithologic units.

laterally discontinuousbodies ("megalenses") of (Ornament as in Figure 1, except t, trondhjemite higher or lowerdensity lithologies occur(Figure5). bodies; squigglesamphibolites.) Note that at The largest of these megalensesare a few hundred meters

thick

and a few kilometers

long.

They are

different locations, these units have variable thicknesses,

may be absent,

above and below.

as 1.0 •n/s

was formed

with

of interlayered

the enveloping

mafic and ultramafic

within potentially Lewis Hills rocks

are

units.

Megalenses

rocks occur

higher velocity dunites in the

Massif and megalenses of ultramafic found on the North

Arm Mountain

and

Table Mountain Massifs (Figure 1). (For detailed descriptions of these megalenses see Karson [1977], Casey and Karson [1981], and Elthon et al.

[1982]).

Within the map units we define here (Figure 3), considerable heterogeneity occurs. This is the

or may have different

types of geological contacts with other units

usually composedof interlayered lithologies that collectively have velocity contrasts of as much

from

The basal crustal

metamorphic aureole

rocks

welded

to

the

ophiolite during obduction. The "residual upper

mantle" harzburgites represent oceanic upper mantle depleted by partial melting and extraction of basaltic liquids. The "magmatic" units represent these basaltic

liquids

that

crystallized

as

parts of either a rapidly chilled intrusive/extrusive carapace that formed the roof of a magma chamber or the sequence of plutonic rocks that formed along the ceiling, walls, and floor of the magma chamber.

6130

Karson

et

al.:

Structure

of the

Crust/Mantle

Transition

Fig. 4. Fine-scale lithologic layering in the mafi½/ultramafi½ transition zone of the Bay of Islands Complex. Lighter layers are gabbroi½ and darker layers are •ltramafi½ in composition. Note the fine lamination on the scale of approximately 1 ½m or less and also thicker layers up to perhaps a few tens of centimeters thick. Layering on all scales tends to be laterally discontinous with an overall lensoid form and length

to thickness

ratios

of 10:1-100:1.

tion as a horizontal reference line (Figure 6). This results in significant relief on various unit contacts and locally steep slopes; however, major unit contacts line up well across the entire complex. Assumingapproximately a 1.0-1.5 km thickness of volcanics plus dikes for all sections from the

3-7),

Blow me Down and North

Arm Massifs

no unreasonable seafloor

in those

areas.

(sections

relief

Reconstructions

is implied

of the upper

portions of sections from the Lewis Hills

and

Table

there-

Mountain

Massifs

cannot

be

fore do not help to constrain

made

and

the relative

verti-

cal alignment of those sections. The contact along the top of continuous ultramafic sections, corresponding to the top of the

upper mantle, has relief km within

individual

distances

of

less

of as much as nearly 3.0

massifs; than

about

that 15-20

is,

over

km.

This

produces slopes of as much as 15 • between the columnar

sections

shown.

On a scale

more compar-

able with seismic refraction experiments (i.e., a few tens of kilometers), slopes of 5•-10 • are common. Locally, however, steep slopes exceeding 30 • occur. We wish to emphasize that these relationships are not the result of faulting or folding related to obduction of the complex. These are

structures

that

once

existed

in

the

oceanic

crust. The slopes and topographic features can be smoothed out to some extent by elevating or depressing the groups of columnar sections from the individual massifs relative to one another; however, this only imposes relief on other contacts or on the paleo-seafloor. Adjacent sections

tive

within

the

massifs

to one another

cannot

be shifted

rela-

because they are not separated

See hammer for

scale.

by faults with large displacements across unit contacts. Only a minor amount of tilting might be tolerated. The columnar sections presented in Figure 6 represent the vertical lithologic successions at different positions in the ophiolite allochthon. They are arranged from SE to NW (left to right) from youngest to oldest. In a general way, the distance from the fracture zone (Coastal Complex) increases in the same direction from massif to massif. Thus collectively the sections describe the crustal structure along a transect that extends from near a ridge-transform intersection across isochrons into older crust at a low angle to the inactive portion of the fracture zone. The angle of the transect relative to the fracture zone is not well constrained but appears to be greater than about 20 •. Therefore, when viewed on a broad scale, the lateral variations in structure probably reflect a component of variability related to seafloor spreading at different distances

from

the

fracture

zone.

Sections

from

individual massifs are constructed from positions along seafloor spreading flow lines; that is, normal

to

the

mean

trend

of

dikes

in

that

area.

Variations within these groups of sections reflect temporal variations in seafloor spreading at a single position on a ridge axis. Mafic/Ultramafi½

The contact

Transition

between mafic

Zone

and ultramafi½

lith-

ologies in the BOIC, which should correspond to the Moho, is not a sharp contact between two distinct

rock units.

Instead,

it

is an interval

Karson

et al.:

Structure

of the

Crust/Mantle

Transition

6131

in the BOIC. Instead of a single,

smooth,

increase in ultramafics downward, there are several megalenses of interlayered mafic and ultramafic

rocks

enclosed

section of dunite.

within

a thick

few hundred meters

thick

and are separated

comparable thicknesses of dunite. layered

on a much coarser

ultramafic

(•3

km)

The megalenses are up to a

transition

scale

zones

the BOIC, we regard this

by

<hough interthan the mafic/

observed

Lewis Hills

elsewhere

in

assemblage

as an anomalously thick transition zone. This unusual structure may be a result of processes occurring durimg crustal formation near the

adjacent fracture

zone [Karson, 1977, 1982; Casey

and Karson, 1981]. Whether such a structure in the oceanic crust would appear to be a velocity

gradient rather than a zone of discrete

velocity

reversals would be determined by the nature the seismic experiment (see below). Scale

and

of

Distribution

of Lith01ogic Layering In nearly all

locations outcrop-scale layering

(a few centimeters

to a few meters

thick)

occurs

in the lower crustal and upper mantle lithologies. In the lower part of the gabbroic unit, the mafic/ultramafic transition zone, and the ultramafic cumulates, igneous cumulate layering

is ubiquitous although in someplaces these lithologies

have been affected

solid state deformation.

by high-temperature

Layer thicknesses range

from less than 1.0 cm (Figure

4) to several

tens

Fig. 5. Oblique air photograph looking due north across the Lewis Hills Massif. Scale is approxi-

of meters (Figure 5), and layering at different scales may dominate in different places. This layering is conspicuously discontinuous, and

mately four kilometers from south to north.

individual layers cannot be traced for more than

Steeply dipping, interlayered mafic and ultramafic

50-100 m along strike.

enclosed within cumulate dunite.

ness of ratios of 10'1 to 100'1.

Individual layers have an

lithologies define a north-south trending megalens overall lensoid form with typical length to thickMegalens is com-

posed of interlayered gabbroic (white) and wehrlite (dark) lithologies and has been offset by several east-west trending strike-slip faults. Dunite crops out both east and west of the megalens; that is, both structurally below and above it.

of finite

width

across which there

is a gradual

changedownwardfrom 100%mafic to 100%ultramafic rocks.

The overall

thickness

of this

interval

varies from less than 50 m (e.g., Figure 6, sections 3-5) to more than 1.0 km (e.g., Figure 6, section 6). Across this mafic/ultramafic transition zone there is a gradual increase in the

proportion and thickness of ultramafic relative

to mafic

layers

with

depth.

layers The most

con,non lithologies in this unit include dunite, wehrlite, clinopyroxenite, troctolite, anorthosite, olivine-gabbro, and gabbro. On an outcrop scale these rock types are intimately and complex-

ly interlayered.

On a broader scale (up to a few

hundred meters), megalenses of dominantly mafic or ultramafic lithologies occur. In some places, these wedge out abruptly along strike, whereas elsewhere they grade laterally into interlayered assemblages with different proportions of mafic to

ultramafic

between layers

may be gradational

or

(ratio layering), changes in the specific mineral phases present (phase layering) or a combination of any of these. The most commontype of layering is a type of phase layering with sharp contacts [Casey and Karson, 1981]. In some places, megalenses of interlayered rocks with a limited compositional range occur within map-scale layered assemblages. Where megalenses of interlayered mafic and ultramafic rocks occur

within ultramafic

cumulate units,

for example in

the Lewis Hills Massif, a very thick (•3 km) transition zone with first-order layering defined by the megalenses

Beneath this

occurs.

sequence of variably

deformed igne-

ous rocks the depleted upper mantle unit is also strongly layered. This unit consists mainly of harzburgite metamorphic tectonites with layering defined by layers a few centimeters to tens of meters thick with varying proportions of ortho-

pyroxene relative have gradational

orthopyroxenite

to olivine. contacts.

These generally Thinner

dunite

layers and crosscutting

and

veins up

a transition

to a few tens of centimeters are also present. These layers and veins tend to have sharp contacts with one another and the harzburgite country

seen

rocks.

materials.

The Lewis Hills Massif contains zone that is different from those

Contacts

sharp. Gradational contacts are defined by gradual changes in grain size, changes in the proportion of various mineral phases present

elsewhere

6132

Karson et al.:

Structure

of the

Crust/Mantle

Transition

A km

NORTH ARMMTN,

Oi 2 J- LEWIS HILLS

BLOW ME DOWN MTN.

3

-------

4

6

EXPLANATION

4

• '--'--,-------

PARAALLOCHTHONOUS SEDIMENTARY ROCKS MTN, BAY OF ISLANDS OPHIOLITE COMPLEX •i• •,•TABLE '.'.i-'•-] Shale, Sandstone, M•lange -• Non-layered Gabbrmc Rocks

5

::;)

"'-

MT Z

6

9



8







I• '•1 I_•.1

Sheeted Oiabase O•ke Complex (hnes show mean d•ke trends)

I '-[ 'J I•.•1

I'. '1

I0

Bosolhc PillowLavas



JO ••'F-•-'• Layered Gabbrmc Rocks M...... Oun,te Cumulates



'•





Interlayered Mafic/Ultromafic Cumulates ('Translhan Zone')

'•

Layered Ult.... fic Cumulates

•L--'/•-I Horzburg,te Tectomtes -m•----• Basal Met .... ph,cA.... le • Basal Thrust Fault

I.'--iJ

r , n

r

ur

12

14

ß

16

Velocity(km/sec) 4

6

8

4 !

k v; ' '•]p''

i

6 i

[

8 [

i

4

6

I

i

8

4 i

i

i

6 i

i

8 i

[

4 i

i

i

6 i

!

8 i

i

4 i

6 i

8

4 i

i

i

6 i

!

8 i

i

4 i

6 [

i

8 i

i

4 i

[

[

6 i

i

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i

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111llll

l Fig. 6. (a) Geological sections through various parts of the Bay of Islands Complex showing some of the variations that occur along the crust/ mantle (Moho) transition zone (MTZ) from SW to NE (left to right) across about 90 km of this slab of oceanic lithosphere. Geologic control for the sections comes from Karson [1977], O'Connell [1979], Casey [1980], Rosencrantz [1980], and J. Karson and J. Casey, (unpublished data , 1983). See Figure 1 for locations of sections. (b) Velocity-depth functions for

each of the columnar sections

shown in Figure

Serpentinization

6a.

See text

the gabbroic section is fresh and unaltered except along a few widely

At different

for explanation.

structural

levels of contemporary

oceanic lithosphere, different factors in addition to primary mineralogy may influence seismic velocity. At shallow crustal levels, cracks and fractures clearly play an important role. At deep

zones.

spaced fault

zones and shear

The ultramafic rocks in the ophiolite are

variably serpentinized, but the most intense alteration occurs along the basal thrust fault and other relatively late fault zones. In general the freshest ultramafics occur at the top of the

crustal and upper mantle levels, serpentinization

section.

of ultramafic material may lower seismic velocities and control the position of the Moho [Hess, 1962; Christensen, 1966; Clague and Straley, 1977; Nichols et al., 1980]. In the Bay of Islands

discontinuous with depth the serpentinization of the basal ultramafic section cannot be related to the same event(s) responsible for the alteration of the upper units. We consider it unlikely that hydration from lateral migration of fluids played

Complex, serpentinization,

although

now wide-

spread, appears to have been a very late (syn- or post-abduction) event, and therefore we have used the anhydrous velocities of the various rock units

in

our

reconstruction.

hydrated lithologies in the complex. The upper units (pillow lavas, sheeted dikes, and uppermost gabbroic rocks) are variably altered by hydrothermal

metamorphism similar

to that

described

in

[glthon and Stern, 1978] and in

DSDP cores [Anderson et al.,

an important role in alteration of the ultramafic rocks without affecting the immediately overlying mafic

rocks.

Although serpentinization

The evidence for the lack of significant preabduction serpentinization comes from several separate observations. Perhaps the most obvious indication is the regional distribution of

other ophiolites

Becausethe hydration of the complexis

1982].

The bulk of

late

fault

zones,

the earliest

is concentrated along movement on many

of these faults appears to have occurred prior to any pervasive serpentinization. Textures of rocks along these faults show fine-grained anhydrous ultramafic mylonites overgrown by static and/or deformed serpentine pseudomorphs and veins. Apparently, little if any serpentinite occurred in these areas during the initial stages of abduction. Furthermore, the basal metamorphic aureole welded to the sole of the ophiolite includes

Karson

et

al.:

Structure

of

the

Crust/Mantle

Transition

6133

high-grade amphibolites and pyroxene-hornfelses

[e.g.,

indicating temperatures in the adjacent peridotite in excess of the upper limits for serpentinite during that metamorphism. No dehydration (deserpentinization) textures have been found in any of the ultramafic lithologies examined, regardless of proximity to fault zones. Finally, preliminary results of a paleomagnetic

section of ultramafic and mafic cumulates are deformed and recrystallized with a similar structural style and metamorphic fabric orientation to that of the immediately underlying harzburgites [Karson, 1977, 1982; Casey, 1980; Casey et al., 1981, 1983; glthon et al., 1982]. In these areas oliv.ine-rich

study of chemical remanent magnetization of

highly

serpentinizedperidotites (J. CaseyandM. Titus, unpublisheddata, 1982) indicate that samplesfrom

rich or plagioclase-rich lithologies. Thus althoughmost of the ultramafic cumulates, transi-

various

probably not significant serpentinization of the ultramafic parts of the Bay of Islands Ophiolite

tion zone lithologies, and even parts of the layered gabbroic units are pervasively deformed the distribution of strain through these units is much more inhomogeneous than in the harzburgites. Thus we expect the same orientation of the anisotropy of the upper mantle rocks to occur in the lower crustal lithologies but to become progressively less important upward through the mafic/ ultramafic transition zone units. Garmany [1981] cites evidence for increased anisotropy with depth

prior to obduction.

in the upper mantle of the Pacific.

parts of the folded

and faulted

slab have a commonpaleopole.

ophiolite

This requires

that

serpentinization occurred after the obductionrelated folding of the complex. The paleopole determined is consistent with an Upper Ordovician

pole position for North America corresponding to the time interval These

during or just

observations

indicate

after

that

obduction.

there

was

A possible exception may have

occurred in the vicinity of the Coastal Complex fracture zone where serpentinites occur at all crustal levels and are cut by dikes that predate

obduction [Karson, 1984].

We wish to emphasize

that we do not interpret the metamorphic relations in the Bay of Islands Complex to be typical of all contemporary oceanic lithosphere, but rather as one possibility that is likely to exist. This particular structure is probably more typical of fast-spreading ridges. Crust formed at slowspreading ridges appears to be much more faulted and heterogeneous with even shallow-level

exposures of serpentinite

1971; Melson et al.,

[Aumento and Loubat,

1978; OceanographerTransform

that

George, 1978], parts of the lower crustal

ultramafic

rocks

tend

deformed than interlayered

such anisotropy

extends

to be much more

clinopyroxene-

at least

We suggest locally

up-

ward into lower crustal levels. This anisotropy has been considered in assigning the velocity bounds for the affected units in Figure 6. Velocity of

the

Structure

Crust-Mantle

Transition

The lateral variability in lithology within the Bay of Islands Complex (BOIC) results in a similar variability in rock velocity. Figure 6 shows the ten lithological sections which we consider to be representative of lateral variations that occur

across the ophiolite.

Compressional wave velocity

Tectonic Research Team, 1984].

Vp andshear wave velocity Vs profilesfor the crust-mantle transition in each of these sections

Anisotropy

are plotted as a function of depth immediately beneath the corresponding section. Reference to Figure 6 shows that we have not attempted to pre-

Laboratory measurements of mafic and ultramafic rocks with pervasive deformation fabrics have demonstrated their seismic anisotropy and the relationships between velocity and mineral pre-

ferred orientations

[Birch,

1960, 1961;

Christensen, 1966, 1971; Christensen and Ramananantoandro, 1971; Baker and Carter, 1972: Peselnick et al., 1974]. In ophiolite complexes the pervasively deformed and recrystallized upper mantle harzburgites have a fairly consistently oriented fabric that would produce a systematic-

ally oriented velocity anisotropy in the oceanic lithosphere [Nicolas et al., 1973; Christensen and Salisbury, and Lundquist,

Olivine

1979; Karson, 1982; Christensen 1982; Nicolas and Violette, 1982].

and pyroxene preferred orientations

produce maximumvelocities

the spreading direction dikes

in the ophiolite),

parallel tions

would

parallel

to

(normal to the trend of intermediate

velocities

to spreading centers or magnetic linea-

(parallel

velocities

generally

to ophiolite

in a vertical

dikes),

orientation

sent a single velocity-depth profile for each of the sections; instead we have presented an envelope of possible values. We justify this approach on the grounds that (1) most of the rock types considered are anisotropic, (2) Our depth scale could be in error locally by as much as 2.0 km

where sections are incomplete (Figure 6), and hence our choices

also be in error

of confining

locally,

pressures

(3) lateral

would

changes in

rock type such as varying olivine content in the gabbros occur rapidly and randomly • and are otherwise impossible to account for, and (4) the velocity envelopes in Figure 6 are narrow enough to reflect the major vertical lithological changes which are likely to have important implicatiu•L• for

the

seismic

structure

of

the

crust/mantle

transition, namely, the variable thickness of the transition zone between the layered gabbros and the underlying ultramafic components and changing

and slowest

crustal

(but

The V. and Vo profiles for the layered gabbro unit were constructed using the results of velocity measurements on samples of gabbro, olivine gabbro, troctolite and anorthosite from

see

thickness.

Elthon et al. [1982] and Casey et al. [1983]). These relationships are in agreement with the locally observed seismic anisotropy of the Pacific oceanic upper mantle [Morris et al., 1969; Raitt et al., 1969; Keen and Barrett, 1971; Shor et al., 1973; Bibee and Shor, 1976]. Obviously, some complications are expected near oceanic fracture

various parts of the BOIC shown in Table I [Salisbury and Christensen, 1978; Christensen and Salisbury, 1982; Karson, 1982; J. Karson and J. Casey, unpublished data, 1979]. Measurements were

zones [Karson, 1982].

carried out on both dry and water-saturated

In the BOIC, as well as many other ophiolites

samples of cylindrical

shape (several

centimeters

6134

Karson et al.:

Structure

of the Crust/Mantle

Transition

TABLE 1. Minimum and Maximum Velocity Bounds for BOIC Lower Crust and Upper Mantle Lithologies

Lithology

Minimum Vp

Layered Gabbro Wehrlite Dunite Harzburgite

In kilometers

Maximum Vp

6.7 7.9 8.2 8.1

Minimum Vs

7.3 8.4 8.7 8.5

per second.

See text

Maximum Vs

3.5 4.5 4.7 4.7

4.0 4.8 5.0 5.0

for explanation.

Fifty-five compressional wavevelocity Vp and26 shearwavevelocity V$

measurements.

Velocities

from Salisbury

and Christensen

[1978],

Christensen

and Salisbury [1979, 1982], Christensen and Lundquist [1982], Karson [1982], J. Karson and J. Casey (unpublished data,

long and about 1-3 cm in diameter) at room temperature and at confining pressures ranging from 1.5 to 2.5 kbars. The velocity difference between water saturated and dry samples is negligible at these confining pressures [e.g., Schreiber and Fox, 1977]. To allow for the effects of anisotropy, compressional and shear wave velocities were measured in three mutually perpendicular directions for 35 and 16 of the samples, respectively. The minimum compressional and shear wave

velocities

(6.7 and 3.5 km/s, respectively)

were

calculated by taking the mean of the velocity minima reported for each of these three-valued measurements and subtracting the standard devia-

tion.

Similarly, the maximum boundson Vp and

Vs (7.3 and 4.0 km/s, respectively) mined by taking

were deter-

the mean of the velocity

maxima

1979),

and Nichols

[1978].

Discussion

In the "layer cake" picture of the seismic structure of the oceanic crust, the crust/mantle boundary was defined by the abrupt vertical transition between compressional velocities in the range 6.9-7.3 km/s and compressional velocities greater than 8.0 km/s. This abrupt boundary has been referred to as the "Moho discontinuity" and has usually been interpreted as a rapid downward change in density and chemical composition from silicic and basic crustal lithologies to ultrabasic lithologies characteristic of the upper mantle.

It

may lie

has also

and correspond

tinized

been suggested

that

beneath the basic/ultrabasic to the boundary

the Moho

transition

between serpen-

and anhydrous ultrabasic

material

[Hess,

and adding the standard deviation. Wherever possible, measurementsmadeat confining pressure of

1962; Claque and Straley, 1977; Nichols et al., 1980]. As seismic aquisition and interpretation

1.5 and 2.5 kbars were used to construct

methods have improved,

the lower

refraction

studies

have

andupperbounds onVpandVs, respectively. shown that theoceanic crust/mantle boundary is, Twelveof the 18 single-valued Vpmeasurements in manyareas,bestdescribed as a smooth gradiand 18 of the 20 single-valued Vs measurements

ent between the above velocity ranges, suggest-

fall within the given bounds. For simplicity we have modeled the velocity strucure of the transition zone as a linear gradi-

ing a gradual transition between basic and ultrabasic lithologies. This Moho transition zone can vary from 0 km to 2 km in thickness and is typi-

ent between 100% layered

cally

gabbro, and 100% dunite

or harzburgite. The velocities for the dunites and harzburgites (confining pressure = 2.0 kbars)

modelled as a linear

velocity

gradient.

On

the basis of seismic refraction studies, marine seismologists have also identified both low- and

are reconstructed (anhydrous) rather than measured high-velocity zonesat the base of the crust (serpentinized) values and are based on the work [Sutton et al., 1971; Lewis and Snydsman,1977; of Christensen and Lundquist [1982]. These reconstructed velocities are generated by using the known modal composition of these rocks and the known velocities of their constituent minerals [e.g., Christensen and Salisbury, 1975]. The V_

andVs envelopes for the dunitelayer are 8.2-• 8.7 km/s and 4.7-5.0

km/s, respectively

and for

the harzburgite are 8.1-8.5 km/s and 4.7-5.0 km/s, respectively. The V_ and V• bounds for the wehrlite unit are 7.9-8.4 km/s and 4.5-4.8 km/s, respectively at 2.0 kbars. These figures are based in part on measurements reported by Nichols [1978] for clinopyroxenite. The lower bound is

for a wehrlite

of composition 50% olivine

(Vo

8.2, Vs = 4.7 km/s) and 50%clinopyroxene (V%

7.7, Vs = 4.3 km/sec.),and

the upper bound

for a composition 70%olivine (V = 8.7, Vs =

5.0 km/s)and30% clinopyroxene •velocityas above). rocks BOIC.

These modal compositions are typical

found in the deep crustal

sections

Spudich and Orcutt, 1980]. Normal-incidence seismic reflection profiles collected on oceanic crust with multichannel hydrophone arrays have further defined the nature of the crust/mantle transition. On some of these

profiles high-amplitude eventscanbe recognized at depths of 2-3 s two-way travel as reflections

of the

from the

crust/mantle

transition

[Grow and Markl, 1977; Herron et al., 1978; Stoffa et al., 1980; Diebold et al., 1981], suggesting an abrupt change in velocity and density. An

alternative

explanation has been proposed by

MacKenzie and Orcutt [1982]. In their model, the crust/mantle transition consists of a 1- to 2-kmthick stack of interbedded, thin (4100 m), highand low-velocity layers. Synthetic modelling has shown

of

time beneath

oceanic basement and these have been interpreted

that

seismic

refraction

studies

cannot

distinguish between such a model and a model consisting of a smooth velocity transition zone of the same thickness [Spudich and Orcutt, 1980].

Karson et al.:

Structure of the Crust/Mantle Transition

6135

kilometers

Fig. 7. Schematic blockdiagramillustrating the internal structure of the oceanic lithosphererepresented in the Bayof IslandsComplex [after Caseyet al., 1981]. (Ornamentas in Fig. 6.) Note variable nature of geologiccontactsbetweenlithologic units, lateral discontinuity of someunits, laterally varying thickness of units,

high-andlow-densitymegalenses within majorunits, andtopography on nearly all major geologiccontacts. Bold lines showthe top andbottomof the Mohotransition zone. This interval varies in thickness and in the geologic units it contains.

At normal incidence, however, constructive interference

of the reflections

from the thin

layers

can result in high-amplitude returns. Fuchs [1969] has proposed a similar model for the continental Moho transition zone and has shown that high-amplitude normal-incidence reflections can

be generated from high- and low-velocity layers with thicknesses corresponding to one quarter the seismic

It

of

wavelength.

can be seen that

the seismic picture

of the

Moho transition zone in the oceans is a complex one; but how is the velocity structure of the Moho transition zone in the BOIC related to the observations noted above? The geologic sections

and velocity-depth profiles constructedfor the

BOIC(Figure 6) showthe following features: (1)

near the fracture

zone marked by the Coastal

Complex. The timing of serpentinization in this region relative to faulting appears to indicate local deep hydration while the complexwas still in an ocean basin [Karson, 1982, 1984].

Second,

the regional variations in lithologic unit thicknesses demonstrate

that

thinning

of mafic crustal

layers and thickening of ultramafic cumulateunits occurs

for

near

the

fracture

the observed

zone.

thinning

This

could

of the crust

account

near

oceanic fracture zones [e.g., Fox et al., 1980]. Finally, the degree of velocity and fabric anisotropy varies from layer to layer and across horizontal lithologic unit contacts but has a fairly consistent

orientation

with

respect

to the paleo-

spreadingdirection (but see Caseyet al. [1983]).

a variable thickness (0-1 km) of the velocity and geologic (mafic/ultramafic) transition zone at

Therefore

crustal

propagation direction. For example, refraction experiments directed parallel to the spreading

the crust/mantle boundary; (2) a reconstructed thickness which varies

from about 3-4 km

(sections 3, 4, 5) to about 6-7 km(sections 6, 7); (3) thin (