Hideki Hasegawa. Quantum Devices and Integrated Circuits....

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Vin. Vout. WPG QWRTr. (active load). WPG SET. (driver Tr.) (S. Kasai and H. Hasegawa ... GaAs etched nanowires and .... AlGaAs/GaAs etched nanowire. V. DS.
Hokkaido University

ECS 2001 Joint Intenational Meeting, San Francisco Sept. 2-7,RC2001 Sixth International Symposium on Quantum Confinement

Quantum Devices and Integrated Circuits Based on Quantum Confinement in III-V Nanowire Networks Controlled by Nano-Schottky Gates

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Hideki Hasegawa Research Center for Integrated Quantum Electronics (RCIQE) and Graduate School of Electronics and Information Engineering Hokkaido University, Japan

Outline

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1. Introduction 2. Hexagonal BDD Quantum Circuits 3. GaAs-Based Quantum BDD Node Devices and Circuits • Novel nanometer-scale Schottky gates • GaAs-based quantum BDD node devices • Integration of BDD node devices on hexagonal nanowire networks

4. Toward Room Temperature Operation and High Density Integration • Formation of InP-based high density hexagonal nanowire networks • Surface related key issue

5. Conclusion Collaborators RCIQE staff Dr. S. Kasai, Dr. C. Jiang and Dr. T. Sato Students T. Muranaka, A. Ito and M. Yumoto

Speed, Delay-Power Product of Quantum Devices

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G ≈ G0 ≡ 2e h

2

τ = C G

J.E.Mooij, 1993 SSDM Ext. Abs. 339 106 300K 104

105K

thermal energy 1K

present-day semiconductor devices

10-15F

2

τ 10 [ps]

10-16F

1

10-17F Single Electronics

10-2 10-14

10-18F

Quantum Limit 10-12 10-10 10-8 P[W]

10-6

10-4

10-2

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Scale-down limit of Si CMOS LSIs

Research on Semiconductor Nanostructure

Growing demands on Information Technology (IT)

Nanotechnology in wide area ~ chemistry, biology, etc.

Semiconductor Nanoelectronics based on Quantum Device and Circuit • delay-power product near quantum limit • small-size and high-density • nano-sensing, nano-control

But, How to ? So far no realistic approach.

High Density Integration ?

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Semi-classical devices First Monolithic Integrated Circuit in the World (Noyce, 1959)

Current Microprocessor (2001)

IBM PowerPC

300µm rule

Discrete quantum devices

64-bit 0.18µm rule 700MHz 1.4mm x 1.4mm SOI technology

How to make QLSIs ?

Example of Quantum Logic Circuits

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QWRTr-load SET inverter (S. Kasai and H. Hasegawa presented at DRC 2000) 25 Gain = 1.3

QWRTr (Active Load)

20

input

output

VDD = 40 mV VBG = -1.0 V VG(QWRTr) = 0 mV

15 10

3-gate WPGSET

5 µm

W = 440 nm SET: LG = 50 nm, df = 200 nm QWRTr: LG = 300 nm VDD VG(QWRTr)

Vin

WPG QWRTr (active load) Vout WPG SET (driver Tr.)

5

T = 1.6 K

0 -550 -500 -450 -400 -350 -300 -250 Vin (mV)

small delay•power product but low gain voltage mismatch poor Vth control poor drivability low temperature

Novel Approach for III-V QLSI

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1. Digital Processing Architecture Binary Decision Diagram (BDD) logic architecture 2. Nanostucture Hexagonal nanowire networks by GaAs etched nanowires and InGaAs nanowires by Selective MBE 3. Nanoscale Gate Technology Schottky in-plane gate (IPG) and wrap gate (WPG) 4. Surface and Interface Control Nano-Schottky interface Interface control layer (ICL)-based passivation 5. Device BDD node devices using gate-control quantum wire (QWR) and quantum dot (QD)

Digital Logic Architecture

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Digital processing (operations on digital functions) Implementation of digital functions Representation Boolean Equation Truth Table

etc. Binary Decision Diagram (BDD)

Implementation Binary Logic Gate Look-Up Table using Memory Transistor Switch ROM device

BDD Device

Hexagonal BDD QLSI Approach

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BDD logic architecture

BDD node device entry branch input 0

messenger Xi

1

0-branch 1-branch QWR switch

r1

root

tunnel barrier

input

0

0

x1

1 0

x12

x13

1 0

x1i

1

0

x1n

quantum dot

terminal

r2

0

Hexagonal network

1

0

0

x2

Boolean Logic Gate

f x1

1

1 0

x2

0

x1 f x2

1

3 devices

node

1

Example: Exclusive OR Logic Function BDD

1

5 gates, 16 Trs

Features of Our Approach

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BDD is suited to quantum devices No direct input-output connection is required •no precise voltage matching •no large voltage gain •no large current drivability •no large fan-in and fan-out

Conventional Logic Gate Architecture

Ultra-low delay-power product near the quantum limit Hexagonal quantum BDD

High density integration •hexagonal closely packed nanowire network •free from contact problem •reduced device count

root

few electron regime

many electron classical regime

r2

x1

x2

x3

node

x4

input

The circuit itself works at room temperature 1 at sacrifice of delay-power product IPG/WPG QWRTr-based BDD devices act as classical path switching devices even under non-quantum conditions. single electron regime

r1

xi xn 0

terminal

Basic Schottky Gate Structure

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Schottky In-Plane Gate (IPG) and Schottky Wrap Gate (WPG) control of AlGaAs/GaAs etched nanowires Schottky Schottky GaAs In-plane Gate (IPG) Wrap Gate (WPG) nanowire electrons AlGaAs GaAs

·lateral structure ·stronger confinement size ~ smaller AlGaAs/GaAs quantum wire nanowire

depletion layer WPG quantum wire transistor (QWRTr)

suitable for planar integration high temperature operation tunnel barrier control WPGs

quantum dot 2-gate WPG single electron transistor (SET)

Gate Control Characteristics of IPG/WPG Structures

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Controlof Weff

SdH oscillation

IPG QWRTr 4

Source Wgeo

T = 4.2K

800

3

400

1 Drain

1µm

0

600

-0.4V

2 IPG

-0.6V

0

1

2

3

4 5 B (T)

6

7

8

200 0

WPG QWRTr LG

Schottky WPG

5

W

500 nm

T=1.6 K

0

-1.5

-1 -0.5 VG (V)

0

WPG QWR

400

15 10

-2

500

20

GaAs exit branch

IPG QWR

VG=0V

-0.48V

-0.36V

300 -0.42V -0.24V

0

1

2

3 4 B (T)

200

VG=0V

5

6

100 0 -0.6

-0.4 -0.2 VG (V)

0

I-V Characteristics of IPG/WPG QWRTrs

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AlGaAs/GaAs etched nanowire IPG QWRTr 30

10

VG =0V

T = 300 K 25

T=1.7K

VG = 0 V

8

20

-0.2V

15

-0.4V

6 -0.05 V 4

10 -0.6V 5 0

WPG QWRTr

-0.1 V

2 -0.2 V

-0.8V 0

0.5

1.5

2

0

0

0.1

VDS (V)

3

2

1

4

W = 530 nm LG = 600 nm T=3K

3

-0.15 V

0.2 0.3 VDS (V)

0.4

0.5

W = 750 nm LG = 300 nm T = 1.7 K

2 1 1 0 -800

0 -600 -400 VG (mV)

-200

-600

-550 -500 VG (mV)

-450

Single Electron Transport in 2-WPG SET

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GaAs SET GaAs nanowire

Lateral resonant tunnling of single electron

WPG

e2 h

I=

|T(E)|2 [f (E) – f (E+qVDS)] dE

0.6 Breit-Wigner formula e 2 Γl Γr 1 ~ l r 4kTΓ +Γ cosh2 E-EF 2kT

0.5

AlGaAs

GaAs

0.4 0.3

Experiment 1.4 1.2 1.0 0.8 0.6 0.4 0.2

Theory

df = 160 nm, W = 820 nm T = 30 K 20 K 15 K 7.5 K 4.2 K 2.5 K 1.5 K

1.4 1.2 1.0 0.8 0.6 0.4 0.2

0.2 0.1

T = 30 K

0.0

0

5

10

5

10

20 K 15 K

60

4.2 K

40

2.5 K

20

1.5 K

20

25

20

25

30

80

7.5 K

0.0 0.0 -1.3 -1.25 -1.2 -1.15 -1.1 -1.3 -1.25 -1.2 -1.15 -1.1 VG (V) VG (V)

15 T (K)

0

0

15 T (K)

30

Various Types of BDD Node Devices by IPG/WPG Control of III-V Nanowires QWR-based BDD node device entry IPG

GaAs nanowire

WPG

QWR 0-branch

1-branch

Single electron BDD node device tunnel barrier

GaAs nanowire

WPG

quantum dot

WPG SET

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WPG BDD Quantum Node Device

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WPG QWR-based BDD device entry GaAs nanowire

500 nm

WPG single electron BDD devices entry GaAs nanowire

500 nm

WPG xi

xi

xi

xi

entry GaAs nanowire xi 0

1-branch

0-branch

0-branch

WPG 1-branch

WPG xi 1 1 µm

entry QWRTr

xi

0-branch

SET

xi

xi

xi

xi

xi

1-branch tunnel barrier

branch switch type

quantum dot

quantum dot

branch switch type

tunnel barrier

node switch type

Switching Characteristics

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QWR branch- switch BDD node device entry QWRTr

xi

xi

0-branch

1-branch

Switching characteristics

Branch I-V T = 300 K 4 1-branch

x

VG = 0 V

x

T = 300 K

0 -1

-0.2

3

0-branch

2

1-branch

-0.4

2

-0.6

1 0 0

-0.8 -1.0 100 200 300 400 500 VG (mV)

1

1 0 0

1

VDD = 200 mV 2 3 4 Time (s)

WPG BDD Single Electron Node Device

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entry 1 µm QD-based node switch GaAs nanowire device WPG xi 0-branch

Conductance oscillation from single channel 0.06

0.04

T = 1.5 K VGent = -3.0 V VGxi = 0.4 V 0-branch: open

-2.0

1-branch

Switching characteristics 3 2

0.02

0

xi

0-branch

VGent = -2.4 V VGxi = +0.4 V

1

-1.8

-1.6 -1.4 VGxi (V)

-1.2

0 -1.9

1-branch

T = 1.5 K

-1.8

-1.7 VGxi (V)

Conductance oscillation due to single electron transport Clear path switching

Quantum BDD Implementation

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Quantum BDD large scale integration hexagonal nanowire network + WPG 0

x1

1

0

x1

x1 1

WPG

x1 0

x2

10

x2 0

x2 1

x3

wiring

x2 x3 1

x3 0

x4

1

0

x4

x4 1

x4

branch cut-off (etching, FIB) one level metallization

WPG BDD OR Logic Function Block

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WPG single electron BDD OR circuit root

x1

hexagonal layout

x1

WPG

f node device

x2

0

x1

root 1

x2 1 GaAs nanowire

1000 nm 1- terminal

1

1-terminal

Operation of WPG BDD OR Logic

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Input/Output waveform

OR 0 x1 1 0 x2 1

1

0.3 0.2

T = 1.6 K x1 x2 output

0.1 0

0

2 VDD = 1 mV clock: 2 Hz

4 6 Time (s) x1: x2:

8

10

pulse height 100 mV 250 mV entry gate: 0 mV

0.7 0.6 0.5 0.4 0.3 0.2 0.1 0

T = 120 K x1 x2 output

0

50 VDD = 0.2 mV clock: 0.1 Hz

100 150 Time (s) x 1: x 2:

pulse height 1200 mV 1000 mV

200

entry gate: +1000 mV

WPG BDD Fundamental Logic Family

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OR

Half adder (exclusive OR) OR

0

0

x2

x1

1

1

x1 x2 0 0 0 1 1 0 1 1

ExOR

x1+x2 0 1 1 1

0

x2

1

x2

1

0

1

x1+ x2 0 1 1 0

1

1 x1

0.6

x1

0

x1 x2 0 0 0 1 1 0 1 1

120 K

RT

x1

x2

x2 output

0.4 output

20 nA

0.2 0

0

50

100 150 Time (s)

200

pulse height x1: 1200 mV x2: 1000 mV entry gate: +1000 mV VDD = 0.2 mV

0

5

10

15 20 25 Time (s) pulse h +x1: 0.02 V - x1: 0.44 +x2: 1.7 - x2: 0.1 VDD: 250 mV

30 offset -0.4 V -1.2 1.9 1.6

35

Circuit Design and Fabrication Technology Towards BDD Quantum Integrated Circuit

Example: BDD 2-bit adder

c1 1

root node

a1 0

c1

s0 a1

a1 0 0 a1 1

1

1

1

b1 0 1 b1 0 0 b1 1 1 a0 0

1

1

b0 0

0

b1

b1 1 0 b1 1

1

s1

1

b0 0

a1

1

0 1

s0

1 0

1

1

1 a1

1 0

b1

b1 a0 0

a0

1 1

b0

b0

0

0 1

terminal-1 sum: s1, s0 carry:c1

nanowire

1

root

s0

0 0

b1 b1

0 a0 1 1 a0 0

b0 0

augend: a1, a0 addend: b1, b0

0

s1

WPG/nanowire layout

s1 1

RC

Fabricated 2-bit adder circuit c1

circuit diagram

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terminal

WPG augend: a1, a0 addend: b1, b0 sum: s1, s0 carry:c1

a0

a1

WPG

b1 QWRTr node device

a0

b0

b0

GaAs nanowire

5 µm 1-terminal

Hexagonal BDD 2 bit Adder

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a1 WPG C

S1

b1

S0 node device

a0 a1 b1

b0 hexagonal nanowire network

a0 terminal 1

5 µm b0

input

a1 a0 b1 b0

800 600 400

carry

200 0 0

10

20

30

40 50 time (s)

60

70

80

T = 300 K VDD = 250 mV

InGaAs Ridge Nanowires for Room Temperature Operation AlGaAs/GaAs etched nanowires: possible minimum width = 70-100 nm Room temperature operation requires sub-10 nm width InGaAs ridge quantum wire

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PL

T=20K QWR

InAlAs

23meV InGaAs

3µm

patterned InP sub.

0.8

Formation Process

4µm

(111)A

Pre-growth etching & O desorption by atomic Hydrogen

narrowest QWR by H* cleaning

1.4

1µm

1.2

InP patterned sub.

InGaAs ridge

MBE growth of InGaAs

1.0 1.2 1.4 Energy (eV)

InGaAs ridge QWR

1.0 theory 0.8

Growth of InAlAs/InGaAs/InAlAs

0

10 20 30 40 50 Effective width, Weff (nm)

Wire width of 6 nm has been achieved

Hexagonal InGaAs Ridge Nanowire Network

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SEM image of hexagonal InGaAs nanowire network

AFM image

µm 0.8 0.4

µm

4 3 3 µm

4 2 1

1

2

3

( Ito et al. IPRM01, ICFSI-8)

Potential Controllability of Nanometer-Sized Schottky Gates

φMS = 1.0 eV Lg = 90nm

n-GaAs 1. With strong pinned surface

2. With unpinned surface

gate

gate

0.8 ~ -2.0 V step 0.4 V 500

0

500 (nm)

RC

nano-Schottky gate

Semiconductor surface 1. Strong pinning (0.88 eV) 2. Unpinning

0

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1000

0.8 ~ -2.0 V step 0.4 V 0

500 (nm)

1000

Control of an environmental Fermi level pinning is important

Conclusion

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1)

A new, simple and realistic approach for quantum LSIs is presented and discussed. •Architecture: BDD logic architecture •Hardware: Schottky WPG control of hexagonal III-V nanowire networks.

2)

WPG QWR and single electron BDD node devices using GaAs etched nanowires have been fabricated and BDD switching was realized.

3)

Hexagonal BDD ICs using GaAs etched nanowires have been fabricated. Logic operation has been confirmed.

4)

Hexagonal InGaAs nanowire network by H* assisted selective MBE combined with IPG/WPG gate technology gives good prospect for high density BDD QLSIs that are operating at delay-power products near the quantum limit at RT.

5)

Control of surface/interface remains to be a key issue.