Metamaterial absorber for efficient perovskite solar cell

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Triangular Wire. Below. Perovskite. Ag or TiN. HTM. Perovskite. Ag or TiN. HTM. Perovskite. Ag or TiN. HTM. Perovskite. Ag or TiN. HTM. 200nm. 600nm. 100nm.
Metamaterial absorber for efficient perovskite solar cell Omar Abdelraouf and Nageh Allam

Energy Material Laboratory, The American University in Cairo

Overview • Why metamaterial absorber • Modeling details • Proposed designs • Results • Current work

MRS Spring 2017

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Why metamaterial absorber surface • Metamaterial: artificial materials consist of periodic array and have exceptional properties • Tune absorption/reflection band of conventional materials from GHz to Optical wavelength https://www.mat.ucsb.edu/~g.legrady/academic/courses/1 0f200a/md/image/metamaterials.jpg

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Modeling Details • Light Absorption • Absorption enhancement

𝑨𝒃𝒔𝒐𝒓𝒑𝒕𝒊𝒐𝒏 𝝀 = 𝟏 − 𝑹 − 𝑻

𝑨𝒃𝒔𝒐𝒓𝒑𝒕𝒊𝒐𝒏 𝑵𝒂𝒏𝒐𝒔𝒕𝒓𝒖𝒄𝒕𝒖𝒓𝒆𝒔 (𝝀) 𝑨𝑬(𝝀) = 𝑨𝒃𝒔𝒐𝒓𝒑𝒕𝒊𝒐𝒏 𝑷𝒍𝒂𝒏𝒂𝒓 (𝝀)

• Optical generation 𝑮𝑶𝒑𝒕𝒊𝒄𝒂𝒍 𝝀 =

‫׬‬

• Generation (𝑚−3 𝑠𝑒𝑐 −1 ) 𝑮𝒆𝒏𝒆𝒂𝒕𝒊𝒐𝒏

(𝒎−𝟑 𝒔𝒆𝒄−𝟏 )

𝜺′′

𝟐

𝑬 𝒂𝒄𝒕𝒊𝒗𝒆 𝒍𝒂𝒚𝒆𝒓 𝒅𝒗 𝟐ℏ

𝑮𝑶𝒑𝒕𝒊𝒄𝒂𝒍 𝝀 = 𝑽𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝒂𝒄𝒕𝒊𝒗𝒆 𝒍𝒂𝒚𝒆𝒓

• Generation enhancement (𝑚−3 𝑠𝑒𝑐 −1 )

𝑮𝒆𝒏𝒆𝒓𝒂𝒕𝒊𝒐𝒏 (𝒎−𝟑 𝒔𝒆𝒄−𝟏 )𝑵𝒂𝒏𝒐𝒔𝒕𝒓𝒖𝒄𝒕𝒖𝒓𝒆𝒔 (𝝀) 𝑮𝑬(𝝀) = 𝑮𝒆𝒏𝒆𝒓𝒂𝒕𝒊𝒐𝒏 (𝒎−𝟑 𝒔𝒆𝒄−𝟏 )𝑷𝒍𝒂𝒏𝒂𝒓 (𝝀) MRS Spring 2017

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Proposed designs Circular Wire Below and above Perovskite Ag or TiN

HTM

Circular Wire Below Perovskite Ag or TiN

HTM

Triangular Wire Below and above Perovskite Ag or TiN

HTM

Triangular Wire Below Perovskite Ag or TiN

HTM

200nm

200nm

200nm

200nm

600nm

600nm

600nm

600nm

100nm

100nm

100nm

100nm

MRS Spring 2017

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Results Circular Wire Below and above Perovskite Ag or TiN

HTM

Circular Wire Below Perovskite Ag or TiN

HTM

Triangular Wire Below and above Perovskite Ag or TiN

HTM

Triangular Wire Below Perovskite Ag or TiN

HTM

200nm

200nm

200nm

200nm

600nm

600nm

600nm

600nm

100nm

100nm

100nm

100nm

MRS Spring 2017

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Circular Wire below and above perovskite Using Silver as metal

Using Titanium nitride instead silver

MRS Spring 2017

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Results Circular Wire Below and above Perovskite Ag or TiN

HTM

Circular Wire Below Perovskite Ag or TiN

HTM

Triangular Wire Below and above Perovskite Ag or TiN

HTM

Triangular Wire Below Perovskite Ag or TiN

HTM

200nm

200nm

200nm

200nm

600nm

600nm

600nm

600nm

100nm

100nm

100nm

100nm

MRS Spring 2017

8

Circular Wire below perovskite Using Silver as metal

Using Titanium nitride instead silver

MRS Spring 2017

9

Results Circular Wire Below and above Perovskite Ag or TiN

HTM

Circular Wire Below Perovskite Ag or TiN

HTM

Triangular Wire Below and above Perovskite Ag or TiN

HTM

Triangular Wire Below Perovskite Ag or TiN

HTM

200nm

200nm

200nm

200nm

600nm

600nm

600nm

600nm

100nm

100nm

100nm

100nm

MRS Spring 2017

10

Triangular Wire below and above perovskite Using Silver as metal

Using Titanium nitride instead silver

MRS Spring 2017

11

Results Circular Wire Below and above Perovskite Ag or TiN

HTM

Circular Wire Below Perovskite Ag or TiN

HTM

Triangular Wire Below and above Perovskite Ag or TiN

HTM

Triangular Wire Below Perovskite Ag or TiN

HTM

200nm

200nm

200nm

200nm

600nm

600nm

600nm

600nm

100nm

100nm

100nm

100nm

MRS Spring 2017

12

Triangular Wire below perovskite Using Silver as metal

Using Titanium nitride instead silver

MRS Spring 2017

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Optimum structures 1. Metamaterial surface with two layers • Total absorption  −3 −1 • Generation enhancement per (𝑚 𝑠𝑒𝑐 ) 

2. Metamaterial surface with one layer • Total absorption  −3 −1 • Generation enhancement per (𝑚 𝑠𝑒𝑐 )  Optimum structure is Circular Wire Below Perovskite MRS Spring 2017

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Current Work • Mie theory • Optimize light absorption and light scattering of metal/dielectric • Develop selection rules based on size/shape/material of metal/dielectric used.

• Genetic Algorithm • Use suggested dimensions for proposed designs as initial input to genetic algorithm code to give us more detailed results about optimized metamaterial surface for solar cell.

MRS Spring 2017

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Thank you MRS Spring 2017

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