Nanoscale

0 downloads 0 Views 867KB Size Report
Feb 28, 2018 - organic cation composition (Formammidinium, FA+;. Methylammonium, MA+; Cesium, Cs+) and halide ratio (Iodide,. I- and Bromide Br-) but all ...
View Article Online View Journal

Nanoscale Accepted Manuscript

This article can be cited before page numbers have been issued, to do this please use: E. J. Palomares, N. Fernandez-Montcada, M. Mendez, K. T. Cho and M. K. Nazeeruddin, Nanoscale, 2018, DOI: 10.1039/C8NR00180D. Volume 8 Number 1 7 January 2016 Pages 1–660

Nanoscale www.rsc.org/nanoscale

This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the author guidelines.

ISSN 2040-3364

PAPER Qian Wang et al. TiC2: a new two-dimensional sheet beyond MXenes

Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the ethical guidelines, outlined in our author and reviewer resource centre, still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains.

rsc.li/nanoscale

$

Page 1 of 6

%

% Nanoscale

& View Article Online

!" # . % ( % 01 )

#

$ '

4 4

56

!23

= % %

8
( " % % & % (/ > ( . < ( > . & & % % ( ( > % % . > % / . % ( . < % ( % % / %

& ( & >%

( (

1 : & &

% ( &

% % (

& .
: & .

! , .

,

/

& &

( (

5

$+

& ' 01 )

6'$78$ " 4 ; , ( % & ) ( (( !23

" #



%$0 1

" 9 : < &

/

%

+ !

".

. & &

& %

> C 7 &

( B"

/ /

. . &

%

( %

%

/ % > % ( . < < (

&

%

%

&

. :

(

% &

> < .

% 1 &

% / &

% /

5

( / > /

.

(

( . < / D1

% (

/

%

%

/ %

% &

(

+

&

.

%

% . & ( % % & & % % / % . / % . > % % / . @ 7 % ( ( % % / ( . < % 7 / % % / & ( / . % > & ! . & " ( " % !"A 8 . , > % - %. . , . -

-

%%

( >

% . % / >

/

.
. & $ ,τMB II N % / . $ " $D ,τM B N ( / . % ( > % , 1 %0 -

"!

$

-0

%

&

Nanoscale Accepted Manuscript

E (

$

Page 3 of 6

%

% Nanoscale

& View Article Online

DOI: 10.1039/C8NR00180D

+'" ,%

7&

$

= % (

% $D %

( (

& %

/-

8 $/

/ . % > > / > % & ( > %? > / >

$

%

"& % & % / . % ( . < & ( < ( A" O ( "& % % 7& ! $ % % > > % % & % F ( . < ( / & 7 8 " $/ ! ,7 F % & ,7 8 $/ % 7 ( . < % . / % % / / / % ( . ( . < & & 7 8 $/ > & % 2 & % & / % %% % / / & > / % / ( ( % % & ( / %& ( % % . % ( J >K ( , & % % ( 7 % % % % ,7 $/ !5 > > > % & % . > / 7& ! > $ % 7 8 $/ / 8 $/ % . ( & : 7 8 $/ > > & ( " % $ " $D % 7& !/ D1 > / % . / $ " $D % > % P 7 8 $/ % 8 $/ < % & / < > % . ( " % ( / ( %% " ( ( & & %( . < . &

/

8

(

(

%$

4

3$ " $D D1 %

,

8 $/ 7 8 $/ 7 8 $/ G "7 8 $/ G '

.

3

"

-


% " O ( > & & / " > / G % % & . % & %% % . ( % ( % / " & >% / %& ( > ( / ( G / & D1 > / % % " C 7& ! $ % & % 7 8 $/ G % 7 8 $/ > % & & % % & % > ( . + , % % " / % . . / & ( % " $ " $D &G ( 7& !/ > D1 % & & 7 > %( .
( (

8 $/ 7 8 $/ 7 8 $/ G

A !! A ! /

7& ! - $ 7 8 $/ G ( .
&

" " F

7 8 $/, :G

":-! ,

(

(

.
( : %

( (( %

%

%

/ /

R 0 % F

7 /

F

& "

G %

(

#

% %% %( .


%

&

&

(

> (

. < %

(

& %

& % ,7 & / & 7 8 $/ G % ( % / % / && % 7 8 $/ G % % /

/

& >

% /

7 8 $/ G % ,7 & ! - .% & !/%

. < ((

)

. ( $

& "(

+

G $ " $D D1

"

%

"

.
% < < 85 1 S A"O C " ( $ < > %& T U T ( C T BA! 8;5 5 7 $B $ / ) C B C V IC IA

% ?E > . / 7 8 $/ G

,

#

%

/

8

%

,* )

=

. +

%

%

(

%

(

& $ / %

.

(

% $ " $D .


&

>

>

/

&

.

&

%

$

% & :

% & %

( & (

/ %

- E / > ( & % &

& %

/

I

& >

,




. % / % ( % $ " $D

.

. < /

%

% $ " $D

% .

/

> 7

( %

( .

& % ( %

"&

&

%

1 %> & .

. %

+

"

&

%

/

2

.

(

%

O

?

>

A B

% &$

/ %

%

% %%

. > . > / % % . / E > . > % 1$D % . / ( % & "& % . / % & ( ( . < & & > ( $ " $D +

/#

C

5 % % %

/ (

%

%

( 3.

?

$ & / & %

. < /

% & / . % 0 / % % & % & % > (( %

!

%

8 4 "L ; 0 < 4 "$ 8 ; 5 : %% 8 W < %% = / E & % %8 T : & & ! A 0 2O2" 22B L W E & S E = "E & L L & % "G & ! / A -1 CC "CCA E 4 / 4 8 G T ( 5 ; 5 0 < 4 "= = & ; = > < % = W & " 4 C 2 I " I I E" ; % 5 "T $ < " 4 C 2 2 B" 2!C L W R G L L % 4 E & C 2 IBOC . 8 ; < %E 4 " 4 I 3 !O O"!O C 5 7 8 % 4 8 8 X "G + = / 4 4 9 :" Y( : / ; 8 ; 5 : %% % $ & 4 B - O " OB 4 8 :( : 8 4 G + %7 0 & O" B & & ! I 1 W : T E $ $ G 8 < 7 7 / & " & 8 " Y 4 G + % T T " G " 4 A 4 I I"I ! $ % 8 % 0 G R 4 5 G 1P & %$ 7 G A 4 !O! 8 0 G T 0 Z / 8 T % D 0Z : 5 : ; % % T T 8 G % 8 $ 4 8 G 8 % $ :: ! & / A 3 3 " 3 L W & 8 T ( 0 8 8 < 8 / = W & 8 % G $ :: 8 E : 8 G 4 E % E 4 / 6 : I - ! I"! 4 "$ "G "E " : = E & % % 4 G + % T & 4 B - AO "AOO

"!

$

%

%

&

/ "G

Nanoscale Accepted Manuscript

Published on 26 February 2018. Downloaded by Universitat Rovira I Vigili on 28/02/2018 09:43:40.

I

( /

((

/

/

"7 8 $/ G -

$

Page 5 of 6

%

% Nanoscale

& View Article Online

DOI: 10.1039/C8NR00180D

+'" ,%

I

Published on 26 February 2018. Downloaded by Universitat Rovira I Vigili on 28/02/2018 09:43:40.

A

B

O

2

!

C

I

4 E

T T % ; 8 $ 4 G + % W / & 4 B - 2I "2IA 4 = % $ ! & / A A I 2" 3 1 W : 8 "8 : 8 " 4 G + %T T "G " 4 I 3 ACI" AI G 8 L & R W & = = L L 4 G + T T "G ; W % $ " 4 I 3 CA2!"CB = 5 8 . 8 8 W < %% 8 ; 5 : %% % 8 T : & & ! I 1 22I" C T ( 0 < 8 8 G 4 8 E : %E 4 & & ! C 4 2O "2OO 5 $ $ T T T & "L L & 8 ; 5 : %% 4 8 % 8 T[: 9 & C 2. ! I "! IB = 0 G 4 & ; : = 4 5 % 4 0 " B !C2A" !I A E < 0 4 . & 0 G > & E ; % %8 0 8 T I 3 A !"A B 0 D % 8 L G L E & % / & ; ; . L . R W & $ 0 >/ 1 7 8 % E & %1 8 G < I ./4 I 2" I L 4 8 G :< 5 " T : 8 W < %% U / & % 8 T : & & ! A 0 AIA"AA E 4 4 & E "G ; ; G = < T "E ; %4 L ; & C 4 O "OI

Nanoscale Accepted Manuscript

C

!

$

%

%

&

"! # 2

Published on 26 February 2018. Downloaded by Universitat Rovira I Vigili on 28/02/2018 09:43:40.

248x130mm (72 x 72 DPI)

Nanoscale Accepted Manuscript

Nanoscale View Article Online

Page 6 of 6

DOI: 10.1039/C8NR00180D