Reagents for Glyco Chemistry & Biology 4th Edition

Table of Contents Table of Contents / 目次 ....................................................................................1 The Functional Oligosaccharides Chain / 機能性糖鎖 ..................................2 TCI Website / ホームページのご案内 ...................................................................4 Catalog Usage・Abbreviations Used in the Catalog / 凡例・略号一覧 .....6 Carbohydrates / 糖 Allose ..............................................................................................................7 Arabinose .......................................................................................................8 Erythrose .........................................................................................................9 Fructose ........................................................................................................10 Fucose ..........................................................................................................11 Galactose ....................................................................................................13 Galactosamine ...........................................................................................20 Glucose ........................................................................................................22 Glucosamine ...............................................................................................38 Gulose...........................................................................................................44 Idose .............................................................................................................45 Inositol ...........................................................................................................46 Lyxose ...........................................................................................................48 Mannose ......................................................................................................49 Mannosamine ..............................................................................................53 Psicose ..........................................................................................................54 Rhamnose ....................................................................................................55 Ribose ...........................................................................................................56 Sialic Acids ...................................................................................................59 Sorbose .........................................................................................................61 Tagatose ......................................................................................................62 Talose ............................................................................................................63 Xylose ............................................................................................................64 Disaccharides ..............................................................................................66 Trisaccharides ..............................................................................................77 Tetrasaccharides .........................................................................................83 Oligosaccharides ........................................................................................85 Polysaccharides ..........................................................................................91 Others ...........................................................................................................95 Reagents for Oligosaccharide Synthesis / 糖鎖合成用反応剤 ...................101 Applications for Sugar-conjugates / 糖鎖コンジュゲートへの応用 ............113 Enzymes / 酵素 Glycosynthase (Endo-M-N175Q) .............................................................114 Endo-M .......................................................................................................116 Endo-α ........................................................................................................117 Glycohydrolase .........................................................................................118 Lectin, Fucose Specific / L-フコース特異的レクチン ....................................120 Antibodies / 抗体 Anti-Glyco Antibodies...............................................................................121 Secondary Antibodies ..............................................................................125 NMR Data / NMR データ .................................................................................127 Product Name Index / 製品名索引 ................................................................319 Appendix / 付録 Basic Structures of Glycolipids / 糖脂質の基本構造 ....................................330 Basic Structures of Glycoproteins / 糖タンパク質の基本構造 ....................331 Basic Structures of Proteoglycans / プロテオグリカンの基本構造 .............332 The Physical Properties of the Typical Organic Solvents・ Freezing Mixtures / おもな有機溶剤の物性・冷却剤とその最低温度 .............333 Preparation of Reagents and Solutions / おもな試薬溶液の調製法 ..........334 Pressure-Temperature Nomograph / 沸点換算図表..................................338 TCI Local Offices / 海外事業所 .......................................................................339 TCI Distributors / 弊社製品取扱店一覧 ..............................................................340 General Information / 試薬のご購入，ご使用時の注意 ..................................347 www.TCIchemicals.com

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The Functional Oligosaccharides Chain-① ■ We are ready to meet your demand. Feel free to send us any serious inquiry, please refer to our contact information

listed on the back cover.

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The Functional Oligosaccharides Chain-② ■ 下記のような機能性糖鎖をご提供いたします。アグリコン（R 部分）につきましては、様々な修飾が可能です。掲載のない糖鎖につきましてもご対応いたしますので、是非お問い合わせ下さい。機能性糖鎖・糖鎖合成中間体の受託合成をお考えの方は、本冊子の最終ページをご確認の上、どうぞお気軽にご連絡・ご相談下さい。


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TCI Website


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Reagents for Glyco-Chemistry & Biology

糖鎖関連試薬

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Catalog Usage

-- M1589

-- 4-Methoxyphenyl 3-O-Allyl-4,6-O-benzylidene-β-D-galactopyranoside 1g 5g-Ph

>98.0%(LC) C23H26O7 = 414.45 [400091-05-6] MFCD06797132 mp 228℃

O

O

NMR P.140

O O

O

OCH3

HO

B0643

25g 500g

Allyl Bromide

-- >98.0%(GC)

C3H5Br = 120.98 [106-95-6] MFCD00000244 bp 71℃ d 1.43 flp 12℃

--

Beil. 1,201 MI14-288

A1651

CH2

RTECS UC7090000

endo-β-N-Acetylglucosaminidase (= Endo-M) Recombinant: from Mucor

Br

100munits

hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)] [37278-88-9] MFCD00151069 EC 3.2.1.96

Product Number Please use the product number

製品コードご注文の際にご利用ください。製品名分子式分子量 CAS 番号（Chemical Abstracts Service Registry Number）

with the chemical name when inquiring and ordering.

Chemical Name Molecular Formula Molecular Weight CAS Registry Number (Chemical Abstracts Service

MDL 番号 * 包装単位構造式純度・含量物理的性質 fp：凝固点（℃）／ mp：融点（℃）／ bp：沸点（℃) ／ d：比重／ flp：引火点（℃)

Registry Number)

MDL Number* Quantity Structural Formula Purity Physical Property fp : freezing point(℃) / mp : melting point(℃) / bp : boiling point(℃) / d : specific gravity / flp : flash point(℃)

参考値として記載しました。規格値ではありません。

参考文献 Beil.：Beilstein（巻数（増補編）パート，頁 ) ／ MI14：Merck Index 14th edition** モノグラフ番号／ F&F：Fieser & Fieser（巻数，頁 ) RTECS 番号（化学物質毒性登録番号（米国））酵素番号 NMR NMR データをご用意しております。

from literature, and not necessarily product specification.

References Beil. : Beilstein(vol. (suppl.) part, page) / MI14 : Monograph Number from "The Merck Index", 14th edition** / F&F : Fieser & Fieser's "Reagents for Organic Synthesis"; vol, page RTECS Number (Registry of Toxic Effects of Chemical Substances Number)

*Reproduced with license of MDL Available Chemicals Directory. **Reproduced with permission from The Merck Index, Fourteenth Edition. Copyright ⓒ 2006 by Merck & Co., Inc., Whitehouse Station, NJ, USA. All rights reserved.

EC Number (Enzyme Commission Number) NMR NMR data are prepared.

> Ac All Bn Boc Bz Fmoc Gal

acetyl allyl benzyl tert-butoxycarbonyl benzoyl (9H-fluoren-9-ylmethoxy)carbonyl galactose

Glc MP Ph pNP

SDS-PAGE sodium dodecylsulfate-polyacrylamide gel electrophoresis Xyl


6

glucose 4-methoxyphenyl phenyl p-nitrophenyl

xylose

Allose A1982 Allitol

100mg CH2OH

>98.0%(GC) C6H14O6 = 182.17 [488-44-8] mp 152℃ Beil. 1(4)2839 RTECS BA1840000

H

OH

H

OH

H

OH

H

OH CH2OH

A1488

D-(+)-Allose

100mg 1g

>98.0%(LC) C6H12O6 = 180.16 [2595-97-3] MFCD00135833 mp 149℃ Beil. 1(4)4299 MI14-280

OH

HO

HO

D2265 1,2:5,6-Di-O -isopropylideneα-D-allofuranose

1g 5g

>98.0%(GC) C12H20O6 = 260.29 [2595-05-3] MFCD00135634 mp 75℃ Beil. 19(5)12,318

F0542

OH O

HO

CH3

O

CH3

O O HO

O O

CH3 CH3

4-Formylphenyl β-D-Allopyranoside

>98.0%(LC) C13H16O7 = 284.26 [80154-34-3] mp 190℃

5g OH O

HO

O O

HO

C H

HO

Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use.


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Arabinose A0513

D-(-)-Arabinose

25g HO

>98.0%(GC) C5H10O5 = 150.13 [10323-20-3] MFCD00135608 mp 161℃ Beil. 1(4)4215

A0515

OH HO

L-(+)-Arabinose

25g 250g OH

>98.0%(GC) C5H10O5 = 150.13 [5328-37-0] MFCD00135866 mp 156℃ Beil. 1(4)4218 MI14-761

A0517

O

HO

OH

O

HO

OH

DL-Arabitol

100mg OH

>95.0%(GC) C5H12O5 = 152.15 [6018-27-5] MFCD00070503 Beil. 1(4)2832 MI14-762

OH

HO OH

OH

relative

A0516

D-(+)-Arabitol

1g 25g CH2OH


HO

H

H

OH

H

OH CH2OH

A0518

L-(-)-Arabitol

1g 25g CH2OH


H

OH

HO

H

HO

H CH2OH

M1019 Methyl β-D-Arabinopyranoside

100mg HO

>99.0%(GC) C6H12O5 = 164.16 [5328-63-2] MFCD00063261 mp 174℃

O

HO

OCH3

HO

T2695

2,3,4-Tri-O -acetyl-β-L-arabinopyranosyl 2,2,2-Trichloroacetimidate

Price on request AcO

C13H16Cl3NO8 = 420.62 [869848-87-3] NMR P.136

NH

OAc O

O C CCl3 OAc

試験，研究を目的とした弊社収載化学品は，その使用により発生した特許法上の諸問題をユーザーの方々に保証するものではありません。

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Erythrose D1320 Dithioerythritol

5g 25g

>98.0%(T) C4H10O2S2 = 154.24 [6892-68-8] MFCD00063750 mp 84℃ Beil. 2(3)2360 RTECS KF2410000

E0021 meso -Erythritol

D-Erythronolactone

>98.0%(GC) C4H6O4 = 118.09 [15667-21-7] MFCD00077763 mp 103℃ Beil. 18,78

I0454

SH OH

25g 500g

>99.0%(LC)(T) C4H10O4 = 122.12 [149-32-6] MFCD00004710 mp 120℃ Beil. 1,525 MI14-3675 RTECS KF2000000

E0455

OH HS

OH HO

OH OH

1g 5g 25g O HO

O OH

2,3-O -Isopropylidene-D-erythronolactone


1g O

O

O

O

H3C

CH3



9

Fructose D3758 2,3:4,5-Di-O -isopropylideneβ-D-fructopyranose

5g 25g CH3 O


O

D-(-)-Fructose

OH

O

25g 500g

>98.0%(LC) C6H12O6 = 180.16 [57-48-7] MFCD00148910 Beil. 31,321 MI14-4273 RTECS LS7120000

OH O

HO

CH2OH OH

F0317

O

CH3 CH3

F0060

O

CH3

L-(+)-Fructose

OH

100mg 1g OH

>97.0%(LC) C6H12O6 = 180.16 [7776-48-9] MFCD05662378

OH CH2OH

O

HO

OH

New

T2755

Topiramate

1g 5g

>98.0%(LC)(T) C12H21NO8S = 339.36 [97240-79-4] MFCD00865320 mp 126℃ MI14-9547 RTECS LS7083000

CH3 O O

O

CH3 O

CH3 CH3

O



OSO2NH2

Fucose-① D0049

D-(+)-Fucose

1g 5g HO

>98.0%(GC) C6H12O5 = 164.16 [3615-37-0] MFCD00135603 mp 137℃ Beil. 31,76 MI14-4278

F0065

CH3

O

HO

OH

HO

L-(-)-Fucose

1g 10g CH3

>97.0%(GC) C6H12O5 = 164.16 [2438-80-4] MFCD00135607 Beil. 31,78 MI14-4279

O

HO

OH OH

OH

M1051 Methyl α-L-Fucopyranoside

1g OCH3

C7H14O5 = 178.18 [14687-15-1] MFCD00069802 mp 159℃

CH3

O

HO

OH

OH

M1050 Methyl β-L-Fucopyranoside

1g CH3

C7H14O5 = 178.18 [24332-98-7] MFCD00069803 mp 123℃

O

HO

M1626 Methyl 2,3,4-Tri-O -acetyl-1-thioβ-L-fucopyranoside

OCH3 OH

OH

1g 5g CH3

>98.0%(LC) C13H20O7S = 320.36 [84635-54-1] MFCD00080803 mp 148℃ NMR P.137

O

AcO

M1628 Methyl 2,3,4-Tri-O -benzyl-1-thioβ-L-fucopyranoside

SCH3 OAc

OAc

1g CH3


O

BnO

SCH3 OBn

OBn

N0392 4-Nitrophenyl α-L-Fucopyranoside

10mg O

>98.0%(LC) C12H15NO7 = 285.25 [10231-84-2] MFCD00063697 CH3 HO

O

OH

OH



NO2

11

Fucose-② N0774 4-Nitrophenyl β-D-Fucopyranoside >98.0%(GC) C12H15NO7 = 285.25 [1226-39-7] mp 184℃

100mg HO

CH3

O

HO

O

NO2

HO

P1842

Phenyl 2,3,4-Tri-O -benzyl-1-thioβ-L-fucopyranoside

>98.0%(LC) C33H34O4S = 526.69 [167612-35-3] mp 108℃

T2207

1g 5g CH3 BnO

OBn

1,2,3,4-Tetra-O -acetylα-L-fucopyranose

>98.0%(LC) C14H20O9 = 332.31 [64913-16-2] MFCD00069791 mp 94℃ Beil. 17(3/4)2549

1g 5g OAc CH3 AcO

O OAc



SPh OBn

O

OAc

Galactose-① A1413 4-Aminophenyl β-D-Galactopyranoside HO

>95.0%(T) C12H17NO6 = 271.27 [5094-33-7] MFCD00067362 mp 163℃ Beil. 17(3/4)3409

G0257 2-[2-(2-Azidoethoxy)ethoxy]ethyl 2,3,4,6-Tetra-O -acetylD-galactopyranoside

1g OH O

HO

O

1g 5g AcO

OAc O

AcO

>96.0%(N) C20H31N3O12 = 505.48 [381716-33-2] MFCD00191441

B3201 5-Bromo-4-chloro-3-indolyl β-D-Galactopyranoside [for Biochemical Research]

AcO

O

O

HO

OH O

Cl O

HO

>98.0%(LC)(N) C14H15BrClNO6 = 408.63 [7240-90-6] MFCD00005666 MI14-10074

B3469 5-Bromo-6-chloro-3-indolyl β-D-Galactopyranoside (contains ca . 10%

20mg 100mg HO

OH O N H

HO

OH O

HO

[for Biochemical Research]

Br

O HO

N H

20mg 100mg HO

OH O

HO

>98.0%(LC) C14H16ClNO6 = 329.73 [138182-21-5] MFCD00467206

O HO

N H

D0050 2-Deoxy-D-galactose C6H12O5 = 164.16 [1949-89-9] MFCD00014649 mp 112℃

Cl

1g HO

OH O

HO



Cl

20mg 100mg

>98.0%(LC) C14H16BrNO6 = 374.19 [97753-82-7] MFCD00063691

C2371 6-Chloro-3-indolyl β-D-Galactopyranoside

Br

O HO

>98.0%(LC) C14H15BrClNO6 = 408.63 [93863-88-8] MFCD00210022

[for Biochemical Research]

Br

N H

HO

B3470 5-Bromo-3-indolyl β-D-Galactopyranoside

N3

O

200mg 1g HO

Ethyl Acetate) [for Biochemical Research]

NH2

HO

OH

13

Galactose-② D2555 1,2:3,4-Di-O -isopropylideneα-D-galactopyranose

5g 25g OH O

CH3 O

>92.0%(GC) C12H20O6 = 260.29 [4064-06-6] MFCD00063225 bp 133℃ /0.2mmHg Beil. 19(5)12,366

G0273

O

CH3

O

CH3

O

CH3

D-Galactal

1g 5g HO

>98.0%(LC) C6H10O4 = 146.14 [21193-75-9] MFCD00038067 Beil. 17(5)5,698

OH O

HO

G0005 Galactitol

25g 250g CH2OH


H

OH

HO

H

HO

H

H

OH CH2OH

G0008

D-(+)-Galactose

Anhydrous

25g 500g HO

>97.0%(LC) C6H12O6 = 180.16 [59-23-4] MFCD00151230 Beil. 1(4)4336 MI14-4335 RTECS LW5490000

OH O

HO HO

G0267

L-(-)-Galactose

100mg 500mg HO

>98.0%(LC) C6H12O6 = 180.16 [15572-79-9] MFCD00063833 Beil. 1(4)4343

G0010 α-D-Galacturonic Acid Hydrate >95.0%(T) C6H10O7・xH2O = 194.14(Anh) [91510-62-2] MFCD00006618 Beil. 3(4)2000 MI14-4337

5g 25g OH COOH O

. xH2O

HO

Isopropyl 1-Thio-β-D-galactopyranoside

OH

1g 5g HO

OH O

HO

S HO



OH

OH

HO

>98.0%(GC) C9H18O5S = 238.30 [367-93-1] MFCD00063273 MI14-5082

OH

O HO

I0328

OH

CH3 CH3

Galactose-③ M1620 4-Methoxyphenyl 3-O -Allyl2-O -benzyl-4,6-O -benzylideneβ-D-galactopyranoside

1g Ph O

>98.0%(LC) C30H32O7 = 504.58 MFCD06797140 mp 177℃ NMR P.139

M1589 4-Methoxyphenyl 3-O -Allyl4,6-O -benzylideneβ-D-galactopyranoside

O O

O

OCH3

OBn

1g 5g Ph O

>98.0%(LC) C23H26O7 = 414.45 [400091-05-6] MFCD06797132 mp 228℃ NMR P.140

O

O O

O

O

OCH3

HO

M1590 4-Methoxyphenyl 3-O -Allyl-4,6-O benzylidene-2-O -(4-methylbenzoyl)β-D-galactopyranoside

1g Ph O

O O

>98.0%(LC) C31H32O8 = 532.59 MFCD06797133 NMR P.141

O

O CH3

O

M1482 4-Methoxyphenyl 3-O -Allylβ-D-galactopyranoside >98.0%(LC) C16H22O7 = 326.35 [144985-19-3] MFCD06797127 mp 143℃ NMR P.142

M1725 4-Methoxyphenyl 3-O -Benzylβ-D-galactopyranoside >98.0%(LC) C20H24O7 = 376.41 [383905-60-0] mp 154℃ NMR P.143

M1710 4-Methoxyphenyl 4,6-O -Benzylideneβ-D-galactopyranoside C20H22O7 = 374.39 [176299-96-0] NMR P.144

OCH3

O

5g OH

OH O

O

O

OCH3

HO

1g 5g HO

OH O

BnO

O

OCH3

HO

Price on request Ph O

O O

HO

O

OCH3

HO

M1597 4-Methoxyphenyl 2,6-Bis-O -(4-methylbenzoyl)β-D-galactopyranoside >98.0%(LC) C29H30O9 = 522.55 MFCD06797138 NMR P.145

1g O CH3 OH

O O

HO

O

OCH3

O O

CH3



15

Galactose-④ M1634 4-Methoxyphenyl 2,6-Di-O -benzylβ-D-galactopyranoside

1g HO


M1633 4-Methoxyphenyl 2,6-Di-O -benzyl3,4-O -isopropylideneβ-D-galactopyranoside

OBn O

HO

O

OCH3

OBn

1g O

CH3 CH3

OBn O

O

O

OCH3

OBn


M1481 4-Methoxyphenyl β-D-Galactopyranoside

5g 25g OH

>98.0%(LC) C13H18O7 = 286.28 [3150-20-7] MFCD06797126 mp 160℃ Beil. 17(3/4)2984 NMR P.148

OH O

HO

O

OCH3

HO

M1596 4-Methoxyphenyl 3,4-O -Isopropylidene2,6-bis-O -(4-methylbenzoyl)β-D-galactopyranoside

1g O CH3 CH3 CH3

>95.0%(LC) C32H34O9 = 562.62 MFCD06797137 NMR P.149

O

O

O O

O

OCH3

O CH3

O

M1593 4-Methoxyphenyl 3,4-O -Isopropylideneβ-D-galactopyranoside

CH3

>98.0%(LC) C16H22O7 = 326.35 [159922-67-5] MFCD06797135 NMR P.150

CH3

1g O

O O

OCH3

CH3 CH3

1g O CH3 O

O O

O

O

OCH3

OH

M1477 4-Methoxyphenyl 2,3,4,6-Tetra-O -acetylβ-D-galactopyranoside AcO >98.0%(LC) C21H26O11 = 454.43 [2872-65-3] MFCD06797123 mp 105℃ NMR P.152

O OH

M1594 4-Methoxyphenyl 3,4-O -Isopropylidene6-O -(4-methylbenzoyl)β-D-galactopyranoside >98.0%(LC) C24H28O8 = 444.48 MFCD06797136 NMR P.151

OH

5g 25g OAc O

AcO

O OAc



OCH3

Galactose-⑤ M1588 4-Methoxyphenyl 2,3,4,6-Tetra-O -benzylβ-D-galactopyranoside BnO >98.0%(LC) C41H42O7 = 646.78 [143536-99-6] MFCD06797131 mp 110℃ NMR P.153

OBn O

BnO

O

OCH3

OBn

M2104 4-Methoxyphenyl 2,3,6-Tri-O -benzylβ-D-galactopyranoside C34H36O7 = 556.66 [869107-36-8]

5g

Price on request HO

OBn O

BnO

O

OCH3

OBn

M1592 4-Methoxyphenyl 2,4,6-Tri-O -benzylβ-D-galactopyranoside >98.0%(LC) C34H36O7 = 556.66 [247027-79-8] MFCD06797134 mp 94℃ NMR P.154

1g BnO

OBn O

HO

O

OCH3

OBn

M1047 Methyl α-D-Galactopyranoside Monohydrate

5g 25g HO

>97.0%(GC) C7H14O6・H2O = 194.18(Anh) [3396-99-4] MFCD00064085 mp 108℃

OH O

2

HO

M1035 Methyl β-D-Galactopyranoside HO

[Substrate for β-D-Galactosidase] >98.0%(LC) C12H15NO8 = 301.25 [369-07-3] MFCD00063255

OH O

HO

OCH3

HO

5g 25g 250g HO


N0418 2-Nitrophenyl β-D-Galactopyranoside

OCH3

1g 5g


M1933 Methyl 2,3,6-Tri-O -benzoylα-D-galactopyranoside

.H O

HO

OBz O

BzO BzO

OCH3

1g 5g 25g HO

OH O

HO

O2N O

HO



17

Galactose-⑥ N0492 4-Nitrophenyl α-D-Galactopyranoside

200mg 1g

[Substrate for α-D-Galactosidase]

HO

>98.0%(LC) C12H15NO8 = 301.25 [7493-95-0] MFCD00065050 mp 168℃

OH O

HO HO

O

N0616 4-Nitrophenyl β-D-Galactopyranoside [Substrate for β-Galactosidase] >98.0%(LC) C12H15NO8 = 301.25 [3150-24-1] MFCD00063256 mp 180℃ Beil. 17(5)7,55

G0247 Penta-O -acetyl-β-D-galactopyranose >97.0%(GC) C16H22O11 = 390.34 [4163-60-4] MFCD00063259 mp 145℃ Beil. 17(5)7,322

New

P2078

Phenyl 2-O -Acetyl-3,4,6-tri-O -benzyl1-thio-β-D-galactopyranoside

C35H36O6S = 584.73 [183875-28-7] NMR P.156

P1660

Phenyl 3-O -Allyl-2,4,6-tri-O -benzyl1-thio-β-D-galactopyranoside

>98.0%(LC) C36H38O5S = 582.76 [1017587-57-3]

NO2

1g 5g HO

OH O

HO

O

NO2

HO

25g 250g AcO

OAc O

AcO

OAc OAc

Price on request OBn OBn O BnO SPh OAc

1g BnO

OBn O

O

SPh OBn

P1326

Phenyl β-D-Galactopyranoside

>98.0%(LC) C12H16O6 = 256.25 [2818-58-8] MFCD00063258 mp 148℃ Beil. 17(5)7,47

P1477

Phenyl 2,3,4,6-Tetra-O -acetyl-1-thioβ-D-galactopyranoside

C20H24O9S = 440.46 [24404-53-3] NMR P.157

1g 5g HO

OH O

HO

OPh HO

5g 25g AcO

OAc O

AcO

SPh OAc



Galactose-⑦ P1679

Phenyl 2,3,4,6-Tetra-O -benzyl-1-thioβ-D-galactopyranoside


P1680

1g BnO BnO

SPh OBn

Phenyl 2,4,6-Tri-O -acetyl-3-O -allyl1-thio-β-D-galactopyranoside

1g AcO

>98.0%(LC) C21H26O8S = 438.49 NMR P.159

T2295

OBn O

OAc O

O

SPh OAc

2,3,4,6-Tetra-O -acetylα-D-galactopyranosyl 2,2,2-Trichloroacetimidate

1g 5g AcO

OAc O

AcO AcO

>93.0%(LC) C16H20Cl3NO10 = 492.68 [86520-63-0] MFCD07369652 mp 122℃ NMR P.160

T1734

Tri-O -acetyl-D-galactal

1g 5g AcO

>95.0%(GC) C12H16O7 = 272.25 [4098-06-0] MFCD00064092 Beil. 17(5)5,700

T1932

T1858

100mg BnO

OBn O

BnO

OH

Tri-O -benzyl-D-galactal

1g BnO


T1935

OAc O

AcO

3,4,6-Tri-O -benzyl-2-deoxyD-galactopyranose

>98.0%(LC) C27H30O5 = 434.53 [94189-64-7] MFCD06797169

NH O C CCl3

BnO

6-O -(Triisopropylsilyl)-D-galactal

>97.0%(GC) C15H30O4Si = 302.49 [166021-01-8]

OBn O

200mg HO

OSi[CH(CH3)2]3 O

HO



19

Galactosamine-① A1245 N -Acetyl-D-galactosamine Hydrate

1g 5g HO

>98.0%(LC)(N) C8H15NO6・xH2O = 221.21(Anh) [14215-68-0] MFCD00065372 Beil. 4(4)2039

.xH O

OH O

2

HO

OH

AcHN

A1833 O -(2-Azido-4,6-O -benzylidene-2-deoxyα-D-galactopyranosyl)-N -[(9H -fluoren-9ylmethoxy)carbonyl]-L-serine tert -Butyl Ester

100mg Ph O

O O

>92.0%(LC) C35H38N4O9 = 658.71 [878483-02-4] NMR P.161

O

HO N3 O

OC(CH3)3 HN

A1832 O -(2-Azido-4,6-O -benzylidene-2-deoxyα-D-galactopyranosyl)-N -[(9H -fluoren-9-ylmethoxy) carbonyl]-L-threonine tert -Butyl Ester

Fmoc

100mg Ph O

O O

HO

>97.0%(LC) C36H40N4O9 = 672.74 [195976-07-9] NMR P.162

N3 O CH3

OC(CH3)3 HN

New

A2627 2-Azidoethyl 2-Acetamido-2-deoxyβ-D-galactopyranoside

D-(+)-Galactosamine

HO

OH O

HO

O

1g 5g HO

>98.0%(LC)(N) C6H13NO5・HCl = 215.63 [1772-03-8] MFCD00135830 MI14-4334 RTECS LW5500000

OH O

HO H2N

C14H18N2O8 = 342.30 [14948-96-0] MFCD00067360 mp 207℃ Beil. 18(5)11,102

O O

O

O

OCH3

Price on request HO

OH O

HO

O AcHN



.HCl

1g

N3

N0865 4-Nitrophenyl 2-Acetamido-2-deoxyβ-D-galactopyranoside

OH

Ph O

>95.0%(LC) C23H25N3O6 = 439.47 [889453-83-2] NMR P.164

N3

AcHN

Hydrochloride

M1643 4-Methoxyphenyl 3-O -Allyl-2-azido4,6-O -benzylidene-2-deoxyβ-D-galactopyranoside

Fmoc

Price on request

C10H18N4O6 = 290.28 [142072-15-9] MFCD19981043 NMR P.163

G0007

O

NO2

Galactosamine-② P1643

Phenyl 2-Deoxy-1-thio2-(2,2,2-trichloroethoxyformamido)β-D-galactopyranoside

Price on request HO HO

C15H18Cl3NO6S = 446.72 [868230-98-2] NMR P.165

P1642

SPh NH C OCH2CCl3 O

Phenyl 3,4,6-Tri-O -acetyl-2-deoxy-1-thio2-(2,2,2-trichloroethoxyformamido)β-D-galactopyranoside

1g 5g AcO AcO

>98.0%(LC)(N) C21H24Cl3NO9S = 572.83 [278784-83-1] mp 117℃ NMR P.166

T1731

OH O

1,3,4,6-Tetra-O -acetyl-2-azido-2-deoxyα-D-galactopyranose

C14H19N3O9 = 373.32 [67817-30-5] MFCD01076182 mp 121℃ Beil. 17(5)6,400 NMR P.167

OAc O SPh NH C OCH2CCl3 O

100mg AcO

OAc O

AcO N3



OAc

21

Glucose-① A2253 2-Acetyl-5-methoxyphenyl β-D-Glucopyranoside

HO HO

C15H20O8 = 328.32 [20309-70-0] mp 83℃ Beil. 17(4)3020 NMR P.168

New

Price on request OH O

Ac O

HO

A2636 6-O -Acetyl-2,3,4-tri-O -benzylD-glucopyranose

OCH3

Price on request OAc O

BnO BnO

C29H32O7 = 492.57 [85011-34-3]

A1074 1,6-Anhydro-β-D-glucose

1g 5g

>99.0%(GC) C6H10O5 = 162.14 [498-07-7] MFCD00063248 mp 183℃

OH O HO

New

OH

OBn

A2637 1,6-Anhydro-2,3,4-tri-O -benzylβ-D-glucopyranose

O

OH

Price on request OBn O

C27H28O5 = 432.52 [10548-46-6] OBn

A0522 Arbutin

O

OBn

5g 25g

>95.0%(LC) C12H16O7 = 272.25 [497-76-7] MFCD00016915 mp 198℃ Beil. 31,210 MI14-773 RTECS CE8863000

HO HO

OH O O

OH

HO

A2267 2-Azidoethyl β-D-Glucopyranoside >98.0%(LC) C8H15N3O6 = 249.22 [165331-08-8]

1g HO HO

OH O O HO

A2377 2-Azidoethyl 2,3,4,6-Tetra-O -acetylβ-D-glucopyranoside >92.0%(LC) C16H23N3O10 = 417.37 [140428-81-5] mp 115℃ NMR P.169

1g 5g AcO AcO

OAc O O OAc



N3

N3

Glucose-② B2835 Baicalin

25g

>90.0%(T) C21H18O11 = 446.36 [21967-41-9] MFCD00134418 mp 196℃ Beil. 18(3/4)5154 RTECS LZ5776910

New

HOOC HO HO

B4170 Benzyl 2,3-Di-O -benzyl4,6-O -benzylideneβ-D-glucopyranoside

HO

O

OH O

O

HO

O

Price on request Ph

O O BnO

O OBn

OBn

C34H34O6 = 538.64 [183953-29-9] mp 136℃ NMR P.170

New

B4171 Benzyl 2,3,4-Tri-O -benzylβ-D-glucopyranoside


BnO BnO

C34H36O6 = 540.66 [27851-29-2] MFCD03701135 mp 103℃ NMR P.171

G0037 Calcium Gluconate Monohydrate

25g 500g COO

>98.0%(T) C12H22CaO14・H2O = 430.37(Anh) [299-28-5] MFCD00064209 Beil. 3,544 MI14-1669 RTECS EW2100000

H

OH

HO

H

H

OH CH2OH

2

C2548 Capsaicin β-D-Glucopyranoside >90.0%(LC) C24H37NO8 = 467.56 [153409-16-6]

HO HO

. H2O

Ca2

OH

H

New

OBn

BnO

200mg OH O O HO

CH3

H N

CH3O

CH3

O

C0543 Carmine

5g 25g

[1390-65-4] MFCD00167028 MI14-1843 RTECS FH8891000

HO HO

OH O

Aluminum Calcium Lake OH O

CH3

HO HO

C22H20O13 = 492.39 [1260-17-9] MFCD00167028 Beil. 10(2)776 MI14-1843

OH

OH O

C0782 Carminic Acid (Natural dye)

COOH

5g 25g HO HO

OH O

OH O

HO HO

OH O

CH3

COOH OH

The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care.


23

Glucose-③ C0074 α-Chloralose (contains β-isomer)

25g HO

>85.0%(GC) C8H11Cl3O6 = 309.52 [15879-93-3] MFCD00005542 mp 181℃ MI14-2072 RTECS FM9450000

HO

OH O O O CCl3

G0275 Copper(II) Gluconate

25g COO

>97.0%(T) C12H22CuO14 = 453.84 [527-09-3] MFCD00075297 Beil. 3(4)1256 MI14-2640 RTECS LZ5058000

H

OH

HO

H

H H

OH CH2OH

New

Cu2

OH

D3920 Daidzin

2

25mg

>98.0%(LC) C21H20O9 = 416.38 [552-66-9] MFCD00017466 Beil. 18(4)1808 RTECS DJ3094000

HO HO

OH

O

OH O O

O

HO

New

D3023 2-Deoxy-2-fluoro-D-glucopyranose

100mg

>98.0%(GC) C6H11FO5 = 182.15 [29702-43-0] MFCD00077527

OH O

HO HO

F

D0051 2-Deoxy-D-glucose

1g 5g

>97.0%(GC) C6H12O5 = 164.16 [154-17-6] MFCD00151328 mp 150℃ MI14-2904 RTECS MQ3325000

OH O

HO HO

OH

D2752 3,4-Di-O -acetyl-6-deoxy-L-glucal

1g 5g CH3 AcO AcO

>95.0%(GC) C10H14O5 = 214.22 [34819-86-8] MFCD00074970 d 1.14 Beil. 17(5)5,94

D1949 1,2:5,6-Di-O -isopropylideneα-D-glucofuranose >97.0%(GC) C12H20O6 = 260.29 [582-52-5] MFCD00005544 mp 110℃ Beil. 19(5)12,318 MI14-2965 RTECS LZ4958000

24

O

10g 25g CH3

O

CH3

O

OH O O O

多くの試薬は，その危険性・有害性に関する知見が十分に得られていません。従って，試薬の使用は化学知識を持った専門家に限られ，それ以外の方の使用はお避けください。なお，ご使用の際には安全面に十分注意し，開封・保管から廃棄に至るまで責任を持って管理してください。


OH

CH3 CH3

Glucose-④ E0024

Esculin Sesquihydrate

5g 25g

>98.0%(LC)(T) C15H16O9・11/2 H2O = 340.28(Anh) [531-75-9] MFCD00006879 Beil. 18(3/4)1326 MI14-3698 RTECS DJ3085000

OH O

HO HO

O

.

E0402

HO

O

1g 5g CH3

O O HO

O HO

Etoposide

OH

100mg

>98.0%(LC) C29H32O13 = 588.56 [33419-42-0] mp 251℃ MI14-3886 RTECS KC0190000

O CH3

O

O HO

O HO

O

OCH3

O

OH OCH3 O

New

O

11/2 H2O

4,6-O -Ethylidene-α-D-glucopyranose

>96.0%(GC) C8H14O6 = 206.19 [13224-99-2] MFCD00006820 mp 173℃

E0675

HO

G0385 Geniposide

O

100mg 1g

>95.0%(LC) C17H24O10 = 388.37 [24512-63-8] MFCD00016659 mp 162℃

HO HO

OH O HO

O

H

CH2OH

O H

CH3O

G0274

O

D-Glucal

1g 5g


G0036 Gluconic Acid (contains Gluconolactone)

OH O

HO HO

25g 500g

(45-50% in Water)

COOH H

C6H12O7 = 196.16 [526-95-4] MFCD00004240 Beil. 3,542 MI14-4456 RTECS LZ5057100

OH

HO

H

H

OH

H

OH CH2OH

G0039

D-(+)-Glucono-1,5-lactone

>98.0%(T) C6H10O6 = 178.14 [90-80-2] MFCD00006647 mp 153℃ Beil. 3(4)1255 MI14-4457 RTECS LZ5184000

25g 500g HO HO

OH O HO



O

25

Glucose-⑤ G0339 β-D-Glucopyranose 1-Phosphate Disodium Salt >98.0%(LC) C6H11Na2O9P = 304.10 [83833-15-2] NMR P.172

G0048

20mg 100mg

D-(+)-Glucose

ONa

OH O

HO HO

OH

HO

L-(-)-Glucose

1g 5g HO

OH OH

O

HO HO

G0047 β-D-Glucose (contains α-D-Glucose)

25g 500g


D-Glucose

ONa

25g 500g

>98.0%(GC) C6H12O6 = 180.16 [921-60-8] MFCD00148913 MI14-4459 RTECS LZ6610000

G0259

O O P

HO

>98.0%(GC) C6H12O6 = 180.16 [50-99-7] MFCD00148912 Beil. 31,83 MI14-4459 RTECS LZ6600000

G0226

OH O

HO HO

OH O

HO HO

OH HO

Diethyl Mercaptal

1g CH3CH2S

C10H22O5S2 = 286.40 [1941-52-2] MFCD00004706 mp 128℃ Beil. 31,475

SCH2CH3 OH

H

H

HO

OH

H H

OH CH2OH

G0052

D-Glucose

6-Phosphate Barium Salt

100mg 1g

Heptahydrate >98.0%(W) C6H11BaO9P・7H2O = 395.45(Anh) [58823-95-3] MFCD00221521

HO HO

O O O P O O HO

G0053 Glucose 1-Phosphate Dipotassium Salt Dihydrate >98.0%(T) C6H11K2O9P・2H2O = 336.32(Anh) [29732-59-0] MFCD00067647

26

Ba2 OH

1g HO HO

OH O HO

O O P

.2H2O



.7H2O

OK OK

Glucose-⑥ G0211

D-Glucose

6-Phosphate Dipotassium Salt

Price on request

Hydrate >98.0%(T) C6H11K2O9P・xH2O = 336.32(Anh) [5996-17-8] MFCD00136041

HO HO

O OK O P OK O HO

New

. xH2O

OH

G0397 Glucotropaeolin Potassium Salt >98.0%(LC) C14H18KNO9S2 = 447.51 [5115-71-9] MFCD00153006

10mg HO HO

OH O S

NOSO3K

HO

G0223

D-Glucuronamide

25g

>98.0%(N) C6H11NO6 = 193.16 [3789-97-7] MFCD00006619 mp 167℃ Beil. 3(4)2009 RTECS LZ8829200

G0302

D-Glucuronic

HO HO

OH

HO

Acid

5g 25g

>96.0%(T) C6H10O7 = 194.14 [6556-12-3] MFCD00077778 Beil. 3(4)1996 MI14-4465 RTECS LZ8836600

G0055

CONH2 O

HO HO

COOH O OH

HO

D-Glucurono-6,3-lactone

25g 500g O

>99.0%(T) C6H8O6 = 176.12 [32449-92-6] MFCD00135622 Beil. 18(3/4)3055 MI14-4467 RTECS LZ8930000

HO O

O

OH OH

H0908 Helicin

1g 5g

>98.0%(LC) C13H16O7 = 284.26 [618-65-5] MFCD00006589 Beil. 31,223 MI14-4628

I0017

Indican Hydrate

OH O

HO HO

CHO O

HO

100mg 500mg

>90.0%(LC) C14H17NO6・xH2O = 295.29(Anh) [487-60-5] MFCD00047169 Beil. 21(3/4)748 MI14-4942

HO HO

OH O O HO

. xH O 2

N H



27

Glucose-⑦ G0038 Iron(II) Gluconate Hydrate

25g 500g COO

>95.0%(T) C12H22FeO14・xH2O = 446.14(Anh) [22830-45-1] MFCD00150872 Beil. 3(4)1256 MI14-4047 RTECS LZ5180000

H

OH

HO

H

H H

OH CH2OH

I0400

1,2-O -Isopropylideneα-D-glucofuranose

. xH2O

Fe2

OH

2

25g HO OH

HO

>97.0%(GC) C9H16O6 = 220.22 [18549-40-1] MFCD00063244 mp 156℃ Beil. 19(3/4)4919

O O O

CH3 CH3

I0688

1,2-O -Isopropylideneα-D-glucurono-6,3-lactone

1g O HO


O

O O O

CH3 CH3

G0276 Magnesium(II) Gluconate Hydrate

25g 500g COO

>98.0%(T) C12H22MgO14・xH2O = 414.60(Anh) [3632-91-5] MFCD00150971 Beil. 3(2)350 RTECS OM3480000

H

OH

HO

H

H

Mg2

OH

H

OH CH2OH

M2065 4-Methoxyphenyl 2-O -Acetyl3-O -allyl-4,6-O -benzylideneβ-D-glucopyranoside

Ph O

O

O

O

O

OCH3

OAc

M2434 4-Methoxyphenyl 2-O -Benzoyl3,6-di-O -benzyl-β-D-glucopyranoside

Price on request HO BnO

C34H34O8 = 570.64 [1393898-89-9] NMR P.173

M1640 4-Methoxyphenyl 3-O -Benzyl4,6-O -benzylideneβ-D-glucopyranoside >98.0%(LC) C27H28O7 = 464.51 [303127-81-3] mp 207℃ NMR P.174

28

2

1g 5g

>98.0%(LC) C25H28O8 = 456.49

New

OBn O OBz

O

OCH3

1g 5g Ph

O O BnO

O O OH



. xH2O

OCH3

Glucose-⑧ M1641 4-Methoxyphenyl 3-O -Benzylβ-D-glucopyranoside

1g HO BnO

>98.0%(LC) C20H24O7 = 376.41 [303127-80-2] NMR P.175

OH O O

M1631 4-Methoxyphenyl β-D-Glucopyranoside >97.0%(LC) C13H18O7 = 286.28 [6032-32-2] MFCD06797143 mp 176℃ NMR P.176

5g 25g HO HO

AcO AcO

O

5g OAc O O

AcO BnO

OAc O O

M2013 Methyl 2,3-Di-O -benzoyl-4,6-O -benzylideneα-D-glucopyranoside


OCH3

OAc

5g 25g Ph


M0228 Methyl α-D-Glucopyranoside

OCH3

1g 5g

M1125 Methyl 4,6-O -Benzylideneα-D-glucopyranoside

>98.0%(LC) C28H26O8 = 490.51 [6748-91-0] MFCD02167693 mp 154℃ Beil. 19(4)4974

OCH3

OAc

M1642 4-Methoxyphenyl 2,4,6-Tri-O -acetyl3-O -benzyl-β-D-glucopyranoside >96.0%(LC) C26H30O10 = 502.52 [303127-79-9] mp 160℃ NMR P.178

OH O HO

M1630 4-Methoxyphenyl 2,3,4,6-Tetra-O -acetylβ-D-glucopyanoside >98.0%(LC) C21H26O11 = 454.43 [14581-81-8] MFCD06797142 NMR P.177

OCH3

OH

O O HO

O HO

OCH3

1g Ph

O O BzO

O BzO

OCH3

25g 500g HO HO

OH O HO

OCH3



29

Glucose-⑨ M0709 Methyl β-D-Glucopyranoside

5g 25g

Hemihydrate >98.0%(GC) C7H14O6・1/2 H2O = 194.18(Anh) [709-50-2] MFCD00006602 mp 111℃ Beil. 17(3/4)2911

OH O

HO HO

OCH3

HO

M1759 Methyl (Phenyl 2,3,4-Tri-O -acetyl-1-thioβ-D-glucopyranosid)uronate

1g AcO AcO

>98.0%(LC) C19H22O9S = 426.44 [62812-42-4] mp 119℃ Beil. 18(3/4)5222 NMR P.179

COOCH3 O SPh OAc

M1868 Methyl 1,2,3,4-Tetra-O -acetylβ-D-glucuronate

1g 5g AcO AcO

>96.0%(GC) C15H20O11 = 376.31 [7355-18-2] MFCD00069834 mp 179℃ Beil. 18(3/4)5187 NMR P.180

COOCH3 O OAc AcO

M1682 Methyl 2,3,4,6-Tetra-O -acetyl-1-thioβ-D-glucopyranoside >98.0%(GC) C15H22O9S = 378.39 [13350-45-3] mp 91℃ Beil. 17(3/4)3729 NMR P.181

1g 5g OAc O

AcO AcO

AcO

M1487 Methyl 2,3,4-Tri-O -benzoylα-D-glucopyranoside

OH O

BzO BzO

BzO

M1488 Methyl 2,3,4-Tri-O -benzylα-D-glucopyranoside

OH O

BnO BnO

BnO

N0493 4-Nitrophenyl α-D-Glucopyranoside

OCH3

1g 5g

[Substrate for α-D-Glucosidase] HO HO

OH O HO

O



OCH3

1g


30

SCH3

1g 5g

>98.0%(LC) C28H26O9 = 506.51 [34234-44-1] MFCD06797128 mp 146℃ Beil. 17(3/4)3309 NMR P.182

C12H15NO8 = 301.25 [3767-28-0] MFCD00064088 mp 212℃

. 1/2 H2O

NO2

Glucose-⑩ N0235 4-Nitrophenyl β-D-Glucopyranoside

1g 5g

Monohydrate [Substrate for β-D-Glucosidase] >98.0%(LC) C12H15NO8・H2O = 301.25(Anh) [2492-87-7] MFCD00006593 mp 167℃

. H2O

OH O

HO HO

O

N0857 4-Nitrophenyl α-D-Glucuronide

25mg

>98.0%(LC) C12H13NO9 = 315.23 [71484-85-0] NMR P.184

HO HO

COOH O HO

O

N0618 4-Nitrophenyl β-D-Glucuronide HO HO

>96.0%(LC) C12H13NO9 = 315.23 [10344-94-2] MFCD00036210 mp 93℃

COOH O O

NO2

HO

N0909 Nonyl β-D-Glucopyranoside

1g

>97.0%(GC) C15H30O6 = 306.40 [69984-73-2] MFCD00063300 mp 70℃

New

NO2

100mg

[Substrate for β-Glucuronidase]

New

NO2

HO

HO HO

O(CH2)8CH3

HO

A2638 6-OAc PtdGlc(di-acyl Chain) C49H92NaO14P = 959.22 [1065483-61-5] NMR P.185

OH O


OAc O

O O

HO

O

P

O ONa

O O

(CH2)16CH3

(CH2)18CH3 O

O0232 n -Octyl β-D-Glucopyranoside >96.0%(GC) C14H28O6 = 292.37 [29836-26-8] MFCD00063288 Beil. 17(5)7,38 MI14-6767

1g 5g HO HO

OH O HO

O(CH2)7CH3

O0355 n -Octyl β-D-Glucopyranoside

1g

[for Biochemical Research] >96.0%(GC) C14H28O6 = 292.37 [29836-26-8] MFCD00063288 Beil. 17(5)7,38 MI14-6767

HO HO

OH O HO

O(CH2)7CH3



31

Glucose-⑪ G0225 Penta-O -acetyl-α-D-glucopyranose

10g 25g 250g


P0028

AcO

Penta-O -acetyl-β-D-glucopyranose

Phenyl 4,6-O -Benzylidene-1-thioβ-D-glucopyranoside

5g Ph

O O HO

1g OH O

HO HO

HO

HO HO

OH O OPh HO

.

xH2O

5g 25g AcO AcO

OAc O SPh AcO

Phenyl 2,4,6-Tri-O -acetyl-3-O -allyl1-thio-β-D-glucopyranoside

1g AcO

OAc O O

SPh OAc



OPh

1g 10g

Phenyl 2,3,4,6-Tetra-O -acetyl-1-thioβ-D-glucopyranoside

>98.0%(LC) C21H26O8S = 438.49 [197005-22-4] mp 115℃ NMR P.188

32

SPh HO

Phenyl β-D-Glucopyranoside Hydrate


P1736

O

Phenyl α-D-Glucopyranoside

>99.0%(GC) C12H16O6・xH2O = 256.25(Anh) [1464-44-4] MFCD03410292 mp 173℃ RTECS LZ5985510

P1476

OAc OAc

>97.0%(GC) C12H16O6 = 256.25 [4630-62-0] MFCD00006594 mp 172℃ Beil. 17(5)7,45 RTECS LZ5985500

P0178

OAc O

AcO AcO


P1346

OAc

100g 500g


P1475

OAc O

AcO AcO

Glucose-⑫ P0248

Phlorizin Hydrate

1g 5g

>97.0%(T) C21H24O10・xH2O = 436.41(Anh) [60-81-1] MFCD00006591 Beil. 17(3/4)3042 MI14-7327 RTECS UC2080000

HO HO

HO OH O

OH O

O

. xH2O

HO

G0040 Potassium Gluconate

OH

25g 500g COOK

>99.0%(T) C6H11KO7 = 234.25 [299-27-4] MFCD00064211 MI14-4456 RTECS LZ5230000

H

OH

HO

H

H

OH

H

OH CH2OH

New

P1886

Puerarin

200mg 1g

>98.0%(LC)(T) C21H20O9 = 416.38 [3681-99-0] MFCD00076007 Beil. 19(4)3200 RTECS UO5216000

HO HO

OH HO O HO

O

O

OH

S0003

Salicin

5g 25g

>98.0%(LC) C13H18O7 = 286.28 [138-52-3] MFCD00006590 mp 200℃ Beil. 31,214 MI14-8324 RTECS LZ5901700

New

S0903

CH2OH O

HO

Sinigrin

100mg

>98.0%(LC) C10H16KNO9S2 = 397.45 [3952-98-5] MFCD00006616 MI14-8545 RTECS LZ5778000

S0156

HO HO

OH O

HO HO

OH O S HO

Sinigrin Hydrate

NOSO3K

100mg

>98.0%(LC) C10H16KNO9S2・xH2O = 397.45(Anh) [3952-98-5] MFCD00006616 mp 127℃ MI14-8545 RTECS LZ5778000

HO HO

OH O S HO

NOSO3K

. xH2O

G0041 Sodium Gluconate >99.0%(T) C6H11NaO7 = 218.14 [527-07-1] MFCD00064210 Beil. 3(1)188 MI14-4456 RTECS LZ5235000

25g 500g COONa H

OH

HO

H

H

OH

H

OH CH2OH



33

Glucose-⑬ S0065

D-Sorbitol

25g 500g CH2OH

>97.0%(GC) C6H14O6 = 182.17 [50-70-4] MFCD00004708 Beil. 1(4)2839 MI14-8725 RTECS LZ4290000

H

OH H

HO H

OH

H

OH CH2OH

New

S0897

Swertiamarin

25mg

>98.0%(LC) C16H22O10 = 374.34 [17388-39-5] MFCD07783984 mp 114℃ MI14-9010 RTECS UQ1366700

O

HO HO

OH O

O O

HO

T2449

OH

CH2

1,2,4,6-Tetra-O -acetyl-3-O -allylβ-D-glucopyranose

1g AcO

>98.0%(LC) C17H24O10 = 388.37 [39698-00-5] mp 119℃ NMR P.189

T1961

O

OAc O O

OAc OAc

2,3,4,6-Tetra-O -acetylα-D-glucopyranosyl Bromide

5g

(stabilized with CaCO3)

OAc O

AcO AcO

AcO

>98.0%(T) C14H19BrO9 = 411.20 [572-09-8] MFCD00063254 mp 89℃ Beil. 17(5)6,368 MI14-60

T1995

2,3,4,6-Tetra-O -acetylα-D-glucopyranosyl Fluoride

1g

AcO

A5514 2,3,4,6-Tetra-O -acetylβ-D-glucopyranosyl Isothiocyanate

OAc O

AcO AcO

NCS AcO

>98.0%(LC)(N) C15H19NO9S = 389.38 [14152-97-7] MFCD00043085 bp 116℃ Beil. 31,161

>98.0%(LC) C16H20Cl3NO10 = 492.68 [92052-29-4] mp 158℃ NMR P.191

34

1g 5g AcO AcO

OAc O OAc

NH O C CCl3



F

100mg 1g

[for HPLC Labeling]

2,3,4,6-Tetra-O -acetylβ-D-glucopyranosyl 2,2,2-Trichloroacetimidate

OAc O

AcO AcO

>98.0%(GC) C14H19FO9 = 350.30 [3934-29-0] MFCD00792705 Beil. 17(5)6,357 NMR P.190

T2491

Br

Glucose-⑭ New

P2079

2,3,4,6-Tetra-O -acetyl-PtdGlc (di-acyl Chain) AcO AcO

C61H114NO17P = 1164.55 [1037195-49-5] NMR P.192

New

P2080

OAc O

O O

OAc

P O

O O

O O

(CH3CH2)3NH

2,3,4,6-Tetra-O -acetyl-PtdGlc (mono-acyl Chain)

(CH2)16CH3

(CH2)18CH3 O

Price on request AcO AcO

C41H76NO16P = 870.02 NMR P.193

T2020

Price on request

OAc O

O O

OAc

P O

O O

O

(CH3CH2)3NH

2,3,4,6-Tetra-O -benzoyl-D-glucopyranose

250mg 1g

>90.0%(LC) C34H28O10 = 596.59 [64768-20-3] MFCD00066004 mp 122℃

BzO BzO

BzO BzO

2,3,4,6-Tetra-O -benzoyl-α-D-glucopyranosyl p -TrifluoromethylbenzylthioN -(p -trifluoromethylphenyl)formimidate BzO

NCS

200mg 1g OBz O

BzO BzO

O

N

CF3

S CH2

2,3,4,6-Tetra-O -benzyl-D-glucopyranose

>95.0%(LC) C34H36O6 = 540.66 [4132-28-9] MFCD00066004

OBz O BzO

>98.0%(LC) C35H27NO9S = 637.66 [132413-50-4] MFCD00075064

T1914

CF3

1g 5g BnO BnO

OBn O BnO

T1971

2,3,4,6-Tetra-O -benzylD-glucopyranosyl Fluoride

>96.0%(LC) C34H35FO5 = 542.65 [122741-44-0] MFCD01862264 mp 45℃

OH

500mg BnO BnO

OBn O BnO



OH

100mg 1g

[for HPLC Labeling]

>96.0%(LC) C50H37F6NO10S = 957.89 [428816-48-2] MFCD06797174 NMR P.194

OBz O BzO

A5515 2,3,4,6-Tetra-O -benzoylβ-D-glucopyranosyl Isothiocyanate

T1991

(CH2)16CH3

OH

F

35

Glucose-⑮ T1922

2,3,4,6-Tetra-O -benzylα-D-glucopyranosyl Fluoride

500mg

>95.0%(GC) C34H35FO5 = 542.65 [89025-46-7] MFCD03701104 mp 69℃ NMR P.195

T1923

BnO

2,3,4,6-Tetra-O -benzylβ-D-glucopyranosyl Fluoride

5g OBn O

BnO BnO

BnO

C38H47N2O7P = 674.77 [143520-19-8] MFCD06797176 NMR P.197

2,3,4,6-Tetra-O -benzyl-α-D-glucopyranosyl p -TrifluoromethylbenzylthioN -(p -trifluoromethylphenyl)formimidate BnO

3,4,6-Tri-O -acetyl-2-deoxyD-glucopyranose

>98.0%(GC) C12H18O8 = 290.27 [69503-94-2] MFCD06797168

T1596

200mg 1g OBn O

T1933

O

N

CF3

S CH2

CF3

100mg 1g AcO AcO

OAc O OH

5g 25g AcO AcO

3,4,6-Tri-O -benzyl-2-deoxyD-glucopyranose

>98.0%(LC) C27H30O5 = 434.53 [132732-60-6] MFCD06797170

36

BnO

Tri-O -acetyl-D-glucal


O O P N(CH3)2 N(CH3)2

BnO

T1931

F BnO

2,3,4,6-Tetra-O -benzyl-α-D-glucopyranosyl N ,N ,N ',N '-Tetramethylphosphorodiamidate

C50H45F6NO6S = 901.96 [468095-63-8] MFCD06797177 mp 123℃ NMR P.198

OBn O

BnO BnO

(ca . 20% in Benzene)

T1999

OAc O

100mg BnO BnO

OBn O



F

500mg

>96.0%(LC) C34H35FO5 = 542.65 [78153-79-4] MFCD01862264 mp 47℃ NMR P.196

T2197

OBn O

BnO BnO

OH

Glucose-⑯ T1859

Tri-O -benzyl-D-glucal

1g 5g


BnO BnO

G0277 Zinc(II) Gluconate Hydrate >98.0%(T) C12H22O14Zn・xH2O = 455.67(Anh) [4468-02-4] MFCD04037230 Beil. 3(3)1059 RTECS ZH3750000

OBn O

25g 500g COO H HO H H

OH H

Zn2

OH

. xH2O

OH CH2OH

2



37

Glucosamine-① A1812 2-Acetamido-3-O -allyl4,6-O -benzylidene-2-deoxyβ-D-glucopyranosyl Azide

1g Ph O

O

O

O NHAc

>98.0%(LC) C18H22N4O5 = 374.40 MFCD06797051 NMR P.199

A1813 2-Acetamido-3-O -benzyl4,6-O -benzylidene-2-deoxyβ-D-glucopyranosyl Azide

1g Ph

O O BnO

O NHAc

>98.0%(LC) C22H24N4O5 = 424.46 [80887-27-0] MFCD06797052 NMR P.200

A1811 2-Acetamido-4,6-O -benzylidene2-deoxy-β-D-glucopyranosyl Azide

>96.0%(LC) C17H29N3O10 = 435.43 [137255-40-4] MFCD06797037 mp 213℃ NMR P.202

Ph

O O HO

O NHAc

HO HO

H N

AcHN

COOH O

AcO AcO

OAc O OAc AcHN

1g 5g AcO AcO

38

OAc O AcHN

A1416 2-Acetamido-3,4,6-tri-O -acetyl2-deoxy-α-D-glucopyranosyl Chloride >93.0%(T) C14H20ClNO8 = 365.76 [3068-34-6] MFCD00069776 Beil. 18(5)10,570

NHBoc

1g 5g

A1616 2-Acetamido-3,4,6-tri-O -acetyl2-deoxy-β-D-glucopyranosyl Azide >98.0%(LC) C14H20N4O8 = 372.33 [6205-69-2] MFCD00216968 Beil. 18(5)10,575 NMR P.203

N3

1g 5g AcO AcO



N3

100mg OH O

A1459 2-Acetamido-1,3,4,6-tetra-O -acetyl2-deoxy-β-D-glucopyranose >98.0%(LC) C16H23NO10 = 389.36 [7772-79-4] MFCD00006595 mp 188℃ Beil. 18(5)11,132

N3

1g 5g

>98.0%(LC) C15H18N4O5 = 334.33 [168397-51-1] NMR P.201

A1614 N ω-(2-Acetamido-2-deoxyβ-D-glucopyranosyl)N α-(tert -butoxycarbonyl)-L-asparagine

N3

OAc O AcHN

Cl

Glucosamine-② A1678 2-Acetamido-3,4,6-tri-O -benzyl2-deoxy-β-D-glucopyranosyl Azide

1g 5g OBn O

BnO BnO

>98.0%(LC) C29H32N4O5 = 516.60 [214467-60-4] MFCD06797049 NMR P.204

N3

AcHN

A1685 N ω-(2-Acetamido-3,4,6-tri-O -benzyl-2-deoxyβ-D-glucopyranosyl)-N α-(tert -butoxycarbonyl)L-asparagine Benzyl Ester BnO

100mg OBn O

BnO

H N

AcHN

>97.0%(LC) C45H53N3O10 = 795.93 [219968-28-2] MFCD06797050 NMR P.205

A0092 N -Acetyl-D-glucosamine

COOBn O

NHBoc

25g 500g

>98.0%(N) C8H15NO6 = 221.21 [7512-17-6] MFCD00136044 Beil. 31,170

HO HO

OH O OH

AcHN

A2172 2-Azidoethyl 2-Acetamido-2-deoxyβ-D-glucopyranoside

500mg OH O

HO HO

>98.0%(LC) C10H18N4O6 = 290.28 [142072-12-6] NMR P.206

O

N3

AcHN

B0200 N -Benzoyl-D-glucosamine

25g

>98.0%(T) C13H17NO6 = 283.28 [655-42-5] MFCD00070521

HO HO

OH O OH

BzHN

G0297 N -GlcNAc-Biotin

50mg O

C18H30N4O7S = 446.52 [1272755-69-7] NMR P.207 HO HO

OH O AcHN

G0042

D-Glucosamic

HN

NH

H

H N

H S

O

Acid

>98.0%(T) C6H13NO6 = 195.17 [3646-68-2] MFCD00037764

1g COOH H

NH2

HO

H

H

OH

H

OH CH2OH



39

Glucosamine-③ G0044

D-(+)-Glucosamine

Hydrochloride

25g 500g

>98.0%(T) C6H13NO5・HCl = 215.63 [66-84-2] MFCD00135831 Beil. 1,902 RTECS LZ6665000

G0045

D-Glucosamine

OH O

HO HO

OH

H2N

Oxime Hydrochloride

. HCl

1g NOH

>98.0%(LC)(N) C6H14N2O5・HCl = 230.65 [54947-34-1] MFCD00060165

H

NH2

HO

H

H

OH

H

. HCl

OH CH2OH

H0118 N -Hexanoyl-D-glucosamine

1g

>98.0%(N) C12H23NO6 = 277.32 [19817-88-0] MFCD00059806

OH O

HO HO

HN C

OH (CH2)4CH3

O

M1834 4-Methoxyphenyl 4-O -Acetyl3,6-di-O -benzyl-2-deoxy-2-phthalimidoβ-D-glucopyranoside AcO

1g 5g OBn O

BnO

>98.0%(LC) C37H35NO9 = 637.69 [140615-77-6]

M1638 4-Methoxyphenyl 3-O -Allyl-2-azido4,6-O -benzylidene-2-deoxyβ-D-glucopyranoside

O

1g Ph O

O

O

O

O

M1604 4-Methoxyphenyl 3-O -Allyl6-O -benzyl-2-deoxy-2-phthalimidoβ-D-glucopyranoside

1g 5g HO

OBn O

O O

>98.0%(LC) C31H31NO8 = 545.59

M1598 4-Methoxyphenyl 3-O -Allyl4,6-O -benzylidene-2-deoxy2-phthalimido-β-D-glucopyranoside

OCH3

N3


>97.0%(LC) C31H29NO8 = 543.57 [889453-84-3] mp 130℃ NMR P.209

OCH3

O N

O

N

O

OCH3

O

1g 5g Ph O

O

O

O

O O

N

O



OCH3

Glucosamine-④ M1616 4-Methoxyphenyl 2-Amino3,6-di-O -benzyl-2-deoxyβ-D-glucopyranoside

1g 5g OBn O

HO BnO

O NH2

C27H31NO6 = 465.55 [1272755-07-3] mp 105℃ NMR P.210

M1637 4-Methoxyphenyl 2-Azido4,6-O -benzylidene-2-deoxyβ-D-glucopyranoside

1g 5g Ph

O O HO

O O N3

>98.0%(LC) C20H21N3O6 = 399.40 MFCD06797146 mp 165℃ NMR P.211

M1617 4-Methoxyphenyl 2-Azido3,6-di-O -benzyl-2-deoxyβ-D-glucopyranoside

OBn O

HO BnO

O N3

O O BnO

O O O

M1610 4-Methoxyphenyl 3-O -Benzyl-2-deoxy2-phthalimido-β-D-glucopyranoside C28H27NO8 = 505.52 [138906-44-2]

OCH3

O

OH O O O

M1479 4-Methoxyphenyl 4,6-O -Benzylidene2-deoxy-2-phthalimidoPh β-D-glucopyranoside

N

Price on request HO BnO

N

OCH3

O

5g O O HO

O O O

>98.0%(LC) C28H25NO8 = 503.51 [138906-43-1] MFCD06797124 mp 142℃ NMR P.214

N

OCH3

O

1g OBn O

HO BnO

O O

C35H33NO8 = 595.65 [129575-89-9] NMR P.215

OCH3

1g Ph


M1615 4-Methoxyphenyl 3,6-Di-O -benzyl2-deoxy-2-phthalimidoβ-D-glucopyranoside

OCH3

1g

C27H29N3O6 = 491.54 [1272755-25-5] NMR P.212

M1609 4-Methoxyphenyl 3-O -Benzyl4,6-O -benzylidene-2-deoxy2-phthalimido-β-D-glucopyranoside

OCH3

N

OCH3

O



41

Glucosamine-⑤ M1480 4-Methoxyphenyl 3,4,6-Tri-O -acetyl2-deoxy-2-phthalimidoβ-D-glucopyranoside

5g OAc O

AcO AcO


O O

M1649 Methyl 3,4,6-Tri-O -acetyl2-deoxy-2-phthalimido-1-thioβ-D-glucopyranoside

N

1g 5g OAc O

AcO AcO

N0866 4-Nitrophenyl 2-Acetamido-2-deoxyβ-D-glucopyranoside

P0130

HO HO

OH O O

100mg

Phenyl 3,4,6-Tri-O -acetyl-2-deoxy-1-thio2-(2,2,2-trichloroethoxyformamido)β-D-glucopyranoside

>98.0%(LC) C21H24Cl3NO9S = 572.83 [187022-49-7] MFCD11112181 mp 143℃

T1732

AcHN

Ph O

O

O

O

N


SPh Bn

O

5g AcO AcO


100mg AcO AcO


42

OPh

1g

1,3,4,6-Tetra-O -acetyl-2-azido2-deoxy-α-D-glucopyranose

C14H19N3O9 = 373.32 [56883-33-1] MFCD01076183 Beil. 17(5)6,400 NMR P.219

OH O

HO HO

>97.0%(LC) C27H25NO5S = 475.56 [910805-49-1] NMR P.218

P1866

NO2

AcHN

Phenyl N -Acetyl-α-D-glucosaminide

Phenyl N -Benzyl-2-amino4,6-O -benzylidene-2-N ,3-O -carbonyl2-deoxy-1-thio-β-D-glucopyranoside

O

200mg 1g

C14H19NO6 = 297.31 [10139-04-5] MFCD00067651 mp 241℃

P1762

SCH3

N

O

>98.0%(LC)(N) C21H23NO9S = 465.47 [79528-48-6] mp 150℃ NMR P.217

>98.0%(LC)(N) C14H18N2O8 = 342.30 [3459-18-5] MFCD00063696 mp 205℃ Beil. 18(5)11,102

OCH3

O

OAc O N3 OAc

Glucosamine-⑥ T2196

1,3,4,6-Tetra-O -acetyl-2-azido2-deoxy-β-D-glucopyranose

200mg 1g

>97.0%(LC) C14H19N3O9 = 373.32 [80321-89-7] mp 97℃ NMR P.220

T2047

T2615

OAc N3

1,3,4,6-Tetra-O -acetyl-2-deoxy2-phthalimido-β-D-glucopyranose

5g 25g

3,4,6-Tri-O -acetyl-2-deoxy2-phthalimido-β-D-glucopyranosyl 2,2,2-Trichloroacetimidate

OAc O

AcO AcO

>97.0%(LC) C22H23NO11 = 477.42 [10022-13-6] mp 200℃ NMR P.221

New

OAc O

AcO AcO

OAc N

O

O

Price on request OAc O

AcO AcO

N

O

C22H21Cl3N2O10 = 579.76 [87190-67-8] MFCD09750821 mp 146℃

T0973 N -Trifluoroacetyl-D-glucosamine

NH O C CCl3 O

1g 5g

>96.0%(N) C8H12F3NO6 = 275.18 [36875-26-0] MFCD00059807

OH O

HO HO

OH HN C CF3 O

V0011 N -Valeryl-D-glucosamine >98.0%(N) C11H21NO6 = 263.29 [63223-57-4] MFCD00059805

1g HO HO

OH O OH NH C (CH2)3CH3 O



43

Gulose D2191 (-)-2,3:4,6-Di-O -isopropylidene-2-ketoL-gulonic Acid Monohydrate

25g O

>97.0%(T) C12H18O7・H2O = 274.27(Anh) [68539-16-2] MFCD00150517 Beil. 19(5)12,520 MI14-3199

O

O O CH3

COOH

O

.HO

CH3

G0235

L-(+)-Gulonic

Acid γ-Lactone

2

5g 25g OH

>98.0%(GC) C6H10O6 = 178.14 [1128-23-0] MFCD00064331 mp 188℃

G0239

L-Gulose

CH3 CH3

OH OH

O

OH

O

1g 5g 25g


HO

OH O OH



OH OH

Idose I0724

D-Iditol

100mg

>98.0%(LC) C6H14O6 = 182.17 [25878-23-3] mp 76℃ bp 230℃ Beil. 1,544

CH2OH HO

H

H

OH

HO

H

H

OH CH2OH

I0725

L-Iditol

200mg CH2OH

>98.0%(LC) C6H14O6 = 182.17 [488-45-9] mp 77℃ Beil. 1(4)2843

H

OH

HO

H

H

OH

HO

H CH2OH



45

Inositol-① I0629

allo -Inositol

25mg

>98.0%(LC) C6H12O6 = 180.16 [643-10-7] MFCD00799555 Beil. 6(4)7919 NMR P.222

I0632

HO

200mg HO OH

1L-chiro -Inositol

HO HO OH

HO

OH

200mg OH

HO

HO

OH OH

OH

muco -Inositol

100mg

myo -Inositol

OH HO HO

HO HO

OH

25g 500g

>99.0%(GC) C6H12O6 = 180.16 [87-89-8] MFCD00077932 mp 226℃ Beil. 6(2)1157 MI14-4978 RTECS NM7520800

I0631

HO

epi -Inositol

>98.0%(LC) C6H12O6 = 180.16 [41546-34-3] MFCD01321249 mp 286℃ Beil. 6(4)7920 NMR P.226

I0040

OH

200mg


I0630

OH

HO HO

>98.0%(LC) C6H12O6 = 180.16 [551-72-4] MFCD00799556 mp 240℃ Beil. 6(4)7920 NMR P.224

I0628

OH

OH

1D-chiro -Inositol


I0633

HO HO OH

scyllo -Inositol

HO HO HO

OH OH

OH

200mg 1g


HO HO HO

OH OH OH



Inositol-② I0634

1L-epi -2-Inosose

200mg

>98.0%(LC) C6H10O6 = 178.14 [33471-33-9] MFCD00038395 NMR P.228

O

HO

OH

HO

OH HO

P0409

Phytic Acid

25g 500g

(ca . 50% in Water, ca . 1.1mol/L) C6H18O24P6 = 660.03 [83-86-3] MFCD00082309 MI14-7387 RTECS NM7525000

OPO3H2 H2O3PO

OPO3H2

H2O3PO

OPO3H2 OPO3H2

P0410

Phytin

25g 500g

[3615-82-5] MFCD00082315 MI14-7387 RTECS NM7530000

Q0070 (+)-epi -Quercitol

200mg

>97.0%(LC) C6H12O5 = 164.16 [131435-06-8] MFCD06797162 NMR P.229

OH

HO

HO

OH HO

Q0071 (+)-proto -Quercitol >97.0%(LC) C6H12O5 = 164.16 [488-73-3] MFCD06797163 mp 237℃ MI14-8036 NMR P.230

Q0069 (-)-vibo -Quercitol

100mg HO

OH

HO HO OH

200mg


HO HO OH

OH

OH



47

Lyxose L0073

D-(-)-Lyxose

1g 5g 25g


L0153

HO HO HO

O OH

L-(+)-Lyxose

1g 5g

>98.0%(LC) C5H10O5 = 150.13 [1949-78-6] MFCD00064111 Beil. 1(4)4232

HO



OH

O

HO

OH

Mannose-① D2024 1,2:5,6-Di-O -isopropylideneD-mannitol >95.0%(GC) C12H22O6 = 262.30 [1707-77-3] MFCD00003211 mp 120℃ Beil. 19(1)826

5g 25g CH3 CH3

D2447 2,3:5,6-Di-O -isopropylideneD-mannofuranose

O

CH3 CH3

O OH

O

5g


I0489

O

OH

CH3

O

CH3

O

O

3,4-O -Isopropylidene-D-mannitol

O

O OH

1g 5g OH


OH

HOH2C

CH2OH O

O

CH3 CH3

M0044

D-Mannitol

25g 500g CH2OH

>99.0%(T) C6H14O6 = 182.17 [69-65-8] MFCD00064287 mp 168℃ Beil. 1,534 MI14-5745 RTECS OP2060000

HO

H

HO

H

H

OH

H

OH CH2OH

M1084

L-Mannitol

100mg CH2OH

>96.0%(GC) C6H14O6 = 182.17 [643-01-6] MFCD00154039 mp 165℃

H

OH

H

OH H

HO

H

HO

CH2OH

M0958

D-Mannono-1,4-lactone

1g 5g HO


New

HO

M2435 N ω-(β-D-Mannopyranosyl)-L-asparagine

O

OH

HO HO

HO

O

O

H N

OH O

NH2



O

Price on request HO

C10H18N2O8 = 294.26 [41355-52-6] NMR P.232

OH

49

Mannose-② M0045

D-(+)-Mannose

25g 500g HO


M1308

HO

HO HO

O OH

L-(-)-Mannose

1g HO


OH

O

HO HO

M0046 Mannose-6-phosphate Barium Salt

OH

100mg

Hydrate Ba2

>85.0%(W) C6H11BaO9P・xH2O = 395.45(Anh) MFCD00067376

O O

O P O HO HO

HO

O OH

. xH2O

M1646 4-Methoxyphenyl α-D-Mannopyranoside >98.0%(LC) C13H18O7 = 286.28 [28541-75-5] NMR P.233

5g HO

OH O

HO HO

O

M1647 4-Methoxyphenyl 2,3,4,6-Tetra-O -acetylα-D-mannopyranoside >98.0%(LC) C21H26O11 = 454.43 [17042-40-9] mp 102℃ NMR P.234

5g AcO

OAc O

AcO AcO

O

M2061 Methyl 2,3:4,6-Di-O -benzylideneα-D-mannopyranoside >98.0%(LC) C21H22O6 = 370.40 [4148-71-4] MFCD00192286 mp 185℃ Beil. 19(4)6150

M0368 Methyl α-D-Mannopyranoside >98.0%(GC) C7H14O6 = 194.18 [617-04-9] MFCD00063262 mp 192℃

OCH3

OCH3

5g 25g Ph Ph O

O

O

O

O OCH3

25g 250g HO

HO

HO HO

O OCH3



Mannose-③ M1501 Methyl 2,3,4,6-Tetra-O -acetyl-1-thioα-D-mannopyranoside

5g AcO

(contains ca . 5% β-isomer)

OAc O

AcO AcO

SCH3

>95.0%(LC) C15H22O9S = 378.39 [64550-71-6] MFCD00080808 NMR P.235

M2102 Methyl 2,3,4,6-Tetra-O -pivaloylD-mannopyranoside

1g RO

OR O

RO RO

>97.0%(LC) C27H46O10 = 530.66 mp 102℃

OCH3 O

R=

C C(CH3)3

N0619 4-Nitrophenyl α-D-Mannopyranoside [Substrate for α-Mannosidase] >98.0%(LC) C12H15NO8 = 301.25 [10357-27-4] MFCD00066002 mp 180℃ Beil. 17(3/4)2951

P1514

1,2,3,4,6-Penta-O -acetylD-mannopyranose

>97.0%(GC) C16H22O11 = 390.34 [25941-03-1] MFCD05864874 mp 68℃ NMR P.236

P1803

1,2,3,4,6-Penta-O -pivaloylD-mannopyranose

>98.0%(GC) C31H52O11 = 600.75 [220017-47-0] mp 169℃ NMR P.237

T1459

1,3,4,6-Tetra-O -acetylβ-D-mannopyranose


T2567

2,3,4,6-Tetra-O -acetylD-mannopyranosyl Fluoride

>95.0%(GC) C14H19FO9 = 350.30 [174511-17-2] NMR P.238

1g HO

HO

HO HO

O O

NO2

5g AcO

AcO

AcO AcO

O OAc

1g RO RO RO

OR O OR O

R=

C C(CH3)3

1g 5g AcO AcO AcO

HO

O OAc

1g 5g AcO AcO AcO

OAc O



F

51

Mannose-④ T2307

1,3,4,6-Tetra-O -acetyl2-O -(trifluoromethanesulfonyl)β-D-mannopyranose

>98.0%(GC) C15H19F3O12S = 480.36 [92051-23-5] mp 122℃ NMR P.239

T2056

2,3,4,6-Tetra-O -benzoylD-mannopyranose

>93.0%(LC) C34H28O10 = 596.59 [113544-59-5] MFCD02683399 mp 182℃

T2568

2,3,4,6-Tetra-O -pivaloylD-mannopyranosyl Fluoride

100mg SO2CF3 AcO

O

AcO AcO

OAc

1g 5g BzO

BzO

BzO BzO

O OH

1g RO RO RO

>95.0%(GC) C26H43FO9 = 518.62 NMR P.240

O

OR O F O

R=

C C(CH3)3



Mannosamine A2160 N -Acetyl-D-mannosamine Monohydrate >98.0%(LC) C8H15NO6・H2O = 221.21(Anh) [3615-17-6] MFCD00136044 mp 125℃

1g 5g HO HO HO

NHAc O OH

. H 2O

T1733

1,3,4,6-Tetra-O -acetyl-2-azido2-deoxy-α-D-mannopyranose

>98.0%(LC) C14H19N3O9 = 373.32 [68733-20-0] MFCD01321201 mp 132℃ Beil. 17(5)6,400 NMR P.241

100mg AcO AcO AcO

N3 O



OAc

53

Psicose P1699

D-Psicose

100mg 1g


CH2OH C O H

OH

H

OH

H

OH CH2OH

P1778

L-Psicose

100mg

>98.0%(LC) C6H12O6 = 180.16 [16354-64-6] mp 113℃ Beil. 1(4)4401

CH2OH C O HO

H

HO

H

HO

H CH2OH



Rhamnose R0013

L-(+)-Rhamnose

Monohydrate

>98.0%(LC) C6H12O5・H2O = 164.16(Anh) [3615-41-6] MFCD00149363 mp 93℃ Beil. 31,65 MI14-8172

5g 25g CH3 HO

OH

O HO

. H 2O

OH

S0091 g -Strophanthin Octahydrate

1g 5g O

>98.0%(E) C29H44O12・8H2O = 584.66(Anh) [11018-89-6] MFCD00003688 Beil. 18(3/4)3554 MI14-6901 RTECS RN3850000

HO HO O CH3 HO

O HO

H H

OH

OH

. 8H2O OH



O

OH CH3

55

Ribose-① New

D4207 2-Deoxy-2,2-difluoroD-erythro -pentonic Acid γ-Lactone 3,5-Dibenzoate

1g 5g F

BzO

O

O

>98.0%(LC) C19H14F2O6 = 376.31 [122111-01-7] MFCD08458308 mp 123℃

OBz F

D0059 2-Deoxy-D-ribose

5g 25g CHO

>98.0%(LC) C5H10O4 = 134.13 [533-67-5] MFCD00135904 mp 90℃ MI14-2908 RTECS SB7230000

H

H

H

OH

H

OH CH2OH

M1965 Methyl β-D-Ribofuranoside

1g 5g OCH3

HO


O OH

A0171 Ribitol

1g 25g

>97.0%(GC) C5H12O5 = 152.15 [488-81-3] MFCD00064291 mp 102℃ Beil. 1,530 MI14-168 RTECS VJ0800000

R0067 β-D-Ribofuranose 1-Acetate 2,3,5-Tribenzoate

OH OH

HO OH

BzO

56

OBz

BzO

1g OBz OBz O BzO

D-(+)-Ribono-1,4-lactone


OAc

1g 5g HO O

O OH



OAc

O

R0080 β-L-Ribofuranose 1-Acetate 2,3,5-Tribenzoate >98.0%(LC) C28H24O9 = 504.49 [3080-30-6] MFCD04114304 mp 130℃

OH

5g 25g


R0063

OH

OH

Ribose-② R0025

D-(-)-Ribose

25g 250g HO

>98.0%(GC) C5H10O5 = 150.13 [50-69-1] MFCD00135453 Beil. 1(4)4214 MI14-8204 RTECS VJ2275000

O

OH OH

OH

R0068

L-Ribose

1g 5g 25g OH


OH

O

OH

HO

R0082 α-D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt

5mg O NaO P O

C5H8Na4O11P2 = 398.01 [113599-17-0] NMR P.242

O

ONa

OH

R0083 β-D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt

O O P ONa OH ONa

Price on request O

O

O P ONa

NaO P O

C5H8Na4O11P2 = 398.01 NMR P.243

O

ONa

OH

R0026 Ribose-5-phosphate Barium Salt

ONa OH

100mg 1g

Hydrate

O

>95.0%(T) C5H9BaO8P・xH2O = 365.42(Anh) [15673-79-7] MFCD00047534 MI14-8205

O P O

Ba

2

O

O

OH

R0066 Tetra-O -acetyl-β-D-ribofuranose >98.0%(GC) C13H18O9 = 318.28 [13035-61-5] MFCD00005358 mp 83℃ Beil. 17(5)6,205

OH

. xH2O

OH

5g 25g AcO

OAc

O OAc

OAc

R0065 Tetra-O -acetyl-β-D-ribopyranose >98.0%(GC) C13H18O9 = 318.28 [4049-34-7] MFCD00006596 mp 110℃ Beil. 17(3/4)2459

1g O

AcO

OAc OAc

OAc



57

Ribose-③ T2607

1,2,3-Tri-O -acetyl-5-deoxyβ-D-ribofuranose

5g 25g CH3

OAc O


T2641

1,3,5-Tri-O -benzoyl-α-D-ribofuranose


58

OAc OAc

5g 25g BzO O OBz OBz OH



Sialic Acids-① New

A2511 N -Acetyl-9-deoxy9-aminoneuraminic Acid

Price on request OH

H2N

HO AcHN

C11H20N2O8 = 308.29 [112037-47-5] MFCD09841684 NMR P.244

New

A2492 N -Acetyl-9-deoxy9-fluoroneuraminic Acid

OH O

Price on request OH

F

OH

HO AcHN

C11H18FNO8 = 311.26 [85819-28-9] mp 167℃ NMR P.245

COOH

HO

COOH

O HO

A2205 N -Acetyl-2,3-didehydro2-deoxyneuraminic Acid

5mg COOH

HO AcHN

>98.0%(LC) C11H17NO8 = 291.26 [24967-27-9] MFCD00057470 mp 134℃

O HO

A0639 N -Acetylneuraminic Acid Hydrate >96.0%(T) C11H19NO9・xH2O = 309.27(Anh) [131-48-6] MFCD00006620 MI14-8484

OH

HO

100mg 1g 5g OH

HO

HO AcHN

OH O

COOH

HO

. xH2O

A1821 N -Acetylneuraminic Acid Methyl Ester >95.0%(LC) C12H21NO9 = 323.30 [22900-11-4] NMR P.246

1g HO

OH

HO AcHN

OH O

COOCH3

HO

G0336 N -Glycolylneuraminic Acid >98.0%(LC) C11H19NO10 = 325.27 [1113-83-3] MFCD00057551

10mg OH

HO O

HO HOCH2 C NH

M1706 Methyl 5-Acetamido-4,7,8,9-tetra-O -acetyl3,5-dideoxy-2-S -phenyl-2-thioD-glycero -D-galacto -2-nonulopyranosylonate >96.0%(LC) C26H33NO12S = 583.61 [155155-64-9] mp 183℃ NMR P.247

OH O

COOH

HO

1g AcO

OAc

AcO AcHN

SPh O

COOCH3

AcO



59

Sialic Acids-② New

M2319 Methyl 5-Acetamido-7,8,9-tri-O -acetyl-5-N , 4-O -carbonyl-3,5-dideoxy-2-S -phenyl-2-thioD-glycero -β-D-galacto -2-nonulopyranosylonate

200mg 1g

>96.0%(LC) C25H29NO12S = 567.56 [934591-76-1] mp 152℃

New

OAc

AcO

M2329 Methyl 5-N ,4-O -Carbonyl3,5-dideoxy-2-S -phenyl-2-thio-D-glycero β-D-galacto -2-nonulopyranosylonate

AcO Ac

M2330 Methyl 7,8,9-Tri-O -acetyl-5-N ,4-O -carbonyl3,5-dideoxy-2-S -phenyl-2-thio-D-glycero β-D-galacto -2-nonulopyranosylonate

O

Price on request OH

HO

SPh

HO HN

O

COOCH3

O O

Price on request OAc

AcO

SPh

AcO HN

C23H27NO11S = 525.53 NMR P.249

O

COOCH3

O O

M1707 2,4,7,8,9-Penta-O -acetylN -acetylneuraminic Acid Methyl Ester


AcO

AcO AcHN

C22H31NO14 = 533.48 [73208-82-9] mp 157℃

OAc COOCH3

O AcO

A1822 4,7,8,9-Tetra-O -acetylN -acetylneuraminic Acid Methyl Ester >90.0%(LC) C20H29NO13 = 491.45 [84380-10-9] NMR P.250

60

COOCH3

O

N O

>98.0%(LC) C17H21NO8S = 399.41 [934591-79-4] NMR P.248

New

SPh

1g AcO

OAc

AcO AcHN

OH O

AcO



COOCH3

Sorbose S0390

D-Sorbose

100mg

>98.0%(GC) C6H12O6 = 180.16 [3615-56-3] MFCD00151095 Beil. 1(4)4411

S0066

O

HO HO

HO

L-(-)-Sorbose

OH CH2OH

25g

>98.0%(LC) C6H12O6 = 180.16 [87-79-6] MFCD00151097 mp 165℃ Beil. 1(4)4412 MI14-8726 RTECS WG3195025

CH2OH O

HO

OH OH

HO



61

Tagatose T1501

D-Tagatose

1g

>98.0%(GC) C6H12O6 = 180.16 [87-81-0] MFCD00134449 Beil. 1(4)4414 MI14-9030 RTECS WW1100000

HO HO HO

O OH

T2535

L-Tagatose

OH

100mg

>98.0%(LC) C6H12O6 = 180.16 [17598-82-2] mp 131℃ Beil. 1(4)4415 MI14-9030

CH2OH C O H

OH

H

OH

HO

H CH2OH

62



Talose T1398

D-Talitol

100mg CH2OH

>98.0%(GC) C6H14O6 = 182.17 [643-03-8] MFCD00191491 mp 88℃

HO

H

HO

H H

HO

OH

H

CH2OH

T2536

L-Talitol

100mg CH2OH

>98.0%(LC) C6H14O6 = 182.17 [60660-58-4]

H

OH

H

OH

H

OH H

HO

CH2OH

T0869

D-(+)-Talose

100mg 500mg

>98.0%(LC) C6H12O6 = 180.16 [2595-98-4] MFCD00135834 mp 134℃ Beil. 31,283

T1767

HO

OH OH O

HO

L-(-)-Talose

OH

100mg

>98.0%(LC) C6H12O6 = 180.16 [23567-25-1] MFCD00135850 mp 133℃

HO

OH

O HO

OH

OH



63

Xylose-① D2616 1,2:3,5-Di-O -isopropylideneα-D-xylofuranose

5g O CH3

C11H18O5 = 230.26 [20881-04-3] MFCD00063224 mp 45℃ bp 125℃ /1mmHg Beil. 19(3/4)6076

I0721

O

O

CH3

O O

1,2-O -Isopropylideneα-D-xylofuranose

5g 25g HO

OH O


O

M1253 Methyl-β-D-xylopyranoside

X0018 Xylitol

CH3

OCH3

HO

100mg O2N

O

HO HO

O HO

N0620 4-Nitrophenyl β-D-Xylopyranoside >98.0%(LC) C11H13NO7 = 271.23 [2001-96-9] MFCD00047519 mp 160℃ Beil. 17(3/4)2438

CH3

O

HO HO

N0868 2-Nitrophenyl β-D-Xylopyranoside

[Substrate for β-Xylosidase]

O

5g 25g


>98.0%(LC) C11H13NO7 = 271.23 [10238-27-4] MFCD00047515 mp 173℃

CH3 CH3

100mg HO HO

O O

NO2

HO

25g 500g CH2OH

>98.0%(T) C5H12O5 = 152.15 [87-99-0] MFCD00064292 mp 92℃ Beil. 1,531 MI14-10085 RTECS ZF0800000

H

OH

HO

H

H

OH CH2OH

X0019

D-(+)-Xylose

25g 500g

>98.0%(LC) C5H10O5 = 150.13 [58-86-6] MFCD00151475 mp 151℃ Beil. 31,47 MI14-10087 RTECS ZF2285000

64

O

HO HO

HO



OH

Xylose-② X0021

L-(-)-Xylose

5g 25g

>97.0%(T) C5H10O5 = 150.13 [609-06-3] MFCD00151096 mp 150℃ Beil. 31,55

O

HO

OH OH

HO



65

Disaccharides-① New

A2630 Allolactose

Price on request HO

C12H22O11 = 342.30 [28447-39-4] mp 168℃ NMR P.251

OH O

HO

O HO

O

HO HO

OH

HO

A0443 Amygdalin

1g 10g

>97.0%(LC) C20H27NO11 = 457.43 [29883-15-6] MFCD00006598 mp 213℃ Beil. 17(3/4)3614 RTECS OO8450000

OH O

HO HO

O HO

CN

O

HO HO

O CH HO

L0006

Calcium Lactobionate Hydrate

25g OH

C24H42CaO24・xH2O = 754.65(Anh) [5001-51-4] MFCD00135895

OH O

O

HO HO

OH OH HO

Ca2

COO

HO

2

. xH2O

C0056

D-(+)-Cellobiose

5g 25g


OH O

HO HO

OH O

O HO

HO

C0861 α-D-Cellobiose Octaacetate

25g


New

OAc O

AcO AcO

D4215 N ,N '-Diacetylchitobiose

OAc O

O AcO

AcO

AcO

OAc

Price on request

C16H28N2O11 = 424.40 [35061-50-8] MFCD00077715 mp 247℃ NMR P.252

HO HO

OH O

OH O

O HO

AcHN

AcHN

D3908 Diosmin

OH

5g 25g

>85.0%(LC) C28H32O15 = 608.55 [520-27-4] MFCD00009772 Beil. 18(4)3270 MI14-3297

66

OH

HO

OH O

O CH3 HO

O HO

HO HO OH

O O

O

HO



OH OCH3

Disaccharides-② G0270 Dipotassium Glycyrrhizinate Hydrate

25g COOH

>75.0%(LC) C42H60K2O16・xH2O = 899.12(Anh) [68797-35-3] MFCD02094742 KOOC HO HO KOOC O HO HO HO

New

F0897

Fucα(1-6)GlcNAc

O

O O

H H

O

. xH O

H

2

Price on request HO

C14H25NO10 = 367.35 [33639-80-4] MFCD04973531 NMR P.253

OH OH

O

CH3

O O

HO HO

OH

AcHN

G0374 Gal[2Ac,346Bn]β(1-3)GlcNPhth[46Bzd]-β-MP

Price on request OBn OBn Ph O O O BnO O OAc

C57H55NO14 = 978.06

O O O

N

G0330 Gal[2346Ac]β(1-3)GalN3[46Bzd]-β-MP

1g 5g Ph

>95.0%(LC) C34H39N3O15 = 729.69 mp 193℃ NMR P.254

AcO

O

OAc O

O O

AcO

O

O N3

OAc

M1694 Gal[2346Ac]β(1-4)Glc[236Ac]-β-MP AcO

C33H42O19 = 742.68 [160227-12-3]

OAc O

OAc O

O OAc AcO

O OAc

G0309 Gal[2346Ac]β(1-3)GlcN3[46Bzd]-β-MP AcO

OAc O

Ph

AcO

O

O

O

O O N3

OAc

O OAc

OCH3

1g 5g

Ph O

AcO

OCH3

1g 5g

G0311 Gal[2346Ac]β(1-3)GlcNPhth[46Bzd]β-MP AcO OAc >97.0%(LC) C42H43NO17 = 833.80 NMR P.256

OCH3

Price on request

AcO

>98.0%(LC) C34H39N3O15 = 729.69 mp 172℃ NMR P.255

OCH3

O

O

O

O O O

N

OCH3

O



67

Disaccharides-③ G0298 Galactinol Hydrate

100mg 1g OH

>99.0%(LC) C12H22O11・xH2O = 342.30(Anh) [3687-64-7] mp 221℃ Beil. 17(3/4)3008

OH O

HO HO

O

OH

HO HO

. xH2O

OH OH

G0379 Gal[3All,246Bn]β(1-3)GlcNPhth[6Bn]β-MP OBn OBn C58H59NO13 = 978.10

Price on request

O HO

O

OBn O O

O

OBn

N

O

OCH3

O

M1686 Gal[26Bn]β(1-4)Glc[236Bn]-β-MP >98.0%(LC) C54H58O12 = 899.05 [358681-61-5] mp 130℃ NMR P.257

1g 5g

HO

OBn O

HO

OBn O

O OBn BnO

O

OCH3

OBn

M1726 Gal[236Bn]β(1-4)Glc[236Bn]-β-MP >92.0%(LC) C61H64O12 = 989.17 [150412-81-0]

1g 5g

HO

OBn O

BnO

OBn O

O OBn BnO

O

OCH3

OBn

M1727 Gal[246Bn]β(1-4)Glc[236Bn]-β-MP >95.0%(LC) C61H64O12 = 989.17 [717132-49-5] NMR P.258

1g

BnO

OBn O

HO

OBn O

O OBn BnO

O

OCH3

OBn

G0375 Galβ(1-3)GalNAc-α-p NP

5mg HO


HO

OH O

HO

OH O

O HO

AcHN

O

G0344 Galβ(1-3)GalNAc-β-p NP >98.0%(LC) C20H28N2O13 = 504.45 [59837-15-9] NMR P.260

5mg HO

OH O

HO

HO

OH O

O HO

68

O AcHN



NO2

NO2

Disaccharides-④ G0340 Galβ(1-3)GalNAc-α-Thr

5mg HO

>97.0%(LC) C18H32N2O13 = 484.46 [60280-58-2] MFCD02683396 NMR P.261

HO

OH O

OH O

O

HO

AcHN

HO

O

O OH

CH3 NH2

M1805 Galβ(1-4)Glc-β-MP >96.0%(LC) C19H28O12 = 448.42 [150412-80-9] Beil. 17(3/4)3528

1g HO

OH O

HO HO

New

O

OCH3

HO

G0420 Galβ(1-3)GlcNAc-β-p NP C20H28N2O13 = 504.45 [57467-13-7] MFCD00037620 mp 186℃ NMR P.262

OH O

O HO

Price on request HO

OH O HO

HO

OH O O

O

G0373 GalNAcβ(1-3)GlcNAc β-Ethylazide

Price on request HO

C18H31N5O11 = 493.47 NMR P.263

OH O HO

HO

OH O O

O

G0352 GalNAcβ(1-3)GlcNAc-β-p NP

2mg HO HO

OH O HO

OH O O

O

NO2

AcHN

AcHN

G0356 GalNAcβ(1-4)GlcNAc-β-p NP >98.0%(LC) C22H31N3O13 = 545.50 [872578-72-8] NMR P.265

N3

AcHN

AcHN

>98.0%(LC) C22H31N3O13 = 545.50 NMR P.264

NO2

AcHN

HO

2mg HO

OH O

HO AcHN

OH O

O HO

O

NO2

AcHN

G0026 Gentiobiose

100mg


HO HO

OH O O HO

HO HO

O HO



OH

69

Disaccharides-⑤ G0376 GlcNAcβ(1-3)GalNAc-α-p NP

5mg

>98.0%(LC) C22H31N3O13 = 545.50 [125455-64-3] NMR P.266

HO

OH O

HO HO

OH O

O AcHN

AcHN

O

NO2

G0341 GlcNAcβ(1-3)GalNAc-α-Thr

2mg

>97.0%(LC) C20H35N3O13 = 525.51 [286959-52-2] NMR P.267

HO

OH O

HO HO

OH O

O AcHN

AcHN

O

O

CH3

OH NH2

G0337 GlcNAcβ(1-2)Man α-1-Ethylazide

100mg

>98.0%(LC) C16H28N4O11 = 452.42 NMR P.268

OH O

HO HO

O AcHN HO O

HO HO

O

G0299 GlcNPhth[346Ac]β(1-3)Gal[246Bn]β-MP

New

200mg 1g OAc O

AcO AcO

>98.0%(LC) C54H55NO16 = 974.03 mp 175℃ NMR P.269

BnO

OBn O

O O

N

O

OCH3

OBn

O

G0394 2-O -α-D-GlucopyranosylL-ascorbic Acid

1g 5g OH OH O

>98.0%(LC)(T) C12H18O11 = 338.27 [129499-78-1] MFCD00925623 mp 160℃

HO

O O

OH OH OH

O HO

G0150 Glycyrrhizin

1g 25g COOH

>93.0%(T) C42H62O16 = 822.94 [1405-86-3] MFCD00065194 Beil. 18(3/4)5156 MI14-4505 RTECS MD2025000

HOOC HO HO HOOC O HO HO HO

O

O O

O

H0049 Hesperidin

H H

H

25g 500g

>90.0%(LC)(T) C28H34O15 = 610.57 [520-26-3] MFCD00075663 Beil. 18(3/4)3219 MI14-4671 RTECS MK6650000

OH

O CH3 HO

HO HO

O HO

70

N3

OH

O O

O

HO OH O



OCH3

Disaccharides-⑥ I0231

Isomaltose

100mg 1g

>97.0%(GC) C12H22O11 = 342.30 [499-40-1] MFCD00065373

OH O

HO HO

HO

O HO HO

O OH

HO

M1733 LacDiNAc MP Glycoside

5mg OH OH O HO OHO NHAc

C23H34N2O12 = 530.53 NMR P.270

OH O

O NHAc

OCH3

M1776 LacDiNAc(I) MP Glycoside OH OH O HO HO O NHAc

C23H34N2O12 = 530.53 NMR P.271

L0005

5mg O NHAc

Lactobionic Acid OH

>96.0%(T) C12H22O12 = 358.30 [96-82-2] MFCD00078147 Beil. 31,415 MI14-5342

D-(+)-Lactose

OH O

O

HO HO

OH OH HO HO

Monohydrate

>98.0%(LC) C12H22O11・H2O = 342.30(Anh) [64044-51-5] MFCD00150747 Beil. 31,408 MI14-5343

COOH

25g 500g OH

OH O

HO

O HO

HO

L0140

OCH3

25g 500g

(mixture of Acid form and Lactone form)

L0008

OH O

OH O HO

. H 2O

OH

Lactulose

25g HO

>98.0%(LC) C12H22O11 = 342.30 [4618-18-2] MFCD00151469 mp 169℃ MI14-5346 RTECS LS6965000

HO

HO OH O CH2OH

OH O

HO

O HO

M0601 Maltitol

25g 500g


HO HO

OH O HO

O

OH OH HO

OH HO



71

Disaccharides-⑦ M0797 Maltitol

25g 500g


OH O

HO HO

HO

OH OH

O

HO

OH HO

M0037

D-(+)-Maltose

Monohydrate

25g 500g

>98.0%(LC) C12H22O11・H2O = 342.30(Anh) [6363-53-7] MFCD00149343 Beil. 17(3/4)3057 MI14-5714 RTECS OO5250000

OH O

HO HO

HO

OH O

O HO

. H2O OH

HO

M1138 Maltulose Monohydrate

1g HO OH O

>98.0%(GC) C12H22O11・H2O = 342.30(Anh) [17606-72-3] MFCD00191667 mp 113℃

M2442 Man[2Bz,3All,46Bzd]β(1-4)GlcNPhth[36Bn]-β-MP

Ph O

OBz O

O O

OBn O

O BnO

O O

D-(+)-Melibiose

. H2O

Price on request

C58H55NO14 = 990.07

M0050

OH OH

HO O

HO HO

New

HO O

N

OCH3

O

Monohydrate

1g 10g OH

C12H22O11・H2O = 342.30(Anh) [585-99-9] MFCD00198188 Beil. 31,421 MI14-5820

OH O

HO HO

. H2O

O

O

HO HO

OH

HO

G0151 Monoammonium Glycyrrhizinate

1g 25g

Hydrate

COOH O

COOH >75.0%(LC) C42H65NO16・xH2O = 839.97(Anh) [53956-04-0] MFCD00167400 O HO HO mp 217℃ HOOC O O RTECS LZ6500000 HO O

H H

. NH . xH O

H

HO

3

HO

N0073 Naringin Hydrate

2

25g

>90.0%(T) C27H32O14・xH2O = 580.54(Anh) [10236-47-2] MFCD00148888 Beil. 18,528 MI14-6425 RTECS QN6340000

OH O

HO HO

OH O

O

O CH3 HO

O HO

OH O OH



. xH2O

Disaccharides-⑧ N0675 Neohesperidin Dihydrochalcone

5g 25g

Hydrate >98.0%(T) C28H36O15・xH2O = 612.58(Anh) [20702-77-6] MFCD03840557 MI14-6452 RTECS LZ5785000

OH O

HO HO

O

CH3 HO

O OH

New

OH

HO

NaOOC

HO

OH O

O

O

O

NH2

HO

N0948 Neu5Acα(2-6)Gal-β-ethylamine

Price on request OH

HO

C19H33N2NaO14 = 536.46

COONa

HO AcHN

O HO

O HO

O HO

N0791 Neu5Acα(2-3)Galβ MP Glycoside HO

O

HO

NH2

10mg 50mg

OH

OH

COOH

HO AcHN

O

O

OH O O

OCH3

OH

HO

N0792 Neu5Acα(2-6)Galβ MP Glycoside

10mg 50mg

HO

>98.0%(LC) C24H35NO15 = 577.54 NMR P.273

. xH2O

OH

HO

>90.0%(LC) C24H35NO15 = 577.54 [159922-54-0] NMR P.272

OH

Price on request HO AcHN

New

OCH3

OH O

N0947 Neu5Acα(2-3)Gal-β-ethylamine C19H33N2NaO14 = 536.46

OH

O

OH

COOH

HO AcHN

O HO

O HO

O

HO

O

OCH3

OH

N0890 Neu5Acα(2-6)GalNAc-α-p NP

5mg OH

HO

>98.0%(LC) C25H35N3O16 = 633.56 NMR P.274

COOH

HO AcHN

O

O HO

HO

O HO AcHN

M1761 Neu5Ac[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP >95.0%(LC) C54H59NO21 = 1058.05 NMR P.275

O

NO2

200mg OAc

AcO

AcO AcHN

COOCH3 O

AcO

O BzO O BnO

O OBz

OCH3



73

Disaccharides-⑨ N0846 Neu5Ac[1Me,4789Ac]α(2-3)Gal[246Bz]-β-MP

200mg 1g OAc

AcO

AcO AcHN

>95.0%(LC) C54H57NO22 = 1072.04 NMR P.276

OBz OBz O O O OBz

CH3OOC O OAc

M1763 Neu5GcAc[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP >97.0%(LC) C56H61NO23 = 1116.09 NMR P.277

OCH3

200mg OAc

AcO

COOCH3

AcO HN

AcO

O BzO

O AcO

O

O

BnO

O

OCH3

OBz

N0816 Neu5GcAc[1Me,4789Ac]α(2-3)Gal[246Bz]-β-MP


AcO

C56H59NO24 = 1130.07 NMR P.278

CH3OOC

AcO HN

AcO

BzO

OBz O

O

O

O

AcO

O

OCH3

OBz

N0793 Neu5Gcα(2-3)Galβ MP Glycoside HO

>95.0%(LC) C24H35NO16 = 593.54

5mg COOH OH

OH HO HN

HO

O

O

OH O O

HO

O

OCH3

OH

N0794 Neu5Gcα(2-6)Galβ MP Glycoside

5mg

HO

>97.0%(LC) C24H35NO16 = 593.54 [1072896-38-8]

COOH

OH

HO HN

HO

O HO

O HO

O

O

HO

O

OCH3

OH

New

M1729 Neu5Troc[1Me,4789Ac]α(2-3)Gal[26Bn]-β-MP >98.0%(LC) C48H56Cl3NO20 = 1073.31 [610763-72-9]

1g O Cl3C

O

HN AcO

AcO

OH

AcO

OAc

O

O

O

OBn O

COOCH3

OCH3

OBn

N0867 4-Nitrophenyl β-D-Cellobioside >98.0%(LC) C18H25NO13 = 463.39 [3482-57-3] MFCD00069845 Beil. 17(4)3523

100mg HO HO

OH O HO

O HO

OH O O HO



NO2

Disaccharides-⑩ S0052

Octa-O -acetyl D-(+)-Sucrose

25g 500g

>98.0%(T) C28H38O19 = 678.59 [126-14-7] MFCD00006623 mp 86℃ MI14-8881 RTECS WN6620000

OAc O

AcO AcO

AcO O AcO O

AcO

OAc

OAc

P1879

Paeonolide

10mg HO

>97.0%(LC) C20H28O12 = 460.43 [72520-92-4] Beil. 17(4)3462

O HO

O HO HO HO

Ac

O

O HO

P1234

Palatinose Hydrate

OCH3

25g 500g

>98.0%(LC) C12H22O11・xH2O = 342.30(Anh) [13718-94-0] MFCD00076094 mp 123℃ Beil. 17(5)7,215 MI14-5182

OH O

HO HO

HO

. xH2O O

HO O

OH CH2OH

OH

R0035 Rutin Trihydrate

25g

>98.0%(T) C27H30O16・3H2O = 610.52(Anh) [153-18-4] MFCD00006830 MI14-8304 RTECS VM2975000

HO

O

CH3 HO

O HO

OH O

OH

O

HO HO

HO

OH

O

O

. 3H2O

R0062 Rutinose

OH

100mg

>98.0%(LC) C12H22O10 = 326.30 [90-74-4] MFCD00161473 MI14-8305

O CH3 HO HO

O

HO HO

O

HO

OH

H0628 Rutinose Heptaacetate >98.0%(GC) C26H36O17 = 620.56 [29202-64-0] MFCD00161474 mp 168℃ MI14-8305

New

S0839

OH

1g O CH3 AcO AcO

O

AcO AcO

O

AcO

OAc

Sucralose

OAc

5g 25g

>98.0%(LC) C12H19Cl3O8 = 397.63 [56038-13-2] MFCD03648615 MI14-8880 RTECS LW5440140

Cl

OH O Cl

HO HO

O

HO O OH



Cl

75

Disaccharides-⑪ S0111

D-(+)-Sucrose

25g 500g

>98.0%(LC) C12H22O11 = 342.30 [57-50-1] MFCD00006626 Beil. 31,424 MI14-8881 RTECS WN6500000

OH O

HO HO

HO O HO O

HO

OH

OH

T0331

D-(+)-Trehalose

Dihydrate

25g 500g

>98.0%(GC) C12H22O11・2H2O = 342.30(Anh) [6138-23-4] MFCD00071594 Beil. 17(3/4)3505 MI14-9580 RTECS LZ5776547

OH O

HO HO

HO

. 2H2O O

OH OH OH

O HO

T0832

D-(+)-Trehalose

Anhydrous

1g 25g

>98.0%(GC) C12H22O11 = 342.30 [99-20-7] MFCD00006628 mp 205℃ Beil. 17(3/4)3505 MI14-9580

OH O

HO HO

HO

O

OH OH OH

O HO

G0217 Trisodium Glycyrrhizinate Hydrate

25g

>75.0%(LC) C42H59Na3O16・xH2O = 888.89(Anh) [71277-78-6] MFCD00070472 RTECS LZ6500500

NaOOC HO HO NaOOC O HO HO HO

T0542

COONa O

O O

H H

O

. xH O

H

2

D-(+)-Turanose

1g 5g

C12H22O11 = 342.30 [547-25-1] MFCD00006606 Beil. 17(3/4)3092 MI14-9821

OH O

HO HO

HO HO

O

O OH

OH

New

X0067 Xylobiose

OH

100mg 1g

>98.0%(LC) C10H18O9 = 282.25 [6860-47-5] MFCD00135984

HO HO

O HO

X0065 Xylosucrose

O

O HO

OH

HO

100mg 1g

>98.0%(LC) C11H20O10 = 312.27 [512-66-3] mp 114℃ Beil. 17(4)3786

O

HO HO HO

HO O HO O OH



OH

Trisaccharides-① New

A2631 A Antigen PEG-trifluoroacetamide HO

C30H51F3N2O19 = 800.73 NMR P.279

HO

Price on request

OH O AcHN

HO

OH O

O

O

CH3

O

H N

O

CF3 O

OH

OH

HO

New

O

O

O

A2485 Acarbose Hydrate

1g 5g OH

>98.0%(LC)(N) C25H43NO18・xH2O = 645.61(Anh) [56180-94-0] MFCD00869592 MI14-18 RTECS LZ7153000

HO N H HO

HO OH

CH3

O HO

OH O

O HO

HO

. xH2O

OH O

O HO

HO

New

B4172 B Antigen PEG-trifluoroacetamide HO

C28H48F3NO19 = 759.68 NMR P.280

HO

Price on request

OH O HO

HO

OH O

O

O

CH3

O

H N

O

OH

C2795 Cellotriose

Price on request

C18H32O16 = 504.44 [33404-34-1] MFCD00069842 mp 209℃

HO HO

OH O

OH O

O HO

HO

OH O

O HO

HO

HO HO

25mg OH O

OH O

O HO

H2N

. .

H2N

OH O

O HO

H 2N

3HCl

OH

xH2O

D1828 Digoxin

100mg 1g O HO CH3

>96.0%(LC) C41H64O14 = 780.95 [20830-75-5] MFCD00003674 Beil. 18(3/4)2453 MI14-3167 RTECS IH6125000 HO

CH3

H3C O

Fucα(1-2)Galβ(1-3)GalNAcα-p NP (=H type 3 α-p NP Glycoside)

OH

H 3

Price on request HO

OH O

HO

C26H38N2O17 = 650.59 [1105508-81-3] NMR P.281

CH3 HO

HO

OH O

O O O

AcHN

O

NO2

OH

OH



O

H H

O HO

F0895

OH

HO

C2642 Chitotriose Trihydrochloride Hydrate >93.0%(LC) C18H35N3O13・3HCl・xH2O = 610.86(Anh) [117436-78-9] mp 255℃

New

CF3 O

OH

HO

New

O

O

O

New

OH

77

Trisaccharides-② New

F0896

Fucα(1-2)Galβ(1-3)GalNAcβ-p NP (=H type 3 β-p NP Glycoside)


C26H38N2O17 = 650.59

O O

HO

F0894

OH O O

Fucα(1-2)Galβ(1-3)GlcNAcβ-p NP (=H type 1 β-p NP Glycoside)

C26H38N2O17 = 650.59 [93496-53-8] MFCD07369574 NMR P.282

NO2

AcHN

O CH3

New

HO

OH O

OH

OH

Price on request HO

OH O HO O O

HO CH3

O

HO

OH O O

NO2

AcHN

OH

OH

G0343 Galβ(1-3)[GlcNAcβ(1-6)]GalNAcα-Thr


HO HO

C26H45N3O18 = 687.65 [186600-27-1] NMR P.283

O AcHN HO OH O O HO

HO HO

O AcHN

O

CH3

G0377 Galβ(1-3)[Neu5Acα(2-6)]GalNAcα-p NP

HO OH O

HO

O

O HO

O O

HO

AcHN

OH

HO

HO

O

O HO OH O

HO O

HO

O

O

NO2

AcHN

HO

2mg OH

HO

COOH

HO AcHN HO HO

O

O HO OH O HO

O O

O AcHN

HO

OH

HO

HO

COOH O

O HO OH O

HO HO

O HO

O O AcHN



NO2

2mg HO AcHN

>90.0%(LC) C31H45N3O21 = 795.70 NMR P.287

NO2

COOH

HO AcHN

G0353 Galβ(1-4)[Neu5Acα(2-6)]GlcNAcβ-p NP

O

5mg

C31H45N3O21 = 795.70 NMR P.285

>92.0%(LC) C31H45N3O21 = 795.70 [754954-71-7] NMR P.286

OH

COOH

HO AcHN

HO

G0347 Galβ(1-3)[Neu5Acα(2-6)]GlcNAcβ-p NP

NH2

2mg OH

HO

>95.0%(LC) C31H45N3O21 = 795.70 [1316822-90-8] NMR P.284

G0345 Galβ(1-3)[Neu5Acα(2-6)]GalNAcβ-p NP

O

NO2

Trisaccharides-③ New

G0422 Ganglioside GM3 (phyto-type) C59H110N2O22 = 1199.52 [1046791-63-2] NMR P.288

Price on request OH

HO

HOOC

HO AcHN

HO O

O

G0419 Ganglioside GM3 [d18:1, (Carbon-13)C16:0] C16C41H104N2O21 = 1169.33 NMR P.289

New

HN

C17H35 OH C13H27

O HO

OH

Price on request HO

OH

HOOC

HO AcHN

13

OH O

O HO

HO

HO

New

O

OH O

HO O

O

O

OH O O HO

HO

HO

OH O

13C

C13H27

HO

G0402 Gb3-β-ethylamine

13C H 15 31

HN O

OH

Price on request HO

C20H37NO16 = 547.51 [261155-98-0]

OH O

HO HO

O

OH O

HO HO

New

G0403 Gb3-β-ethylazide

OH O

O HO

O

NH2

HO

Price on request HO

C20H35N3O16 = 573.51

OH O

HO HO

O

OH O

HO

OH O

O HO

HO

M1767 Gb3-β-MP

N3

100mg

>95.0%(LC) C25H38O17 = 610.56 [898826-64-7] NMR P.290

HO

OH O

HO HO

O

OH O

HO HO

New

O

HO

G0423 GlcNAcβ(1-4)[Fucα(1-6)]GlcNAc

OH O

O HO

O

Price on request HO

C22H38N2O15 = 570.55 [108964-40-5] NMR P.291 HO HO

OH

G0342 GlcNAcβ(1-3)[GlcNAcβ(1-6)]GalNAc-α-Thr

OH

O

CH3 OH O AcHN

O O

O HO

OH

AcHN

2mg HO HO

>94.0%(LC) C28H48N4O18 = 728.70 [1304646-03-4] NMR P.292

OCH3

HO

HO HO

OH O O AcHN HO OH O O AcHN

O AcHN CH3

O

O NH2



OH

79

Trisaccharides-④ G0378 GlcNAcβ(1-3)[Neu5Acα(2-6)]GalNAc-α-p NP

2mg OH

HO

COOH

HO AcHN

>97.0%(LC) C33H48N4O21 = 836.75 NMR P.293

O

O HO OH O

HO HO

HO O O

AcHN

I0329

AcHN

Isomaltotriose

O

NO2

100mg 1g

>97.0%(LC) C18H32O16 = 504.44 [3371-50-4] MFCD00070623

OH O

HO HO

HO O HO HO

O HO O HO HO

O OH

HO

K0032 1-Kestose

1g

>98.0%(GC) C18H32O16 = 504.44 [470-69-9] MFCD00142647 Beil. 17(5)8,416

OH O

HO HO

HO HOO O

HO

OH HO

O HO O

OH

M0677

D-(+)-Maltotriose

Hydrate

1g 5g

>98.0%(LC) C18H32O16・xH2O = 504.44(Anh) [1109-28-0] MFCD00006629

OH O

HO HO

HO

O

OH O HO

.

M0049

D-(+)-Melezitose

N0949 Neu5Acα(2-3)Galβ(1-4)GlcNAcβ-ethylamine HO

HO

HO

OH

OH

NaOOC

HO AcHN

OH

HO

O OH O

HO

OH O

O

O

HO AcHN

HO O

HO

HO

. xH2O O

Price on request

HO

N0950 Neu5Acα(2-6)Galβ(1-4)GlcNAcβ-ethylamine OH HO C27H46N3NaO19 = 739.66

OH O

OH HO O

HO HO

HO

New

xH2O

O

5g 25g

HO

C27H46N3NaO19 = 739.66

HO

Hydrate

>99.0%(GC) C18H32O16・xH2O = 504.44(Anh) [597-12-6] MFCD00149448 mp 153℃ Beil. 31,466 MI14-5819

New

OH

O HO

OH O O AcHN

Price on request COONa O

O HO

HO

O HO HO

O HO

OH O O AcHN



NH2

NH2

Trisaccharides-⑤ N0853 Neu5Acα(2-3)Galβ(1-3)GlcNAcβ-p NP OH HO HO AcHN

C31H45N3O21 = 795.70 NMR P.294

Price on request OH COOH O

O

N0854 Neu5Acα(2-3)Galβ(1-4)GlcNAcβ-p NP OH HO HO AcHN

O

O

O

O

OH O

N0855 Neu5Acα(2-6)Galβ(1-3)GlcNAcβ-p NP OH HO

OH O

O HO

HO

HO AcHN

O

COOH O HO

HO

O HO

HO

OH O O

O

HO AcHN

O

NO2

AcHN

HO

>97.0%(LC) C31H45N3O21 = 795.70 [501427-93-6] NMR P.297

NO2

AcHN

1mg

O

N0856 Neu5Acα(2-6)Galβ(1-4)GlcNAcβ-p NP OH HO

NO2

AcHN

2mg OH COOH

HO

>97.0%(LC) C31H45N3O21 = 795.70 NMR P.296

OH O

HO

HO

>95.0%(LC) C31H45N3O21 = 795.70 [501427-92-5] NMR P.295

OH O HO

2mg COOH O HO

HO

OH O

O HO HO

O HO

O

NO2

AcHN

N0860 Neu5Acα(2-3)Galβ(1-4)Glc-β-p NP >97.0%(LC) C29H42N2O21 = 754.65 NMR P.298

OH COOH

OH

HO

HO AcHN

O

O

HO

P0927

5mg OH O HO

OH O

O HO

O

NO2

HO

Panose

100mg

>98.0%(LC) C18H32O16 = 504.44 [33401-87-5] MFCD00151376 mp 223℃

HO HO

OH O HO

O

HO HO

O HO

OH O O

HO HO

R0002

D-(+)-Raffinose

Pentahydrate

25g HO

>98.0%(LC) C18H32O16・5H2O = 504.44(Anh) [17629-30-0] MFCD00006630 mp 80℃ Beil. 31,462 MI14-8096

OH O

HO HO

O O

HO HO HO

. 5H O 2

HO O HO O OH



OH

OH

81

Trisaccharides-⑥ New

T2912 N ,N ',N ''-Triacetylchitotriose C24H41N3O16 = 627.60 [38864-21-0] MFCD00136047 NMR P.299


OH O AcHN

O HO

OH O AcHN

O HO

OH O AcHN



OH

Tetrasaccharides-① New

C2796 Cellotetraose

Price on request

C24H42O21 = 666.58 [38819-01-1] MFCD00079079 mp 253℃

OH O

HO HO

HO

New

OH O

O HO

OH O

O HO

HO

C2641 Chitotetraose Tetrahydrochloride

25mg

Hydrate

OH O

HO HO

>95.0%(LC) C24H46N4O17・4HCl・xH2O = 808.48(Anh) [117399-50-5]

OH O

O HO

H2N

H2N

>97.0%(LC) C32H48N2O23 = 828.73 [148705-09-3] NMR P.300

C32H48N2O23 = 828.73 [197526-33-3] NMR P.301

OH O AcHN

OH O

O HO

HO

OH O

O HO

HO

O

NO2

HO

OH O

O AcHN

O HO

HO

O HO

O AcHN

HO

OH O

O HO

O

NO2

HO


O HO

OH O

O HO

O

NO2

HO

G0354 GalNAcβ(1-3)Galα(1-4)Galβ(1-4)Glcβ-p NP HO HO OH OH >88.0%(LC) C32H48N2O23 = 828.73 [1134635-03-2] NMR P.303

OH

xH2O

OH O

G0380 GalNAcβ(1-3)Galα(1-3)Galβ(1-4)Glcβ-p NP HO HO OH OH C32H48N2O23 = 828.73 NMR P.302

H2N

4HCl

Price on request

O HO

HO O

O

HO

G0351 Galβ(1-4)GlcNAcβ(1-3)Galβ(1-4)Glc-β-p NP HO OH HO

H2N

OH O

O HO

5mg

O HO

HO

OH O

O HO

. .

G0348 Galβ(1-3)GlcNAcβ(1-3)Galβ(1-4)Glc-β-p NP HO OH

OH

HO

2

O

O

HO

5mg

O AcHN

HO

O

OH O

HO

O HO

HO

G0372 GlcA[3S ]β(1-3)Galβ(1-4)GlcNAcβ(1-2)Man α-Ethylazide HO NaO3SO

C28H44N4Na2O25S = 914.70 NMR P.304

OH O O

NO2

HO

Price on request COONa O

HO

OH O

O HO

HO

O HO

OH O O AcHN HO HO HO

O O



N3

83

Tetrasaccharides-② H1284 Hyaluronate Tetrasaccharide HOOC HO HO

C28H44N2O23 = 776.65 [57282-61-8] Beil. 18(4)7588

1mg 5mg OH O

O HO

L0237

NHAc

C34H57N7O21 = 899.86 NMR P.305

AcHN

L0229

HO

OH O

O HO

OH NHAc

OH O

O AcHN

OH O

O HO

AcHN

O

N3

AcHN

Lacβ(1-4)Lac-β-C10

10mg 100mg HO

>98.0%(LC) C34H62O21 = 806.85

O

Price on request

OH O

HO

OH O

OH

LacDiNAc Dimer Ethylazide HO

O HO

O HO

O

OH

New

HOOC

OH O

HO HO

O HO

OH O O

OH O

HO HO

HO

M1022 Maltotetraose

OH O

O HO

O(CH2)9CH3

HO

100mg 500mg OH O

>95.0%(LC) C24H42O21 = 666.58 [34612-38-9] MFCD00010576 HO

OH O

HO HO

O

HO

3

OH

HO

N0571 Nistose Trihydrate

1g OH O

HO HO

>98.0%(LC) C24H42O21・3H2O = 666.58(Anh) [13133-07-8] MFCD00191672 Beil. 17(5)8,417

HO HOO O

HO

. 3H2O O HO O

HO HO

O

HO HO

HO O OH

HO

S0397

Stachyose Hydrate

1g 5g HO

>98.0%(LC) C24H42O21・xH2O = 666.58(Anh) [54261-98-2] MFCD00071593

HO

OH O HO HO O

HO HO HO

New

T2910 N ,N ',N '',N '''-Tetraacetylchitotetraose C32H54N4O21 = 830.79 [2706-65-2] MFCD00136030 mp 300℃ NMR P.306

HO HO

O HO

HO

O

O HO

OH O AcHN

O HO


OH

OH

2

OH O AcHN


84

HO O

Price on request

OH O AcHN

. xH2O

O

HO O

OH

Oligosaccharides-① A2122 3A-Amino-3A-deoxy-(2AS ,3AS )α-cyclodextrin Hydrate

1g

>90.0%(LC) C36H61NO29・xH2O = 971.86(Anh) [121916-94-7]

α-CD

. xH2O

NH2

(2AS, 3AS)-α-CD

A1916 3A-Amino-3A-deoxy-(2AS ,3AS )β-cyclodextrin Hydrate

1g

>97.0%(T) C42H71NO34・xH2O = 1134.00(Anh) [117194-77-1]

β-CD

. xH2O

NH2

(2AS, 3AS)-β-CD

A2123 3A-Amino-3A-deoxy-(2AS ,3AS )γ-cyclodextrin Hydrate

1g

>95.0%(LC) C48H81NO39・xH2O = 1296.14(Anh) [189307-64-0]

γ-CD

. xH2O

NH2

(2AS, 3AS)-γ-CD

New

C2644 Cellopentaose

25mg

>95.0%(LC) C30H52O26 = 828.72 [2240-27-9] MFCD00151164

HO HO

OH O HO

New

C2762 Chitin Oligosaccharides

O HO

OH O HO

O HO 3

OH O OH

HO

25g

(contains N -Acetylglucosamine)

C0776 α-Cyclodextrin

10g 25g

>98.0%(LC) C36H60O30 = 972.85 [10016-20-3] MFCD00078207 MI14-2718 F&F 9,129 RTECS GU2292000

C0777 β-Cyclodextrin

α-CD

25g


β-CD



85

Oligosaccharides-② C0900 β-Cyclodextrin

25g 500g


β-CD

C0869 γ-Cyclodextrin

5g 25g


New

γ-CD

D4217 Disialylnonasaccharide β-Ethylazide

Price on request OH

HO

HO AcHN

C86H141N9O62 = 2293.08 NMR P.307

HO AcHN

O HO

O HO

O

HO

OH

HO

New

COOH

O HO

HO

O HO

HO

O O O HO O

COOH O

OH O AcHN HO HO HO

O

HO

HO

N0913 Disialylnonasaccharide-β-p NP

HO O

NHAc O HO

HO O

O OH

HO HO O OH OH O O O HO AcHN

HO AcHN

C90H141N7O64 = 2345.10

N3

COOH O HO

O HO

HO AcHN

O

HO

OH

HO

O HO

HO

O HO

HO

OH O AcHN HO HO HO

O O O HO O

COOH O

O

HO

HO O


HO

D4065 Disialyloctasaccharide

HO O

NHAc O HO

O OH

OH O AcHN

O

NO2

Price on request OH

HO

HO AcHN

C76H125N5O57 = 2020.81 NMR P.308

COOH O HO

O HO

HO

OH

HO

HO AcHN

O HO

O HO

OH O AcHN HO HO HO

O HO

HO

O O O HO O

COOH O

HO

O HO

HO HO HO HO O O HO AcHN

HO O

HO O

O

NHAc O OH

OH

O

D3690 DNS-SGN

1mg HO

OH HO AcHN

C100H155N9O66S = 2571.40

COOH O HO

O HO

HO

O HO

O HO

OH O AcHN HO HO HO

O O

R= O

HO

OH HO AcHN

HO O

COOH O HO

O HO

HO

O HO

HO O HO

Forssman Pentaose MP Glycoside OH

C41H64N2O27 = 1016.95 NMR P.309

O

Price on request OH

HO

F0584

OH O AcHN

OH O

OH

HO AcHN

O

OH O

HO HO HO O AcHN

HO O

HO O

O

OH NHAc O O O HO AcHN OH

NH O S O

R Me

N

Me

O

Price on request OH

OH O HO

O

OH O

HO HO

HO HO O

O O OH



COOH O

O AcHN

86

H N

OCH3

Oligosaccharides-③ G0355 Galβ(1-3)GalNAcβ(1-3)Galα(1-4)Galβ(1-4)Glc-β-p NP

5mg HO HO

HO

OH O

O HO

>95.0%(LC) C38H58N2O28 = 990.87 NMR P.310

OH O

HO

OH O

O HO

AcHN

O

HO

OH O

New

G0421 Ganglioside GM1 [d18:1, (Carbon-13)C16:0] C16C55H127N3O31 = 1534.66 NMR P.311

O

OH O

HO

OH O

O

HO

O AcHN

HO OH

HOOC

HO AcHN

O

O

O

OH O

OH O

O HO

HO

HO

13C

C13H27

HO

Xyl α

OH

Xyl

1

α

6

Glc

Glc

4

1

α

6

β 1

Xyl

1

6

β 1

4

Glc

H1044 Heptasaccharide Glc4Xyl3

β 1

4

Glc

100mg Xyl

>90.0%(LC) C39H66O33 = 1062.92 [121591-98-8] MFCD04040861

α

Xyl

1

α

6

Glc

H1333 HNK-1 Ethylazide HO NaO3SO

15H31

O

100mg

>95.0%(LC) C39H66O33 = 1062.92 [121591-98-8] MFCD04040861

COONa O

13C

HN

H1041 Heptasaccharide Glc4Xyl3

C34H54N4Na2O30S = 1076.84 NMR P.312

NO2

HO


13

OH O

O HO

HO

1

Glc

4

1

α

6

β 1

Xyl 6

β 1

4

Glc

β 1

4

Glc

Price on request HO

OH O

O HO

HO

O HO

OH O

HO

OH O

O AcHN

OH O

O HO

HO

O

H1285 Hyaluronate Hexasaccharide HOOC

C42H65N3O34 = 1155.97 [73603-40-4] HO

HO

O HO OH

N3

HO

1mg 5mg OH O O NHAc

HOOC O HO

O HO

OH O O

OH NHAc

OH

2

H0979 Hydroxypropyl-β-cyclodextrin

25g 100g OR O

[128446-35-5] MFCD00074978 RO

RO

O

7

CH3 R=

CH2CHO n = 0,1,2...



n

H

87

Oligosaccharides-④ M1025 Maltoheptaose

100mg OH O

>90.0%(LC) C42H72O36 = 1153.00 MFCD00064605 HO

OH O

HO HO

O

6

HO

OH

HO

M1024 Maltohexaose

100mg OH O

>95.0%(LC) C36H62O31 = 990.86 [34620-77-4] MFCD00083650 HO

OH O

HO HO

O

5

M1023 Maltopentaose

HO

OH

HO

100mg 1g OH O

>95.0%(LC) C30H52O26 = 828.72 [34620-76-3] MFCD00151333 HO

OH O

HO HO

O

4

HO

OH

HO

M1219 6-O -α-D-Maltosyl-β-cyclodextrin

1g 5g

>98.0%(LC) C54H90O45 = 1459.27 [104723-60-6] MFCD00671560

OH O

HO HO

HO

O O

HO HO

HO

O

β-CD

New

M2439 Manα(1-2)Manα(1-3)[Manα(1-6)Manα(1-6)]Manβ(1-4)GlcNAc

Price on request HO HO HO

HO O O HO HO

C38H65NO31 = 1031.91 NMR P.313

HO O O HO O

HO O

O HO

HO HO O O HO HO HO O HO OH

M1356 Methyl-β-cyclodextrin OR O RO RO

D1732 Methyl-β-cyclodextrin (2,6-Di-O -methyl- and partially 2,3,6-Tri-O -methyl- mixture)

O

7

R = H, CH3

1g OCH3 O HO

>90.0%(LC) C56H98O35 = 1331.37 [51166-71-3] MFCD00011616

88

CH3O



OH

25g 250g

(mixture of several Methylated) [128446-36-6] MFCD00074980

OH O AcHN

O

7

Oligosaccharides-⑤ M1212 Mono-6-O -mesitylenesulfonylγ-cyclodextrin

1g CH3 O SO2

C57H90O42S = 1479.37 MFCD00671559

CH3 CH3

γ-CD

M1741 Mono-2-O -(p -toluenesulfonyl)β-cyclodextrin

1g

>97.0%(LC) C49H76O37S = 1289.17 [84216-71-7]

β-CD OTs

N0693 Nonasaccharide Glc4Xyl3Gal2

100mg Gal β 1

>75.0%(LC) C51H86O43 = 1387.21 [129865-06-1] MFCD04040971

Gal β 1

2

Xyl α

1

New

P2027 N ,N ',N '',N ''',N ''''Pentaacetylchitopentaose

1

4

Glc

OH O

HO HO

1

4

OH O

O HO

AcHN

Glc

β 1

4

Glc

OH O

O HO

AcHN

3

OH

AcHN

Poly-β-cyclodextrin

1g 5g OH O

MFCD00147960

HO

O 7 HO cross-linked by Epichlorohydrin

Sialylglycopeptide

10mg OH

HO

HO AcHN

>95.0%(LC) C112H187N15Na2O70 = 2909.74 [189035-43-6] NMR P.315

COONa O HO

O HO HO

O HO

O HO

OH O AcHN HO HO HO

O NH2 Lys

O O

OH

HO

HO AcHN

S0849

6

β

(Cross-linked by Epichlorohydrin)

S0523

1

α

6

β

Price on request

C40H67N5O26 = 1033.99 [36467-68-2] MFCD00210240 mp 295℃ NMR P.314

P0977

Xyl

1

α

6

Glc

2

Xyl

HO O

COONa O HO

O HO

HO

O HO


Sialyl Lewis X-Lactose

>97.0%(LC) C43H72N2O33 = 1145.03 [127923-85-7] NMR P.316

HO O

O

HO O


Val Ala Asn Lys Thr COOH

O

1mg 5mg HO

OH HO AcHN

HOOC O HO

HO

OH O

O

O HO CH3 HO

O

OH O O

OH O

O AcHN

OH

HO

HO

O HO

OH O HO

OH



OH

89

Oligosaccharides-⑥ New

S0910

Sialyl Neolactotetraosylceramide (=Sialyl nLc4 Cer)

C73H131N3O31 = 1546.84 [128529-29-3] NMR P.317

T1844

HO

OH

HO AcHN

HOOC HO O

HO

O

OH O HO

O HO

OH HO O O AcHN

Price on request OH O HO

O HO

OH O HO

O O

HN

C17H35 C13H27 OH

Triacetyl-β-cyclodextrin

25g OAc O

>97.0%(LC) C84H112O56 = 2017.76 [23739-88-0] MFCD00074981 AcO

AcO

90



O

7

Polysaccharides-① A0733 Alginic Acid

25g 500g

[9005-32-7] MFCD00081309 MI14-242 RTECS AZ5775000

A0456 Amylopectin Hydrate (Amylose free),

25g 500g

from Waxy Corn (C6H10O5)n・xH2O [9037-22-3] MFCD00130510 MI14-481

A0846 Amylose (Mw .=ca . 2,800)

1g

[9005-82-7] MFCD00134652 MI14-8798

A0847 Amylose (Mw .=ca . 15,000)

1g

[9005-82-7] MFCD00134652 MI14-8798

A1328 (+)-Arabinogalactan from Larch Wood

25g

[(C5H8O4)(C6H10O5)6]x [9036-66-2] MFCD00062638

A0738 Calcium Alginate

25g 500g

[9005-35-0] MFCD00143567 MI14-242 RTECS AZ5810000

C1805 ι-Carrageenan

25g 500g O3SO

[9062-07-1] MFCD00151512 MI14-1858

OH O

O

O O

HO

O OSO3



n

91

Polysaccharides-② C1804 κ-Carrageenan

25g 500g O3SO

[11114-20-8] MFCD00151514 MI14-1864 RTECS FI0703000

OH O

O

O O

HO

C0072 Chitin

O OH

n

25g 250g

(C8H13NO5)n [1398-61-4] MFCD00466914 MI14-2065 RTECS FM6125000

C2395 Chitosan

25g 500g

(5-20mPa･s, 0.5% in 0.5% Acetic Acid at 20℃) [9012-76-4] MFCD00161512 RTECS FM6300000

C2396 Chitosan

25g 100g

(50-100mPa･s, 0.5% in 0.5% Acetic Acid at 20℃) [9012-76-4] MFCD00161512 RTECS FM6300000

C0831 Chitosan

25g 500g

(200-500mPa･s, 0.5% in 0.5% Acetic Acid at 20℃) [9012-76-4] MFCD00161512

C0335 Chondroitin Sulfate Sodium Salt

25g

[9082-07-9] MFCD01310245 RTECS GA8410000

D3672 Dermatan Sulfate Sodium Salt

20mg 100mg

[54328-33-5] MFCD00151683

92



Polysaccharides-③ D1448 Dextran 40 (Mw .=ca . 40,000)

25g 500g

[9004-54-0] MFCD00130935 MI14-2948 RTECS HH9246000

D1449 Dextran 70 (Mw .=ca . 70,000)

25g 500g

[9004-54-0] MFCD00130935 MI14-2948 RTECS HH9247500

D1776 Dextran Sulfate Sodium

25g

(from Dextran of Mw . Approx. 25,000) [9011-18-1] MFCD00081551 MI14-2951 RTECS HH9290000

G0331 Glucan from Black Yeast

1g 5g

[9012-72-0] MFCD00466924 RTECS LZ3982600

H0393 Heparin Sodium Salt from Hog intestine

100mg 1g

[9041-08-1] MFCD00081689 RTECS MI0850000

H0595 Hyaluronic Acid from Cockscomb

1g CH2OH

[9004-61-9] MFCD00131348 MI14-4757

COOH

O

O O

O

OH

HO OH

NHCOCH3

H0165 Hyaluronic Acid

Price on request

from Bovine Vitreous Humor [Substrate for Hyaluronidase]

CH2OH

COOH

O

O O

>75.0%(E) [9004-61-9] MFCD00131348 MI14-4757

n

O

OH

HO NHCOCH3

OH



n

93

Polysaccharides-④ I0041

Inulin

5g 25g

(C6H10O5)n [9005-80-5] MFCD00131407 MI14-5004

P0024

Pectin from Citrus

25g 500g

[9000-69-5] MFCD00081838 MI14-7063

H0652 Potassium Hyaluronate from Cockscomb

1g COOK

CH2OH

[31799-91-4] MFCD00131349

O

O O

O

OH

HO NHCOCH3

H0603 Sodium Hyaluronate from Cockscomb

OH

n

100mg 1g CH2OH

[9067-32-7] MFCD00875848 MI14-4757 RTECS MT7250000

COONa

O

O O

O

OH

HO NHCOCH3

X0048 Xanthan Gum

OH

n

25g 500g

[11138-66-2] MFCD00131256 MI14-10057

Z0008

Zymosan [Immunological Reagent]

100mg 1g

[9010-72-4] MFCD00082157 MI14-10200 RTECS ZI2750000

94



Others-① A0520

D-Araboascorbic

Acid

25g 500g HO

>98.0%(T) C6H8O6 = 176.12 [89-65-6] MFCD00005378 MI14-5126 RTECS KF3015000

HO

O

O

HO

A0537

L-Ascorbic

Acid

OH

25g 500g OH

>99.0%(T) C6H8O6 = 176.12 [50-81-7] MFCD00064328 mp 192℃ Beil. 18(3/4)3038 MI14-830 RTECS CI7650000

OH O

O

HO

A1205

L-Ascorbyl

OH

2,6-Dibutyrate

1g O

>98.0%(T) C14H20O8 = 316.31 [4337-04-6] MFCD00144561 mp 125℃

O C CH2CH2CH3 OH O

O O C CH2CH2CH3

HO

O

B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]2,2-dimethyl-1,3-dioxolane

5g

>97.0%(LC) C31H30O4 = 466.58 [93379-48-7] MFCD00064467 mp 196℃

OH

HO

O

O

H3C CH3

C1527 Crocin (Gardenia Fruits Extract)

25g

C44H64O24 = 976.97 [42553-65-1] MFCD00017495 MI14-2589 RTECS HL7380000

D2239 (+)-1,4-Di-O -benzyl-D-threitol >98.0%(GC) C18H22O4 = 302.37 [91604-41-0] MFCD00077722 mp 56℃

1g OH O

O OH

D2240 (-)-1,4-Di-O -benzyl-L-threitol >98.0%(GC) C18H22O4 = 302.37 [17401-06-8] MFCD00077723 mp 56℃

1g OH O

O OH



95

Others-② D0540 Digitonin

100mg H

C56H92O29 = 1229.32 [11024-24-1] MFCD00077729 Beil. 19(3/4)1243 MI14-3161 RTECS IH2050050

O

CH3 CH3 HO

H

CH3 H

O

H H

CH3

O H OH

H Gal Glc Xyl Gal Glc

D0542 Digitoxin

100mg O

>98.0%(LC) C41H64O13 = 764.95 [71-63-6] MFCD00003686 mp 257℃ Beil. 18(3/4)1478 MI14-3163 RTECS IH2275000

O

H 3C CH3

HO

H

H3C O

OH

H

O

H

HO

3

A0757 2,6-Di-O -palmitoyl-L-ascorbic Acid

25g O

>97.0%(T) C38H68O8 = 652.95 [4218-81-9] MFCD00059738 mp 113℃

O C

(CH2)14CH3

OH O

O O C

HO

(CH2)14CH3

O

D1071

DL-Dithiothreitol

1g 5g 25g OH

>98.0%(T) C4H10O2S2 = 154.24 [3483-12-3] MFCD00004877 mp 43℃ bp 130℃ /2mmHg Beil. 1(3)2360 MI14-3376 RTECS XO8576500

D1589

HS

relative

L-Dithiothreitol

1g 5g OH

>95.0%(T) C4H10O2S2 = 154.24 [16096-97-2] MFCD00064305 mp 51℃ RTECS EK1612000

HS

CH3

1g CH2O3S

SO3CH2 O

>95.0%(LC) C21H26O8S2 = 470.55 [51064-65-4] MFCD00063235 mp 90℃

CH3

O

CH3 CH3

D1623 (-)-1,4-Di-O -tosyl-2,3-O -isopropylideneL-threitol CH3

>95.0%(LC) C21H26O8S2 = 470.55 [37002-45-2] MFCD00003212 mp 93℃

SH OH

D1622 (+)-1,4-Di-O -tosyl-2,3-O -isopropylideneD-threitol

96

SH OH

1g 5g CH2O3S

SO3CH2 O

O

CH3 CH3



CH3

Others-③ New

E0926

3-O -Ethyl-L-ascorbic Acid

5g 25g OH OH O

>98.0%(T) C8H12O6 = 204.18 [86404-04-8] MFCD09261382 mp 114℃

O

CH3CH2O

New

E0923 N -Ethyl-D-glucamine

OH

25g 250g CH2NHCH2CH3

>98.0%(T) C8H19NO5 = 209.24 [14216-22-9] MFCD03789564 mp 139℃

H

OH H

HO H

OH

H

OH CH2OH

New

G0383 Gentamicin Sulfate [1405-41-0] MFCD00270181 RTECS LY2625000

1g 5g R1

R2

NHCH3 O

HO O

CH3

H2N

HO

O

O

. xH2SO4

OH

R1=CH3, R2=NHCH3

NH2 R1=CH3, R2=NH2 R1=H, R2=NH2

H2N

G0252

D-Glucamine

5g 25g CH2NH2

>95.0%(T) C6H15NO5 = 181.19 [488-43-7] MFCD00077776 Beil. 4(4)1913 MI14-4449

OH

H

H

HO

OH

H

OH

H

CH2OH

G0216

DL-Glyceraldehyde

Diethyl Acetal

>95.0%(GC) C7H16O4 = 164.20 [10487-05-5] MFCD00059599 bp 136℃ /27mmHg d 1.06

5g 25g O HO

CH3 O

CH3

OH

H1144 α-Homonojirimycin >98.0%(LC) C7H15NO5 = 193.20 [119557-99-2] MFCD06797112 mp 207℃ NMR P.318

I0043

Invertose

10mg HO HO

OH NH HO

OH

25g

[8013-17-0] MFCD00148911 MI14-5006



97

Others-④ I0406

Isomannide

25g HO

>97.0%(GC) C6H10O4 = 146.14 [641-74-7] MFCD00064818 mp 86℃ bp 150℃ /12mmHg Beil. 19(3/4)990

I0507

O

(+)-5,6-O -Isopropylidene-L-ascorbic Acid

H

O

H

OH

5g 25g CH3

O

>98.0%(LC)(T) C9H12O6 = 216.19 [15042-01-0] MFCD00010552 Beil. 19(5)10,501

O

CH3 O

O

HO

I0376

(+)-2,3-O -Isopropylidene-L-threitol


I0375

Isosorbide

CH2OH

HOCH2 O

O

CH3 CH3

1g 5g CH2OH

HOCH2 O

O

CH3 CH3

25g 500g

>98.0%(GC) C6H10O4 = 146.14 [652-67-5] MFCD00064827 mp 61℃ MI14-5224 RTECS LZ4380000

I0403

1g 5g

(-)-2,3-O -Isopropylidene-D-threitol

>97.0%(GC) C7H14O4 = 162.19 [73346-74-4] MFCD00009761 mp 50℃ bp 96℃ /0.7mmHg Beil. 19(3/4)971

I0407

OH

HO

O

Isosorbide 5-Nitrate

>98.0%(N) C6H9NO6 = 191.14 [16051-77-7] MFCD00143462 mp 92℃ MI14-5225 RTECS LZ4386500

M0227 N -Methyl-D-glucamine >99.0%(T) C7H17NO5 = 195.22 [6284-40-8] MFCD00004707 mp 131℃ MI14-6078

H

O

H

OH

10g HO

O

H

O

H

ONO2

25g 500g CH2NHCH3 H

OH

HO

H

H

OH

H

OH CH2OH

98



Others-⑤ M0713 N -Methyl-D-glucamine Hydrochloride

5g 25g

[for Buffer]

CH2NHCH3 H

>98.0%(T) C7H17NO5・HCl = 231.67 [35564-86-4] MFCD00060164 mp 150℃

OH

HO

. HCl

H

H

OH

H

OH CH2OH

A0540 6-O -Palmitoyl-L-ascorbic Acid

25g O

>95.0%(T) C22H38O7 = 414.54 [137-66-6] MFCD00005377 mp 114℃ RTECS CI7671040

O C

(CH2)14CH3

OH O

O

HO

New

OH

R0095 Rebaudioside A

5g 25g

>98.0%(LC) C44H70O23 = 967.02 [58543-16-1] MFCD02183463 mp 235℃ RTECS NZ8174800

HO HO HO HO

OH O HO OH HO O

O

O

CH2

H3C H

HO HO HO

S0019

OH O O

OH H O O CH3 O HO

Saponin

25g 250g

[8047-15-2] MFCD00081981 RTECS VQ1400000

A0539 Sodium L-Ascorbate

25g 500g OH

>98.0%(T) C6H7NaO6 = 198.11 [134-03-2] MFCD00082340 RTECS CI7671000

OH O

O

NaO

G0214 Sodium Glucoheptonate Dihydrate

OH

25g 500g COONa

>98.0%(T) C7H13NaO8・2H2O = 248.16(Anh) [31138-65-5] MFCD00013425

H

OH

H

OH

HO

. 2H2O

H

H

OH

H

OH CH2OH

A0617 6-O -Stearoyl-L-ascorbic Acid

5g O

>95.0%(T) C24H42O7 = 442.59 [10605-09-1] MFCD00059739 mp 117℃ RTECS CI7671310

O C OH O HO

(CH2)16CH3 O OH



99

Others-⑥ S0585

Streptomycin Sulfate

25g 500g

>95.0%(N) C21H39N7O12・11/2 H2SO4 = 728.69 [3810-74-0] MFCD00037023 Beil. 18(5)11,82 MI14-8826 RTECS WK4990000

O H C H3C HO HO

S0112

Sucrose Fatty Acid Ester

OH O

OH

NH

O

NH2

OH

HO O

NH

NH OH NH

NH2

O NHCH3

. 11/2 H2SO4

25g 500g

MFCD00148531

T1647

L-Threitol

1g


100

CH2OH H HO



OH H CH2OH

Reagents for Oligosaccharide Synthesis-① A1668 Acetic Anhydride (ca . 1mol/L in Dichloromethane)

500ml O

C4H6O3 = 102.09 [108-24-7] MFCD00008705 Beil. 2(4)386 MI14-56 F&F 15,1

O

CH3

A1500 Acetoxyacetyl Chloride

O

CH3

25g 100g O

>95.0%(GC)(T) C4H5ClO3 = 136.53 [13831-31-7] MFCD00011535 bp 160℃ d 1.27 flp 71℃ Beil. 3,240

CH3

O

Cl

O

B0643 Allyl Bromide

25g 500g CH2

>98.0%(GC) C3H5Br = 120.98 [106-95-6] MFCD00000244 bp 71℃ d 1.43 flp 12℃ Beil. 1,201 MI14-288 RTECS UC7090000

A1247 p -Anisaldehyde Dimethyl Acetal

Br

25ml 500ml OCH3

>95.0%(GC) C10H14O3 = 182.22 [2186-92-7] MFCD00036507 d 1.07 flp 98℃ Beil. 8,74

CH

OCH3

OCH3

New

A2294 11-Azido-3,6,9-trioxaundecanol

Price on request N3

C8H17N3O4 = 219.24 [86770-67-4]

B1197 Benzaldehyde Dimethyl Acetal >98.0%(GC) C9H12O2 = 152.19 [1125-88-8] MFCD00008491 bp 196℃ d 1.02 flp 71℃ Beil. 7,209 RTECS CU5774000

B0041 Benzenethiol

O

O

O

OH

25ml 500ml CH

OCH3 OCH3

25ml 500ml

>98.0%(GC) C6H6S = 110.17 [108-98-5] MFCD00004826 d 1.08 flp 76℃ Beil. 6,294 MI14-9355 F&F 10,399 RTECS DC0525000



SH

101

Reagents for Oligosaccharide Synthesis-② B0078 Benzoic Anhydride

25g 100g 500g O

>97.0%(GC)(T) C14H10O3 = 226.23 [93-97-0] MFCD00003073 mp 42℃ bp 158℃ /1mmHg Beil. 9,164 MI14-1092 F&F 5,23

O

C O C

B0105 Benzoyl Chloride

25ml 500ml O

>98.0%(GC)(T) C7H5ClO = 140.57 [98-88-4] MFCD00000653 bp 198℃ d 1.22 flp 72℃ Beil. 9,182 MI14-1112 F&F 5,24 RTECS DM6600000

C Cl

B0411 Benzyl Bromide

25g 100g 500g

(stabilized with Propylene Oxide)

CH2Br

>98.0%(GC) C7H7Br = 171.04 [100-39-0] MFCD00000172 d 1.44 flp 79℃ Beil. 5,306 MI14-1128 F&F 5,25 RTECS XS7965000

B0412 Benzyl Chloride (stabilized with ε-Caprolactam)

25g 500g CH2Cl

>99.0%(GC) C7H7Cl = 126.58 [100-44-7] MFCD00000889 bp 179℃ d 1.10 flp 67℃ Beil. 5,292 MI14-1129 RTECS XS8925000

D1356 Bis(4-hydroxyphenyl) Sulfide >98.0%(GC) C12H10O2S = 218.27 [2664-63-3] MFCD00002349 mp 152℃ Beil. 6,860 RTECS SN0800000

B0527 Boron Trifluoride Ethyl Ether Complex

25g 500g HO

S

OH

25ml 100ml 500ml BF3

.

CH3

O

CH3

>98.0%(W) BF3・C4H10O = 141.93 [109-63-7] MFCD00013194 bp 124℃ d 1.13 MI14-1350 F&F 9,64

B0656 N -Bromosuccinimide >98.0%(T) C4H4BrNO2 = 177.99 [128-08-5] MFCD00005510 Beil. 21(5)9,543 MI14-1438 F&F 9,70

102

25g 100g 500g O



N Br

O

Reagents for Oligosaccharide Synthesis-③ A5603 BSTFA [=N ,O -Bis(trimethylsilyl)trifluoroacetamide] [for Gas Chromatography]

5ml CH3 CH3

Si CH3 N

>95.0%(GC) C8H18F3NOSi2 = 257.40 [25561-30-2] MFCD00008269 bp 142℃ flp 24℃

B0995 tert -Butyldimethylchlorosilane

CF3

CH3

5g 25g 100g

[tert -Butyldimethylsilylating Agent]

CH3 CH3 CH3 C

>98.0%(GC) C6H15ClSi = 150.72 [18162-48-6] MFCD00000501 mp 88℃ bp 125℃ F&F 10,62 RTECS VV2000000

T1525 tert -Butyldimethylsilyl Trifluoromethanesulfonate >98.0%(T) C7H15F3O3SSi = 264.33 [69739-34-0] MFCD00000405 d 1.15 flp 36℃ F&F 15,54

B1223 tert -Butyldiphenylchlorosilane

CH3 O Si CH3

Si Cl

CH3 CH3

5g 25g CH3 CH3 CH3 C

Si

O O S CF3 O

CH3 CH3

5ml 25ml 100ml

>95.0%(GC) C16H19ClSi = 274.86 [58479-61-1] MFCD00000497 bp 125℃ /0.06mmHg d 1.07 flp 112℃ F&F 6,81

H3C H3C C Si

Cl

H3C

C0016 (±)-10-Camphorsulfonic Acid

25g 500g CH2SO3H

>98.0%(T) C10H16O4S = 232.29 [5872-08-2] MFCD00074827 Beil. 11,316

C0015 (+)-10-Camphorsulfonic Acid >98.0%(T) C10H16O4S = 232.29 [3144-16-9] MFCD00064157 Beil. 11,314 MI14-1734 F&F 4,68 RTECS ED1550000

C0972 (-)-10-Camphorsulfonic Acid >98.0%(T) C10H16O4S = 232.29 [35963-20-3] MFCD00064158 Beil. 11(3)585

O

25g 500g CH3 O

CH3 CH2SO3H

25g 500g CH3 HO3SCH2



CH3 O

103

Reagents for Oligosaccharide Synthesis-④ C0098 Chloroacetyl Chloride

25g 100g 500g O

>98.0%(GC)(T) C2H2Cl2O = 112.94 [79-04-9] MFCD00000725 bp 105℃ d 1.42 Beil. 2,199 MI14-2067 F&F 3,46 RTECS AO6475000

Cl

C1339 2-(Chloromethoxy)ethyltrimethylsilane

5ml 25ml

(stabilized with Diisopropylethylamine) >95.0%(GC) C6H15ClOSi = 166.72 [76513-69-4] MFCD00009919 bp 59℃ /8mmHg d 0.95 flp 46℃ F&F 10,431

C0903 2-Chloro-1-methylpyridinium Iodide

Cl

CH3 CH3

Si

CH2CH2OCH2Cl

CH3

25g 500g

>98.0%(T) C6H7ClIN = 255.48 [14338-32-0] MFCD00011984 MI14-6301 F&F 8,95

N

I

Cl

CH3

C0306 Chlorotrimethylsilane

25ml 100ml 500ml CH3

>98.0%(GC) C3H9ClSi = 108.64 [75-77-4] MFCD00000502 bp 57℃ d 0.86 flp -28℃ Beil. 4(3)1857 F&F 10,96 RTECS VV2710000

T1292

CH3

Copper(II) Trifluoromethanesulfonate

>98.0%(T) C2CuF6O6S2 = 361.67 [34946-82-2] MFCD00077492

5g 25g O CF3

Cu2

S O O

B0682 Diacetyl

Si Cl CH3

2

25ml 500ml

>98.0%(GC) C4H6O2 = 86.09 [431-03-8] MFCD00008756 bp 88℃ d 0.98 flp 11℃ Beil. 1,769 MI14-2966 F&F 7,21 RTECS EK2625000

D0134 1,4-Diazabicyclo[2.2.2]octane

O CH3

25g 500g

>98.0%(GC)(T) C6H12N2 = 112.18 [280-57-9] MFCD00006689 mp 155℃ MI14-9669 F&F 7,86 RTECS HM0354200



CH3 O

N N

Reagents for Oligosaccharide Synthesis-⑤ D1270 1,8-Diazabicyclo[5.4.0]-7-undecene

25g 100g 500g N

>98.0%(GC)(T) C9H16N2 = 152.24 [6674-22-2] MFCD00006930 bp 128℃ /14mmHg d 1.02 flp 116℃ F&F 7,87

N

A0776 Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca . 1.7mol/L) C16H14N2O4 = 298.30 [2449-05-0] MFCD00016737

D1547 Di-tert -butyl Dicarbonate [Boc-reagent for Amino Acid] >95.0%(T) C10H18O5 = 218.25 [24424-99-5] MFCD00008805 fp 23℃ flp 47℃ F&F 10,122 RTECS HT0230000

25g O

CH2O C N N C OCH2

25g 100g 500g CH3

C10H18O5 = 218.25 [24424-99-5] MFCD00008805

D0223 Dibutyltin Dichloride >97.0%(T) C8H18Cl2Sn = 303.84 [683-18-1] MFCD00000518 mp 42℃ F&F 1,213 RTECS WH7100000

O

O

CH3

CH3 CH3

100g 500g CH3

O

O

CH3

CH3 C O C O C O C CH3 CH3

CH3

100g 500g CH3

C10H18O5 = 218.25 [24424-99-5] MFCD00008805

CH3

CH3 C O C O C O C CH3

D3880 Di-tert -butyl Dicarbonate (ca . 30% in Toluene)

CH3

100g 500g

D3879 Di-tert -butyl Dicarbonate (ca . 30% in Tetrahydrofuran)

O

CH3

CH3

C10H18O5 = 218.25 [24424-99-5] MFCD00008805

O

CH3 C O C O C O C CH3

D3878 Di-tert -butyl Dicarbonate (ca . 30% in Dioxane)

O

O

O

CH3

CH3 C O C O C O C CH3 CH3

CH3

25g 500g Cl CH3(CH2)3

Sn

(CH2)3CH3

Cl



105

Reagents for Oligosaccharide Synthesis-⑥ D0305 Dibutyltin Oxide

25g 500g

>95.0%(W) C8H18OSn = 248.94 [818-08-6] MFCD00001992 Beil. 4(1)588 F&F 9,141 RTECS WH7175000

O CH3(CH2)3 Sn (CH2)3CH3

D1070 2,3-Dichloro-5,6-dicyano1,4-benzoquinone

25g 250g O NC

>97.0%(T) C8Cl2N2O2 = 227.00 [84-58-2] MFCD00001593 mp 214℃ Beil. 10,902 MI14-3063 F&F 10,135 RTECS GU4825000

NC

Cl O

D0436 N ,N '-Dicyclohexylcarbodiimide

25g 400g

>98.0%(GC) C13H22N2 = 206.33 [538-75-0] MFCD00011659 fp 34℃ MI14-3096 F&F 10,142 RTECS FF2160000

D1868 (Diethylamino)sulfur Trifluoride

Cl

N C N

5g 25g 100g

[Fluorinating Reagent]

F

CH3CH2 CH3CH2

>90.0%(T) C4H10F3NS = 161.19 [38078-09-0] MFCD00000363 bp 32℃ /10mmHg d 1.23 flp 23℃ MI14-3113 F&F 10,142

A0705 Diethyl Azodicarboxylate (40% in Toluene, ca . 2.2mol/L)

N S

F

F

25g 100g 250g OCH2CH3

O N N

C6H10N2O4 = 174.16 [1972-28-7] MFCD00009103 d 0.96 flp 41℃ Beil. 3,123 F&F 9,160

D2971 Diisobutylaluminum Hydride (19% in Hexane, ca . 1.0mol/L)

O

CH3CH2O

100ml 500ml [(CH3)2CHCH2]2AlH

C8H19Al = 142.22 [1191-15-7] MFCD00008928 flp -23℃ Beil. 4(4)4400 F&F 17,123

A0057 2,2-Dimethoxypropane >98.0%(GC) C5H12O2 = 104.15 [77-76-9] MFCD00008479 bp 80℃ d 0.85 flp -9℃ Beil. 1,648 F&F 5,226

25ml 500ml CH3O

OCH3

CH3

CH3



Reagents for Oligosaccharide Synthesis-⑦ D4029 1-(3-Dimethylaminopropyl)3-ethylcarbodiimide

5g 25g CH3 CH3CH2 N C N

(CH2)3N CH3

>98.0%(GC)(T) C8H17N3 = 155.25 [1892-57-5] MFCD00044916 bp 45℃ /0.3mmHg d 0.88

D1601 1-(3-Dimethylaminopropyl)3-ethylcarbodiimide Hydrochloride [Coupling Agent for Peptides Synthesis]

5g 25g 250g CH3 CH3CH2 N C N

. HCl

(CH2)3N CH3

>98.0%(T) C8H17N3・HCl = 191.70 [25952-53-8] MFCD00012503 mp 115℃ RTECS FF2200000

D1450 4-Dimethylaminopyridine

25g 100g 500g N

>99.0%(T) C7H10N2 = 122.17 [1122-58-3] MFCD00006418 mp 110℃ bp 190℃ /150mmHg Beil. 22(2)341 MI14-3389 F&F 10,155 RTECS US9230000

CH3 CH3

N

D2159 Dimethylthiophosphinoyl Chloride >97.0%(GC) C2H6ClPS = 128.55 [993-12-4] MFCD00014454 bp 78℃ /15mmHg d 1.22

P0801

Diphenyl Phosphate

1g 5g CH3 CH3

1g 25g

>99.0%(LC)(T) C12H11O4P = 250.19 [838-85-7] MFCD00003033 mp 69℃ Beil. 6,178 RTECS TC5470000

C1415 Diphenylphosphinic Chloride >98.0%(GC)(T) C12H10ClOP = 236.63 [1499-21-4] MFCD00002077 bp 222℃ /16mmHg d 1.27 flp 26℃ Beil. 16(4)1038 F&F 15,150

P0231

Diphenyl Sulfone

S P Cl

O O

O P OH

10g 25g O P Cl

25g 500g

>99.0%(GC) C12H10O2S = 218.27 [127-63-9] MFCD00007548 mp 127℃ Beil. 6,300 MI14-3332 RTECS SX2400000

O S O



107

Reagents for Oligosaccharide Synthesis-⑧ D1002 Diphenyl Sulfoxide

5g 25g 100g O

>99.0%(GC) C12H10OS = 202.27 [945-51-7] MFCD00002085 mp 71℃ bp 198℃ /10mmHg Beil. 6,300 F&F 1,348 RTECS DA9185000

S

D2358 Diphenyltin Sulfide

1g

[Activator for O -Glycoside Synthesis] >97.0%(W) C12H10SSn = 304.98 [20332-10-9] MFCD00058856 mp 185℃

E0077

Ethylenediamine Anhydrous

Sn

25ml 500ml H2 N

>98.0%(GC)(T) C2H8N2 = 60.10 [107-15-3] MFCD00008204 fp 10℃ bp 116℃ d 0.90 flp 34℃ Beil. 4,230 MI14-3795 F&F 4,231 RTECS KH8575000

E0081

Ethylenediamine Monohydrate

>98.0%(T) C2H8N2・H2O = 60.10(Anh) [6780-13-8] MFCD00149563 bp 118℃ d 0.96 Beil. 4,230 MI14-3795 F&F 4,231

F0516

F0517

F0341

H2N

NH2

Fluoromethyl Phenyl Sulfone

O HO

OC(CH3)3 HN

Fmoc

1g 5g OH

O OC(CH3)3

CH3 HN

Fmoc

1g 5g

>97.0%(GC) C7H7FO2S = 174.19 [20808-12-2] MFCD00191650 mp 53℃



. H2O

1g 5g

N α-[(9H -Fluoren-9-ylmethoxy)carbonyl]L-threonine tert -Butyl Ester

>98.0%(LC)(N) C23H27NO5 = 397.47 [120791-76-6] mp 100℃

NH2

25ml 500ml

N α-[(9H -Fluoren-9-ylmethoxy)carbonyl]L-serine tert -Butyl Ester

>98.0%(LC)(N) C22H25NO5 = 383.44 [110797-35-8] mp 127℃

S

SO2CH2F

Reagents for Oligosaccharide Synthesis-⑨ H0914 Hafnocene Dichloride

1g 5g 25g

>98.0%(T) C10H10Cl2Hf = 379.58 [12116-66-4] MFCD00001438 F&F 16,120 RTECS MG4815000

Cl

H0989 Hexyldimethyloctylammonium Bromide >97.0%(T) C16H36BrN = 322.38 [187731-26-6] MFCD03093632

Hf

Cl

5g 25g CH3 CH3(CH2)7 N

(CH2)5CH3

Br

CH3

H0172 Hydrazine Monohydrate

25ml 500ml H2NNH2 . H2O

>98.0%(T) H4N2・H2O = 32.05(Anh) [7803-57-8] MFCD00149931 d 1.03 flp 75℃ MI14-4771 F&F 9,236 RTECS MV8050000

H0204 Hydrazine Monohydrate (79%)

25g 500g H2NNH2 . H2O

H4N2・H2O = 32.05(Anh) [7803-57-8] MFCD00149931 d 1.03 flp 75℃ MI14-4771 F&F 9,236 RTECS MV8050000

H1112 Hydrazine Acetate >98.0%(T) H4N2・C2H4O2 = 92.10 [13255-48-6] mp 101℃ Beil. 2,107 F&F 1,445

H0182 Hydrogen Bromide (30% in Acetic Acid, ca . 5.1mol/L) [for Peptide research]

5g 25g O H2NNH2

.

CH3 C OH

25g 500g HBr

HBr = 80.91 [10035-10-6] MFCD00011323 d 1.40 MI14-4778

H0468 1-Hydroxybenzotriazole Monohydrate >97.0%(T) C6H5N3O・H2O = 135.13(Anh) [80029-43-2] MFCD00005805 mp 160℃ Beil. 26,41 F&F 6,288 RTECS DM1288000

25g 200g 500g N N

N

. H2O

OH



109

Reagents for Oligosaccharide Synthesis-⑩ I0001

Imidazole

25g 100g 500g N

>98.0%(T) C3H4N2 = 68.08 [288-32-4] MFCD00005183 mp 90℃ Beil. 23(3/4)564 MI14-4912 F&F 2,220 RTECS NI3325000

I0060

Iodomethane (stabilized with Copper chip)

N H

10ml 100ml 300ml CH3I

>99.5%(GC) CH3I = 141.94 [74-88-4] MFCD00001073 bp 43℃ d 2.28 Beil. 1,69 MI14-6087 F&F 9,308 RTECS PA9450000

I0074

N -Iodosuccinimide

5g 25g 100g

>98.0%(T) C4H4INO2 = 224.99 [516-12-1] MFCD00005512 Beil. 21(3/4)4576 MI14-5045 RTECS WN2817000

L0042

Levulinic Acid

N

2,3-Lutidine

O CH3

OH O

25ml 500ml CH3

>98.0%(GC)(T) C7H9N = 107.16 [583-61-9] MFCD00009605 bp 161℃ d 0.95 flp 50℃ Beil. 20(3/4)2765

L0085

2,4-Lutidine

N

CH3

25ml 500ml CH3

>95.0%(GC) C7H9N = 107.16 [108-47-4] MFCD00006337 bp 157℃ d 0.93 flp 37℃ Beil. 20(3/4)2768 F&F 6,224 RTECS OK9400000

L0065

O

I

25g 500g

>97.0%(GC)(T) C5H8O3 = 116.12 [123-76-2] MFCD00002796 fp 29℃ Beil. 3,671 MI14-5472 F&F 10,230 RTECS OI1575000

L0063

O

2,5-Lutidine

N

CH3

5ml 25ml 500ml

>98.0%(GC) C7H9N = 107.16 [589-93-5] MFCD00006343 bp 157℃ d 0.93 flp 48℃ Beil. 20(3/4)2774 RTECS OK9625000

CH3 N



CH3

Reagents for Oligosaccharide Synthesis-⑪ L0067

2,6-Lutidine

25ml 500ml

>98.0%(GC) C7H9N = 107.16 [108-48-5] MFCD00006345 bp 144℃ d 0.92 flp 33℃ Beil. 20(3/4)2776 MI14-5616 F&F 1,626 RTECS OK9700000

L0066

3,4-Lutidine

CH3

CH3

25ml 500ml CH3

>98.0%(GC) C7H9N = 107.16 [583-58-4] MFCD00006403 bp 179℃ d 0.96 flp 61℃ Beil. 20(3/4)2787 RTECS OK9800000

L0068

N

3,5-Lutidine

CH3 N

25ml 500ml

>98.0%(GC) C7H9N = 107.16 [591-22-0] MFCD00006404 bp 172℃ d 0.94 flp 47℃ Beil. 20(3/4)2788

CH3

CH3 N

M0676 4-Methoxybenzyl Chloride

25ml

(stabilized with Amylene)

CH2Cl

>98.0%(GC)(T) C8H9ClO = 156.61 [824-94-2] MFCD00000915 bp 127℃ /24mmHg d 1.15 flp 109℃ Beil. 6(4)2137 F&F 1,668

OCH3

M1264 Methoxymethyltrimethylsilane >95.0%(GC) C5H14OSi = 118.25 [14704-14-4] MFCD00009843 bp 85℃ d 0.76 flp -5℃ Beil. 4(3)1844

M0123 4-Methoxyphenol

5ml CH3 CH3

Si CH2OCH3 CH3

25g 500g

>99.0%(GC) C7H8O2 = 124.14 [150-76-5] MFCD00002332 mp 57℃ bp 243℃ Beil. 6,843 RTECS SL7700000

OH

OCH3

M0137 Methylamine (ca . 40% in Water, ca . 12mol/L)

25ml 500ml CH3NH2

CH5N = 31.06 [74-89-5] MFCD00008104 d 0.90 flp -10℃ RTECS PF6300000



111

Reagents for Oligosaccharide Synthesis-⑫ M0558 Methylhydrazine

25ml 100ml H2NNHCH3

>98.0%(GC) CH6N2 = 46.07 [60-34-4] MFCD00007621 bp 87℃ d 0.87 Beil. 4(2)957 MI14-6086 F&F 4,340 RTECS MV5600000

M1494 Methyl Tributylstannyl Sulfide

25g 100g (CH2)3CH3

>98.0%(W) C13H30SSn = 337.15 [17314-32-8] d 1.16

T0680

CH3(CH2)3 Sn SCH3 (CH2)3CH3

Methyl Trifluoroacetate

25g 500g O

>98.0%(GC) C3H3F3O2 = 128.05 [431-47-0] MFCD00000417 bp 43℃ d 1.29 flp -20℃ Beil. 2(4)463

CF3

M1573 Morpholinosulfur Trifluoride

OCH3

1g 5g SF3

>93.0%(T) C4H8F3NOS = 175.17 [51010-74-3] MFCD00037057 bp 42℃ /0.5mmHg flp 76℃

N O

N0155 2-Nitrobenzoic Acid

25g 500g O

>90.0%(GC) C7H5NO4 = 167.12 [552-16-9] MFCD00007137 mp 144℃ Beil. 9,370 MI14-6588 RTECS DH5050000

T2669

C OH NO2

Tetrabutylammonium p -Nitrophenoxide

>98.0%(LC)(T) C22H40N2O3 = 380.57 [3002-48-0] mp 145℃ RTECS 4078078

5g 25g O (CH2)3CH3 CH3(CH2)3 N

(CH2)3CH3

(CH2)3CH3 NO2

M0450 Trichloro(methyl)silane >98.0%(GC)(T) CH3Cl3Si = 149.47 [75-79-6] MFCD00000481 bp 65℃ d 1.28 flp -8℃ Beil. 4(3)1896 RTECS VV4550000

25g 500g Cl CH3



Si Cl Cl

Applications for Sugar-conjugates Applications for Sugar-conjugates 糖鎖コンジュゲートへの応用

New

Through the research in carbohydrate field, various biological functions of oligosaccharides have been elucidated in life phenomena such as infection, cell-cell recognition, information transmission, fertilization and cell division. The materials containing sugar chains are expected as new functional bioengineering materials which can be applied to medical materials, for example biosensors which specifically bind to toxins or pathogens, composite materials used for surface plasmon resonance (SPR) or crystal oscillator (QCM), or affinity chromatography for the purification of various biopolymers. Sugar chains having a thiol group, carboxyl group, amino group or azido group at the reducing terminal can be applied to immobilization onto resin beads and gold substrates, introduction of fluorescent groups or biotin, or the use of click chemistry as shown below. Sugar-conjugates are expected as important tools for new bioengineering building materials.

· Surface Plasmon Resonance (SPR)

近年の糖鎖機能解明に向けた研究により，感染，細胞間認識，情報伝達，受精，細胞分裂に関わる役割など，生命現象における糖鎖の新たな機能が解明されてきています。このような糖鎖を効果的に利用することで，新しい機能を持たせた生命工学材料が構築できると期待されています。例えば，病原体や毒素に特異的に結合する機能性糖鎖をビーズやナノ粒子等の固相担体に固定化することによりバイオセンサーなど医療材料への応用が可能と考えられます。固定化担体に金基板，金粒子を用いれば表面プラズモン共鳴（SPR），水晶発振子（QCM）を利用することができるなど，生体認識性を持った複合材料とすることができます。また，機能性糖鎖をクロマトグラフィー担体に固定化することでアフィニティクロマトグラフィーとして様々な生体高分子の分離・精製に応用することも可能となります。その他，DDSや蛍光分析などにも利用可能と考えられます。還元末端にチオール基，カルボキシル基，アミノ基やアジド基を有する糖鎖は，その官能基の性質を利用して金基板や樹脂・ビーズへの固定化，ビオチンや蛍光基の導入，クリックケミストリーの利用など，以下のような応用が可能な新たな生命工学材料構築のツールとして期待されます。

HO

HO

OH O

HO

AcHN

HO O OH O O HO OH HO

· Biotin

OH O

OH HOOC

HO AcHN

O

HO OH O

O HO HO

OH O

O HO

O

OH

O

O

O

O

R

O

OH

R= NHTFAc (A2631) / NH2

R

AcHN

O

R= NH2 (N0949) /

OH OH O

R

OH

HO

O

O O

R= NH2 (G0402) / N3 (G0403)

HO

· Beads / Resins

OH O

HO

SH

HN

/

O

CH C

HN

O HO HO

HO AcHN

O HO

· Click Chemistry

O HO

O HO HO

HOOC

HO AcHN

COOH

OH

OH

O HO

O HO

OH O AcHN HO HO HO

HO

HO AcHN

· Fluorecent Groups

COOH O

HO

O HO HO

O HO

OH O OH

G0422

HN

C17H35 OH

O

C13H27 OH

O O O HO O O HO O HO

OH

HO OH O O O HO OH

OH O O HO

AcHN

OH O AcHN

O

N3

HO HO O HO OH O O HO O AcHN D4217

Sugar derivatives applied to sugar-conjugates.



113

Glycosynthase (Endo-M-N175Q)-① An enzyme that adds whole sugar chains without breaking down products 糖鎖を丸ごと付加し，生成物を分解しない酵素 New ―Endo-M-N175Q―

G0365 Glycosynthase (Endo-M-N175Q) is an enzyme developed by Yamamoto, Umekawa, et al. through site-directed mutation of areas around the active center of A1651 Endo-M1) which is already marketed. Since the feature of Glycosynthase is efficient transglycosylation activity by using oxazoline derivatives as glycosyl donors while suppressing sugar hydrolysis activity, the resulting glycosylated products are obtained in high yield with less digestion of the products by the enzyme. Due to this feature Glycosynthase is expected to be applied as useful tool in glycotechnology.

G0365 グライコシンターゼ（Endo-M-N175Q）は山本・梅川らによって開発され，弊社で先に販売している A1651 Endo-M1）の活性中心付近を部位特異的に変異させた酵素です。この酵素は糖供与体としてオキサゾリン体を用いることによって糖鎖を効率よく付加転移させる一方で，糖加水分解活性が抑制されている特長を持っています。このため糖転移生成物は酵素によって分解されにくく，生成物を高収率で得ることができます。この特長によって本酵素は糖鎖工学の有用なツールとして応用が期待されています。

Umekawa and her colleagues caused transglycosylation reactions at the GlcNAc site of sperm antigen CD52 using oxazoline derivatives of the high-mannose type sugar chains or the complex type sugar chains as glycosyl donors2). They succeeded in obtaining glycosylated products in high yield of 84% and 76%, respectively. Moreover, they also achieved transglycosylation reactions using two biologically active blood-pressure-lowing peptides, PAMP12 and Substance P, as glycosyl acceptors and the oxazoline derivative of a complex type sugar chain containing sialic acids as a glycosyl donor in 95% and 98% yield, respectively3). The articles in 2009 describe the advantages of this glycosylation method using sugar-oxazoline derivatives4-5).

梅川らは精子抗原CD52のGlcNAc部分に高マンノース型糖鎖のオキサゾリン体または複合型糖鎖のオキサゾリン体を糖供与体として糖転移反応を行い，それぞれ84％，76％と高い転移率で糖転移生成物を得ることに成功しました2）。また血圧降下作用を持つ２つの生理活性ペプチドPAMP12と Substance Pを受容体とし，シアロ複合糖鎖のオキサゾリン体を糖供与体とした糖転移反応においてもそれぞれ95％， 98％の高い転移率を示しています（Fig. 2）3)。2009年の論文ではこの糖−オキサゾリン体を用いた糖鎖合成反応の優位性が報告されています4-5)。

Practical realization of efficient transglycosylation reactions would also be useful for expansion into glycoprotein synthesis, such as the area of biosimilars, and creation of new functional sugar complexes can be expected.

References

効率の良い糖転移反応の実用化はバイオシミラーなどの糖タンパク質合成への展開にも有効であり，新しい機能性糖鎖複合体の創製が期待されます。

1) K. Yamamoto, S. Kadowaki, J. Watanabe, H. Kumagai, Biochem. Biophys. Res. Commun. 1994, 203, 244. 2) M. Umekawa, C. Li, T. Higashiyama, W. Huang, H. Ashida, K. Yamamoto, L-X. Wang, J. Biol. Chem. 2010, 285, 511. 3) M. Umekawa, T. Higashiyama, T. Tanaka, M. Noguchi, A. Kobayashi, S. Shoda, W. Huang, L-X. Wang, H. Ashida, K. Yamamoto, Biochimica et Biophysica Acta 2010, 1800, 1203. 4) P. Bojarova, V. Kren, Trends in Biotechnology 2001, 92, 493. 5) J. R. Rich, S. G. Withers, Nature Chemical Biology 2009, 5, 206.



Glycosynthase (Endo-M-N175Q)-② A set of the transglycosylation data using a glycosynthase (Endo-M-N175Q) is shown below (Fig. 3). The oxazoline derivative of a complex type sugar as a glycosyl donor was transglycosylated with GlcNAc-β-p NP as a glycosyl acceptor, and the glycosylated product was afforded in a high yield of 95% after 24 hours. T h e s u s t a i n e d a n d e f fe c t i ve p r o d u c t i o n o f t h e glycosylated compound was identified from HPLC profiles and MALDI-TOF MS as shown below (Fig. 4 and 5).

HO

COONa

OH

HO AcHN

O HO

HO

O HO HO

O HO

O HO

OH O AcHN HO HO HO

HO HO

O

COONa

OH

HO AcHN

O HO

O HO HO

O HO

OH O

O

COONa

OH

HO AcHN NO2

O HO

O HO HO

AcHN

O HO

GlcNAc-β-pNP (N0866)

O O HO O O HO O HO

HO

G0365 グライコシンターゼ(Endo-M-N175Q)の糖転移反応の例をご紹介します。シアロ複合型糖鎖オキサゾリン体を糖供与体，N0866 GlcNAc-β-p NPを受容体とした糖転移反応を行ったところ，24時間後に95%という高い転移率で生成物が確認されています。以下その反応スキーム(Fig. 3)と HPLCによる反応追跡，生成物のMALDI-TOF-MSをお示しします(Fig. 4,5)。これらの結果をみるとオキサゾリン体から持続的かつ効率的に糖転移反応物が得られていることがわかります。

OH O

OH O AcHN HO HO HO

O O O HO O O HO O HO

Endo-M-N175Q (G0365)

N O

HO HO O HO OH O O HO O AcHN

O HO

HO

COONa

OH

HO AcHN

O HO

O HO HO

O HO

oxazoline derivative of a complex type sugar

OH O O HO

AcHN

OH O AcHN

O

NO2

HO HO O HO OH O O HO O AcHN

glycosylated product

Fig. 3 Transglycosylation of oxazoline derivative and GlcNAc-β-p NP

Fig. 4 HPLC profiles of transglycosylation reaction. HPLC: ODS, CH3CN / H2O, UV 260nm : GlcNAc-β-p NP : glycosylated product

2345.940

1000

1500

2000 2500 Mass/Charge

3000

Fig. 5 MALDI-TOF MS spectrum of transglycosyled product. Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use.


115

Endo-M An Enzyme Transfers the Intact Oligosaccharides 糖鎖を丸ごと付加する酵素 ―Endo-M― Hydrolysis

Endo-M A1651

Man GlcNAc

+ GlcNAc Protein

Man GlcNAc GlcNAc Protein Man GlcNAc O-R + GlcNAc Protein

glycoprotein

HO R

transglycosylation product

acceptor

Transglycosylation

A1651 Endo-M is one of the enzymes called endo-βN-acetylglucosaminidases (endo-β-GlcNAc-ases). This enzyme was found by Yamamoto et al., in the culture fluid of Mucor hiemalis isolated from soil 1). Endo-M hydrolyzes N,N'-diacetylchitobiose moiety in oligosaccharides bound to the asparaginyl residue of various glycoproteins through N-glycosidic linkage. The efficacy of this enzyme comes from the fact that one N-acetylglucosamine residue remains bound to the protein while cleaving the N,N'-diacetylchitobiose moiety. The enzyme is thus able to transfer the intact oligosaccharide to suitable acceptors (Fig.1). Haneda et al. have transferred oligosaccharides to 9-fluorenylmethoxycarbonyl-asparaginyl-Nacetylglucosaminide [Fmoc-Asn(GlcNAc)] by incubating sialotransferrin glycopeptide, asialotransferrin glycopeptide and Man 6 GlcNAc 2 -Asn-peptide with Endo-M 2). Furthermore, synthetic hCG (β12-16)GlcNAc-peptide has been subjected to transglycosylate of sialo complex type oligosaccharide. An alternative synthetic method of peptide containing GlcNAc has been developed by Inazu et al 3). This method uses Fmoc-Asn(GlcNAc), which is synthesized from NFmoc aspartic acid (Fmoc-Asp-OH) and azide of GlcNAc, instead of Fmoc-Asn-OH, and it is applied to a mixed acid anhydride method using dimethylphosphothioic acid (Mpt-MA) which generally shows poor responses toward hydroxyl group. By combining this method with Endo-M, many glycopeptides can be designed and easily prepared. Yamamoto has compiled the outline of this methodology as the Chemo-Enzymatic Synthesis in his review 4). Endo-M can also be used to create new functions, by introducing oligosaccharides, to the substances that originally do not have the oligosaccharide 5). Unlike the conventional endo-β-GlcNAc-ase, it has been found that Endo-M is an enzyme with a broad substrate specificity, cleaving not only the high mannose type and hybrid type of asparagine-linked oligosaccharides but also the complex type oligosaccharides in glycoproteins. Especially, the transglycosylation reaction of sialo complex type oligosaccharides was possible only by using Endo-M. Therefore, Endo-M is expected to be applied to various fields.

A1651 Endo-Mは，山本らが糸状菌Mucor hiemalisの培養液より見出したエンド-β-N-アセチルグルコサミニダーゼで，糖タンパク質のアスパラギン結合糖鎖のジアセチルキトビオース結合を加水分解し，タンパク質側にN-アセチルグルコサミン1残基を残して糖鎖を遊離させます。その際，適当な受容体が存在すると遊離した糖鎖がその受容体に転移します1）。羽田ら2）はシアロトランスフェリン糖ペプチド，アシアロトランスフェリン糖ペプチド，高マンノース型糖鎖を有するペプチドにEndo-Mを作用させ，9-フルオレニルメトキシカルボニルアスパラギニル-N-アセチルグルコサミン（FmocAsn(GlcNAc)）に糖鎖を転移させています。また，稲津らの開発した方法によりヒト絨毛性性腺刺激ホルモン（hCG）の部分ペプチドhCG(β12-16)にGlcNAcを導入したペプチドを合成し，これにシアロ複合型糖鎖を転移させています。稲津ら3）の開発した方法は，N末をFmocで保護したアスパラギン酸とGlcNAcのアジドから合成されるFmoc-Asn(GlcNAc)を Fmoc-Asn-OHの代わりに使用し，ジメチルチオホスフィン酸混合酸無水物（Mpt-MA）法を用いるもので，GlcNAcを有する人工ペプチドの簡便な合成法といえます。この方法と Endo-Mを組み合わせることにより，糖鎖ペプチドを自由に設計し，調製することができます。この方法は，化学−酵素合成法として，山本の総説にまとめられています4）。また， Endo-Mは，本来糖鎖を持たない物質に糖鎖を導入し，新たな機能の発現にも利用されています5 ）。 Endo-Mは，従来から知られているEndo-β-GlcNAc-aseと異なり，高マンノース型糖鎖，混成型糖鎖のみならず複合型糖鎖にも作用する基質特異性の広い酵素で，適当な受容体に糖鎖を転移させることができることから多方面での応用が期待されています。

This Endo-M was merchandised as the fruition of NEDO project under licenses from patent-holding companies of Takara Bio Inc. and Kirin Brewery Co., LTD.

本酵素は，タカラバイオ株式会社，麒麟麦酒株式会社の所有の特許を利用し，NEDO プロジェクトの成果として製品化しました。 References

1) S. Kadowaki, K. Yamamoto, M. Fujisaki, K. Izumi, T. Tochikura, T. Yokoyama, Agric. Biol. Chem. 1988, 54, 97; K. Yamamoto, S. Kadowaki, J. Watanabe, H. Kumagai, Biochem. Biophys. Res. Commun. 1994, 203, 244. K. Haneda, T. Inazu, K. Yamamoto, H. Kumagai, Y. Nakahara, A. Kobata, Carbohydr. Res. 1996, 292, 61. M. Mizuno, I. Muramoto, T. Kawakami, M. Seike, S. Aimoto, K. Haneda, T. Inazu, Tetrahedron Lett. 1998, 39, 55. K. Yamamoto, J. Biosci. Bioeng. 2001, 92, 493. S. Kojima, T. Hasegawa, T. Yonemura, K. Sasaki, K. Yamamoto, Y. Makimura, T. Takahashi, T. Suzuki, Y. Suzuki, K. Kobayashi, Chem. Commun. 2003, 1250. 6) T. Onozawa, J. Kumada, Trends in Glycoscience and Glycotechnology, 2003, 15, 359.

2) 3) 4) 5)



Endo-α An Enzyme Transfers the Intact Oligosaccharides 糖鎖を丸ごと付加する酵素 ―Endo-α― HO HO

HO

OH O

EndoA1844

OH O

O AcHN

OH

OH

HO

OH O

HO

O

Donor

OH

HO

OH O

O AcHN

OH

+

O

Acceptor

Acceptor : compounds possessing hydroxyl groups e.g. monosaccharides, peptides, proteins, etc.

Yamamoto et al. have purified and isolated A1844 endoα-N-acetylgalactosaminidase (Endo-α) found in the culture fluid of Bifidobacterium longum1). Endo-α can recognize the structure of the Galβ1-3GalNAc disaccharide α-linked with a hydroxyl group. It releases Galβ1-3GalNAc by hydrolysis. When a compound possessing a hydroxyl group coexists as an acceptor, the released Galβ1-3GalNAc is transferred to the acceptor2). Discovered by Yamamoto et al., Endo-α can transfer Galβ1-3GalNAc to various compounds such as monosaccharides, peptides, and proteins, using core 1 contained in mucin-type oligosaccharide chains as a donor. As a tool for the enzymatic synthesis of glycoconjugates, it is expected that many applications for Endo-α will be found in a wide range of fields.

山本らは乳酸菌(Bifidobacterium longum)を培養し，その培養液中にA1844 エンド-α-N-アセチルガラクトサミニダーゼ (Endo-α)の存在を見い出し，精製単離しています 1）。このEndo-αは，Galβ1-3GalNAcの二糖が水酸基とα結合した構造を認識し，この結合を加水分解によりGalβ1-3GalNAc を遊離させます。その際，水酸基を有する化合物を受容体として共存させると遊離したGalβ1-3GalNAcがその受容体に転移します2）。この山本らの見い出したEndo-αは，ムチン型糖鎖に含まれるコア1をドナーとして，糖やペプチド･蛋白など幅広い化合物にGalβ1-3GalNAcを転移させることができ，酵素法による複合糖鎖合成のツールとして多方面での応用が期待されています。

This Endo-α was merchandised as the fruition of NEDO project.

本酵素は，NEDO プロジェクトの成果として製品化致しました。 References

1) K. Fujita, F. Oura, N. Nagamine, T. Katayama, J. Hiratake, K. Sakata, H. Kumagai, K. Yamamoto, J. Biol. Chem. 2005, 280, 37415. 2) H. Ashida, K. Yamamoto, T. Murata, T. Usui, H. Kumagai, Arch. Biochem.Biophys. 2000, 373, 394; T. Katayama, K. Fujita, K. Yamamoto, J. Biosci. Bioeng. 2005, 99, 457.

This product is not available for purchase in the U.S.



117

Glycohydrolase-① A1844 endo -α-N -Acetylgalactosaminidase(=Endo-α) Recombinant: from Bifidobacterium longum expressed in Escherichia coli

100munits

[59793-96-3] MFCD00131003 EC 3.2.1.97

A1651 endo -β-N -Acetylglucosaminidase(=Endo-M) Recombinant: from Mucor hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)]

100munits

[37278-88-9] MFCD00151069 EC 3.2.1.96

A0447 α-Amylase diluted with Starch,

25g 500g

from Bacillus subtilis [9000-90-2] MFCD00081319 EC 3.2.1.1 MI14-599 RTECS BU7432500

A0448 β-Amylase from Soybean

25g

[9000-91-3] MFCD00081391 EC 3.2.1.2 MI14-599 RTECS BU7435000

C0057 Cellulase from Aspergillus niger

1g 5g 25g

[9012-54-8] MFCD00081510 EC 3.2.1.4 RTECS FJ5375000

M0035 Glucoamylase from Rhizopus

25g

(contains 50% Diatomaceous earth) [9032-08-0] MFCD00081321 EC 3.2.1.3

G0050 Glucose Oxidase from Aspergillus niger [9001-37-0] MFCD00131182 EC 1.1.3.4 MI14-4460 RTECS RQ8452000



1g

Glycohydrolase-② G0035 β-Glucosidase from Almonds

100mg

[9001-22-3] MFCD00130628 EC 3.2.1.21

G0365 Glycosynthase (Endo-M-N175Q) Recombinant: from Mucor hiemalis expressed in Escherichia coli

100munits

[37278-88-9] MFCD00151069 EC 3.2.1.96

P0026

Pectinase from Aspergillus niger

25g

[9032-75-1] MFCD00131809 EC 3.2.1.15



119

Lectin, Fucose Specific Lectin, Fucose Specific L -フコース特異的レクチン Lectins recognize oligosaccharides and specifically well reversibly binded ones. Thus, lectins are widely utilized in cell biology related fields such as blood-type studies and binding studies of oligosaccharides to cancer cell surfaces, and many other important studies 1). Lectins are widely distributed in nature and found from almost all types of living beings organisms like plants, microorganisms, fungus, invertebrates, vertebrates and viruses. The product introduced today is a new-type of lectin isolated from Aspergillus oryzae in Japanese sake fermentation. This lectin has proven to have a strong affinity toward L-fucose according to the results of hemagglutination inhibition assay 2). The fucose bonding position shows the highest binding for oligosaccharides are the ones containing L-Fuc α1,6 and α1,2. Fucosyl residues α1,3 and α1,4 also possess the specificity. The molecular weight of L-fucose specific lectin subunit, a dimeric substance, showed 35,000 (Fig. 1). This lectin shows 26% similarity to lectine isolated from Aleuria aurantia 2), and its substrate specificity is also thought to be relatively similar. Generally, lectins have been applied for the detection and the analysis of complex-type oligosaccharides as they can specifically recognize oligosaccharides. Especially, the ones with fucose typically possess physiological properties. Therefore, these lectins are often used for such purposes. For example, fucosylated oligosaccharides are known to participate in the life processes such as embryonic growth, differentiation, cell recognition, canceration, and inflammation. When in-vivo transformations of the fucose to oligosaccharides take place, such reactions are recognized as important indications of the antigen epitopes for the Lewis blood-type and cancer related carbohydrate antigens 3). The Aspergillus oryzae fucose specific lectin is not only utilized as an analyzing tool for the sugarbinding specificity of complex-type oligosaccharides, but it is highly applicable for a wide spectrum of studies on oligosaccharides 4).

糖鎖を認識して特異的かつ可逆的に結合するレクチンは，血液型の研究をはじめ，癌細胞の表面糖鎖の研究など，細胞生物学関連分野で広く利用されています 1）。その起源は，植物・微生物・キノコ・無脊椎動物・脊椎動物・ウィルスなど，あらゆる生物に広く分布することが明らかになってきています。本品は，清酒醸造で用いられる麹菌Aspergillus oryzae により単離された新規レクチンで，赤血球凝集阻害アッセイから，L-フコースに親和性を持つことが明らかとなっています 2）。また，フコースの結合様式については， L-Fucα1,6に対して最も高い結合性を持ち，L-Fucα1,2， L-Fucα1,3，L-Fucα1,4残基に対しても結合性を有します。サブユニット分子量は35,000（Fig.1）の2量体です。本レクチンは，遺伝子配列でヒイロチャワンタケレクチンと26%の相同性を持ち2），基質特異性も比較的類似していると考えられています。一般的に，レクチンは糖鎖を特異的に認識することから，複合糖鎖の検出・解析に応用されています。特にフコースを含む糖鎖は生理機能を持つ糖鎖が多く，検出・解析の対象となる場合が多いとされています。例えば，フコシル化糖鎖は胚発生・分化・細胞認識・癌化・炎症などの生命現象に関与していることが知られています。また人体においてもフコースが糖鎖に転移することは，ルイス式血液型や癌関連糖鎖抗原の抗原エピトープの重要な指標とされています 3）。この麹菌フコースレクチンは，複合糖鎖の結合様式解析のツールにとどまらず，糖鎖研究に広く応用可能なレクチンです4）。

Fig.1. SDS-PAGE L : 0.25mg/ml×5 l CBB Staining pure grade : single band Gel : Gradient 10-20 subunit Mr : 35000

This lectin was merchandised under the technical tie-up with GEKKEIKAN SAKE COMPANY, LTD.

本レクチンは，月桂冠株式会社の技術協力のもと製品化しました。

L0169

Lectin, Fucose specific from Aspergillus oryzae (5mg/mL, PBS pH6.5)

1ml

MFCD06798677 References 1) N. Sharon, H. Lis, Lectins (Japanese translation), Japan Scientific Societies Press: Tokyo, 1990. 2) Molecular cloning and overexpression of fleA gene encoding a fucose-specific lectin of Aspergillus oryzae H. Ishida, T. Moritani, Y. Hata, A. Kawato, K. Suginami, Y. Abe, S. Imayasu, Biosci. Biotechnol. Biochem. 2002, 66(5), 1002. 3) H. Narimatsu, Tanpakushitsu Kakusan Koso 1998, 43(16), 2394. 4) A. Kuno, Y. Kato, A. Matsuda, M. K. Kaneko, H. Ito, K. Amano, Y. Chiba, H. Narimatsu, J. Hirabayashi, Mol. Cell. Proteomics 2009, 8, 99.

120



Anti-Glyco Antibodies

New

Anti-Glyco Antibodies 抗糖鎖抗体

Carbohydrate chains are called the third life chain following the protein and the nucleic acid and are one of the most important issues in the post genome research. Tokyo Chemical Industry Co. LTD. (TCI) supports glycoscience research by providing useful anti-carbohydrate chain antibodies. Most carbohydrate chains attach to lipids or proteins and occur in the form of glycoproteins or glycolipids (N-glycan, O-glycan, proteoglycans and others). Carbohydrate chains are known to be expressed on brain, nerve, cancer, and endothelial cells. Some carbohydrate chains are known to relate to diseases (e.g., cancer, Alzheimer's disease, Guillain-Barré syndrome, Lysosome syndrome such as Fabry disease, gangliosidosis), differentiation and development (iPS/ES cells). Antibodies are proteins which are one of the components of the immune system. The specificity of antibodies is likened to the interaction between a key and a keyhole. Antibodies are useful reagents for research in many scientific disciplines including life science and diagnostic reagents. Anti-carbohydrate antibodies can recognize glycolipids or glycoproteins. TCI mainly produces antibodies against glycolipids; ganglio series, globo series, lacto series, and neo-lacto series. These antibodies can be used for immunohistochemistry, cell-staining, inhibition assay for cell adhesion, flow cytometry, ELISA, TLC-immunostaining and other methods. TCI antibodies are very useful tools for analyzing the expression of carbohydrate chains and their functions. Labeled anti-carbohydrate chain antibodies will also be available soon.

糖鎖は，生命第3の鎖としてその生物機能が重要視され，ポストゲノム研究の一端を担う領域として注目されています。 TCIでは，ポストゲノム時代の糖鎖研究に有用な抗糖鎖抗体でお客様の研究をサポート致します。多くの糖鎖は，脂質やタンパク質などに結合し，糖脂質あるいは糖タンパク質（N型，O型，プロテオグリカンなど）として存在しています。糖鎖は，脳，神経，癌細胞，血管内皮細胞などに存在することが知られており，iPS/ES細胞，癌，アルツハイマー，ギランバレー症候群，ファブリー病やガングリオシドーシスなどのリソソーム病などの疾患，発生，分化などで重要な役割を担うと考えられ，その重要性が注目されています。抗体は，免疫系を構成するタンパク質で，対応する抗原と鍵と鍵穴の関係のように高い特異性で結合します。抗体は，その高い特異性から生命科学の研究や診断薬の検出系として活用されています。抗糖鎖抗体は，糖脂質，糖タンパク質などの糖鎖を特異的に認識できる抗体です。東京化成工業では，抗糖鎖抗体の中でもガングリオ系，グロボ系，ラクト系，ネオラクト系などの糖脂質に関連する抗体を中心に品揃えしています。東京化成工業の抗糖鎖抗体は，細胞，組織，生体試料での糖鎖（抗原）の局在，疾患や発生，分化過程での糖鎖の変化などを調べるツールとして有用で，組織染色，細胞染色，細胞接着阻害研究，フローサイトメトリー，ELISA，TLC免疫染色などの幅広い用途でご使用いただけます。また，各種標識した抗糖鎖抗体の製品化も予定しています。

ELISA, Cell ELISA

Western blotting TLC-immunostaining



121

Anti-Glyco Antibodies-① New

A2506 Anti-Gb3 Monoclonal Antibody

Price on request

New

A2586 Anti-Gb3 Monoclonal Antibody

Price on request

New

A2507 Anti-GD1a Monoclonal Antibody

1vial

New

A2508 Anti-GD1b Monoclonal Antibody

1vial

New

A2580 Anti-GD3 Monoclonal Antibody

Price on request

New

A2579 Anti-GD3 Monoclonal Antibody

Price on request

New

A2505 Anti-GM1 Monoclonal Antibody

122

(Culture Supernatant)




1vial

Anti-Glyco Antibodies-② New


Price on request

New


Price on request

New


Price on request

New


Price on request

New

A2578 Anti-Lewis X Monoclonal Antibody

Price on request

New

A2577 Anti-Lewis X Monoclonal Antibody

Price on request

New

A2510 Anti-Lewis Y Monoclonal Antibody




Price on request



123

Anti-Glyco Antibodies-③ New

A2587 Anti-Lewis Y Monoclonal Antibody

New

A2509 Anti-Sialyl Lewis A Monoclonal Antibody (2D3)

1vial

New

A2584 Anti-Sialyl Lewis A Monoclonal Antibody (1H4)

Price on request

New

A2583 Anti-Sialyl Lewis A Monoclonal Antibody (1H4)

Price on request

Price on request



124



Secondary Antibodies New

G0406 Goat Anti-Mouse IgG FITC Conjugate

Price on request

New

G0407 Goat Anti-Mouse IgG HRP Conjugate

Price on request

New

G0408 Goat Anti-Mouse IgM

Price on request

New

G0417 Goat Anti-Mouse IgM HRP Conjugate

Price on request

New

G0418 Goat Anti-Rabbit IgG HRP Conjugate

Price on request



125

126

NMR Data

183 main Glyco products among our glycochemistry-related products show 1H NMR spectrum. 弊社糖鎖関連試薬のうち，主な製品183品の1H NMRスペクトルデータを掲載しています。

127

Layout of the Index ／凡例

NMR Data Index NH

OAc O

AcO

O C CCl3

M1637

211 Ph

O O HO

3

T2695

136

Arabinose

1

O O

Page 掲載ページ Product Number 製品コード 3 Structural Formula 構造式 2

M1626 138

137 CH3

Fucose

SCH3 OAc

O

AcO

M1620 140

1

OCH3

N3

OAc

139

2

Ph

OAc

O

O

O

OCH3

OH

O

O

O

O O

OCH3

HO

M1725 144

M1710 145

O

OCH3

M1634 147

M1633

O CH3

O

O

OH

HO

HO

O HO

O

O

OCH3

HO

OCH3

O

HO

O

OCH3

OBn

CH3

OBn O

O

O

OCH3

OBn

CH3

O

M1481 149

O

CH3

OBn O

O

OCH3

148

O HO

CH3

M1597 146

Ph OH O

OH O

O

OCH3

O

O

M1482

O O

O O

OBn

HO

OBn

M1590 142

O

O O

BnO

SCH3 OBn

O

BnO

M1589 141

Ph

O

Galactosamine

HO

CH3

Ph

Galactose &

143

M1628

M1596 150

M1593 151

M1594 152

M1477

O

OH

O

CH3

OH O

CH3

HO

O

OCH3

HO

CH3

O

O

O O

O

OCH3

O

BnO

M1588 154 BnO

OBn O O

OCH3

OBn

O

CH3

O

O

M1933 156 HO

OBn

HO

OCH3

O

BzO

OCH3

OBn

OBz O BzO

P1680 160

OCH3

OCH3

AcO

OBn O

BnO

OAc O

O

SPh

SPh

OBn OBn O BnO SPh OAc

T2295 161

A2627 164

HO HO

O

O AcHN

N3

O

AcO

NH

HO O

HO

O O

O N3

OCH3

SPh OAc

A1832 O O

HO N3 O

O N3 O

OC(CH3)3 HN

AcO


128

OAc O

AcO

O

P1643 166

O

P1477

AcO

O

HO

AcO SPh NH C OCH2CCl3

OCH3

Ph

O C CCl3

OH O

O OAc

A1833 162

O

M1643 165 Ph

OH O

OAc O

AcO

OAc

OBn

163

AcO

AcO

P2078 157

Ph

BnO

OAc O

O

OH

M1592 155

P1679 159

158

O OH

O

BnO

O

O

CH3

CH3

O

153

O

CH3

AcO

CH3

OH

O

CH3

O

CH3

OC(CH3)3 HN

Fmoc

Fmoc

P1642 167

T1731 AcO


OAc O

AcO N3

OAc

A2253 169

168

Glucose &

OH O

HO HO

Glucosamine

OH O

HO HO

O O P

HO

O

ONa ONa

OAc O

AcO AcO

O

OCH3

OAc

M2434 174

OBn O

HO BnO

Ph

OBz

O

OAc O O

OCH3

OAc

OH O

BzO BzO

BzO

OH O

OAc O

AcO AcO

AcO AcO

O O

OAc

P O

O O

(CH3CH2)3NH

(CH2)18CH3

AcO AcO

OAc O

P O

O O

O

OBn O

BnO BnO

O

O

OBn O

OAc

O P N(CH3)2

O

O

S CH2

O

NHAc

CF3

N(CH3)2

A1614 203

202

HO HO

OH O AcHN

H N

COOH O

NHBoc

AcO AcO

A1616 204 OAc O AcHN

N3

BnO

Ph

O

BnO BnO

N3

AcHN

N3

NH

OAc

F

O C CCl3

T1923 OBn O

BnO BnO

F BnO

F

O O BnO

Ph

O NHAc

BnO BnO

OAc O

A1813 201

A1678 205 OBn O

T2491

AcO AcO

OBn O

BnO BnO

O

SPh

T1922 196

A1812 200

O

O HO

OAc O

CF3

S CH2

P1475 O O HO

(CH2)16CH3

(CH2)18CH3

AcO

CF3

N

SCH3

T1995 191

AcO AcO

OBz O

Ph CF3

N

O O

T1991 195

BzO

OH

OAc O

O

OAc O

OCH3

M1682

AcO AcO

Ph

O

P O ONa

OAc

BzO BzO

O HO

AcO

O O

NO2

O

OH O

HO HO

A2638 186

HO

T1999 199

BnO

OAc AcO

T2449 190

(CH3CH2)3NH

T2197 198

BnO

(CH2)16CH3

OCH3

COOCH3 O

OAc O

OBn

M1631

M1868 181

AcO AcO

HO HO

AcO

SPh

O O

O

COOH O

OH O

BnO BnO

BnO

OH O

HO BnO

N0857 185

P2080 194

OAc

O

197 BnO BnO

(CH2)16CH3

SPh

OAc

O O

COOCH3 O

OCH3

O

P2079 193 OAc O

HO HO

OBn

B4171

M1641 176

M1759 180

AcO AcO

OAc O

AcO

192

OBn

OH

P1736 189

AcO

SPh

OCH3

OH

HO

BnO

OCH3

O

OAc

P1476 188

187

O

M1488 184

BnO BnO

O O BnO

N3

O

M1642 179

AcO BnO

B4170 171

M1640 175

O O BnO

OCH3

M1487 183

182

O OAc

OCH3

M1630 178

177

AcO AcO

HO

Ph

OAc O

Ac

G0339 173

172

A2377 170

N3

A1811 O O HO

NHAc

A1685 206 OBn O AcHN

H N

COOBn O

NHBoc

O

HO HO

N3

A2172 OH O O AcHN

N3


129

G0297 208

207

M1638 209 Ph

O HN

OH O

HO HO

H

H N

AcHN

NH

Ph O

H

O

O

O

O

O

O

O

OCH3

O N

O

O

OBn O

HO BnO

Ph

OBn O O

M1609 214

O O BnO

Ph

O N

O

OAc O

AcO AcO O

SCH3

N

O

O

N

O

O

O

SPh Bn

N

AcO AcO

OH

I0630 227

226

OH HO HO

HO HO

OH OH OH

OH

HO

Mannosamine OH

M1501 236

AcO AcO

AcO AcO

RO

OR O F

R=

C C(CH3)3

OH

OH

AcO AcO

OH O

HO HO

AcO

AcO AcO

AcO F

O

AcO AcO

R0083 O

NaO P O ONa

O OAc

R0082 243

O

NaO P O O OH


T2307 SO2CF3

OAc O

242

OAc

OCH3

T2567 239

C C(CH3)3

Ribose

OAc O O

OCH3

AcO OR

M1647

AcO AcO

O

OR O

OH

OH

O

N3 O

Q0071

M1646 234

HO HO

OH OH

HO OH

NH2

O

OAc

HO

OH

HO

HO

T1733 AcO

O

O

OH

OH

P1803 238

RO RO

O

I0628

Q0070 230

OH

O

H N O

R=

T2568 241

240

AcO

OAc N

O

HO

HO

HO O

OAc O

AcO AcO

HO

P1514 237

AcO SCH3

RO RO

HO

HO HO

OCH3

O

T2047

HO HO OH

M2435 233

RO

OAc O

OH

OH

OH

235 AcO

HO

232

Mannose &

HO HO OH

HO

O N

I0633 225

HO

Q0069

231

O

OAc O

AcO AcO

OAc

I0634 229

HO HO HO

OAc O

OCH3

M1480

T2196 221

OH

I0631 228

O

O

HO

OH

O N3

N3

HO HO

OH

OCH3

I0632 224 HO

O O HO

O

AcO AcO

N3 OAc

HO HO OH HO

O N

T1732 220

I0629 223

222

OBn O O

OAc O

M1637

M1615 216

HO BnO

O

O

Inositol

OCH3

O

P1762 219

Ph

O

O

O

M1649 218

217

OCH3

M1479 215

O O HO

OCH3

O

OCH3

Ph

O NH2

M1617 213

N3

130

M1616 211

O

212

HO BnO

O

OCH3

N3

S

M1598 210

O O P ONa OH ONa

ONa

O P ONa O OH

ONa OH

A2511 245

244 OH

H2N

Sialic Acids

O

OH

HO

SPh

HO HN

HO

OAc

SPh

O

COOCH3

O

O

D4215 253

O

O HO

AcHN

AcO

O

HO HO

M1686 258

257

O

OAc O

AcO

A2630

Disaccharides

OH O

HO

O HO

BnO

OBn O

G0309 256 AcO

O

OAc

AcO

O

O O

O

O

O

HO

OBn O

O OBn BnO

O

OCH3

OBn

HO

O

OAc Ph O O

HO

OBn O

O OBn BnO

O

OCH3

OBn

HO

HO

OH O

HO

O HO

O

HO

OH O

OH O

O O N

O

O

HO

OH O

OH O

O AcHN

HO

NO2

AcHN

OCH3

O

G0340

HO

O HO

NO2

O

G0344 261

HO

AcHN

O

OAc

OCH3

N3

G0375 260 OH O

OH

G0311

AcO

O

OAc

OCH3

N3

OAc

Ph

AcO

M1727 259

OBn O

O

HO HO

HO

HO HO

COOCH3

AcO

251

COOCH3

O

OH

AcHN

SPh O

HO

Ph

O

OH

AcHN

COOCH3

G0330 255

OH

O

AcO AcHN

AcO

OH

CH3

OH O

OH

F0897 254

HO OH O

HO HO

AcO AcHN

OAc

HO

OAc

O

252

O

M1706

AcO

OH

A1822

AcO

O

OH

HO AcHN

HO

AcO HN

A1821 247

HO COOH

O

M2330 250

AcO

COOCH3

O

OH

HO AcHN

COOH

M2329 249

248

OH

F

OH

HO AcHN

A2492 246

O

O OH

CH3 NH2

G0420 263

262 HO

OH O HO

HO

HO

OH O O

O

NO2

AcHN

HO

G0373 264

OH O HO

HO

O

O

AcHN

AcHN

G0341 268

267 HO

OH O

HO HO

AcHN

O

O

HO HO

OH

N0791 273

OH

COOH

HO AcHN

OH

O

O

OH O O OH

HO

OCH3

HO

OH

COOH

AcO

AcO HN

HO

O

N

O

OCH3

OBn

O

AcHN

BnO

AcO

O O OBz

OCH3

OAc

CH3OOC

O

O

O O

AcO

BzO

OCH3

OBz O

O

O OBz

O

NO2

AcHN

HO

OH O

HO HO

OH O

O AcHN

AcHN

M1733 271

OH OH O

HO

OH

O NHAc

OCH3

NO2

OH O

HO O NHAc

HO

O

M1776

OH OH O

OH O

OHO NHAc

COOH O

O NHAc

OCH3

M1761 276 OAc

AcO

O HO O

AcO

O BzO

O AcO

HO AcHN

COOCH3

AcO AcHN

OCH3

O

HO

OH O AcHN

CH3OOC

OBz OBz O O

O

O

HO HO

OH O

O

O CH3 HO

O OH

OH

O

O

O

O

HO

H N

CF3

OH O HO

OCH3

OBz

OAc

A2631 280

279

Trisaccharides

OAc

OCH3

OBz

NO2

N0846

AcO AcHN

O BnO

O

N0816

AcO HN

O HO

HO

HO

AcO

O BzO

OH O

N0890 275

HO

HO

COOCH3 O

AcO

OBn O

O

HO AcHN

O HO

O

M1763 278 OAc

AcO

BnO

N0792 274

HO AcHN

NO2

OH O

G0376

N3

OH

277

O

G0356 266

G0299 270

O

O

HO HO

O AcHN

OAc O

O

NH2

272

HO

OH O

AcHN

AcO AcO

AcHN HO

O

CH3

HO

OH O

O AcHN

N3

OH O HO

G0337 269

HO HO

OH O

HO

OH O

G0352 265

B4172

HO

OH O

O

O

O CH3 HO

O

O

O

O

O

H N

CF3 O

OH

OH


131

F0895 282

281 HO

HO

OH O

HO

OH O

HO

O

CH3

O

O

NO2 CH3

OH

OH

HO

OH O HO O O

HO

AcHN

O

F0894 283

O

G0343 284 OH O

HO HO

OH O O

HO

NO2

AcHN

HO

OH

OH

HO

G0347 287

OH

HO

HO OH O HO

HO

O

HO

O

O AcHN

HO

HO

HO AcHN

O HO

O

HO HO

O

O HO

AcHN

OH

AcHN

OH O HO

O HO HO

O HO

O

O HO

NO2

AcHN

HO

O NH2

HO

O HO

HO

OH O HO

HO

HO

O AcHN

OH O HO HO

O

O

AcHN

OH COOH

OH

OH O

O

O

OH O

OH O AcHN

O HO

OH O

HO

O

OH O

O AcHN

AcHN

O HO

OH O HO

C13H27

O

OH O

HO

O HO

OH O O

O

OH O

O AcHN

HO

O

OH COOH

HO AcHN

NO2

AcHN

OH O

O

O

HO

HO

OH O

O HO

O AcHN

HO

NO2

HO

AcHN

OH O

O HO

O HO

OH O AcHN

OH O

O HO

OH

AcHN

O

AcHN

NO2

O HO

O

OH O

OH O AcHN

N3

HO O

OH O

AcHN

HO

OH O

O HO

O

HO AcHN

G0372 HO

COONa O

OH O

O HO

HO

OH O

O HO

O AcHN HO

OH O

O HO

O

HO HO

NO2

HO

NO2

HO

O O

OH O

O HO

O HO

N3

AcHN

2

OH O OH

AcHN

D4217 308

OH

COOH O HO

O HO HO

Oligosaccharides OH HO AcHN

OH O

O HO

T2910

HO HO

HO

HO

HO NaO3SO

HO

HO

OH O

OH O

HO

O

G0351

HO

HO

NO2

OH O

NO2

T2912

G0354 304 OH O

OCH3

HO

N0854

OH

HO

OH O O

HO

OH O

HO HO O

307 O HO

HO

O HO HO

O HO

OH O AcHN HO HO HO

O HO

OH HO AcHN

COOH O HO

O HO HO

O

O HO

O O HO O

COOH O

D4065 HO


HO O

HO O



132

C15H31

OH

NO2

L0237 306

HO

O

O

HO

HO

AcHN

HO

305 HO

O

OH O

O HO

HO

HO

NO2

AcHN

OH O

O HO

HO

OH COOH

OH

N0860 299

HO AcHN

OH O

HO

OH O

HO

13

O HO

O AcHN

HO HO

HN

C

N0853 295

HO

G0380 303

302 OH O

O HO

13

G0348 301

HO

HO

HO

OH O

OH O

HO

O

OH O

O

O

HO AcHN

O

300

Tetrasaccharides

HO

HO

HO

OH

HO

O HO

O HO

O

HO AcHN

COOH

HO AcHN

OH O

C17H35 OH C13H27

HOOC

OH

HO

HO OH O

N0856 298

OH

HO

COOH

HO AcHN

O

CH3

N0855 297

296

OH

HO

M1767

O

O

HO HO

NO2

COOH

HO AcHN

O

O AcHN

G0419 290

G0378 294 OH

HO

O

AcHN

O O

HO

HO

OH O AcHN HO OH O O AcHN

HO HO

HN O

HO

HO

HO

NO2

NO2

AcHN

HO HO

O

OH O

O HO

HO

G0342 293

OH

O

CH3 OH O

O

O

HO OH O

OH

O

OH O

HO

HO

OH

HO

HOOC

O

G0423 292

291

HO

HO OH O

HO

NO2

NH2

O

HO

OH

HO

HO

O AcHN

O

O

HO

O HO

O

G0422 289

O

O

O

HO

HO

AcHN

COOH

HO AcHN

COOH

HO AcHN

O

O

HO OH O

G0345

OH

HO

O

O

HO

O

G0353 288

OH

HO

COOH

HO AcHN

COOH

HO AcHN

CH3

286

OH

HO

O AcHN HO OH O O HO

G0377 285

O

N3

HO

OH HO AcHN

O HO

OH O AcHN HO HO HO

HO

O HO HO

O O HO O

COOH O

O

O HO


O O

HO O

HO O

NHAc O OH

OH

F0584 310

309 OH

OH O

HO OH

HO AcHN

OH

OH O

O

OH O HO

HO

OH O

HO

HO O

OH O

HO

HO

OH O

O

O AcHN

G0355 311

HO

AcHN

HO

O O OH

HO HO HO

HO

COONa O

OH O O HO

O HO

HO

HO

OH O

OH O

O AcHN

HO

OH HO AcHN

HO

HO O


N3

O HO

O HO

O HO

O HO

OH O AcHN HO HO HO

HO

O NH2 Lys

O O

OH HO AcHN

HO

HO

O HO

OH O

13C

13C

HN O

15H31

C13H27

HO

OH

P2027

O HO

OH O AcHN

OH O

HO HO

OH

AcHN

OH O

O HO

OH O

O HO

AcHN

3

OH

AcHN

S0849 317

S0910

COONa

HO

HO

O

O

HO O

S0523 316

315 HO

O HO

O

O

OH O

HOOC

HO AcHN

NO2

O AcHN

M2439 314 O HO O

OH O

O HO

OH O

O HO OH

HO

OH O

O HO

HO O O HO HO

HO NaO3SO

OH O HO

H1333 313

312

O

HO

OCH3

HO

OH O

HO

O

HO HO O

HO

OH O

G0421

HO O

COONa O HO

O HO HO

O HO


O

HO O

HO O

OH O

NHAc O O HO AcHN OH

Val Ala Asn Lys

OH HO AcHN

HOOC O HO

HO

OH O

O

O HO CH3 HO

Thr COOH

O

OH O O

HO

OH O

O AcHN

HO

OH O HO

OH

HO OH

OH

OH

HO AcHN

HOOC HO O

HO

O

OH O HO

O HO

OH HO O O

AcHN

OH O HO

O HO

OH O HO

O O

HN

C17H35 C13H27 OH

O

H1144

318

Others

O HO

HO HO

OH NH HO

OH


133

134

Layout of the Sheet ／凡例 3 5

M1628 Methyl 2,3,4-Tri-O-benzyl-1-thio-Ǫ-L-fucopyranoside

1

C28H32O4S = 464.62 [107802-80-2] CH3

Solvent : CDCl3 Internal Standard : Si(CH3)4 Measured Temperature : 22.4 ℃

2

BnO

O

SCH3 OBn

6

OBn

4

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

1 2 3 PPM 5. 0

4. 0

本データの無断転用はご遠慮下さい。こちらのデータは弊社のホームページでも公開しています。


4 5 6

1H‐NMR 1

Chemical Name Molecular Formula Molecular Weight CAS Registry Number Product Number Structural Formula

製品名分子式分子量 CAS番号製品コード構造式

Spectra were recorded on a JEOL JNM‐ECX 400 spectrometer.

H‐NMRスペクトルは、日本電子社製JNM‐ECX 400型で測定しました。


135

T2695 2,3,4-Tri-O -acetyl-β-L-arabinopyranosyl 2,2,2-Trichloroacetimidate C13H16Cl3NO8 = 420.62 [869848-87-3] AcO

NH

OAc O


O C CCl3 OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

M1626 Methyl 2,3,4-Tri-O-acetyl-1-thio-β-L-fucopyranoside C13H20O7S = 320.36 [84635-54-1] CH3


O

AcO

SCH3 OAc

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

Please refrain from the conversion of these data without permission. These data have been released on our homepage.


M1628 Methyl 2,3,4-Tri-O-benzyl-1-thio-β-L-fucopyranoside C28H32O4S = 464.62 [107802-80-2] CH3


BnO

O

SCH3 OBn

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1620 4-Methoxyphenyl 3-O-Allyl-2-O-benzyl-4,6-O-benzylideneβ-D-galactopyranoside Ph C30H32O7 = 504.58

O O


O O

O

OCH3

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



M1589 4-Methoxyphenyl 3-O-Allyl-4,6-O-benzylidene-β-D-galactopyranoside Ph

C23H26O7 = 414.45 [400091-05-6]

O O


O O

O

OCH3

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

M1590 4-Methoxyphenyl 3-O-Allyl-4,6-O-benzylidene-2-O-(4-methylPh benzoyl)-β-D-galactopyranoside O

C31H32O8 = 532.59

O O


O

O

OCH3

O CH3 O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



M1482 4-Methoxyphenyl 3-O-Allyl-β-D-galactopyranoside C16H22O7 = 326.35 [144985-19-3]

OH

Solvent : CD3OD Internal Standard : Si(CH3)4 Measured Temperature : 19.9 ℃

OH O

O

O

OCH3

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

M1725 4-Methoxyphenyl 3-O-Benzyl-β-D-galactopyranoside C20H24O7 = 376.41 [383905-60-0]

HO


OH O

BnO

O

OCH3

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1710 4-Methoxyphenyl 4,6-O-Benzylidene-β-D-galactopyranoside Ph

C20H22O7 = 374.39 [176299-96-0]

O O


O HO

O

OCH3

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



3. 0

M1597 4-Methoxyphenyl 2,6-Bis-O-(4-methylbenzoyl)-β-D-galactopyranoside O CH3

C29H30O9 = 522.55

OH

O O

Solvent : CD3OD/CDCl3 = 1/1 Internal Standard : Si(CH3)4 Measured Temperature : 21.8 ℃

HO

O

OCH3

O CH3 O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1634 4-Methoxyphenyl 2,6-Di-O-benzyl-β-D-galactopyranoside C27H30O7 = 466.53 [159922-50-6]

HO


OBn O

HO

O

OCH3

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1633 4-Methoxyphenyl 2,6-Di-O-benzyl-3,4-O-isopropylideneβ-D-galactopyranoside C30H34O7 = 506.60 [159922-68-6]

CH3 CH3


O

OBn O

O

O

OCH3

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1481 4-Methoxyphenyl β-D-galactopyranoside C13H18O7 = 286.28 [3150-20-7]

OH


OH O

HO

O

OCH3

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1596 4-Methoxyphenyl 3,4-O-Isopropylidene-2,6-bisO-(4-methylbenzoyl)-β-D-galactopyranoside

O

C32H34O9 = 562.62

O

CH3 CH3 CH3


O

O O

O

OCH3

O CH3 O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0



M1593 4-Methoxyphenyl 3,4-O-Isopropylidene-β-D-galactopyranoside C16H22O7 = 326.35

[159922-67-5] CH3


CH3

O

OH O

O

O

OCH3

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1594 4-Methoxyphenyl 3,4-O-Isopropylidene-6-O-(4-methylbenzoyl)β-D-galactopyranoside O

C24H28O8 = 444.48

CH3 CH3


O

O O

CH3

O

O

OCH3

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



M1477 4-Methoxyphenyl 2,3,4,6-Tetra-O-acetyl-β-D-galactopyranoside C21H26O11 = 454.43 [2872-65-3]

AcO


OAc O

AcO

O

OCH3

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1588 4-Methoxyphenyl 2,3,4,6-Tetra-O-benzyl-β-D-galactopyranoside C41H42O7 = 646.78 [143536-99-6]

BnO


OBn O

BnO

O

OCH3

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1592 4-Methoxyphenyl 2,4,6-Tri-O-benzyl-β-D-galactopyranoside C34H36O7 = 556.66 [247027-79-8]

OBn

BnO

O


HO

O

OCH3

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1933 Methyl 2,3,6-Tri-O-benzoyl-α-D-galactopyranoside HO

C28H26O9 = 506.51 [3601-36-3]

OBz O

BzO


BzO

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



P2078 Phenyl 2-O -Acetyl-3,4,6-tri-O -benzyl1-thio-β-D-galactopyranoside OBn OBn O BnO SPh OAc

C35H36O6S = 584.73 [183875-28-7] Solvent : CDCl3 Internal Standard : Si(CH3)4 Measured Temperature : 27.6 ℃

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P1477 Phenyl 2,3,4,6-Tetra-O-acetyl-1-thio-β-D-galactopyranoside C20H24O9S = 440.46 [24404-53-3]

AcO


OAc O

AcO

SPh OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P1679 Phenyl 2,3,4,6-Tetra-O-benzyl-1-thio-β-D-galactopyranoside C40H40O5S = 632.82 [74801-29-9]

BnO


OBn O

BnO

SPh OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P1680 Phenyl 2,4,6-Tri-O-acetyl-3-O-allyl-1-thio-β-D-galactopyranoside AcO

C21H26O8S = 438.49 Solvent : CDCl3 Internal Standard : Si(CH3)4 Measured Temperature : 22.6 ℃

OAc O

O

SPh OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



T2295 2,3,4,6-Tetra-O -acetyl-α-D-galactopyranosyl 2,2,2-Trichloroacetimidate AcO

C16H20Cl3NO10 = 492.68 [86520-63-0]

OAc O

AcO


AcO

NH O C CCl3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

A1833 O-(2-Azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-serine tert-Butyl Ester Ph

C35H38N4O9 = 658.71 [878483-02-4]

O O O


O

HO N3 O

OC(CH3)3 HN

Fmoc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0

3. 0



A1832 O-(2-Azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-threonine tert-Butyl Ester Ph

O

C36H40N4O9 = 672.74 [195976-07-9]

O O HO


N3 O CH3

O OC(CH3)3

HN

Fmoc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



3. 0

A2627 2-Azidoethyl 2-Acetamido-2-deoxyβ-D-galactopyranoside HO

C10H18N4O6 = 290.28 [142072-15-9]

OH O

HO

Solvent : D2O

O AcHN

N3

Measured Temperature : 20.9 ℃

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



M1643 4-Methoxyphenyl 3-O-Allyl-2-azido-4,6-O-benzylidene-2-deoxyβ-D-galactopyranoside Ph O

C23H25N3O6 = 439.47 [889453-83-2]

O O


O

O

OCH3

N3

PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

P1643 Phenyl 2-Deoxy-1-thio-2-(2,2,2-trichloroethoxyformamido)β-D-galactopyranoside HO

C15H18Cl3NO6S = 446.72 [868230-98-2]

HO


OH O SPh NH C OCH2CCl 3 O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P1642 Phenyl 3,4,6-Tri-O-acetyl-2-deoxy-1-thio2-(2,2,2-trichloroethoxyformamido)-β-D-galactopyranoside AcO

C21H24Cl3NO9S = 572.83 [278784-83-1]

AcO


OAc O SPh NH C OCH2CCl 3 O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



T1731 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-α-D-galactopyranose C14H19N3O9 = 373.32 [67817-30-5]

AcO


OAc O

AcO N3

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



A2253 2-Acetyl-5-methoxyphenyl β-D-Glucopyranoside C15H20O8 = 328.32 [20309-70-0]

HO HO

Solvent : CD3OD Measured Temperature : 24.1 ℃

OH O

Ac O

HO

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



A2377 2-Azidoethyl 2,3,4,6-Tetra-O -acetyl-β-D-glucopyranoside C16H23N3O10 = 417.37 [140428-81-5]

AcO AcO

OAc O O


OAc

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



B4170 Benzyl 2,3-Di-O -benzyl-4,6-O -benzylideneβ-D-glucopyranoside Ph

C34H34O6 = 538.64 [183953-29-9]

O O BnO

O OBn OBn


PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



3. 0

B4171 Benzyl 2,3,4-Tri-O -benzyl-β-D-glucopyranoside C34H36O6 = 540.66 [27851-29-2]

BnO BnO


OH O OBn BnO

PPM 9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0339 β-D-Glucopyranose 1-Phosphate Disodium Salt C6H11Na2O9P = 304.10 [83833-15-2] HO HO

Solvent : D2O

OH O

O O P

HO

ONa ONa


PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



3. 0

M2434 4-Methoxyphenyl 2-O -Benzoyl3,6-di-O -benzyl-β-D-glucopyranoside C34H34O8 = 570.64 [1393898-89-9]

HO BnO

OBn O O

OCH3

OBz


PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1640 4-Methoxyphenyl 3-O-Benzyl-4,6-O-benzylidene-β-D-glucopyranoside Ph

C27H28O7 = 464.51 [303127-81-3]

O O BnO

O O

Solvent : DMSO-d6 Internal Standard : Si(CH3)4 Measured Temperature : 21.1 ℃

OCH3

OH

PPM . 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



M1641 4-Methoxyphenyl 3-O-Benzyl-β-D-glucopyranoside C20H24O7 = 376.41 [303127-80-2]

HO BnO

Solvent : DMSO-d6 Internal Standard : Si(CH3)4 Measured Temperature : 22.7 ℃

OH O O

OCH3

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



M1631 4-Methoxyphenyl β-D-Glucopyranoside C13H18O7 = 286.28 [6032-32-2] HO HO


OH O O

OCH3

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1630 4-Methoxyphenyl 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranoside C21H26O11 = 454.43 [14581-81-8] AcO AcO


OAc O O

OCH3

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1642 4-Methoxyphenyl 2,4,6-Tri-O-acetyl-3-O-benzyl-β-D-glucopyranoside C26H30O10 = 502.52 [303127-79-9]

AcO BnO

OAc O O

OCH3

OAc


PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1759 Methyl (Phenyl 2,3,4-Tri-O-acetyl-1-thio-β-D-glucopyranosid)uronate C19H22O9S = 426.44 [62812-42-4] AcO AcO


COOCH3 O SPh OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1868 Methyl 1,2,3,4-Tetra-O-acetyl-β-D-glucuronate C15H20O11 = 376.31 [7355-18-2]

AcO AcO


COOCH3 O OAc AcO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0



4. 0

M1682 Methyl 2,3,4,6-Tetra-O-acetyl-1-thio-β-D-glucopyranoside C15H22O9S = 378.39 [13350-45-3]

OAc O

AcO AcO


SCH3 AcO

PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1487 Methyl 2,3,4-Tri-O-benzoyl-α-D-glucopyranoside C28H26O9 = 506.51 [34234-44-1] BzO BzO


OH O BzO

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



3. 0

M1488 Methyl 2,3,4-Tri-O-benzyl-α-D-glucopyranoside C28H32O6 = 464.56 [53008-65-4] BnO BnO


OH O BnO

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



N0857 4-Nitrophenyl α-D-Glucuronide C12H13NO9 = 315.23 [71484-85-0] HO HO

Solvent : D2O External Standard : t-BuOH (δ 1.23) Measured Temperature : 22.9 ℃

COOH O HO

O

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 5

5. 0

4. 5

4. 0



3. 5

3. 0

A2638 6-OAc PtdGlc(di-acyl Chain) C49H92NaO14P = 959.22 [1065483-61-5]

HO HO

OAc O

O O

Solvent : CDCl3/CD3OD = 1/1 Internal Standard : Si(CH3)4 Measured Temperature : 26.6 ℃

HO

O

P

O ONa

O O

(CH2)16CH3

(CH2)18CH3 O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P1475 Phenyl 4,6-O-Benzylidene-1-thio-β-D-glucopyranoside C19H20O5S = 360.42 [87508-17-6] Ph


O O HO

O SPh HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0



P1476 Phenyl 2,3,4,6-Tetra-O-acetyl-1-thio-β-D-glucopyranoside C20H24O9S = 440.46 [23661-28-1] Solvent : CDCl3 Internal Standard : Si(CH3)4 Measured Temperature : 19.8 ℃

AcO AcO

OAc O SPh AcO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P1736 Phenyl 2,4,6-Tri-O -acetyl-3-O -allyl-1-thio-β-D-glucopyranoside C21H26O8S = 438.49 [197005-22-4]

AcO


OAc O O

SPh OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

T2449 1,2,4,6-Tetra-O -acetyl-3-O -allyl-β-D-glucopyranose C17H24O10 = 388.37 [39698-00-5]

AcO


OAc O O

OAc OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



T1995

2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Fluoride C14H19FO9 = 350.30 [3934-29-0] AcO AcO


OAc O AcO

F

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

T2491 2,3,4,6-Tetra-O -acetyl-β-D-glucopyranosyl 2,2,2-Trichloroacetimidate C16H20Cl3NO10 = 492.68 [92052-29-4]

AcO AcO


OAc O OAc

NH O C CCl3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



P2079 2,3,4,6-Tetra-O -acetyl-PtdGlc(di-acyl Chain) C61H114NO17P = 1164.55 [1037195-49-5]

AcO AcO

OAc O

O O

OAc


P O

O O

O O

(CH3CH2)3NH

(CH2)16CH3

(CH2)18CH3 O

PPM 12 .0

11 .0

10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P2080 2,3,4,6-Tetra-O -acetyl-PtdGlc(mono-acyl Chain) C41H76NO16P = 870.02

AcO AcO


OAc O

O O

OAc

P O

O O

O

(CH2)16CH3

OH

(CH3CH2)3NH

PPM 12 .0

11 .0

10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



T1991 2,3,4,6-Tetra-O-benzoyl-α-D-glucopyranosyl p-Trifluoromethylbenzylthio-N-(p-trifluoromethylphenyl)formimidate OBz O

C50H37F6NO10S = 957.89 [428816-48-2] BzO BzO


BzO

N

CF3

O S CH2

CF3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 7. 0

6. 0

5. 0



4. 0

T1922 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl Fluoride C34H35FO5 = 542.65 [89025-46-7] BnO BnO


OBn O BnO

F

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



T1923 2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl Fluoride C34H35FO5 = 542.65 [78153-79-4] BnO BnO


OBn O F BnO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



T2197 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl N,N,N',N'-Tetramethylphosphorodiamidate (ca. 20% in Benzene) C38H47N2O7P = 674.77 [143520-19-8]

BnO BnO


OBn O BnO

O O P N(CH3)2 N(CH3)2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



T1999 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl p-Trifluoromethylbenzylthio-N-(p-trifluoromethylphenyl)formimidate C50H45F6NO6S = 901.96 [468095-63-8] BnO BnO


OBn O BnO

N

CF3

O S CH2

CF3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



A1812 2-Acetamido-3-O-allyl-4,6-O-benzylidene2-deoxy-β-D-glucopyranosyl Azide C18H22N4O5 = 374.40 Ph


O O

O

O

N3 NHAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0

3. 0



A1813 2-Acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxyβ-D-glucopyranosyl Azide C22H24N4O5 = 424.46 [80887-27-0] Ph


O O BnO

O N3 NHAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



A1811 2-Acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl Azide C15H18N4O5 = 334.33 [168397-51-1] Ph


O O HO

O N3 NHAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



A1614 Nω-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)-Nα-(tert-butoxycarbonyl)-L-asparagine C17H29N3O10 = 435.43 [137255-40-4] HO HO


OH O

H N

AcHN

COOH O

NHBoc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



3. 0

A1616 2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl Azide C14H20N4O8 = 372.33 [6205-69-2] Solvent : CDCl3 Internal Standard : Si(CH3)4 Measured Temperature : 21.2 ℃

OAc O

AcO AcO

N3 AcHN

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



A1678 2-Acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl Azide C29H32N4O5 = 516.60 [214467-60-4] BnO BnO


OBn O N3 AcHN

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



A1685 Nω-(2-Acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)Nα-(tert-butoxycarbonyl)-L-asparagine Benzyl Ester C45H53N3O10 = 795.93 [219968-28-2] BnO BnO


OBn O AcHN

H N

COOBn O

NHBoc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0

3. 0



A2172 2-Azidoethyl 2-Acetamido-2-deoxy-β-D-glucopyranoside C10H18N4O6 = 290.28 [142072-12-6] HO HO

Solvent : D2O Internal Standard : t-BuOH (δ 1.23) Measured Temperature : 23.2 ℃

OH O O AcHN

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



G0297 N-GlcNAc-Biotin O

C18H30N4O7S = 446.52 [1272755-69-7] HO HO

Solvent : DMSO-d6

OH O

HN

NH

H

H N

H S

AcHN O


PPM . 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0

2. 0

1. 0



M1638 4-Methoxyphenyl 3-O-Allyl-2-azido-4,6-O-benzylidene-2-deoxyβ-D-glucopyranoside C23H25N3O6 = 439.47 [889453-78-5]

Ph

O O


O

O

O

OCH3

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

M1598 4-Methoxyphenyl 3-O-Allyl-4,6-O-benzylidene-2-deoxy-2-phthalimidoβ-D-glucopyranoside Ph

C31H29NO8 = 543.57 [889453-84-3]

O O

O

O

O O


N

OCH3

O

PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1616 4-Methoxyphenyl 2-Amino-3,6-di-O-benzyl-2-deoxyβ-D-glucopyranoside C27H31NO6 = 465.55 [1272755-07-3] HO BnO


OBn O O

OCH3

NH2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



3. 0

M1637 4-Methoxyphenyl 2-Azido-4,6-O-benzylidene-2-deoxyβ-D-glucopyranoside C20H21N3O6 = 399.40

Ph

O O HO


O O

OCH3

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1617 4-Methoxyphenyl 2-Azido-3,6-di-O -benzyl-2-deoxyβ-D-glucopyranoside C27H29N3O6 = 491.54 [1272755-25-5]

HO BnO


OBn O O

OCH3

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1609 4-Methoxyphenyl 3-O-Benzyl-4,6-O-benzylidene-2-deoxy2-phthalimido-β-D-glucopyranoside Ph

C35H31NO8 = 593.63 [129575-88-8]

O O BnO

O O O


N

OCH3

O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



M1479 4-Methoxyphenyl 4,6-O-Benzylidene-2-deoxy-2-phthalimidoβ-D-glucopyranoside Ph

C28H25NO8 = 503.51 [138906-43-1]

O O HO


O O O

N

OCH3

O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

M1615 4-Methoxyphenyl 3,6-Di-O-benzyl-2-deoxy-2-phthalimidoβ-D-glucopyranoside C35H33NO8 = 595.65 [129575-89-9]

OBn O

HO BnO

O O


N

OCH3

O

PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1480 4-Methoxyphenyl 3,4,6-Tri-O-acetyl-2-deoxy-2-phthalimidoβ-D-glucopyranoside OAc O

AcO AcO

C27H27NO11 = 541.51 [138906-41-9]

O O


N

OCH3

O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

M1649 Methyl 3,4,6-Tri-O-acetyl-2-deoxy-2-phthalimido-1-thioβ-D-glucopyranoside

OAc O

AcO AcO

C21H23NO9S = 465.47 [79528-48-6]

SCH3 O


N

O

PPM 9. 0

10 .0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



P1762 Phenyl N-Benzyl-2-amino-4,6-O-benzylidene-2-N,3-O-carbonyl2-deoxy-1-thio-β-D-glucopyranoside Ph

C27H25NO5S = 475.56 [910805-49-1]

O O


O

O N

SPh Bn

O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



3. 0

T1732 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-α-D-glucopyranose C14H19N3O9 = 373.32 [56883-33-1] AcO AcO


OAc O N3

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



T2196 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-β-D-glucopyranose C14H19N3O9 = 373.32 [80321-89-7] AcO AcO


OAc O OAc N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



T2047 1,3,4,6-Tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose OAc O

AcO AcO

C22H23NO11 = 477.42 [10022-13-6]

OAc N

O


O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 7. 0

6. 0

5. 0

4. 0



I0629 allo-Inositol HO HO OH

C6H12O6 = 180.16 [643-10-7] HO

OH


OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



3. 5

I0632 1D-chiro-Inositol C6H12O6 = 180.16 [643-12-9]

HO

OH

HO HO


OH

OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



I0633 1L-chiro-Inositol HO HO OH

C6H12O6 = 180.16 [551-72-4] HO


HO

OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



I0628 epi-Inositol C6H12O6 = 180.16 [488-58-4]

OH


HO

HO

OH OH

OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



I0630 muco-Inositol C6H12O6 = 180.16 [41546-34-3]

OH HO HO


HO HO

OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



I0631 scyllo-Inositol C6H12O6 = 180.16 [488-59-5]

HO HO HO


OH OH OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 3. 5

3. 0



I0634 1L-epi-2-Inosose C6H10O6 = 178.14 [33471-33-9]

O


HO

HO

OH OH

HO

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



Q0070 (+)-epi-Quercitol C6H12O5 = 164.16 [131435-06-8]

OH


HO

HO OH

HO

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0

2. 0



Q0071 (+)-proto-Quercitol C6H12O5 = 164.16 [488-73-3]

HO

OH

HO HO


OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0



2. 0

Q0069 (-)-vibo-Quercitol C6H12O5 = 164.16 [488-76-6]

HO HO OH


OH

OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0

2. 0



M2435 N ω-(β-D-Mannopyranosyl)-L-asparagine HO

C10H18N2O8 = 294.26 [41355-52-6]

HO HO

HO O

Solvent : D2O Internal Standard : Acetone (δ 2.22) Measured Temperature : 19.6 ℃

O

H N

OH O

NH2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



3. 0

M1646 4-Methoxyphenyl α-D-Mannopyranoside HO

C13H18O7 = 286.28 [28541-75-5]

HO HO


OH O

O

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1647 4-Methoxyphenyl 2,3,4,6-Tetra-O-acetyl-α-D-mannopyranoside AcO

C21H26O11 = 454.43 [17042-40-9]

AcO AcO


OAc O

O

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0



4. 0

M1501 Methyl 2,3,4,6-Tetra-O-acetyl-1-thio-α-D-mannopyranoside (contains ca.5% β-isomer) C15H22O9S = 378.39 [64550-71-6]

AcO AcO AcO


OAc O

SCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



P1514 1,2,3,4,6-Penta-O-acetyl-D-mannopyranose C16H22O11 = 390.34 [25941-03-1]

AcO


AcO O

AcO AcO

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

P1803 1,2,3,4,6-Penta-O-pivaloyl-D-mannopyranose RO C31H52O11 = 600.75 [220017-47-0]

RO RO


OR O OR O

R=

C C(CH 3 ) 3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



T2567 2,3,4,6-Tetra-O-acetyl-D-mannopyranosyl Fluoride C14H19FO9 = 350.30 [174511-17-2]

AcO Solvent : CDCl3 Internal Standard : Si(CH3)4 Measured Temperature : 20.9 ℃

AcO AcO

OAc O F

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0



4. 0

T2307 1,3,4,6-Tetra-O-acetyl-2-O-(trifluoromethanesulfonyl)β-D-mannopyranose SO2CF3

C15H19F3O12S = 480.36 [92051-23-5] AcO


O O

AcO AcO

OAc

PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



T2568 2,3,4,6-Tetra-O-pivaloyl-D-mannopyranosyl Fluoride RO C26H43FO9 = 518.62

RO RO


OR O F O

R=

C C(CH 3 ) 3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

T1733 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-α-D-mannopyranose C14H19N3O9 = 373.32 [68733-20-0]

AcO AcO AcO


N3 O

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



R0082 α-D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt O NaO P O

C5H8Na4O11P2 = 398.01 [113599-17-0]

ONa

Solvent : D2O

O OH


O O P ONa OH ONa

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



R0083 β-D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt O

O C5H8Na4O11P2 = 398.01

O P ONa

NaO P O ONa

Solvent : D2O Measured Temperature : 19.3 ℃

O OH

ONa OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



A2511 N -Acetyl-9-deoxy-9-aminoneuraminic Acid OH

H 2N

C11H20N2O8 = 308.29 [112037-47-5]

OH

HO AcHN

Solvent : D2O Internal Standard : t -BuOH (δ 1.23) Measured Temperature : 20.7 ℃

O

COOH

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0



2. 0

1. 0

A2492 N -Acetyl-9-deoxy-9-fluoroneuraminic Acid OH

F

C11H18FNO8 = 311.26 [85819-28-9]

OH

HO AcHN


COOH

O HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0



A1821 N-Acetylneuraminic Acid Methyl Ester C12H21NO9 = 323.30 [22900-11-4]

HO

OH

HO AcHN


OH O

COOCH3

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0



2. 0

M1706 Methyl 5-Acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-2-S-phenyl2-thio-D-glycero-D-galacto-2-nonulopyranosylonate C26H33NO12S = 583.61 [155155-64-9] AcO


OAc

AcO AcHN

SPh O

COOCH3

AcO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M2329 Methyl 5-N ,4-O -Carbonyl-3,5-dideoxy-2-S -phenyl-2-thioD-glycero -β-D-galacto -2-nonulopyranosylonate HO

C17H21NO8S = 399.41 [934591-79-4]

OH

SPh

HO HN


O

COOCH3

O O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



2. 0

M2330 Methyl 7,8,9-Tri-O -acetyl-5-N ,4-O -carbonyl-3,5-dideoxy-2-S -phenyl-2-thioD-glycero -β-D-galacto -2-nonulopyranosylonate AcO

C23H27NO11S = 525.53

OAc

SPh

AcO HN


COOCH3

O O

O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0

3. 0



A1822 4,7,8,9-Tetra-O-acetyl-N-acetylneuraminic Acid Methyl Ester C20H29NO13 = 491.45 [84380-10-9]

AcO


OAc

AcO AcHN

OH O

COOCH3

AcO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0



4. 0

A2630 Allolactose HO

C12H22O11 = 342.30 [28447-39-4]

OH O

HO


O HO

HO HO

O HO

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



D4215 N ,N '-Diacetylchitobiose C16H28N2O11 = 424.40 [35061-50-8] HO HO


OH O AcHN

O HO

OH O AcHN

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



F0897 Fucα(1-6)GlcNAc

HO CH3

C14H25NO10 = 367.35 [33639-80-4]

OH OH

O

O


HO HO

O AcHN

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0330 Gal[2346Ac]β(1-3)GalN3[46Bzd]-β-MP Ph

C34H39N3O15 = 729.69 AcO


OAc O

AcO

O

O O

O OAc

O

OCH3

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



3. 0

G0309 Gal[2346Ac]β(1-3)GlcN3[46Bzd]-β-MP AcO

C34H39N3O15 = 729.69

OAc O

Ph

AcO


O

O

O

O O

OCH3

N3

OAc

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0

3. 0



G0311 Gal[2346Ac]β(1-3)GlcNPhth[46Bzd]-β-MP AcO

C42H43NO17 = 833.80

OAc Ph O

AcO

O

O

O

OAc


O O O

N

OCH3

O

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1686 Gal[26Bn]β(1-4)Glc[236Bn]-β-MP HO

C54H58O12 = 899.05 [358681-61-5]

OBn O

HO


O OBn BnO

OBn O O

OCH3

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1727 Gal[246Bn]β(1-4)Glc[236Bn]-β-MP BnO

C61H64O12 = 989.17 [717132-49-5]

OBn O

HO


O OBn BnO

OBn O O

OCH3

OBn

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0375 Galβ(1-3)GalNAc-α-p NP HO

C20H28N2O13 = 504.45 [59837-14-8]

OH O

HO


HO

OH O

O HO

AcHN

O

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



G0344 Galβ(1-3)GalNAc-β-pNP C20H28N2O13 = 504.45 [59837-15-9]

HO

Solvent : D2O

OH O

HO

HO O

HO


OH O O

NO 2

AcHN

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0340 Galβ(1-3)GalNAc-α-Thr

HO

OH O

HO

C18H32N2O13 = 484.46 [60280-58-2]

HO

OH O

O AcHN

HO


O

O OH

CH3 NH2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0420 Galβ(1-3)GlcNAc-β-p NP HO

C20H28N2O13 = 504.45 [57467-13-7]

HO


OH O HO

OH O O

O

NO2

AcHN

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0373 GalNAcβ(1-3)GlcNAc β-Ethylazide HO

C18H31N5O11 = 493.47

HO


OH O HO AcHN

OH O O

O AcHN

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0352 GalNAcβ(1-3)GlcNAc-β-p NP HO

C22H31N3O13 = 545.50

OH O HO

HO

Solvent : DMSO-d6

OH O O

O

NO2

AcHN

AcHN


PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0356 GalNAcβ(1-4)GlcNAc-β-p NP HO

C22H31N3O13 = 545.50 [872578-72-8]

OH O

HO

Solvent : DMSO-d6/D2O=8/2 Internal Standard : DMSO Measured Temperature : 23.8 ℃

AcHN

O HO

OH O O

NO2

AcHN

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0376 GlcNAcβ(1-3)GalNAc-α-p NP C22H31N3O13 = 545.50 [125455-64-3]

HO HO


OH O

HO

OH O

O AcHN

AcHN

O

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0341 GlcNAcβ(1-3)GalNAc-α-Thr HO HO

C20H35N3O13 = 525.50 [286959-52-2]

OH O

HO

OH O

O AcHN

AcHN


O

O

CH3

OH NH2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0337 GlcNAcβ(1-2)Man α-1-Ethylazide HO HO

OH O O AcHN HO

C16H28N4O11 = 452.42

HO HO


O O

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0299 GlcNPhth[346Ac]β(1-3)Gal[246Bn]-β-MP C54H55NO16 = 974.03

OAc O

AcO AcO

OBn O

O O


BnO

N

O

O OBn

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



M1733 LacDiNAc MP Glycoside OH OH O HO OHO NHAc

C23H34N2O12 = 530.53 Solvent : DMSO-d6/D2O=49/1 Internal Standard : t-BuOH (δ 1.23) Measured Temperature : 22.3 ℃

OH O O NHAc

OCH3

PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1776 LacDiNAc(I) MP Glycoside OH OH O HO HO O NHAc

C23H34N2O12 = 530.53 Solvent : DMSO-d6/D2O=49/1 Internal Standard : t-BuOH (δ 1.23) Measured Temperature : 50.0 ℃

OH O O NHAc

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0




C24H35NO15 = 577.54 [159922-54-0]

OH

HO AcHN


COOH O

O

OH

OH O O OH

HO

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



3. 0


C24H35NO15 = 577.54

OH

HO AcHN


COOH O HO

O HO

HO

O O

OCH3

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



N0890 Neu5Acα(2-6)GalNAc-α-p NP

OH

HO

COOH

HO AcHN

C25H35N3O16 = 633.56

O HO

O HO

O HO

Solvent : D2O

AcHN


O

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1761 Neu5Ac[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP AcO

C54H59NO21 = 1058.05

OAc AcO AcHN

COOCH3 O BzO

O AcO


O BnO

O

OCH3

OBz

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



N0846 Neu5Ac[1Me,4789Ac]α(2-3)Gal[246Bz]-β-MP OAc

AcO

C54H57NO22 = 1072.04

CH3OOC

AcO AcHN


O OAc

OBz OBz O O O OBz

OCH3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



M1763 Neu5GcAc[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP OAc

AcO

C56H61NO23 = 1116.09 AcO


AcO HN O

COOCH3 O BzO

O AcO

O

BnO

O

OCH3

OBz

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



N0816 Neu5GcAc[1Me,4789Ac]α(2-3)Gal[246Bz]-β-MP AcO

C56H59NO24 = 1130.07 Solvent : CDCl3 Internal Standard : Si(CH3)4 Measured Temperature : 20.5 ℃

AcO

OAc

CH3OOC

AcO HN O

BzO

OBz O

O

O

O

OCH3

OBz

AcO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



A2631 A Antigen PEG-trifluoroacetamide HO HO

C30H51F3N2O19 = 800.73

OH O AcHN

HO

OH O

O

O

O


CH3

O

HO

O

O

O

H N

CF3 O

OH

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



B4172 B Antigen PEG-trifluoroacetamide HO HO

C28H48F3NO19 = 759.68

OH O HO

HO

OH O

O

O

O


CH3

O

HO

O

O

O

H N

CF3 O

OH

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



F0895 Fucα(1-2)Galβ(1-3)GalNAc-α-p NP (=H type 3 α-p NP Glycoside) HO

C26H38N2O17 = 650.59 [1105508-81-3]

OH O

HO

HO O

O


CH3 HO

OH O

O

AcHN

O

NO2

OH

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



F0894 Fucα(1-2)Galβ(1-3)GlcNAc-β-p NP (=H type 1 β-p NP Glycoside) HO

C26H38N2O17 = 650.59 [93496-53-8]

OH O HO O O

HO


CH3 HO

O

OH O O AcHN

NO2

OH

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0343 Galβ(1-3)[GlcNAcβ(1-6)]GalNAc-α-Thr OH O

HO HO

C26H45N3O18 = 687.65 [186600-27-1]

HO HO


O AcHN HO OH O O HO

O AcHN CH3

O

O NH2

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0377 Galβ(1-3)[Neu5Acα(2-6)]GalNAc-α-p NP HO

C31H45N3O21 = 795.70 [1316822-90-8]

OH

COOH

HO AcHN HO


O

O HO OH O

HO

HO O O

HO

AcHN

O

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0



4. 0

G0345 Galβ(1-3)[Neu5Acα(2-6)]GalNAc-β-pNP HO

C31H45N3O21 = 795.70

OH

COOH

HO AcHN HO

Solvent : D2O

HO OH O

HO


O

O HO

O O

O AcHN

HO

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



G0347 Galβ(1-3)[Neu5Acα(2-6)]GlcNAc-β-p NP OH

HO

C31H45N3O21 = 795.70 [754954-71-7]

COOH

HO AcHN HO

Solvent : D2O

HO


O

O HO OH O HO

O O

O AcHN

HO

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0353 Galβ(1-4)[Neu5Acα(2-6)]GlcNAc-β-p NP OH

HO

COOH

HO AcHN

C31H45N3O21 = 795.70

HO

Solvent : D2O HO

HO


O

O HO OH O

O

O HO

O AcHN

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0422 Ganglioside GM3 (phyto-type) C59H110N2O22 = 1199.52 [1046791-63-2]

OH

HO

HOOC

HO AcHN


O

HO O

HO

HO

O

OH O O HO

OH O

HN

C17H35 OH C13H27

O HO

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0



G0419 Ganglioside GM3[d18:1, (Carbon-13)C16:0] 13

C16C41H104N2O21 = 1169.33

OH

HO

Solvent : CDCl3/CD3OD/D2O = 5/5/1 Internal Standard : Si(CH3)4 Measured Temperature : 23.9 ℃

HOOC

HO AcHN

O

HO O

HO

HO

O

OH O O HO

OH O

13C

HN

13C H 15 31

O HO

C13H27 OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0

3. 0



M1767 Gb3-β-MP

HO

OH O

HO

C25H38O17 = 610.56 [898826-64-7]

HO

Solvent : D2O

O

OH O

HO HO


O HO

OH O O

OCH3

HO

PPM . 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0423 GlcNAcβ(1-4)[Fucα(1-6)]GlcNAc HO

C22H38N2O15 = 570.55 [108964-40-5] Solvent : D2O Internal Standard : Acetone (δ 2.22) Measured Temperature : 22.6 ℃

HO HO

OH O

CH3 OH O AcHN

OH O O

O HO

AcHN

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0342 GlcNAcβ(1-3)[GlcNAcβ(1-6)]GalNAc-α-Thr OH O

HO HO

C28H48N4O18 = 728.70 [1304646-03-4] HO HO

Solvent : D2O

O AcHN HO OH O O AcHN

O AcHN CH3


O

O NH2

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 6. 0

5. 0

4. 0



3. 0

G0378 GlcNAcβ(1-3)[Neu5Acα(2-6)]GalNAc-α-p NP OH

HO

C33H48N4O21 = 836.75

COOH

HO AcHN

Solvent : D2O

HO HO

O

O HO OH O

HO O O

AcHN


AcHN

O

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



N0853 Neu5Acα(2-3)Galβ(1-3)GlcNAc-β-p NP HO

C31H45N3O21 = 795.70

OH COOH

OH HO AcHN


O

O

OH O HO HO

HO

OH O O

O AcHN

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



N0854 Neu5Acα(2-3)Galβ(1-4)GlcNAc-β-pNP HO

C31H45N3O21 = 795.70 [501427-92-5]

OH COOH

OH HO AcHN


O

O

OH O HO

HO

OH O

O HO

O AcHN

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



N0855 Neu5Acα(2-6)Galβ(1-3)GlcNAc-β-pNP OH

HO

C31H45N3O21 = 795.70

COOH

HO AcHN


O HO

O HO O HO

HO

HO

OH O O

O AcHN

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



N0856 Neu5Acα(2-6)Galβ(1-4)GlcNAc-β-pNP HO

C31H45N3O21 = 795.70 [501427-93-6]

OH

COOH

HO AcHN

O

O HO

HO


OH O

O HO HO

O HO

O AcHN

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



N0860 Neu5Acα(2-3)Galβ(1-4)Glc-β-p NP HO

C29H42N2O21 = 754.65

OH COOH

OH HO AcHN


O

O

OH O HO

HO

O HO

OH O O HO

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



T2912 N ,N ',N ''-Triacetylchitotriose C24H41N3O16 = 627.60 [38864-21-0]

HO HO


OH O

OH O

O HO

AcHN

AcHN

O HO

OH O AcHN

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0348 Galβ(1-3)GlcNAcβ(1-3)Galβ(1-4)Glc-β-p NP HO

C32H48N2O23 = 828.73 [148705-09-3]

HO

OH O HO

OH O O

HO

Solvent : D2O

HO

OH O

O AcHN

HO

O HO

OH O O HO

NO2


PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0351 Galβ(1-4)GlcNAcβ(1-3)Galβ(1-4)Glc-β-p NP HO

C32H48N2O23 = 828.73 [197526-33-3]

HO

OH O HO


O HO

OH O

HO O

AcHN

OH O HO

O HO

OH O O HO

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0380 GalNAcβ(1-3)Galα(1-3)Galβ(1-4)Glc-β-p NP HO

C32H48N2O23 = 828.73

OH O

HO

HO

O AcHN


OH O HO HO

OH O

O HO

O HO

OH O O HO

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0354 GalNAcβ(1-3)Galα(1-4)Galβ(1-4)Glc-β-p NP HO

C32H48N2O23 = 828.73 [1134635-03-2]

HO

OH O

HO

OH O

O AcHN

HO

Solvent : D2O

O

HO

OH O HO


O HO

OH O O HO

NO2

PPM 9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0372 GlcA[3S ]β(1-3)Galβ(1-4)GlcNAcβ(1-2)Man α-Ethylazide HO NaO3SO

C28H44N4Na2O25S = 914.70

COONa O

HO

OH O

O HO

HO

O HO


OH O O AcHN HO HO HO

O O

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



L0237 LacDiNAc Dimer Ethylazide HO

C34H57N7O21 = 899.86

OH O

HO AcHN


OH O

O HO

HO

OH O

O AcHN

AcHN

OH O

O HO

O AcHN

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



T2910 N ,N ',N '',N '''-Tetraacetylchitotetraose C32H54N4O21 = 830.79 [2706-65-2]

HO HO


OH O

OH O

O HO

AcHN

AcHN

O HO

2

OH O AcHN

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



D4217 Disialylnonasaccharide β-Ethylazide OH

HO

HO AcHN

COOH O HO

HO

C86H141N9O62 = 2293.08 Solvent : D2O Internal Standard : t -BuOH (δ 1.23) Measured Temperature : 27.9 ℃

OH

HO

HO AcHN

O HO

O HO

HO

O HO HO

OH O AcHN HO HO HO

O O O HO O

COOH O

O HO

O HO

HO O


HO O

NHAc O HO

O OH

OH O AcHN

O

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0

2. 0



D4065 Disialyloctasaccharide

HO

OH HO AcHN

COOH O HO

O HO HO

O HO

C76H125N5O57 = 2020.81 HO


OH HO AcHN

O HO

OH O AcHN HO HO HO

HO

O HO HO

O O HO O

COOH O

O

O HO


HO O

HO O

O

NHAc O OH

OH

O

PPM 9. 0

10 .0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



2. 0

F0584 Forssman Pentaose MP Glycoside OH

C41N64N2O27 = 1016.95

OH O

OH

HO AcHN

O

OH O

OH O

O AcHN


OH

HO

O

OH O

HO

HO HO O

HO

O O OH

OCH3

PPM 10 . 0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0355 Galβ(1-3)GalNAcβ(1-3)Galα(1-4)Galβ(1-4)Glc-β-p NP HO

C38H58N2O28 = 990.87

HO

OH O

HO O

HO

OH O

HO

OH O

O AcHN

HO

Solvent : D2O

O

HO

OH O HO


O HO

OH O O HO

NO2

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



G0421 Ganglioside GM1[d18:1, (Carbon-13)C16:0] HO

OH O

HO

13

C16C55H127N3O31 = 1534.66

OH O

O

HO

Solvent : DMSO-d6/D2O = 49/1 Internal Standard : DMSO Measured Temperature : 60.0 ℃

HO

O AcHN

HO OH

HOOC

HO AcHN

O

O

HO

HO

O

OH O O HO

OH O

13C

HN

13C

O HO

15H31

C13H27 OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



H1333 HNK-1 Ethylazide C34H54N4Na2O30S = 1076.84

HO NaO3SO


COONa O

HO

OH O

O HO

HO

OH O

O HO

HO

OH O

O AcHN

HO

O HO

OH O O HO

N3

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0



M2439 HO HO HO

Manα(1-2)Manα(1-3)[Manα(1-6)Manα(1-6)]Manβ(1-4)GlcNAc

HO O O HO HO

C38H65NO31 = 1031.91

HO O O HO O



HO O

O HO

OH O AcHN

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

5. 0



P2027 N ,N ',N '',N ''',N ''''-Pentaacetylchitopentaose C40H67N5O26 = 1033.99 [36467-68-2]

HO HO


OH O O HO

AcHN

OH O AcHN

O HO

3

OH O AcHN

OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



S0523 Sialylglycopeptide

HO

OH HO AcHN

COONa O HO

O HO HO

O HO

O HO

C112H187N15Na2O70 = 2909.74 [189035-43-6] HO

Solvent : D2O

OH HO AcHN

OH O AcHN HO HO HO

O


O HO HO

O HO


NH2 Lys

O O HO O

COONa

HO

O

HO O

HO O

O

NHAc O HO

O OH

OH O AcHN

Val Ala Asn Lys Thr COOH

O

PPM 9. 0

10 .0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0

2. 0

1. 0



S0849 Sialyl Lewis X-Lactose C43H72N2O33 = 1145.03 [127923-85-7]

OH

HO

HO AcHN


HOOC O HO

HO

OH O

O

O HO CH3

O

OH O O

HO

OH O

O AcHN

HO

OH

O HO

OH O HO

OH

OH

HO

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0



S0910 Sialyl Neolactotetraosylceramide (=Sialyl nLc4 Cer) C73H131N3O31 = 1546.84 [128529-29-3] HO

Solvent : DMSO-d6/D2O = 49/1 Internal Standard : DMSO Measured Temperature : 50.0 ℃

OH

HO AcHN

HOOC HO O

O

HO

OH O HO

O HO

OH HO O O AcHN

OH O HO

O HO

OH O HO

O O

HN

C17H35 C13H27 OH

PPM 10 .0

9. 0

8. 0

7. 0

6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 5. 0

4. 0

3. 0



H1144 α-Homonojirimycin C7H15NO5 = 193.20 [119557-99-2] HO HO


OH NH HO OH

PPM 6. 0

5. 0

4. 0

3. 0

2. 0

1. 0

0. 0

PPM 4. 0

3. 0



Product Name Index-① A AA-2G .................................................................................. G0394.... 70 A Antigen PEG-trifluoroacetamide ...................................... A2631.... 77 Acarbose Hydrate .............................................................. A2485.... 77 2-Acetamido-3-O -allyl-4,6-O -benzylidene-2-deoxyβ-D-glucopyranosyl Azide ................................................. A1812.... 38 5-Acetamido-9-amino-3,5,9-trideoxy-D-glycero -D-galacto nonulopyranosonic Acid .................................................... A2511.... 59 2-Acetamido-3-O -benzyl-4,6-O -benzylidene-2-deoxyβ-D-glucopyranosyl Azide ................................................. A1813.... 38 2-Acetamido-4,6-O -benzylidene-2-deoxyβ-D-glucopyranosyl Azide ................................................. A1811.... 38 2-Acetamido-N -biotinyl-2-deoxyβ-D-glucopyranosylamine ................................................. G0297.... 39 O -[2-Acetamido-2-deoxy-3-O -(2-acetamido-2-deoxyβ-D-glucopyranosyl)-α-D-galactopyranosyl]-L-threonine .. G0341.... 70 2-Acetamido-2-deoxy-4-O -(2-acetamido-2-deoxyβ-D-glucopyranosyl)-D-glucopyranose .............................. D4215.... 66 2-Acetamido-2-deoxy-D-galactopyranose Hydrate ............. A1245.... 20 O -[2-Acetamido-2-deoxy-3-O -(β-D-galactopyranosyl)α-D-galactopyranosyl]-L-threonine................................... G0340.... 69 2-Acetamido-2-deoxy-D-glucopyranose .............................. A0092.... 39 2-Acetamido-2-deoxyβ-D-glucopyranose 1,3,4,6-Tetraacetate ......................... A1459.... 38 2-Acetamido-2-deoxy-β-D-glucopyranosylaminobiotin ...... G0297.... 39 N ω-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)N α-Boc-L-asparagine .......................................................... A1614.... 38 N ω-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)N α-(tert -butoxycarbonyl)-L-asparagine .............................. A1614.... 38 2-Acetamido-2-deoxy-α-D-glucopyranosyl Chloride 3,4,6-Triacetate ................................................................ A1416.... 38 2-Acetamido-2-deoxy-D-mannopyranose Monohydrate ..... A2160.... 53 5-Acetamido-3,5-dideoxy-D-glycero -D-galacto nonulopyranosonic Acid Hydrate ...................................... A0639.... 59 2-Acetamido-1,3,4,6-tetra-O -acetyl-2-deoxyβ-D-glucopyranose............................................................ A1459.... 38 2-Acetamido-3,4,6-tri-O -acetyl-2-deoxyβ-D-glucopyranosyl Azide ................................................. A1616.... 38 2-Acetamido-3,4,6-tri-O -acetyl-2-deoxyα-D-glucopyranosyl Chloride ............................................ A1416.... 38 2-Acetamido-3,4,6-tri-O -benzyl-2-deoxyβ-D-glucopyranosyl Azide ................................................. A1678.... 39 N ω-(2-Acetamido-3,4,6-tri-O -benzyl-2-deoxyβ-D-glucopyranosyl)-N α-Boc-L-asparagine Benzyl Ester ... A1685.... 39 N ω-(2-Acetamido-3,4,6-tri-O -benzyl-2-deoxyβ-D-glucopyranosyl)-N α-(tert -butoxycarbonyl)L-asparagine Benzyl Ester ................................................. A1685.... 39 5-Acetamido-3,5,9-trideoxy-9-fluoro-D-glycero -D-galacto nonulopyranosonic Acid .................................................... A2492.... 59 Acetic Anhydride (ca . 1mol/L in Dichloromethane) ........... A1668.. 101 Acetone Dimethyl Acetal .................................................... A0057.. 106 Acetoxyacetyl Chloride....................................................... A1500.. 101 N -Acetyl-Chitooligosaccharides (contains N -Acetylglucosamine) ........................................ C2762.... 85 N -Acetyl-D-chondrosamine Hydrate ................................... A1245.... 20 N -Acetyl-9-deoxy-9-aminoneuraminic Acid ........................ A2511.... 59 N -Acetyl-9-deoxy-9-fluoroneuraminic Acid......................... A2492.... 59 N -Acetyl-2,3-didehydro-2-deoxyneuraminic Acid ............... A2205.... 59 N -Acetyl-D-galactosamine Hydrate ..................................... A1245.... 20 endo -α-N -Acetylgalactosaminidase (=Endo-α) Recombinant: from Bifidobacterium longum expressed in Escherichia coli .................................................................... A1844.. 118 N -Acetyl-D-glucosamine ...................................................... A0092.... 39 endo -β-N -Acetylglucosaminidase (=Endo-M) Recombinant: from Mucor hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)] ......................... A1651.. 118 N -Acetyl-D-mannosamine Monohydrate ............................. A2160.... 53 2-Acetyl-5-methoxyphenyl 6-O -(α-L-Arabinopyranosyl)β-D-glucopyranoside......................................................... P1879.... 75 2-Acetyl-5-methoxyphenyl β-D-Glucopyranoside .............. A2253.... 22 N -Acetylneuraminic Acid Hydrate ...................................... A0639.... 59 N -Acetylneuraminic Acid Methyl Ester ................................ A1821.... 59 N -Acetylneuraminic Acid Methyl Ester 2,4,7,8,9-Pentaacetate ..................................................... M1707.... 60 N -Acetylneuraminic Acid Methyl Ester 4,7,8,9-Tetraacetate ......................................................... A1822.... 60 3-Acetylpropionic Acid ........................................................L0042.. 110 1-O -Acetyl-2,3,5-tri-O -benzoyl-β-D-ribofuranose .............. R0067.... 56 1-O -Acetyl-2,3,5-tri-O -benzoyl-β-L-ribofuranose .............. R0080.... 56

6-O -Acetyl-2,3,4-tri-O -benzyl-D-glucopyranose .................. A2636.... 22 Acid Maltase from Rhizopus (contains 50% Diatomaceous earth) .................................. M0035.. 118 Adonitol .............................................................................. A0171.... 56 Alginic Acid ......................................................................... A0733.... 91 Alginic Acid Calcium Salt..................................................... A0738.... 91 Allitol .................................................................................. A1982...... 7 Allolactose .......................................................................... A2630.... 66 4-(β-D-Allopyranosyloxy)benzaldehyde ............................. F0542...... 7 D-(+)-Allose ......................................................................... A1488...... 7 Allyl Bromide ...................................................................... B0643.. 101 3A-Amino-3A-deoxy-(2AS ,3AS )-α-cyclodextrin Hydrate ... A2122.... 85 3A-Amino-3A-deoxy-(2AS ,3AS )-β-cyclodextrin Hydrate ... A1916.... 85 3A-Amino-3A-deoxy-(2AS ,3AS )-γ-cyclodextrin Hydrate ... A2123.... 85 1-Amino-1-deoxy-D-glucitol ................................................ G0252.... 97 2-Amino-2-deoxy-D-glucopyranose Hydrochloride ............. G0044.... 40 1-Amino-1-deoxy-D-sorbitol ................................................ G0252.... 97 Aminomethane (ca . 40% in Water, ca . 12mol/L) ................ M0137.. 111 4-Aminophenyl β-D-Galactopyranoside ............................. A1413.... 13 Amygdalase from Almonds ................................................. G0035.. 119 Amygdalin ........................................................................... A0443.... 66 α-Amylase diluted with Starch, from Bacillus subtilis ........ A0447.. 118 β-Amylase from Soybean .................................................. A0448.. 118 Amyloheptaose ................................................................... M1025.... 88 Amylohexaose ..................................................................... M1024.... 88 Amylopectin Hydrate (Amylose free), from Waxy Corn ..... A0456.... 91 Amylopentaose ................................................................... M1023.... 88 Amylose (Mw.=ca . 15,000) ................................................. A0847.... 91 Amylose (Mw.=ca . 2,800) ................................................... A0846.... 91 Amylotetraose..................................................................... M1022.... 84 1,5-Anhydro-2-deoxy-D-arabino -hex-1-enitol ...................... G0274.... 25 1,5-Anhydro-2-deoxy-D-lyxo -hex-1-enitol .......................... G0273.... 14 1,5-Anhydro-2-deoxy-D-arabino -hex-1-enitol 3,4,6-Tri-O -acetyl Ether .................................................... T1596.... 36 1,5-Anhydro-2-deoxy-D-lyxo -hex-1-enitol 3,4,6-Tri-O -acetyl Ether .................................................... T1734.... 19 1,5-Anhydro-2-deoxy-D-arabino -hex-1-enitol 3,4,6-Tribenzyl Ether ........................................................ T1859.... 37 1,5-Anhydro-2-deoxy-D-lyxo -hex-1-enitol 3,4,6-Tribenzyl Ether ........................................................ T1858.... 19 1,5-Anhydro-2-deoxy-6-O -(triisopropylsilyl)D-lyxo -hex-1-enitol ............................................................ T1935.... 19 1,6-Anhydro-β-D-glucose ................................................... A1074.... 22 1,6-Anhydro-2,3,4-tri-O -benzyl-β-D-glucopyranose .......... A2637.... 22 p -Anisaldehyde Dimethyl Acetal ......................................... A1247.. 101 Anisyl Chloride (stabilized with Amylene) ......................... M0676.. 111 Anti-Gb3 Monoclonal Antibody ............................................ A2506.. 122 Anti-Gb3 Monoclonal Antibody (Culture Supernatant) ....... A2586.. 122 Anti-GD1a Monoclonal Antibody ........................................... A2507.. 122 Anti-GD1b Monoclonal Antibody ........................................... A2508.. 122 Anti-GD3 Monoclonal Antibody ............................................ A2580.. 122 Anti-GD3 Monoclonal Antibody (Culture Supernatant) ....... A2579.. 122 Anti-GM1 Monoclonal Antibody ............................................ A2505.. 122 Anti-GM2 Monoclonal Antibody ............................................ A2576.. 123 Anti-GM2 Monoclonal Antibody (Culture Supernatant) ....... A2575.. 123 Anti-GM3 Monoclonal Antibody ............................................ A2582.. 123 Anti-GM3 Monoclonal Antibody (Culture Supernatant) ....... A2581.. 123 Anti-Lewis X Monoclonal Antibody ...................................... A2578.. 123 Anti-Lewis X Monoclonal Antibody (Culture Supernatant) .. A2577.. 123 Anti-Lewis Y Monoclonal Antibody ...................................... A2510.. 123 Anti-Lewis Y Monoclonal Antibody (Culture Supernatant) .. A2587.. 124 Anti-Sialyl Lewis A Monoclonal Antibody (2D3) ................... A2509.. 124 Anti-Sialyl Lewis A Monoclonal Antibody (1H4) ................... A2584.. 124 Anti-Sialyl Lewis A Monoclonal Antibody (1H4) (Culture Supernatant) ....................................................... A2583.. 124 DL-Arabinitol ....................................................................... A0517...... 8 D-(+)-Arabinitol ................................................................... A0516...... 8 L-(-)-Arabinitol .................................................................... A0518...... 8 (+)-Arabinogalactan from Larch Wood ............................... A1328.... 91 D-(-)-Arabinose .................................................................... A0513...... 8 L-(+)-Arabinose ................................................................... A0515...... 8 DL-Arabitol .......................................................................... A0517...... 8 D-(+)-Arabitol ...................................................................... A0516...... 8 L-(-)-Arabitol ....................................................................... A0518...... 8 D-Araboascorbic Acid .......................................................... A0520.... 95 Arbutin................................................................................ A0522.... 22 L-Ascorbic Acid ................................................................... A0537.... 95 L-Ascorbic Acid Sodium Salt ................................................ A0539.... 99 L-Ascorbyl 2,6-Dibutyrate ................................................... A1205.... 95


319

Product Name Index-② L-Ascorbyl 2,6-Dipalmitate ................................................. A0757.... 96 L-Ascorbyl 6-Palmitate ........................................................ A0540.... 99 L-Ascorbyl 6-Stearate ......................................................... A0617.... 99

O -(2-Azido-4,6-O -benzylidene-2-deoxyα-D-galactopyranosyl)-N -[(9H -fluoren9-ylmethoxy)carbonyl]-L-serine tert -Butyl Ester ............... A1833.... 20 O -(2-Azido-4,6-O -benzylidene-2-deoxyα-D-galactopyranosyl)-N -[(9H -fluoren9-ylmethoxy)carbonyl]-L-threonine tert -Butyl Ester ......... A1832.... 20 O -(2-Azido-4,6-O -benzylidene-2-deoxyα-D-galactopyranosyl)-N -Fmoc-L-serine tert -Butyl Ester .. A1833.... 20 O -(2-Azido-4,6-O -benzylidene-2-deoxyα-D-galactopyranosyl)-N -Fmoc-L-threonine tert -Butyl Ester ..A1832.... 20 2-[2-(2-Azidoethoxy)ethoxy]ethyl 2,3,4,6-Tetra-O -acetyl-D-galactopyranoside...................... G0257.... 13 2-Azidoethyl 2-Acetamido-2-deoxy-β-D-galactopyranoside .. A2627.... 20 2-Azidoethyl 2-Acetamido-2-deoxy-β-D-glucopyranoside .. A2172.... 39 2-Azidoethyl β-D-Glucopyranoside .................................... A2267.... 22 2-Azidoethyl 2,3,4,6-Tetra-O -acetyl-β-D-glucopyranoside .. A2377.... 22 11-Azido-3,6,9-trioxaundecanol......................................... A2294.. 101 Azodicarboxylic Acid Dibenzyl Ester (40% in Dichloromethane, ca . 1.7mol/L) ........................... A0776.. 105 Azodicarboxylic Acid Diethyl Ester (40% in Toluene, ca . 2.2mol/L) .......................................... A0705.. 106

B Baicalin ............................................................................... B2835.... 23 B Antigen PEG-trifluoroacetamide ...................................... B4172.... 77 Barosmin ............................................................................. D3908.... 66 Benzaldehyde Dimethyl Acetal ........................................... B1197.. 101 2-Benzamido-2-deoxy-D-glucopyranose .............................. B0200.... 39 Benzenethiol ...................................................................... B0041.. 101 Benzoic Anhydride .............................................................. B0078.. 102 1,2,3-Benzotriazol-1-ol Monohydrate................................ H0468.. 109 Benzoyl Chloride................................................................. B0105.. 102 N -Benzoyl-D-glucosamine .................................................... B0200.... 39 Benzyl Bromide (stabilized with Propylene Oxide) ........... B0411.. 102 Benzyl Chloride (stabilized with ε-Caprolactam) ............. B0412.. 102 Benzyl 2,3-Di-O -benzyl-4,6-O -benzylideneβ-D-glucopyranoside......................................................... B4170.... 23 Benzyl 2,3,4-Tri-O -benzyl-β-D-glucopyranoside ................ B4171.... 23 BGIT .................................................................................... A5515.... 35 (+)-(2R ,3R )-1,4-Bis(benzyloxy)-2,3-butanediol................... D2239.... 95 (-)-(2S ,3S )-1,4-Bis(benzyloxy)-2,3-butanediol .................... D2240.... 95 Bis(cyclopentadienyl)hafnium Dichloride ........................... H0914.. 109 (-)-4,5-Bis[hydroxy(diphenyl)methyl]2,2-dimethyl-1,3-dioxolane .............................................. B1614.... 95 (4R ,5R )-(-)-4,5-Bis(hydroxymethyl)2,2-dimethyl-1,3-dioxolane ................................................I0375.... 98 (4S ,5S )-(+)-4,5-Bis(hydroxymethyl)2,2-dimethyl-1,3-dioxolane ................................................I0376.... 98 Bis(4-hydroxyphenyl) Sulfide .............................................. D1356.. 102 (4R ,5R )-(+)-4,5-Bis(tosyloxymethyl)2,2-dimethyl-1,3-dioxolane .............................................. D1622.... 96 (4S ,5S )-(-)-4,5-Bis(tosyloxymethyl)2,2-dimethyl-1,3-dioxolane .............................................. D1623.... 96 N ,O -Bis(trimethylsilyl)trifluoroacetamide ........................... A5603.. 103 Bluo-Gal .............................................................................. B3470.... 13 Boc Anhydride..................................................................... D1547.. 105 Boc2O .................................................................................. D1547.. 105 Boc2O (ca . 30% in Dioxane) ................................................ D3878.. 105 Boc2O (ca . 30% in Tetrahydrofuran) ................................... D3879.. 105 Boc2O (ca . 30% in Toluene) ................................................ D3880.. 105 Boron Trifluoride - Ethyl Ether Complex............................. B0527.. 102 5-Bromo-4-chloro-3-(β-D-galactopyranosyloxy)indole....... B3201.... 13 5-Bromo-4-chloro-3-indolyl β-D-Galactopyranoside [for Biochemical Research] ............................................... B3201.... 13 5-Bromo-6-chloro-3-indolyl β-D-Galactopyranoside (contains ca . 10% Ethyl Acetate) [for Biochemical Research] .. B3469.... 13 5-Bromo-3-indolyl β-D-Galactopyranoside [for Biochemical Research] ............................................... B3470.... 13 3-Bromo-1-propene ............................................................ B0643.. 101 3-Bromopropylene .............................................................. B0643.. 101 N -Bromosuccinimide ........................................................... B0656.. 102 α-Bromotoluene (stabilized with Propylene Oxide) ......... B0411.. 102 BSTFA [=N ,O -Bis(trimethylsilyl)trifluoroacetamide] [for Gas Chromatography] ................................................ A5603.. 103 2,3-Butanedione ................................................................. B0682.. 104 L-1,2,3,4-Butanetetrol ....................................................... T1647.. 100

tert -Butylchlorodimethylsilane ........................................... B0995.. 103 tert -Butylchlorodiphenylsilane ........................................... B1223.. 103 tert -Butyldimethylchlorosilane [tert -Butyldimethylsilylating Agent] .................................. B0995.. 103 tert -Butyldimethylsilyl Chloride .......................................... B0995.. 103 tert -Butyldimethylsilyl Triflate ............................................ T1525.. 103 tert -Butyldimethylsilyl Trifluoromethanesulfonate ............. T1525.. 103 tert -Butyldiphenylchlorosilane ........................................... B1223.. 103

C Calcium Alginate ................................................................. A0738.... 91 Calcium Gluconate Monohydrate ....................................... G0037.... 23 Calcium Lactobionate Hydrate ...........................................L0006.... 66 Calcium Phytate.................................................................. P0410.... 47 (±)-10-Camphorsulfonic Acid ............................................. C0016.. 103 (+)-10-Camphorsulfonic Acid .............................................. C0015.. 103 (-)-10-Camphorsulfonic Acid ............................................... C0972.. 103 Capsaicin β-D-Glucopyranoside ......................................... C2548.... 23 Carmine .............................................................................. C0543.... 23 Carmine Red ....................................................................... C0543.... 23 Carminic Acid (Natural dye) ............................................... C0782.... 23 ι-Carrageenan ................................................................... C1805.... 91 κ-Carrageenan ................................................................... C1804.... 92 D-(+)-Cellobiose .................................................................. C0056.... 66 α-D-Cellobiose Octaacetate ............................................... C0861.... 66 Cellopentaose ..................................................................... C2644.... 85 D-(+)-Cellose ....................................................................... C0056.... 66 Cellotetraose ...................................................................... C2796.... 83 Cellotriose .......................................................................... C2795.... 77 Cellulase from Aspergillus niger ........................................... C0057.. 118 Chitin .................................................................................. C0072.... 92 Chitin Oligosaccharides (contains N -Acetylglucosamine) ... C2762.... 85 Chitosan (5-20mPa･s, 0.5% in 0.5% Acetic Acid at 20℃) ... C2395.... 92 Chitosan (50-100mPa･s, 0.5% in 0.5% Acetic Acid at 20℃) .. C2396.... 92 Chitosan (200-500mPa･s, 0.5% in 0.5% Acetic Acid at 20℃) .. C0831.... 92 Chitosan Tetramer Hydrate ................................................ C2641.... 83 Chitosan Trimer Hydrate .................................................... C2642.... 77 Chitotetraose Tetrahydrochloride Hydrate ........................ C2641.... 83 Chitotriose Trihydrochloride Hydrate ................................ C2642.... 77 α-Chloralose (contains β-isomer) .................................... C0074.... 24 1-Chloro-2-acetamido-2-deoxy-3,4,6-tri-O -acetylα-D-glucose ...................................................................... A1416.... 38 Chloroacetyl Chloride ......................................................... C0098.. 104 Chlorodimethylphosphine Sulfide ....................................... D2159.. 107 Chlorodiphenylphosphine Oxide ......................................... C1415.. 107 6-Chloro-3-indolyl β-D-Galactopyranoside [for Biochemical Research] ............................................... C2371.... 13 2-(Chloromethoxy)ethyltrimethylsilane (stabilized with Diisopropylethylamine) ........................... C1339.. 104 4-(Chloromethyl)anisole (stabilized with Amylene) .......... M0676.. 111 2-Chloro-1-methylpyridinium Iodide .................................. C0903.. 104 α-Chlorotoluene (stabilized with ε-Caprolactam) ........... B0412.. 102 Chlorotrimethylsilane ......................................................... C0306.. 104 Chondroitin Sulfate B Sodium Salt ...................................... D3672.... 92 Chondroitin Sulfate Sodium Salt ......................................... C0335.... 92 Chondrosamine Hydrochloride ........................................... G0007.... 20 Cleland's Reagent................................................................ D1071.... 96 L-Cleland's Reagent ............................................................. D1589.... 96 Copper(II) Gluconate........................................................... G0275.... 24 Copper(II) Triflate ............................................................... T1292.. 104 Copper(II) Trifluoromethanesulfonate ................................ T1292.. 104 Crocetin Digentiobiosyl Ester (Gardenia Fruits Extract) .... C1527.... 95 Crocin (Gardenia Fruits Extract) ........................................ C1527.... 95 α-Cyclodextrin ................................................................... C0776.... 85 β-Cyclodextrin ................................................................... C0777.... 85 β-Cyclodextrin ................................................................... C0900.... 86 γ-Cyclodextrin ................................................................... C0869.... 86 β-Cyclodextrin Henicosaacetate ....................................... T1844.... 90 Cycloheptaamylose ............................................................. C0777.... 85 Cyclohexaamylose .............................................................. C0776.... 85 1D-1,2,3,5/4-Cyclohexanepentol ........................................ Q0070.... 47 1L-1,2,4/3,5-Cyclohexanepentol ........................................ Q0069.... 47 1L-1,3,4/2,5-Cyclohexanepentol ........................................ Q0071.... 47 Cyclooctaamylose ............................................................... C0869.... 86

D DABCO ................................................................................. D0134.. 104 Daidzin ................................................................................ D3920.... 24 DANA ................................................................................... A2205.... 59


320

Product Name Index-③ DAST ................................................................................... D1868.. 106 DBU ..................................................................................... D1270.. 105 DCC ..................................................................................... D0436.. 106 DDQ ..................................................................................... D1070.. 106 DEAD (40% in Toluene, ca . 2.2mol/L) ................................. A0705.. 106 Decyl 4-O -β-D-Lactopyranosyl-β-D-lactopyranoside ..........L0229.... 84 2,3-Dehydro-2-deoxy-N -acetylneuraminic Acid .................. A2205.... 59 4'-Demethylepipodophyllotoxin 9-(4,6-O -Ethylideneβ-D-glucopyranoside) ........................................................E0675.... 25 2-Deoxy-2,2-difluoro-D-erythro -pentonic Acid γ-Lactone 3,5-Dibenzoate.................................................................. D4207.... 56 2-Deoxy-2-fluoro-D-glucopyranose ..................................... D3023.... 24 2-Deoxy-2-fluoro-D-glucose ................................................ D3023.... 24 2-Deoxy-D-galactopyranose 3,4,6-Tribenzyl Ether ............. T1932.... 19 2-Deoxy-D-galactose ........................................................... D0050.... 13 6-Deoxy-D-galactose ........................................................... D0049.... 11 6-Deoxy-L-galactose............................................................ F0065.... 11 2-Deoxy-D-glucopyranose 3,4,6-Triacetate ........................ T1931.... 36 2-Deoxy-D-glucose .............................................................. D0051.... 24 2-Deoxy-2-hexanamido-D-glucopyranose............................ H0118.... 40 6-Deoxy-L-mannose Monohydrate...................................... R0013.... 55 2-Deoxy-2-pentanamido-D-glucopyranose .......................... V0011.... 43 2-Deoxy-D-ribose ................................................................ D0059.... 56 2-Deoxy-2-trifluoroacetamido-D-glucopyranose ................. T0973.... 43 2-Deoxy-2-valeramido-D-glucopyranose ............................. V0011.... 43 Dermatan Sulfate Sodium Salt ............................................ D3672.... 92 Dextran 40 (Mw.=ca . 40,000) ............................................. D1448.... 93 Dextran 70 (Mw.=ca . 70,000) ............................................. D1449.... 93 Dextran Sulfate Sodium (from Dextran of Mw. Approx . 25,000) ............................... D1776.... 93 D-(+)-Dextrose .................................................................... G0048.... 26 Diacetone-D-glucose ........................................................... D1949.... 24 Diacetyl ............................................................................... B0682.. 104 3,4-Di-O -acetyl-1,5-anhydro-2,6-dideoxy-L-arabino hex-1-enitol ...................................................................... D2752.... 24 N ,N '-Diacetylchitobiose ....................................................... D4215.... 66 3,4-Di-O -acetyl-6-deoxy-L-glucal ........................................ D2752.... 24 3,4-Di-O -acetyl-L-rhamnal .................................................. D2752.... 24 1,4:3,6-Dianhydroglucitol.....................................................I0407.... 98 1,4:3,6-Dianhydromannitol ..................................................I0406.... 98 1,4:3,6-Dianhydrosorbitol ....................................................I0407.... 98 1,4-Diazabicyclo[2.2.2]octane ........................................... D0134.. 104 1,8-Diazabicyclo[5.4.0]-7-undecene .................................. D1270.. 105 DIBAL-H (19% in Hexane, ca . 1.0mol/L) ............................. D2971.. 106 Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca . 1.7mol/L) ........................... A0776.. 105 (+)-1,4-Di-O -benzyl-D-threitol ............................................ D2239.... 95 (-)-1,4-Di-O -benzyl-L-threitol ............................................. D2240.... 95 DiBoc................................................................................... D1547.. 105 Di-tert -butyl Dicarbonate [Boc-reagent for Amino Acid] .... D1547.. 105 Di-tert -butyl Dicarbonate (ca . 30% in Dioxane) .................. D3878.. 105 Di-tert -butyl Dicarbonate (ca . 30% in Tetrahydrofuran) ..... D3879.. 105 Di-tert -butyl Dicarbonate (ca . 30% in Toluene) .................. D3880.. 105 Dibutyldichlorotin ............................................................... D0223.. 105 Di-tert -butyl Pyrocarbonate ................................................ D1547.. 105 Di-tert -butyl Pyrocarbonate (ca . 30% in Dioxane) .............. D3878.. 105 Di-tert -butyl Pyrocarbonate (ca . 30% in Tetrahydrofuran) .. D3879.. 105 Di-tert -butyl Pyrocarbonate (ca . 30% in Toluene) .............. D3880.. 105 Dibutyltin Dichloride .......................................................... D0223.. 105 Dibutyltin Oxide.................................................................. D0305.. 106 2,6-Di-O -butyryl-L-ascorbic Acid ......................................... A1205.... 95 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone ..................... D1070.. 106 1-(1,6-Dichloro-1,6-dideoxy-β-D-fructofuranosyl)4-chloro-4-deoxy-α-D-galactopyranoside .......................... S0839.... 75 N ,N '-Dicyclohexylcarbodiimide ........................................... D0436.. 106 (Diethylamino)sulfur Trifluoride [Fluorinating Reagent] ... D1868.. 106 Diethyl Azodicarboxylate (40% in Toluene, ca . 2.2mol/L) .. A0705.. 106 Digitonin ............................................................................. D0540.... 96 Digitoxin ............................................................................. D0542.... 96 Digoxin ................................................................................ D1828.... 77 2,3-Dihydroxy-1,4-butanedithiol ........................................ D1320...... 9 DL-2,3-Dihydroxy-1,4-butanedithiol ................................... D1071.... 96 (2R ,3R )-(-)-2,3-Dihydroxy-1,4-butanedithiol ...................... D1589.... 96 (3R ,4R )-Dihydroxydihydro-2(3H )-furanone ..........................E0455...... 9 4,4'-Dihydroxydiphenyl Sulfide........................................... D1356.. 102 5,6-Dihydroxy-4-oxo-2-phenyl-4H -1-benzopyran-7-yl β-D-Glucopyranosiduronic Acid ........................................ B2835.... 23 Diisobutylaluminum Hydride (19% in Hexane, ca . 1.0mol/L)..D2971.. 106 1,2:5,6-Di-O -isopropylidene-α-D-allofuranose................... D2265...... 7

2,3:4,5-Di-O -isopropylidene-β-D-fructopyranose .............. D3758.... 10 1,2:3,4-Di-O -isopropylidene-α-D-galactopyranose ............ D2555.... 14 1,2:5,6-Di-O -isopropylidene-α-D-glucofuranose ................ D1949.... 24 (-)-2,3:4,6-Di-O -isopropylidene-2-ketoL-gulonic Acid Monohydrate ............................................. D2191.... 44 1,2:5,6-Di-O -isopropylidene-D-mannitol ............................. D2024.... 49 2,3:5,6-Di-O -isopropylidene-D-mannofuranose .................. D2447.... 49 2,3:4,5-Di-O -isopropylidene-1-O -sulfamoylβ-D-fructopyranose .......................................................... T2755.... 10 1,2:3,5-Di-O -isopropylidene-α-D-xylofuranose .................. D2616.... 64 (-)-2,3:4,6-Di-O -isopropylideneα-L-xylo-2-hexulofuranosonic Acid Monohydrate ............ D2191.... 44 2,3-Diketobutane................................................................ B0682.. 104 1,4-Dimercapto-2,3-butanediol .......................................... D1320...... 9 DL-1,4-Dimercapto-2,3-butanediol ..................................... D1071.... 96 (2R ,3R )-(-)-1,4-Dimercapto-2,3-butanediol ........................ D1589.... 96 2,2-Dimethoxypropane ....................................................... A0057.. 106 α,α-Dimethoxytoluene ..................................................... B1197.. 101 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide ............... D4029.. 107 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide Hydrochloride [Coupling Agent for Peptides Synthesis] ... D1601.. 107 4-Dimethylaminopyridine ................................................... D1450.. 107 (4R ,5R )-(+)-2,2-Dimethyl-4,5-bis(tosyloxymethyl)1,3-dioxide ........................................................................ D1622.... 96 (4S ,5S )-(-)-2,2-Dimethyl-4,5-bis(tosyloxymethyl)1,3-dioxide ........................................................................ D1623.... 96 2,6-Di-O -methyl-β-cyclodextrin ........................................ D1732.... 88 (4R ,5R )-(-)-2,2-Dimethyl-1,3-dioxolane-4,5-dimethanol ......I0375.... 98 (4S ,5S )-(+)-2,2-Dimethyl-1,3-dioxolane-4,5-dimethanol ......I0376.... 98 (-)-trans -α,α'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) ...................................................... B1614.... 95 Dimethylglyoxal .................................................................. B0682.. 104 Dimethylphosphinothioyl Chloride ..................................... D2159.. 107 2,3-Dimethylpyridine...........................................................L0063.. 110 2,4-Dimethylpyridine...........................................................L0085.. 110 2,5-Dimethylpyridine...........................................................L0065.. 110 2,6-Dimethylpyridine...........................................................L0067.. 111 3,4-Dimethylpyridine...........................................................L0066.. 111 3,5-Dimethylpyridine...........................................................L0068.. 111 Dimethylthiophosphinoyl Chloride ..................................... D2159.. 107 Diosmin ............................................................................... D3908.... 66 2,6-Di-O -palmitoyl-L-ascorbic Acid ..................................... A0757.... 96 Diphenyl Phosphate ............................................................ P0801.. 107 Diphenylphosphinic Chloride .............................................. C1415.. 107 Diphenyl Sulfone................................................................. P0231.. 107 Diphenyl Sulfoxide .............................................................. D1002.. 108 Diphenyltin Sulfide [Activator for O -Glycoside Synthesis] .. D2358.. 108 Dipotassium D-Glucose-6-phosphate Hydrate .................... G0211.... 27 Dipotassium Glycyrrhizinate Hydrate ................................ G0270.... 67 Disialylnonasaccharide β-Ethylazide ................................. D4217.... 86 Disialylnonasaccharide-β-p NP ........................................... N0913.... 86 Disialyloctasaccharide ........................................................ D4065.... 86 Dithioerythritol ................................................................... D1320...... 9 DL-Dithiothreitol ................................................................. D1071.... 96 L-Dithiothreitol ................................................................... D1589.... 96 (+)-1,4-Di-O -tosyl-2,3-O -isopropylidene-D-threitol ............. D1622.... 96 (-)-1,4-Di-O -tosyl-2,3-O -isopropylidene-L-threitol .............. D1623.... 96 DMAP ................................................................................... D1450.. 107 DNS-SGN .............................................................................. D3690.... 86 DTE ..................................................................................... D1320...... 9 DL-DTT ................................................................................ D1071.... 96 L-DTT .................................................................................. D1589.... 96 Dulcitol ............................................................................... G0005.... 14

E EDAC ................................................................................... D1601.. 107 EDAC ................................................................................... D4029.. 107 EDC ..................................................................................... D1601.. 107 EDC ..................................................................................... D4029.. 107 EDCI .................................................................................... D1601.. 107 Emulsin from Almonds ....................................................... G0035.. 119 Endo-α Recombinant: from Bifidobacterium longum expressed in Escherichia coli ............................................... A1844.. 118 Endo-M Recombinant: from Mucor hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)] .. A1651.. 118 D-Erythorbic Acid ................................................................ A0520.... 95 meso -Erythritol.....................................................................E0021...... 9 D-Erythronic γ-Lactone ......................................................E0455...... 9 D-Erythronolactone ..............................................................E0455...... 9


321

Product Name Index-④ Esculin Sesquihydrate .........................................................E0024.... 25 3-O -Ethyl-L-ascorbic Acid .....................................................E0926.... 97 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide ............... D4029.. 107 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide Hydrochloride ................................................................... D1601.. 107 Ethylenediamine Anhydrous ...............................................E0077.. 108 Ethylenediamine Monohydrate ...........................................E0081.. 108 N -Ethyl-D-glucamine.............................................................E0923.... 97 4,6-O -Ethylidene-α-D-glucopyranose ..................................E0402.... 25 4,6-O -Ethylidene-α-D-glucose .............................................E0402.... 25 Etoposide .............................................................................E0675.... 25

F Fatty Acid Sucrose Ester ...................................................... S0112.. 100 N α-[(9H -Fluoren-9-ylmethoxy)carbonyl]L-serine tert -Butyl Ester .................................................... F0516.. 108 N α-[(9H -Fluoren-9-ylmethoxy)carbonyl]L-threonine tert -Butyl Ester .............................................. F0517.. 108 Fluoromethyl Phenyl Sulfone ............................................. F0341.. 108 Fluoromethylsulfonylbenzene ............................................ F0341.. 108 Fmoc-Ser[GalN3[46Bzd]-α]-Ot Bu ....................................... A1833.... 20 N α-Fmoc-L-serine tert -Butyl Ester....................................... F0516.. 108 Fmoc-Ser-Ot Bu .................................................................... F0516.. 108 N α-Fmoc-L-threonine tert -Butyl Ester ................................. F0517.. 108 Fmoc-Thr[GalN3[46Bzd]-α]-Ot Bu ....................................... A1832.... 20 Fmoc-Thr-Ot Bu ................................................................... F0517.. 108 4-Formylphenyl β-D-Allopyranoside .................................. F0542...... 7 2-Formylphenyl β-D-Glucopyranoside ............................... H0908.... 27 Forssman Pentaose MP Glycoside........................................ F0584.... 86 β-D-Fructofuranosyl O -α-D-Galactopyranosyl-(1-6)-O -αD-galactopyranosyl-(1-6)-α-D-glucopyranoside Hydrate ... S0397.... 84 β-D-Fructofuranosyl α-D-Xylopyranoside .......................... X0065.... 76 D-(-)-Fructose ..................................................................... F0060.... 10 L-(+)-Fructose ..................................................................... F0317.... 10 Fucα(1-2)Galβ(1-3)GalNAc-α-p NP (=H type 3 α-p NP Glycoside) ............................................ F0895.... 77 Fucα(1-2)Galβ(1-3)GalNAc-β-p NP (=H type 3 β-p NP Glycoside) ............................................ F0896.... 78 Fucα(1-2)Galβ(1-3)GlcNAc-β-p NP (=H type 1 β-p NP Glycoside) ............................................ F0894.... 78 Fucα(1-6)GlcNAc................................................................ F0897.... 67 α-L-Fucopyranose 1,2,3,4-Tetraacetate ............................ T2207.... 12 D-(+)-Fucose ........................................................................ D0049.... 11 L-(-)-Fucose ......................................................................... F0065.... 11 Fungitetraose Trihydrate ................................................... N0571.... 84

G Gal[246Ac,3All]-β-SPh ....................................................... P1680.... 19 Gal[2Ac,346Bn]β(1-3)GlcNPhth[46Bzd]-β-MP .................. G0374.... 67 Gal[2Ac,346Bn]-β-SPh ....................................................... P2078.... 18 Gal[2346Ac]β(1-3)GalN3[46Bzd]-β-MP ............................. G0330.... 67 Gal[2346Ac]β(1-4)Glc[236Ac]-β-MP................................. M1694.... 67 Gal[2346Ac]β(1-3)GlcN3[46Bzd]-β-MP ............................. G0309.... 67 Gal[2346Ac]β(1-3)GlcNPhth[46Bzd]-β-MP ....................... G0311.... 67 D-Galactal............................................................................ G0273.... 14 Galactinol Hydrate ............................................................. G0298.... 68 Galactitol ............................................................................ G0005.... 14 4-O -β-D-Galactopyranosyl-D-fructose .................................L0140.... 71 6-O -α-D-Galactopyranosyl-D-glucopyranose Monohydrate .. M0050.... 72 6-O -β-D-Galactopyranosyl-D-glucopyranose ....................... A2630.... 66 1-O -α-D-Galactopyranosyl-L-myo -inositol Hydrate ............ G0298.... 68 D-(+)-Galactosamine Hydrochloride .................................... G0007.... 20 D-(+)-Galactose Anhydrous................................................. G0008.... 14 L-(-)-Galactose .................................................................... G0267.... 14 β-D-Galactose Pentaacetate .............................................. G0247.... 18 α-D-Galacturonic Acid Hydrate ......................................... G0010.... 14 Gal[3All,246Bn]β(1-3)GlcNPhth[6Bn]-β-MP ..................... G0379.... 68 Gal[246Bn,3All]-β-SPh....................................................... P1660.... 18 Gal[26Bn]β(1-4)Glc[236Bn]-β-MP .................................... M1686.... 68 Gal[246Bn]β(1-4)Glc[236Bn]-β-MP .................................. M1727.... 68 Gal[236Bn]β(1-4)Glc[236Bn]-β-MP .................................. M1726.... 68 Gal[2346Bn]-β-SPh ............................................................ P1679.... 19 Galα(1-3)[Fucα(1-2)]Gal-β-PEG-trifluoroacetamide ....... B4172.... 77 Galα(1-4)Galβ(1-4)Glc-β-ethylamine .............................. G0402.... 79 Galα(1-4)Galβ(1-4)Glc-β-ethylazide ............................... G0403.... 79 Galβ(1-3)GalNAcβ(1-3)Galα(1-4)Galβ(1-4)Glc-β-p NP ... G0355.... 87 Galβ(1-3)GalNAc-α-p NP .................................................... G0375.... 68 Galβ(1-3)GalNAc-β-p NP .................................................... G0344.... 68 Galβ(1-3)GalNAc-α-Thr..................................................... G0340.... 69

Galβ(1-4)Glc-β-MP ............................................................ M1805.... 69 Galβ(1-3)GlcNAcβ(1-3)Galβ(1-4)Glc-β-p NP .................... G0348.... 83 Galβ(1-4)GlcNAcβ(1-3)Galβ(1-4)Glc-β-p NP .................... G0351.... 83 Galβ(1-3)[GlcNAcβ(1-6)]GalNAc-α-Thr ........................... G0343.... 78 Galβ(1-3)GlcNAc-β-p NP .................................................... G0420.... 69 GalNAcα(1-3)[Fucα(1-2)]Gal-β-PEG-trifluoroacetamide .. A2631.... 77 GalNAcβ(1-3)Galα(1-3)Galβ(1-4)Glc-β-p NP .................... G0380.... 83 GalNAcβ(1-3)Galα(1-4)Galβ(1-4)Glc-β-p NP .................... G0354.... 83 GalNAcα(1-3)GalNAcβ(1-3)Galα(1-4)Galβ(1-4)Glcβ MP Glycoside ................................................. F0584.... 86 GalNAcβ(1-3)GlcNAcβ-Ethylazide..................................... G0373.... 69 GalNAcβ(1-4)GlcNAcβ(1-3)GalNAcβ(1-4)GlcNAcβ-ethylazide ......................................................................L0237.... 84 GalNAcβ(1-3)GlcNAc-β-p NP .............................................. G0352.... 69 GalNAcβ(1-4)GlcNAc-β-p NP .............................................. G0356.... 69 Galβ(1-3)[Neu5Acα(2-6)]GalNAc-α-p NP .......................... G0377.... 78 Galβ(1-3)[Neu5Acα(2-6)]GalNAc-β-p NP .......................... G0345.... 78 Galβ(1-3)[Neu5Acα(2-6)]GlcNAc-β-p NP .......................... G0347.... 78 Galβ(1-4)[Neu5Acα(2-6)]GlcNAc-β-p NP .......................... G0353.... 78 Ganglioside GM3 (phyto-type) ............................................ G0422.... 79 Ganglioside GM1[d18:1, (Carbon-13)C16:0] ........................ G0421.... 87 Ganglioside GM3[d18:1, (Carbon-13)C16:0] ........................ G0419.... 79 Gb3-β-ethylamine .............................................................. G0402.... 79 Gb3-β-ethylazide ............................................................... G0403.... 79 Gb3-β-MP ............................................................................ M1767.... 79 Geniposide .......................................................................... G0385.... 25 Gentamicin Sulfate ............................................................. G0383.... 97 Gentiobiose......................................................................... G0026.... 69 GITC .................................................................................... A5514.... 34 GlcA[234Ac,6Me]-β-SPh .................................................... M1759.... 30 GlcA[3S]β(1-3)Galβ(1-4)GlcNAcβ(1-3)Galβ(1-4)Glc β-Ethylazide ..................................................................... H1333.... 87 GlcA[3S]β(1-3)Galβ(1-4)GlcNAcβ(1-2)Man α-Ethylazide ..................................................................... G0372.... 83 Glcβ(1-4)Glcβ(1-4)Glc ...................................................... C2795.... 77 Glcβ(1-4)Glcβ(1-4)Glcβ(1-4)Glc ...................................... C2796.... 83 Glcβ(1-4)Glcβ(1-4)Glcβ(1-4)Glcβ(1-4)Glc ...................... C2644.... 85 Glcβ(1-4)Glc-β-p NP .......................................................... N0867.... 74 N -GlcNAc-Biotin .................................................................. G0297.... 39 GlcNAcβ(1-4)[Fucα(1-6)]GlcNAc ...................................... G0423.... 79 GlcNAcβ(1-3)GalNAc-α-p NP .............................................. G0376.... 70 GlcNAcβ(1-3)GalNAc-α-Thr .............................................. G0341.... 70 GlcNAcβ(1-4)GlcNAc .......................................................... D4215.... 66 GlcNAcβ(1-3)[GlcNAcβ(1-6)]GalNAc-α-Thr ..................... G0342.... 79 GlcNAcβ(1-4)GlcNAcβ(1-4)GlcNAc.................................... T2912.... 82 GlcNAcβ(1-4)GlcNAcβ(1-4)GlcNAcβ(1-4)GlcNAc ............. T2910.... 84 GlcNAcβ(1-4)GlcNAcβ(1-4)GlcNAcβ(1-4)GlcNAcβ(1-4)GlcNAc .................................................................... P2027.... 89 GlcNAcβ(1-2)Manα-1-Ethylazide ...................................... G0337.... 70 GlcNAcβ(1-3)[Neu5Acα(2-6)]GalNAc-α-p NP .................... G0378.... 80 GlcNPhth[346Ac]β(1-3)Gal[246Bn]-β-MP ......................... G0299.... 70 GlcNPhth[36Bn,4Ac]-β-MP ................................................ M1834.... 40 D-Glucal .............................................................................. G0274.... 25 D-Glucamine........................................................................ G0252.... 97 Glucan from Black Yeast .................................................... G0331.... 93 Glucoamylase from Rhizopus (contains 50% Diatomaceous earth) .................................. M0035.. 118 α-1,6-Glucobiose .................................................................I0231.... 71 Glucoheptonic Acid Sodium Salt Dihydrate ........................ G0214.... 99 Gluconic Acid (contains Gluconolactone) (45-50% in Water) ............................................................. G0036.... 25 Gluconic Acid Anhydride ..................................................... G0039.... 25 Gluconic Acid Calcium Salt Monohydrate ........................... G0037.... 23 Gluconic Acid Copper(II) Salt .............................................. G0275.... 24 Gluconic Acid Iron(II) Salt Hydrate ..................................... G0038.... 28 Gluconic Acid δ-Lactone .................................................... G0039.... 25 Gluconic Acid Magnesium(II) Salt Hydrate.......................... G0276.... 28 Gluconic Acid Potassium Salt .............................................. G0040.... 33 Gluconic Acid Sodium Salt .................................................. G0041.... 33 Gluconic Acid Zinc(II) Salt Hydrate .................................... G0277.... 37 D-(+)-Glucono-1,5-lactone .................................................. G0039.... 25 β-D-Glucopyranose 1-Phosphate Disodium Salt ................. G0339.... 26 2-O -α-D-Glucopyranosyl-L-ascorbic Acid ............................ G0394.... 70 8-(β-D-Glucopyranosyl)-4',7-dihydroxyisoflavone ............. P1886.... 33 4-O -α-D-Glucopyranosyl-D-fructose Monohydrate ............. M1138.... 72 6-O -α-D-Glucopyranosyl-D-fructose Hydrate ..................... P1234.... 75 6-O -α-D-Glucopyranosyl-D-glucose .......................................I0231.... 71 2-(β-D-Glucopyranosyloxy)benzaldehyde .......................... H0908.... 27 7-(β-D-Glucopyranosyloxy)-4'-hydroxyisoflavone .............. D3920.... 24


322

Product Name Index-⑤ (1S )-1α-(β-D-Glucopyranosyloxy)-7-(hydroxymethyl)1,4aα,5,7aα-tetrahydrocyclopenta[c ]pyran4-carboxylic Acid Methyl Ester .......................................... G0385.... 25 D-Glucosamic Acid ............................................................... G0042.... 39 D-(+)-Glucosamine Hydrochloride ....................................... G0044.... 40 D-Glucosamine Oxime Hydrochloride ................................. G0045.... 40 D-Glucosaminic Acid ............................................................ G0042.... 39 D-(+)-Glucose ...................................................................... G0048.... 26 L-(-)-Glucose ....................................................................... G0226.... 26 β-D-Glucose (contains α-D-Glucose) ................................ G0047.... 26 Glucosecarboxylic Acid Sodium Salt Dihydrate .................. G0214.... 99 D-Glucose Diethyl Dithioacetal ........................................... G0259.... 26 D-Glucose Diethyl Mercaptal ............................................... G0259.... 26 Glucose Oxidase from Aspergillus niger ................................ G0050.. 118 α-D-Glucose Pentaacetate ................................................. G0225.... 32 β-D-Glucose Pentaacetate ................................................. P0028.... 32 D-Glucose 6-Phosphate Barium Salt Heptahydrate ............ G0052.... 26 Glucose 1-Phosphate Dipotassium Salt Dihydrate .............. G0053.... 26 D-Glucose 6-Phosphate Dipotassium Salt Hydrate ............. G0211.... 27 β-Glucosidase from Almonds ............................................ G0035.. 119 Glucotropaeolin Potassium Salt .......................................... G0397.... 27 D-Glucuronamide ................................................................ G0223.... 27 D-Glucuronic Acid ............................................................... G0302.... 27 D-Glucuronic Acid Lactone .................................................. G0055.... 27 D-Glucurono-6,3-lactone .................................................... G0055.... 27 DL-Glyceraldehyde Diethyl Acetal ....................................... G0216.... 97 N -Glycolylneuraminic Acid .................................................. G0336.... 59 Glycosynthase (Endo-M-N175Q) Recombinant: from Mucor hiemalis expressed in Escherichia coli ................ G0365.. 119 Glycyrrhizic Acid................................................................. G0150.... 70 Glycyrrhizic Acid Dipotassium Salt Hydrate ....................... G0270.... 67 Glycyrrhizic Acid Monoammonium Salt Hydrate ................ G0151.... 72 Glycyrrhizic Acid Trisodium Salt Hydrate........................... G0217.... 76 Glycyrrhizin ........................................................................ G0150.... 70 Glycyrrhizin Dipotassium Salt Hydrate .............................. G0270.... 67 Glycyrrhizin Monoammonium Salt Hydrate........................ G0151.... 72 Glycyrrhizin Trisodium Salt Hydrate .................................. G0217.... 76 Glyoxaline .............................................................................I0001.. 110 Goat Anti-Mouse IgG FITC Conjugate .................................. G0406.. 125 Goat Anti-Mouse IgG HRP Conjugate ................................... G0407.. 125 Goat Anti-Mouse IgM ........................................................... G0408.. 125 Goat Anti-Mouse IgM HRP Conjugate ................................... G0417.. 125 Goat Anti-Rabbit IgG HRP Conjugate ................................... G0418.. 125 L-(+)-Gulonic Acid γ-Lactone ............................................. G0235.... 44 L-Gulonolactone .................................................................. G0235.... 44 L-Gulose .............................................................................. G0239.... 44

H Hafnocene Dichloride ......................................................... H0914.. 109 Helicide............................................................................... F0542...... 7 Helicin ................................................................................ H0908.... 27 Heparin Sodium Salt from Hog intestine ............................ H0393.... 93 Hepta-O -acetyl Rutinose ..................................................... H0628.... 75 Heptakis(2,6-di-O -methyl)-β-cyclodextrin ........................ D1732.... 88 Heptasaccharide Glc4Xyl3 ................................................... H1041.... 87 Heptasaccharide Glc4Xyl3 ................................................... H1044.... 87 Hesperidin .......................................................................... H0049.... 70 N -Hexanoyl-D-glucosamine.................................................. H0118.... 40 Hexyldimethyloctylammonium Bromide ............................. H0989.. 109 HNK-1 Ethylazide ................................................................ H1333.... 87 HOBt Monohydrate ............................................................. H0468.. 109 α-Homonojirimycin............................................................ H1144.... 97 H type 1 β-p NP Glycoside .................................................. F0894.... 78 H type 3 α-p NP Glycoside .................................................. F0895.... 77 H type 3 β-p NP Glycoside .................................................. F0896.... 78 Hyaluronate Hexasaccharide .............................................. H1285.... 87 Hyaluronate Tetrasaccharide .............................................. H1284.... 84 Hyaluronic Acid from Bovine Vitreous Humor [Substrate for Hyaluronidase] ........................................... H0165.... 93 Hyaluronic Acid from Cockscomb ...................................... H0595.... 93 Hyaluronic Acid Potassium Salt from Cockscomb............... H0652.... 94 Hyaluronic Acid Sodium Salt from Cockscomb ................... H0603.... 94 Hydrazine Monohydrate ..................................................... H0172.. 109 Hydrazine Monohydrate (79%) ........................................... H0204.. 109 Hydrazine Acetate .............................................................. H1112.. 109 Hydrobromic Acid (30% in Acetic Acid, ca . 5.1mol/L) ........ H0182.. 109 Hydrogen Bromide (30% in Acetic Acid, ca . 5.1mol/L) [for Peptide research] ....................................................... H0182.. 109 Hydroquinone-β-D-glucoside ............................................. A0522.... 22

Hydroquinone Monomethyl Ether ....................................... M0123.. 111 4-Hydroxyanisole ................................................................ M0123.. 111 1-Hydroxybenzotriazole Monohydrate .............................. H0468.. 109 7-Hydroxycoumarin-6-yl β-D-Glucopyranoside Sesquihydrate.....................................................................E0024.... 25 2-(Hydroxymethyl)phenyl β-D-Glucopyranoside................. S0003.... 33 4-Hydroxyphenyl β-D-Glucopyranoside ............................. A0522.... 22 Hydroxypropyl-β-cyclodextrin .......................................... H0979.... 87

I D-Iditol ..................................................................................I0724.... 45 L-Iditol ..................................................................................I0725.... 45

Imidazole ..............................................................................I0001.. 110 Indican Hydrate ...................................................................I0017.... 27 3-Indole-D-glucoside Hydrate...............................................I0017.... 27 3-Indoxyl-D-glucoside Hydrate .............................................I0017.... 27 allo -Inositol ...........................................................................I0629.... 46 1D-chiro -Inositol ....................................................................I0632.... 46 1L-chiro -Inositol ....................................................................I0633.... 46 epi -Inositol ............................................................................I0628.... 46 muco -Inositol .........................................................................I0630.... 46 myo -Inositol ...........................................................................I0040.... 46 scyllo -Inositol .........................................................................I0631.... 46 1L-epi -2-Inosose ....................................................................I0634.... 47 Inulin.....................................................................................I0041.... 94 Invertose ...............................................................................I0043.... 97 Iodomethane (stabilized with Copper chip) ........................I0060.. 110 N -Iodosuccinimide.................................................................I0074.. 110 Iron(II) Gluconate Hydrate ................................................. G0038.... 28 D-Isoascorbic Acid ............................................................... A0520.... 95 Isomaltose .............................................................................I0231.... 71 Isomaltotriose .......................................................................I0329.... 80 Isomaltulose Hydrate ......................................................... P1234.... 75 Isomannide ...........................................................................I0406.... 98 (+)-5,6-O -Isopropylidene-L-ascorbic Acid .............................I0507.... 98 (4R ,5R )-(+)-2,3-O -Isopropylidene-1,4-di-O -tosyl-D-threitol .. D1622.... 96 (4S ,5S )-(-)-2,3-O -Isopropylidene-1,4-di-O -tosyl-L-threitol .. D1623.... 96 2,3-O -Isopropylidene-D-erythronolactone ............................I0454...... 9 1,2-O -Isopropylidene-α-D-glucofuranose .............................I0400.... 28 1,2-O -Isopropylidene-α-D-glucurono-6,3-lactone ................I0688.... 28 3,4-O -Isopropylidene-D-mannitol ..........................................I0489.... 49 (2R ,3R )-2,3-O -Isopropylidene-1,1,4,4-tetraphenyl1,2,3,4-butanetetrol ......................................................... B1614.... 95 (-)-2,3-O -Isopropylidene-1,1,4,4-tetraphenyl-L-threitol .... B1614.... 95 (+)-2,3-O -Isopropylidene-L-threitol ......................................I0376.... 98 (-)-2,3-O -Isopropylidene-D-threitol .......................................I0375.... 98 1,2-O -Isopropylidene-α-D-xylofuranose ...............................I0721.... 64 Isopropyl-β-D-thiogalactopyranoside ...................................I0328.... 14 Isopropyl 1-Thio-β-D-galactopyranoside ..............................I0328.... 14 Isosorbide .............................................................................I0407.... 98 Isosorbide 5-Mononitrate ......................................................I0403.... 98 Isosorbide 5-Nitrate ..............................................................I0403.... 98

K 1-Kestose ............................................................................ K0032.... 80

L LacDiNAc Dimer Ethylazide .................................................L0237.... 84 LacDiNAc MP Glycoside ....................................................... M1733.... 71 LacDiNAc(I) MP Glycoside.................................................... M1776.... 71 Lacβ(1-4)Lac-β-C10 ............................................................L0229.... 84 LacMP.................................................................................. M1805.... 69 LacMP 3'-OH, per OBn ......................................................... M1727.... 68 LacMP 4'-OH, per OBn ......................................................... M1726.... 68 LacMP 3'4'-OH, per OBn ...................................................... M1686.... 68 LacMP per OAc .................................................................... M1694.... 67 Lactobionic Acid (mixture of Acid form and Lactone form) ..L0005.... 71 Lactobionic Acid Calcium Salt Hydrate ...............................L0006.... 66 D-(+)-Lactose Monohydrate .................................................L0008.... 71 Lactulose .............................................................................L0140.... 71 Lectin, Fucose specific from Aspergillus oryzae (5mg/mL, PBS pH6.5) .........................................................L0169.. 120 Levulinic Acid ......................................................................L0042.. 110 D-(-)-Levulose ..................................................................... F0060.... 10 Lupeose Hydrate ................................................................. S0397.... 84 2,3-Lutidine .........................................................................L0063.. 110 2,4-Lutidine .........................................................................L0085.. 110 2,5-Lutidine .........................................................................L0065.. 110 2,6-Lutidine .........................................................................L0067.. 111


323

Product Name Index-⑥ 3,4-Lutidine .........................................................................L0066.. 111 3,5-Lutidine .........................................................................L0068.. 111 D-(-)-Lyxose.......................................................................... L0073.... 48 L-(+)-Lyxose ......................................................................... L0153.... 48

M Magenta-Gal (contains ca . 10% Ethyl Acetate) ................... B3469.... 13 Mag-Gal (contains ca . 10% Ethyl Acetate) .......................... B3469.... 13 Magnesium(II) Gluconate Hydrate ...................................... G0276.... 28 Maltitol................................................................................ M0797.... 72 Maltitol................................................................................ M0601.... 71 Maltoheptaose .................................................................... M1025.... 88 Maltohexaose ...................................................................... M1024.... 88 Maltopentaose .................................................................... M1023.... 88 D-(+)-Maltose Monohydrate ................................................ M0037.... 72 6-O -α-D-Maltosyl-β-cyclodextrin ...................................... M1219.... 88 Maltotetraose ...................................................................... M1022.... 84 D-(+)-Maltotriose Hydrate .................................................. M0677.... 80 Maltulose Monohydrate ...................................................... M1138.... 72 Man[2Bz,3All,46Bzd]β(1-4)GlcNPhth[36Bn]-β-MP ........... M2442.... 72 Manα(1-2)Manα(1-3)[Manα(1-6)Manα(1-6)]Manβ(1-4)GlcNAc ............................................................. M2439.... 88 Manneotetrose Hydrate ...................................................... S0397.... 84 D-Mannitol ........................................................................... M0044.... 49 L-Mannitol ........................................................................... M1084.... 49 D-Mannono-1,4-lactone....................................................... M0958.... 49 N ω-(β-D-Mannopyranosyl)-L-asparagine ............................. M2435.... 49 D-(+)-Mannose ..................................................................... M0045.... 50 L-(-)-Mannose ...................................................................... M1308.... 50 Mannose-6-phosphate Barium Salt Hydrate ....................... M0046.... 50 MEHQ .................................................................................. M0123.. 111 D-(+)-Melezitose Hydrate ................................................... M0049.... 80 D-(+)-Melibiose Monohydrate ............................................. M0050.... 72 Melitose Pentahydrate ....................................................... R0002.... 81 4-Methoxybenzaldehyde Dimethyl Acetal .......................... A1247.. 101 4-Methoxybenzyl Chloride (stabilized with Amylene) ....... M0676.. 111 Methoxymethyltrimethylsilane ........................................... M1264.. 111 4-Methoxyphenol ................................................................ M0123.. 111 4-Methoxyphenyl 3-O -(2-Acetamido-2-deoxyβ-D-galactopyranosyl)-2-acetamido-2-deoxyβ-D-glucopyranoside......................................................... M1776.... 71 4-Methoxyphenyl 4-O -(2-Acetamido-2-deoxyβ-D-galactopyranosyl)-2-acetamido-2-deoxyβ-D-glucopyranoside......................................................... M1733.... 71 4-Methoxyphenyl O -(5-Acetamido-3,5-dideoxy-D-glycero α-D-galacto -2-nonulopyranosonic Acid)-(2-3)β-D-galactopyranoside...................................................... N0791.... 73 4-Methoxyphenyl O -(5-Acetamido-3,5-dideoxy-D-glycero α-D-galacto -2-nonulopyranosonic Acid)-(2-6)β-D-galactopyranoside...................................................... N0792.... 73 4-Methoxyphenyl 2-O -Acetyl-3-O -allyl-4,6-O -benzylideneβ-D-glucopyranoside......................................................... M2065.... 28 4-Methoxyphenyl 4-O -Acetyl-3,6-di-O -benzyl-2-deoxy2-phthalimido-β-D-glucopyranoside ................................. M1834.... 40 4-Methoxyphenyl 3-O -(N -Acetyl-α-neuraminosyl)β-D-galactopyranoside...................................................... N0791.... 73 4-Methoxyphenyl 6-O -(N -Acetyl-α-neuraminosyl)β-D-galactopyranoside...................................................... N0792.... 73 4-Methoxyphenyl 3-O -Allyl-2-azido-4,6-O -benzylidene2-deoxy-β-D-galactopyranoside........................................ M1643.... 20 4-Methoxyphenyl 3-O -Allyl-2-azido-4,6-O -benzylidene2-deoxy-β-D-glucopyranoside........................................... M1638.... 40 4-Methoxyphenyl 3-O -Allyl-2-O -benzyl-4,6-O -benzylideneβ-D-galactopyranoside ...................................................... M1620.... 15 4-Methoxyphenyl 3-O -Allyl-6-O -benzyl-2-deoxy2-phthalimido-β-D-glucopyranoside ................................. M1604.... 40 4-Methoxyphenyl 3-O -Allyl-4,6-O -benzylidene-2-deoxy2-phthalimido-β-D-glucopyranoside ................................. M1598.... 40 4-Methoxyphenyl 3-O -Allyl-4,6-O -benzylideneβ-D-galactopyranoside...................................................... M1589.... 15 4-Methoxyphenyl 3-O -Allyl-4,6-O -benzylidene2-O -(4-methylbenzoyl)-β-D-galactopyranoside ................ M1590.... 15 4-Methoxyphenyl 3-O -Allyl-β-D-galactopyranoside ............ M1482.... 15 4-Methoxyphenyl 2-Amino-3,6-di-O -benzyl-2-deoxyβ-D-glucopyranoside......................................................... M1616.... 41 4-Methoxyphenyl 2-Azido-4,6-O -benzylidene-2-deoxyβ-D-glucopyranoside......................................................... M1637.... 41 4-Methoxyphenyl 2-Azido-3,6-di-O -benzyl-2-deoxyβ-D-glucopyranoside......................................................... M1617.... 41

4-Methoxyphenyl 2-O -Benzoyl-3,6-di-O -benzylβ-D-glucopyranoside......................................................... M2434.... 28 4-Methoxyphenyl 3-O -Benzyl-4,6-O -benzylidene-2-deoxy2-phthalimido-β-D-glucopyranoside ................................. M1609.... 41 4-Methoxyphenyl 3-O -Benzyl-4,6-O -benzylideneβ-D-glucopyranoside......................................................... M1640.... 28 4-Methoxyphenyl 3-O -Benzyl-2-deoxy-2-phthalimidoβ-D-glucopyranoside......................................................... M1610.... 41 4-Methoxyphenyl 3-O -Benzyl-β-D-galactopyranoside ........ M1725.... 15 4-Methoxyphenyl 3-O -Benzyl-β-D-glucopyranoside ........... M1641.... 29 4-Methoxyphenyl 4,6-O -Benzylidene-2-deoxy2-phthalimido-β-D-glucopyranoside ................................. M1479.... 41 4-Methoxyphenyl 4,6-O -Benzylideneβ-D-galactopyranoside...................................................... M1710.... 15 4-Methoxyphenyl 2,6-Bis-O -(4-methylbenzoyl)β-D-galactopyranoside...................................................... M1597.... 15 4-Methoxyphenyl 2,4-Di-O -benzoyl-3-O -benzyl-6-O (methyl 5-Acetamido-4,7,8,9-tetra-O -acetyl-3,5-dideoxyD-glycero -α-D-galacto -2-nonulopyranosonate)β-D-galactopyranoside ...................................................... M1761.... 73 4-Methoxyphenyl 2,4-Di-O -benzoyl-3-O -benzyl-6-O [methyl 5-(Acetoxyacetamido)-4,7,8,9-tetra-O -acetyl3,5-dideoxy-D-glycero -α-D-galacto -2-nonulopyranosonate]β-D-galactopyranoside ...................................................... M1763.... 74 4-Methoxyphenyl 3,6-Di-O -benzyl-2-deoxy-2-phthalimidoβ-D-glucopyranoside......................................................... M1615.... 41 4-Methoxyphenyl 2,6-Di-O -benzyl-β-D-galactopyranoside .. M1634.... 16 4-Methoxyphenyl 4-O -(2,6-Di-O -benzylβ-D-galactopyranosyl)-2,3,6-tri-O -benzylβ-D-glucopyranoside......................................................... M1686.... 68 4-Methoxyphenyl 2,6-Di-O -benzyl-3,4-O -isopropylideneβ-D-galactopyranoside...................................................... M1633.... 16 4-Methoxyphenyl β-D-Galactopyranoside .......................... M1481.... 16 4-Methoxyphenyl O -(α-D-Galactopyranosyl)-(1-4)O -(β-D-galactopyranosyl)-(1-4)-β-D-glucopyranoside ...... M1767.... 79 4-Methoxyphenyl 4-O -(β-D-Galactopyranosyl)β-D-glucopyranoside......................................................... M1805.... 69 4-Methoxyphenyl β-D-Glucopyranoside ............................. M1631.... 29 4-Methoxyphenyl O -(5-Hydoxyacetamido-3,5-dideoxyD-glycero -α-D-galacto -2-nonulopyranosonic Acid)-(2-6)β-D-galactopyranoside...................................................... N0794.... 74 4-Methoxyphenyl O -(5-Hydroxyacetamido-3,5-dideoxyD-glycero -α-D-galacto -2-nonulopyranosonic Acid)-(2-3)β-D-galactopyranoside...................................................... N0793.... 74 4-Methoxyphenyl 3-O -[N -(Hydroxyacetyl)-α-neuraminosyl]β-D-galactopyranoside ....................................................... N0793.... 74 4-Methoxyphenyl 6-O -[N -(Hydroxyacetyl)-α-neuraminosyl]β-D-galactopyranoside ....................................................... N0794.... 74 4-Methoxyphenyl 3,4-O -Isopropylidene-2,6-bisO -(4-methylbenzoyl)-β-D-galactopyranoside .................... M1596.... 16 4-Methoxyphenyl 3,4-O -Isopropylideneβ-D-galactopyranoside...................................................... M1593.... 16 4-Methoxyphenyl 3,4-O -Isopropylidene6-O -(4-methylbenzoyl)-β-D-galactopyranoside ................ M1594.... 16 4-Methoxyphenyl α-D-Mannopyranoside............................ M1646.... 50 4-Methoxyphenyl 2,3,4,6-Tetra-O -acetylβ-D-galactopyranoside...................................................... M1477.... 16 4-Methoxyphenyl 3-O -(2,3,4,6-Tetra-O -acetylβ-D-galactopyranosyl)-2-azido-4,6-O -benzylidene2-deoxy-β-D-galactopyranoside........................................ G0330.... 67 4-Methoxyphenyl 3-O -(2,3,4,6-Tetra-O -acetylβ-D-galactopyranosyl)-2-azido-4,6-O -benzylidene2-deoxy-β-D-glucopyranoside........................................... G0309.... 67 4-Methoxyphenyl 3-O -(2,3,4,6-Tetra-O -acetylβ-D-galactopyranosyl)-4,6-O -benzylidene-2-deoxy2-phthalimido-β-D-glucopyranoside ................................. G0311.... 67 4-Methoxyphenyl 4-O -(2,3,4,6-Tetra-O -acetylβ-D-galactopyranosyl)-2,3,6-tri-O -acetylβ-D-glucopyranoside......................................................... M1694.... 67 4-Methoxyphenyl 2,3,4,6-Tetra-O -acetylβ-D-glucopyanoside .......................................................... M1630.... 29 4-Methoxyphenyl 2,3,4,6-Tetra-O -acetylα-D-mannopyranoside ...................................................... M1647.... 50 4-Methoxyphenyl 2,3,4,6-Tetra-O -benzylβ-D-galactopyranoside...................................................... M1588.... 17 4-Methoxyphenyl 2,4,6-Tri-O -acetyl-3-O -benzylβ-D-glucopyranoside......................................................... M1642.... 29 4-Methoxyphenyl 3,4,6-Tri-O -acetyl-2-deoxy2-phthalimido-β-D-glucopyranoside ................................. M1480.... 42


324

Product Name Index-⑦ 4-Methoxyphenyl 3-O -(3,4,6-Tri-O -acetyl-2-deoxy2-phthalimido-β-D-glucopyranosyl)-2,4,6-tri-O -benzylβ-D-galactopyranoside...................................................... G0299.... 70 4-Methoxyphenyl 2,4,6-Tri-O -benzoyl-3-O (methyl 5-Acetamido-4,7,8,9-tetra-O -acetyl-3,5-dideoxyD-glycero -α-D-galacto -2-nonulopyranosonate)β-D-galactopyranoside...................................................... N0846.... 74 4-Methoxyphenyl 2,4,6-Tri-O -benzoyl-3-O (methyl 5-Acetoxyacetamido-4,7,8,9-tetra-O -acetyl-3,5dideoxy-D-glycero -α-D-galacto -2-nonulopyranosonate)β-D-galactopyranoside...................................................... N0816.... 74 4-Methoxyphenyl 2,3,6-Tri-O -benzylβ-D-galactopyranoside...................................................... M2104.... 17 4-Methoxyphenyl 2,4,6-Tri-O -benzylβ-D-galactopyranoside.......................................................... M1592.... 17 4-Methoxyphenyl 4-O -(2,3,6-Tri-O -benzylβ-D-galactopyranosyl)-2,3,6-tri-O -benzylβ-D-glucopyranoside......................................................... M1726.... 68 4-Methoxyphenyl 4-O -(2,4,6-Tri-O -benzylβ-D-galactopyranosyl)-2,3,6-tri-O -benzylβ-D-glucopyranoside......................................................... M1727.... 68 Methyl 5-Acetamido-3,5-dideoxyD-glycero -D-galacto -2-nonulopyranosonate ......................... A1821.... 59 Methyl 5-Acetamido-2,4,7,8,9-penta-O -acetyl3,5-dideoxy-D-glycero -D-galacto -2-nonulopyranosonate ..... M1707.... 60 Methyl 5-Acetamido-4,7,8,9-tetra-O -acetyl3,5-dideoxy-D-glycero -D-galacto -2-nonulopyranosonate ....... A1822.... 60 Methyl 5-Acetamido-4,7,8,9-tetra-O -acetyl-3,5-dideoxy2-S -phenyl-2-thio-D-glycero -D-galacto -2-nonulopyranosylonate... M1706.... 59 Methyl 5-Acetamido-7,8,9-tri-O -acetyl-5-N ,4-O -carbonyl3,5-dideoxy-2-S -phenyl-2-thio-D-glycero -β-D-galacto 2-nonulopyranosylonate .................................................... M2319.... 60 Methylamine (ca . 40% in Water, ca . 12mol/L) .................... M0137.. 111 Methyl β-D-Arabinopyranoside .......................................... M1019...... 8 Methyl 4,6-O -Benzylidene-α-D-glucopyranoside ................ M1125.... 29 Methyl 5-N ,4-O -Carbonyl-3,5-dideoxy-2-S -phenyl-2-thioD-glycero -β-D-galacto -2-nonulopyranosylonate .................. M2329.... 60 Methyl-β-cyclodextrin (mixture of several Methylated)... M1356.... 88 Methyl-β-cyclodextrin (2,6-Di-O -methyl- and partially 2,3,6-Tri-O -methyl- mixture) ............................................ D1732.... 88 Methyl 2,3-Di-O -benzoyl-4,6-O -benzylideneα-D-glucopyranoside......................................................... M2013.... 29 Methyl 2,3:4,6-Di-O -benzylidene-α-D-mannopyranoside .. M2061.... 50 Methyl α-L-Fucopyranoside ............................................... M1051.... 11 Methyl β-L-Fucopyranoside ............................................... M1050.... 11 Methyl α-D-Galactopyranoside Monohydrate .................... M1047.... 17 Methyl β-D-Galactopyranoside ........................................... M1035.... 17 N -Methyl-D-glucamine ......................................................... M0227.... 98 N -Methyl-D-glucamine Hydrochloride [for Buffer] ............. M0713.... 99 Methyl α-D-Glucopyranoside .............................................. M0228.... 29 Methyl β-D-Glucopyranoside Hemihydrate ....................... M0709.... 30 Methyl (1S )-1α-(β-D-Glucopyranosyloxy)7-(hydroxymethyl)-1,4aalpha,5,7aalphatetrahydrocyclopenta[c ]pyran-4-carboxylate ................... G0385.... 25 Methyl α-D-Glucoside......................................................... M0228.... 29 Methyl β-D-Glucoside Hemihydrate .................................. M0709.... 30 Methylhydrazine ................................................................. M0558.. 112 Methyl Iodide (stabilized with Copper chip) ........................I0060.. 110 Methyl α-D-Mannopyranoside ............................................ M0368.... 50 α-Methyl-D-mannoside ....................................................... M0368.... 50 Methyl α-D-Mannoside ....................................................... M0368.... 50 Methyl (Phenyl 5-Acetamido-4,7,8,9-tetra-O -acetyl-3,5dideoxy-2-thio-D-glycero -D-galacto -2-nonulopyranosid)onate .. M1706.... 59 Methyl (Phenyl 5-Acetamido-7,8,9-tri-O -acetyl5-N ,4-O -carbonyl-3,5-dideoxy-2-thio-D-glycero β-D-galacto -2-nonulopyranosid)onate ............................... M2319.... 60 Methyl (Phenyl 5-N ,4-O -Carbonyl-3,5-dideoxy-2-thioD-glycero -β-D-galacto -2-nonulopyranosid)onate ................ M2329.... 60 Methyl (Phenyl 7,8,9-Tri-O -acetyl-5-N ,4-O -carbonyl-3,5dideoxy-2-thio-D-glycero -β-D-galacto -2-nonulopyranosid)onate .. M2330.... 60 Methyl (Phenyl 2,3,4-Tri-O -acetyl-1-thioβ-D-glucopyranosid)uronate ............................................. M1759.... 30 Methyl β-D-Ribofuranoside ................................................ M1965.... 56 Methyl 1,2,3,4-Tetra-O -acetyl-β-D-glucopyranuronate ..... M1868.... 30 Methyl 1,2,3,4-Tetra-O -acetyl-β-D-glucuronate ................ M1868.... 30 Methyl 2,3,4,6-Tetra-O -acetyl-1-thioβ-D-glucopyranoside......................................................... M1682.... 30 Methyl 2,3,4,6-Tetra-O -acetyl-1-thioα-D-mannopyranoside (contains ca . 5% β-isomer) ......... M1501.... 51

Methyl 2,3,4,6-Tetra-O -pivaloyl-D-mannopyranoside ......... M2102.... 51 Methyl 7,8,9-Tri-O -acetyl-5-N ,4-O -carbonyl-3,5-dideoxy2-S -phenyl-2-thio-D-glycero -β-D-galacto 2-nonulopyranosylonate .................................................... M2330.... 60 Methyl 3,4,6-Tri-O -acetyl-2-deoxy-2-phthalimido-1-thioβ-D-glucopyranoside......................................................... M1649.... 42 Methyl 2,3,4-Tri-O -acetyl-1-thio-β-L-fucopyranoside ........ M1626.... 11 Methyl 2,3,6-Tri-O -benzoyl-α-D-galactopyranoside ........... M1933.... 17 Methyl 2,3,4-Tri-O -benzoyl-α-D-glucopyranoside .............. M1487.... 30 Methyl 2,3,4-Tri-O -benzyl-α-D-glucopyranoside ................ M1488.... 30 Methyl 2,3,4-Tri-O -benzyl-1-thio-β-L-fucopyranoside ....... M1628.... 11 Methyl Tributylstannyl Sulfide ............................................ M1494.. 112 Methyltrichlorosilane .......................................................... M0450.. 112 Methyl Trifluoroacetate ...................................................... T0680.. 112 Methyl-β-D-xylopyranoside ................................................ M1253.... 64 Monoammonium Glycyrrhizinate Hydrate ......................... G0151.... 72 Mono-6-O -mesitylenesulfonyl-γ-cyclodextrin ................... M1212.... 89 Mono-2-O -(p -toluenesulfonyl)-β-cyclodextrin ................... M1741.... 89 Morph-DAST ........................................................................ M1573.. 112 Morpholinosulfur Trifluoride ............................................... M1573.. 112

N NANA Hydrate .................................................................... A0639.... 59 Naringenin 7-Rhamnoglucoside Hydrate ............................ N0073.... 72 Naringin Hydrate................................................................ N0073.... 72 NBS ..................................................................................... B0656.. 102 Neohesperidin Dihydrochalcone Hydrate .......................... N0675.... 73 Neu5Ac Hydrate ................................................................. A0639.... 59 Neu5Acα(2-3)Gal-β-ethylamine ....................................... N0947.... 73 Neu5Acα(2-6)Gal-β-ethylamine ....................................... N0948.... 73 Neu5Acα(2-3)Galβ(1-4)[Fucα(1-3)]GlcNAcβ(1-3)Galβ(1-4)Glc ........................................................................... S0849.... 89 NeuAcα(2-3)Galβ(1-4)Glc-ceramide (phyto-type) ........... G0422.... 79 Neu5Acα(2-3)Galβ(1-4)GlcNAc-β-ethylamine ................. N0949.... 80 Neu5Acα(2-6)Galβ(1-4)GlcNAc-β-ethylamine ................. N0950.... 80 Neu5Acα(2-3)Galβ(1-4)GlcNAcβ(1-3)Galβ(1-4)Glc-ceramide ........................................................... S0910.... 90 Neu5Acα(2-3)Galβ(1-3)GlcNAc-β-p NP ............................. N0853.... 81 Neu5Acα(2-3)Galβ(1-4)GlcNAc-β-p NP ............................. N0854.... 81 Neu5Acα(2-6)Galβ(1-3)GlcNAc-β-p NP ............................. N0855.... 81 Neu5Acα(2-6)Galβ(1-4)GlcNAc-β-p NP ............................. N0856.... 81 Neu5Acα(2-3)Galβ(1-4)Glc-β-p NP ................................... N0860.... 81 Neu5Acα(2-3)Galβ MP Glycoside ...................................... N0791.... 73 Neu5Acα(2-6)Galβ MP Glycoside ...................................... N0792.... 73 Neu5Acα(2-6)GalNAc-α-p NP ............................................. N0890.... 73 Neu5Ac[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP............. M1761.... 73 Neu5Ac[1Me,4789Ac]α(2-3)Gal[246Bz]-β-MP .................. N0846.... 74 Neu5Ac[1Me,4789Ac]-SPh .................................................. M1706.... 59 Neu5Gc ............................................................................... G0336.... 59 Neu5GcAc[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP ........ M1763.... 74 Neu5GcAc[1Me,4789Ac]α(2-3)Gal[246Bz]-β-MP .............. N0816.... 74 Neu5Gcα(2-3)Galβ MP Glycoside ...................................... N0793.... 74 Neu5Gcα(2-6)Galβ MP Glycoside ...................................... N0794.... 74 Neu5Troc[1Me,4789Ac]α(2-3)Gal[26Bn]-β-MP................. M1729.... 74 NIS.........................................................................................I0074.. 110 Nistose Trihydrate.............................................................. N0571.... 84 2-Nitrobenzoic Acid ............................................................ N0155.. 112 4-Nitrophenyl 2-Acetamido-2-deoxy3-O -(2-acetamido-2-deoxy-β-D-galactopyranosyl)β-D-glucopyranoside......................................................... G0352.... 69 4-Nitrophenyl 2-Acetamido-2-deoxy4-O -(2-acetamido-2-deoxy-β-D-galactopyranosyl)β-D-glucopyranoside......................................................... G0356.... 69 4-Nitrophenyl 2-Acetamido-2-deoxyβ-D-galactopyranoside...................................................... N0865.... 20 4-Nitrophenyl 2-Acetamido-2-deoxy3-O -(β-D-galactopyranosyl)-β-D-galactopyranoside ......... G0344.... 68 4-Nitrophenyl 2-Acetamido-2-deoxy3-O -(β-D-galactopyranosyl)-β-D-glucopyranoside ............ G0420.... 69 4-Nitrophenyl 2-Acetamido-2-deoxyβ-D-glucopyranoside......................................................... N0866.... 42 4-Nitrophenyl N -Acetyl-β-D-galactosaminide..................... N0865.... 20 4-Nitrophenyl N -Acetyl-β-D-glucosaminide........................ N0866.... 42 4-Nitrophenyl β-D-Cellobioside ......................................... N0867.... 74 4-Nitrophenyl α-L-Fucopyranoside .................................... N0392.... 11 4-Nitrophenyl β-D-Fucopyranoside .................................... N0774.... 12 2-Nitrophenyl β-D-Galactopyranoside [Substrate for β-D-Galactosidase] .................................... N0418.... 17


325

Product Name Index-⑧ 4-Nitrophenyl α-D-Galactopyranoside [Substrate for α-D-Galactosidase] .................................... N0492.... 18 4-Nitrophenyl β-D-Galactopyranoside [Substrate for β-Galactosidase] ....................................... N0616.... 18 4-Nitrophenyl α-D-Glucopyranoside [Substrate for α-D-Glucosidase] ....................................... N0493.... 30 4-Nitrophenyl β-D-Glucopyranoside Monohydrate [Substrate for β-D-Glucosidase] ....................................... N0235.... 31 4-Nitrophenyl α-D-Glucopyranosiduronic Acid .................. N0857.... 31 4-Nitrophenyl β-D-Glucopyranosiduronic Acid .................. N0618.... 31 4-Nitrophenyl α-D-Glucuronide ......................................... N0857.... 31 4-Nitrophenyl β-D-Glucuronide [Substrate for β-Glucuronidase] ...................................... N0618.... 31 4-Nitrophenyl α-D-Mannopyranoside [Substrate for α-Mannosidase] ......................................... N0619.... 51 2-Nitrophenyl β-D-Xylopyranoside..................................... N0868.... 64 4-Nitrophenyl β-D-Xylopyranoside [Substrate for β-Xylosidase] ............................................ N0620.... 64 Nonasaccharide Glc4Xyl3Gal2 .............................................. N0693.... 89 Nonyl β-D-Glucopyranoside ............................................... N0909.... 31 Nystose Trihydrate ............................................................. N0571.... 84

O 6-OAc PtdGlc(di-acyl Chain) ............................................... A2638.... 31 Octa-O -acetyl α-D-Cellobiose ............................................. C0861.... 66 Octa-O -acetyl D-(+)-Saccharose ........................................... S0052.... 75 Octa-O -acetyl D-(+)-Sucrose ................................................. S0052.... 75 2,3,4,6,7,8,9,10-Octahydropyrimido[1,2-a ]azepine.......... D1270.. 105 n -Octyl β-D-Glucopyranoside [for Biochemical Research] .. O0355.... 31 n -Octyl β-D-Glucopyranoside ............................................. O0232.... 31 ONPG................................................................................... N0418.... 17 Ouabain Octahydrate .......................................................... S0091.... 55 4-Oxovaleric Acid.................................................................L0042.. 110

Phenyl 2,4,6-Tri-O -acetyl-3-O -allyl-1-thioβ-D-glucopyranoside......................................................... P1736.... 32 Phenyl 3,4,6-Tri-O -acetyl-2-deoxy-1-thio-2(2,2,2-trichloroethoxyformamido)-β-D-galactopyranoside .. P1642.... 21 Phenyl 3,4,6-Tri-O -acetyl-2-deoxy-1-thio-2(2,2,2-trichloroethoxyformamido)-β-D-glucopyranoside .. P1866.... 42 Phenyl 2,3,4-Tri-O -benzyl-1-thio-β-L-fucopyranoside ....... P1842.... 12 Phlorizin Hydrate............................................................... P0248.... 33 Phosphoric Acid Diphenyl Ester .......................................... P0801.. 107 Phytic Acid (ca . 50% in Water, ca . 1.1mol/L) ..................... P0409.... 47 Phytin ................................................................................. P0410.... 47 PNPG ................................................................................... N0616.... 18 Polyarabinogalactan from Larch Wood .............................. A1328.... 91 Poly-β-cyclodextrin (Cross-linked by Epichlorohydrin) .... P0977.... 89 Potassium Gluconate........................................................... G0040.... 33 Potassium Hyaluronate from Cockscomb ........................... H0652.... 94 D-Psicose ............................................................................. P1699.... 54 L-Psicose ............................................................................. P1778.... 54 Puerarin .............................................................................. P1886.... 33 N -(4-Pyridyl)dimethylamine ................................................ D1450.. 107 Pyrocarbonic Acid Di-tert -butyl Ester ................................. D1547.. 105 Pyrocarbonic Acid Di-tert -butyl Ester (ca . 30% in Dioxane) .. D3878.. 105 Pyrocarbonic Acid Di-tert -butyl Ester (ca . 30% in Tetrahydrofuran) ............................................. D3879.. 105 Pyrocarbonic Acid Di-tert -butyl Ester (ca . 30% in Toluene).. D3880.. 105

Q (+)-epi -Quercitol ................................................................. Q0070.... 47 (+)-proto -Quercitol .............................................................. Q0071.... 47 (-)-vibo -Quercitol ................................................................ Q0069.... 47

R D-(+)-Raffinose Pentahydrate ............................................. R0002.... 81

Rebaudioside A ................................................................... R0095.... 99

P Paeonolide .......................................................................... P1879.... 75 Paeonoside.......................................................................... A2253.... 22 Palatinose Hydrate ............................................................. P1234.... 75 6-O -Palmitoyl-L-ascorbic Acid ............................................. A0540.... 99 Panose ................................................................................ P0927.... 81 Pectin from Citrus.............................................................. P0024.... 94 Pectinase from Aspergillus niger .......................................... P0026.. 119 2,4,7,8,9-Penta-O -acetylN -acetylneuraminic Acid Methyl Ester ............................... M1707.... 60 Penta-N -acetylchitopentaose .............................................. P2027.... 89 N ,N ',N '',N ''',N ''''-Pentaacetylchitopentaose .......................... P2027.... 89 Penta-O -acetyl-β-D-galactopyranose ................................. G0247.... 18 Penta-O -acetyl-α-D-glucopyranose .................................... G0225.... 32 Penta-O -acetyl-β-D-glucopyranose .................................... P0028.... 32 Pentaacetyl-β-D-glucosamine ............................................ A1459.... 38 Pentaacetyl-α-D-glucose .................................................... G0225.... 32 Pentaacetyl-β-D-glucose .................................................... P0028.... 32 1,2,3,4,6-Penta-O -acetyl-D-mannopyranose....................... P1514.... 51 2L-2,3,4,6/5-Pentahydroxycyclohexanone ...........................I0634.... 47 1,2,3,4,6-Penta-O -pivaloyl-D-mannopyranose .................... P1803.... 51 Phenyl 2-Acetamido-2-deoxy-α-D-glucopyranoside ........... P0130.... 42 Phenyl N -Acetyl-α-D-glucosaminide ................................... P0130.... 42 Phenyl 2-O -Acetyl-3,4,6-tri-O -benzyl-1-thioβ-D-galactopyranoside...................................................... P2078.... 18 Phenyl 3-O -Allyl-2,4,6-tri-O -benzyl-1-thioβ-D-galactopyranoside...................................................... P1660.... 18 Phenyl N -Benzyl-2-amino-4,6-O -benzylidene2-N ,3-O -carbonyl-2-deoxy-1-thio-β-D-glucopyranoside.... P1762.... 42 Phenyl 4,6-O -Benzylidene-1-thio-β-D-glucopyranoside ..... P1475.... 32 Phenyl 2-Deoxy-1-thio-2-(2,2,2-trichloroethoxyformamido)β-D-galactopyranoside ....................................................... P1643.... 21 Phenyl β-D-Galactopyranoside ........................................... P1326.... 18 Phenyl α-D-Glucopyranoside.............................................. P1346.... 32 Phenyl β-D-Glucopyranoside Hydrate ............................... P0178.... 32 Phenyl α-D-Glucoside ........................................................ P1346.... 32 Phenyl β-D-Glucoside Hydrate .......................................... P0178.... 32 Phenyl Mercaptan ............................................................... B0041.. 101 Phenyl Sulfone .................................................................... P0231.. 107 Phenyl Sulfoxide ................................................................. D1002.. 108 Phenyl 2,3,4,6-Tetra-O -acetyl-1-thio-β-D-galactopyranoside .. P1477.... 18 Phenyl 2,3,4,6-Tetra-O -acetyl-1-thio-β-D-glucopyranoside .. P1476.... 32 Phenyl 2,3,4,6-Tetra-O -benzyl-1-thio-β-D-galactopyranoside .. P1679.... 19 Phenyl 2,4,6-Tri-O -acetyl-3-O -allyl-1-thioβ-D-galactopyranoside...................................................... P1680.... 19

L-(+)-Rhamnose Monohydrate ............................................ R0013.... 55 D-(+)-Rhodeose ................................................................... D0049.... 11 L-(-)-Rhodeose .................................................................... F0065.... 11

Ribitol ................................................................................. A0171.... 56 β-D-Ribofuranose 1-Acetate 2,3,5-Tribenzoate................. R0067.... 56 β-L-Ribofuranose 1-Acetate 2,3,5-Tribenzoate ................. R0080.... 56 β-D-Ribofuranose 1,2,3,5-Tetraacetate ............................. R0066.... 57 D-(+)-Ribonic Acid γ-Lactone ............................................. R0063.... 56 D-(+)-Ribono-1,4-lactone .................................................... R0063.... 56 β-D-Ribopyranose 1,2,3,4-Tetraacetate ............................ R0065.... 57 D-(-)-Ribose ......................................................................... R0025.... 57 L-Ribose .............................................................................. R0068.... 57 α-D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt ............... R0082.... 57 β-D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt ............... R0083.... 57 Ribose-5-phosphate Barium Salt Hydrate .......................... R0026.... 57 Rose-Gal .............................................................................. C2371.... 13 Rutin Trihydrate................................................................. R0035.... 75 Rutinose .............................................................................. R0062.... 75 Rutinose Heptaacetate ....................................................... H0628.... 75

S D-(+)-Saccharose .................................................................. S0111.... 76

Saccharose Fatty Acid Ester ................................................. S0112.. 100 D-(+)-Saccharose Octaacetate .............................................. S0052.... 75

Salicin .................................................................................. S0003.... 33 Salicylaldehyde-β-D-glucoside ........................................... H0908.... 27 Salmon-Gal .......................................................................... C2371.... 13 Saponin ................................................................................ S0019.... 99 Schardinger α-Dextrin ....................................................... C0776.... 85 Schardinger β-Dextrin ....................................................... C0777.... 85 Schardinger β-Dextrin ....................................................... C0900.... 86 Schardinger γ-Dextrin ....................................................... C0869.... 86 SEM-Chloride (stabilized with Diisopropylethylamine) ...... C1339.. 104 SGP ...................................................................................... S0523.... 89 SG-p NP ................................................................................ N0913.... 86 Sialylglycopeptide ................................................................ S0523.... 89 Sialyl Lewis X-Lactose .......................................................... S0849.... 89 Sialyl Neolactotetraosylceramide (=Sialyl nLc4 Cer) ........... S0910.... 90 Sialyl nLc4 ............................................................................ S0910.... 90 Sinigrin Hydrate .................................................................. S0156.... 33 Sinigrin................................................................................. S0903.... 33 Sodium 6-O -Acetyl-β-D-glucopyranosyl (R )-2-(Icosanoyloxy)-3-(stearoyloxy)propyl Phosphate ..... A2638.... 31 Sodium L-Ascorbate ............................................................ A0539.... 99 Sodium Glucoheptonate Dihydrate .................................... G0214.... 99


326

Product Name Index-⑨ Sodium Gluconate ............................................................... G0041.... 33 Sodium Hyaluronate from Cockscomb ............................... H0603.... 94 D-Sorbitol ............................................................................. S0065.... 34 D-Sorbose ............................................................................. S0390.... 61 L-(-)-Sorbose ........................................................................ S0066.... 61 Stachyose Hydrate .............................................................. S0397.... 84 6-O -Stearoyl-L-ascorbic Acid ............................................... A0617.... 99 Streptomycin Sulfate ........................................................... S0585.. 100 g -Strophanthin Octahydrate ............................................... S0091.... 55 Sucralose ............................................................................. S0839.... 75 D-(+)-Sucrose ....................................................................... S0111.... 76 Sucrose Fatty Acid Ester ...................................................... S0112.. 100 D-(+)-Sucrose Octaacetate ................................................... S0052.... 75 Sulfur Trifluoride Diethylamine Complex ........................... D1868.. 106 Swertiamarin ....................................................................... S0897.... 34 Synaptase from Almonds .................................................... G0035.. 119

T D-Tagatose ........................................................................... T1501.... 62 L-Tagatose ........................................................................... T2535.... 62 D-Talitol............................................................................... T1398.... 63 L-Talitol ............................................................................... T2536.... 63 D-(+)-Talose ......................................................................... T0869.... 63 L-(-)-Talose .......................................................................... T1767.... 63

TATM ................................................................................... T2307.... 52 TBDMSCl .............................................................................. B0995.. 103 TBDMS Triflate .................................................................... T1525.. 103 TBSCl................................................................................... B0995.. 103 TBS Triflate ......................................................................... T1525.. 103 4,7,8,9-Tetra-O -acetyl-N -acetylneuraminic Acid Methyl Ester .. A1822.... 60 1,2,4,6-Tetra-O -acetyl-3-O -allyl-β-D-glucopyranose .......... T2449.... 34 1,3,4,6-Tetra-O -acetyl-2-azido-2-deoxyα-D-galactopyranose......................................................... T1731.... 21 1,3,4,6-Tetra-O -acetyl-2-azido-2-deoxyα-D-glucopyranose............................................................ T1732.... 42 1,3,4,6-Tetra-O -acetyl-2-azido-2-deoxyβ-D-glucopyranose............................................................ T2196.... 43 1,3,4,6-Tetra-O -acetyl-2-azido-2-deoxyα-D-mannopyranose ......................................................... T1733.... 53 Tetra-N -acetylchitotetraose ................................................ T2910.... 84 N ,N ',N '',N '''-Tetraacetylchitotetraose ................................... T2910.... 84 1,3,4,6-Tetra-O -acetyl-2-deoxy-2-phthalimidoβ-D-glucopyranose............................................................ T2047.... 43 1,2,3,4-Tetra-O -acetyl-α-L-fucopyranose .......................... T2207.... 12 2,3,4,6-Tetra-O -acetyl-α-D-galactopyranosyl 2,2,2-Trichloroacetimidate ............................................... T2295.... 19 2,3,4,6-Tetra-O -acetyl-α-D-glucopyranosyl Bromide (stabilized with CaCO3)...................................................... T1961.... 34 2,3,4,6-Tetra-O -acetyl-α-D-glucopyranosyl Fluoride ......... T1995.... 34 2,3,4,6-Tetra-O -acetylβ-D-glucopyranosyl Isothiocyanate [for HPLC Labeling] .. A5514.... 34 2,3,4,6-Tetra-O -acetylβ-D-glucopyranosyl 2,2,2-Trichloroacetimidate ............... T2491.... 34 1,2,3,4-Tetra-O -acetylβ-D-glucopyranuronic Acid Methyl Ester .......................... M1868.... 30 1,2,3,4-Tetra-O -acetyl-β-D-glucuronic Acid Methyl Ester .. M1868.... 30 1,3,4,6-Tetra-O -acetyl-β-D-mannopyranose ...................... T1459.... 51 2,3,4,6-Tetra-O -acetyl-D-mannopyranosyl Fluoride ........... T2567.... 51 2,3,4,6-Tetra-O -acetyl-PtdGlc(di-acyl Chain) ..................... P2079.... 35 2,3,4,6-Tetra-O -acetyl-PtdGlc(mono-acyl Chain)................ P2080.... 35 Tetra-O -acetyl-β-D-ribofuranose ........................................ R0066.... 57 Tetra-O -acetyl-β-D-ribopyranose ....................................... R0065.... 57 1,3,4,6-Tetra-O -acetyl-2-O -(trifluoromethanesulfonyl)β-D-mannopyranose ......................................................... T2307.... 52 2,3,4,6-Tetra-O -benzoyl-D-glucopyranose .......................... T2020.... 35 2,3,4,6-Tetra-O -benzoylβ-D-glucopyranosyl Isothiocyanate [for HPLC Labeling] .. A5515.... 35 2,3,4,6-Tetra-O -benzoyl-α-D-glucopyranosyl p -Trifluoromethylbenzylthio-N -(p -trifluoromethylphenyl) formimidate ...................................................................... T1991.... 35 2,3,4,6-Tetra-O -benzoyl-D-mannopyranose ........................ T2056.... 52 2,3,4,6-Tetra-O -benzyl-D-glucopyranose ............................ T1914.... 35 2,3,4,6-Tetra-O -benzyl-D-glucopyranosyl Fluoride ............. T1971.... 35 2,3,4,6-Tetra-O -benzyl-α-D-glucopyranosyl Fluoride ........ T1922.... 36 2,3,4,6-Tetra-O -benzyl-β-D-glucopyranosyl Fluoride ........ T1923.... 36 2,3,4,6-Tetra-O -benzyl-α-D-glucopyranosyl N ,N ,N ',N '-Tetramethylphosphorodiamidate (ca . 20% in Benzene) ......................................................... T2197.... 36

2,3,4,6-Tetra-O -benzyl-α-D-glucopyranosyl p -Trifluoromethylbenzylthio-N -(p -trifluoromethylphenyl) formimidate ...................................................................... T1999.... 36 Tetrabutylammonium p -Nitrophenoxide ............................. T2669.. 112 2,3,4,6-Tetra-O -pivaloyl-D-mannopyranosyl Fluoride ......... T2568.... 52 4,4'-Thiodiphenol ............................................................... D1356.. 102 Thiophenol.......................................................................... B0041.. 101 L-Threitol ............................................................................ T1647.. 100 TMCS ................................................................................... C0306.. 104 Topiramate .......................................................................... T2755.... 10 D-(+)-Trehalose Anhydrous................................................. T0832.... 76 D-(+)-Trehalose Dihydrate .................................................. T0331.... 76 2,3,4-Tri-O -acetyl-β-L-arabinopyranosyl 2,2,2-Trichloroacetimidate ............................................... T2695...... 8 Tri-N -acetylchitotriose ........................................................ T2912.... 82 N ,N ',N ''-Triacetylchitotriose ................................................ T2912.... 82 Triacetyl-β-cyclodextrin .................................................... T1844.... 90 3,4,6-Tri-O -acetyl-2-deoxy-D-glucopyranose ...................... T1931.... 36 3,4,6-Tri-O -acetyl-2-deoxy-2-phthalimidoβ-D-glucopyranosyl 2,2,2-Trichloroacetimidate ............... T2615.... 43 1,2,3-Tri-O -acetyl-5-deoxy-β-D-ribofuranose .................... T2607.... 58 Tri-O -acetyl-D-galactal ........................................................ T1734.... 19 Tri-O -acetyl-D-glucal ........................................................... T1596.... 36 1,3,5-Tri-O -benzoyl-α-D-ribofuranose ............................... T2641.... 58 3,4,6-Tri-O -benzyl-2-deoxy-D-galactopyranose .................. T1932.... 19 3,4,6-Tri-O -benzyl-2-deoxy-D-glucopyranose ..................... T1933.... 36 Tri-O -benzyl-D-galactal ....................................................... T1858.... 19 Tri-O -benzyl-D-glucal .......................................................... T1859.... 37 Tributyl(methylthio)tin ....................................................... M1494.. 112 Trichloro(methyl)silane ...................................................... M0450.. 112 Triethylammonium (R )-2-Hydroxy3-(stearoyloxy)propyl 2,3,4,6-Tetra-O -acetylβ-D-glucopyranosyl Phosphate ......................................... P2080.... 35 Triethylammonium (R )-2-(Icosanoyloxy)3-(stearoyloxy)propyl 2,3,4,6-Tetra-O -acetylβ-D-glucopyranosyl Phosphate ......................................... P2079.... 35 Triethylenediamine............................................................. D0134.. 104 Trifluoroacetic Acid Methyl Ester........................................ T0680.. 112 N -Trifluoroacetyl-D-glucosamine ......................................... T0973.... 43 Trifluoromethanesulfonic Acid tert -Butyldimethylsilyl Ester .. T1525.. 103 Trifluoromethanesulfonic Acid Copper(II) Salt .................... T1292.. 104 3',5,7-Trihydroxy-4'-methoxyflavone 7-Rutinoside ............ D3908.... 66 6-O -(Triisopropylsilyl)-D-galactal ......................................... T1935.... 19 α,α,4-Trimethoxytoluene ................................................. A1247.. 101 Trimethylchlorosilane ......................................................... C0306.. 104 Trimethylsilyl Chloride ....................................................... C0306.. 104 2-(Trimethylsilyl)ethoxymethyl Chloride (stabilized with Diisopropylethylamine) ........................... C1339.. 104 Trimethylsilylmethyl Methyl Ether ..................................... M1264.. 111 Trisodium Glycyrrhizinate Hydrate .................................... G0217.... 76 D-(+)-Turanose .................................................................... T0542.... 76

V N -Valeryl-D-glucosamine ..................................................... V0011.... 43 Vitamin C ............................................................................ A0537.... 95 Vitamin C Sodium Salt ......................................................... A0539.... 99 Vitamin P ............................................................................ H0049.... 70

X Xanthan Gum ...................................................................... X0048.... 94 X-Gal ................................................................................... B3201.... 13 XLLG Glc4Xyl3Gal2 ............................................................... N0693.... 89 XXXG Glc4Xyl3 ..................................................................... H1041.... 87 XXXG Glc4Xyl3 ..................................................................... H1044.... 87 Xylitol ................................................................................. X0018.... 64 Xylobiose ............................................................................ X0067.... 76 Xyloglucan Heptasaccharide Glc4Xyl3 ................................. H1041.... 87 Xyloglucan Heptasaccharide Glc4Xyl3 ................................. H1044.... 87 Xyloglucan Nonasaccharide Glc4Xyl3Gal2 ............................ N0693.... 89 4-O -β-D-Xylopyranosyl-D-xylose ......................................... X0067.... 76 D-(+)-Xylose ........................................................................ X0019.... 64 L-(-)-Xylose ......................................................................... X0021.... 65 Xylosucrose ......................................................................... X0065.... 76

Z Zinc(II) Gluconate Hydrate ................................................. G0277.... 37 Zymosan [Immunological Reagent] .....................................Z0008.... 94


327

328

Appendix

付録

Basic Structures of Glycolipids / 糖脂質の基本構造 ......................................330 Basic Structures of Glycoproteins / 糖タンパク質の基本構造 ......................331 Basic Structures of Proteoglycans / プロテオグリカンの基本構造 ..............332 The Physical Properties of the Typical Organic Solvents・ Freezing Mixtures / おもな有機溶剤の物性・冷却剤とその最低温度 ..............333 Preparation of Reagents and Solutions / おもな試薬溶液の調製法 ...........334 Pressure-Temperature Nomograph / 沸点換算図表....................................338

329

Basic Structures of Glycolipids


330

Basic Structures of Glycoproteins


331

Basic Structures of Proteoglycans


332

The Physical Properties of the Typical Organic Solvents 1) Organic Solvents Methanol (MeOH) Ethanol (EtOH) Propanol (n -PrOH) Isopropyl Alcohol (i -PrOH) Butanol (BuOH) Isobutyl Alcohol (i -BuOH) sec -Butyl Alcohol (s -BuOH) tert -Butyl Alcohol (t -BuOH) Ethylene Glycol 1,2-Dimethoxyethane (Glyme) Diethyl Ether (Et2O) Diisopropyl Ether (i -Pr2O) Acetic Acid (AcOH) Ethyl Acetate (AcOEt) Acetic Anhydride (Ac2O) Tetrahydrofuran (THF) 1,4-Dioxane Acetone Ethyl Methyl Ketone Carbon Tetrachloride (CCl4) Chloroform (CHCl3) Dichloromethane (CH2Cl2) 1,2-Dichloroethane (ClCH2CH2Cl) Benzene (C6H6) Toluene o -Xylene Cyclohexane Pentane Hexane Heptane Acetonitrile (CH3CN) Nitromethane (CH3NO2) Dimethylformamide (DMF) Hexamethylphosphoric Triamide (HMPA) Triethylamine (Et3N) Pyridine (Py) Dimethyl Slufoxide (DMSO) Carbon Disulfide (CS2) a) It doesn't form azeotropic mixture

bp（°C）

mp（°C）

64.5 78.3 97.2 82.2 117.7 107.9 99.5 82.3 197.5 84.5 34.4 68.5 117.9 77.1 140.0 66.0 101.3 56.1 79.6 76.6 61.2 39.6 83.5 80.1 110.6 144.4 80.7 36.1 68.7 98.4 81.6 101.2 153 233 89.6 115.3 189.0 46.2

-97.7 -114.5 -126.2 -88.0 -88.6 -108 -114.7 25.6 -12.6 -69 -116 -85.5 16.7 -83.6 -73.1 -108.4 11.8 -94.7 -86.7 -22.8 -63.5 -94.9 -35.7 5.5 -95.0 -25.2 6.7 -129.7 -95.3 -90.6 -43.8 -28.6 -60.4 7.2 -114.7 -41.6 18.5 -111.6

d（20/4°C）

Compatibility with Water（°C） Miscibility with Waterb) （weight ％ of solvents）

0.791 0.789 0.804 0.785 0.810 0.802 0.807 0.781 1.114 0.869 0.714 0.724 1.050 0.901 1.083 0.889 1.034 0.790 0.805 1.594 1.489 1.326 1.252 0.879 0.867 0.880 0.779 0.626 0.659 0.684 0.782 1.138 0.949 1.027 0.728 0.983 1.100 1.263

ー a) 78.2(96.0) 87.7(71.7) 80.1(88.0) 92.7(57.5) 89.8(67) 87.0(73.2) 79.7(88.2) ー a) 77.4(89.9) 34.2(98.7) 62.2(95.5) ー a) 70.4(91.5)

○ ○ ○ ○ △ △ △ ○ ○ ○ × c) × ○ × c)

63.4(93.3) 87.8(82) ー a) 73.4(88.7) 66(95.9) 56.1(97.8) 38.1(98.5) 72(91.8) 69.3(91.2) 85(79.8) 93.5(50.1) 69.0(91) 34.6(98.6) 61.6(94.4)

○ ○ ○ △ × × × × × × × × × × × ○ × ○ ○ ○ ○ △ ×

76.7(84.2) 83.6(76.4) ー a)

93.6(58.7) ー a) 42.6(97.2)

b) ○：freely miscible △：partially miscible × ：practically immiscible (solubility : less than 1%)

c) highly soluble in water

Example of combination of recrystallization solvents The crystals are obtained from the solution of single or more than one solvent. In the two solvent system, solvent A and B should be miscible : when solubility is A > B, it is desirable that the boiling point is A < B and the density is A > B.

Freezing Mixtures Freezing mixtures Ice Ethylene Glycol / CO2 Ice(100) / NH4Cl (25) Ice(100) / NaCl(33) Carbon Tetrachloride / N2 Carbon Tetrachloride / CO2 Ice(100) / EtOH (100) Acetonitrile / N2 Ice(100) / CaCl2 (150)

Temp. （°C） 0 -15 -15 -21 -23 -23 -30 -41 -49

2)

Freezing mixtures Chloroform / N2 Chloroform / CO2 Ethanol / CO2 Ether / CO2 Acetone / CO2 Methanol / N2 n-Pentane / N2 N2

Temp. （°C） -63 -63 -72 -77 -78 -98 -131 -180

References 1）"Yuki Kagaku Jikken no Tebiki 1", editors : T. Goto, T. Shiba, T. Matsuura, Kagaku Dojin 2）"Shinhan Kiso Yuki Kagaku Jikken", K. Hata, K. Watanabe, Maruzen


333

Preparation of Reagents and Solutions ■Concentration of Liquid Acids and Bases: Common Commercial Strength Substance

Formula

MW

Hydrochloric Acid Sulfuric Acid Nitric Acid Perchloric Acid

HCl H2SO4 HNO3 HClO4

36.46 98.08 63.01 100.46

Phosphoric Acid

H3PO4

98.00

Acetic Acid Aqueous Ammonia

CH3COOH NH4OH

60.05 35.05

Concentration

Concentration

(mol/L) 12 18 15 9.4 14.8 15.7 17.4 15

(%) 35∼37 > 95 60∼62 60∼62 85 89 99.5 28

Specific Gravity 1.18 1.84 1.38 1.54 1.70 1.73 1.05 0.90

Modified from JIS (Japanese Industrial Standard) K 0050“General rules of chemical analysis”

Initial Concentration of Ammonium Sulfate (%)

■The Amount of Ammonium Sulfate to be Added to Give the Desired Final Concentration at 25℃

0 10 20 25 30 33 35 40 45 50 55 60 65 70 75 80 90

10

20

25

30

56

114 57

144 86 29

176 118 59 30

S. Englard, S. Seifter,

Final Concentration of Ammonium Sulfate (%) 33 35 40 45 50 55 60 65 70 Ammonium Sulfate (solid) to be added (g) to 1L 196 209 243 277 313 351 390 430 472 137 150 183 216 251 288 326 365 406 78 91 123 155 189 225 262 300 340 49 61 93 125 158 193 230 267 307 19 30 62 94 127 162 198 235 273 12 43 74 107 142 177 214 252 31 63 94 129 164 200 238 31 63 97 132 168 205 32 65 99 134 171 33 66 101 137 33 67 103 34 69 34

. 1990, , 285-300; W. I. Wood, , 3rd ed., Springer-Verlag, New York, 1994, p.346.


334

. 1976,

75

80

90

100

516 449 382 348 314 292 278 245 210 176 141 105 70 35

561 494 424 390 356 333 319 285 250 214 179 143 107 72 36

662 592 520 485 449 426 411 375 339 302 264 227 190 153 115 77

767 694 619 583 546 522 506 469 431 392 353 314 275 237 198 157 79

, 250; R. K. Scopes,

■Buffer Solution １． Phosphate Buffer A. 0.2M NaH2PO4 • H2O（Sodium Diydrogenphosphate Monohydrate; FW 137.99）27.6g/L H2O B. 0.2M Na2HPO4 • 7H2O（Disodium Hydrogenphosphate Heptahydrate; FW 268.07）53.6g/L H2O Mix solution A and B in the proportions indicated shown below, then adjust the final volume to 200mL with deionized water. Adjust the final pH using a sensitive pH meter. pH (25ºC) NaH2PO4 (mL) Na2HPO4 (mL)

5.8 92.0 8.0

6.0 87.7 12.3

6.2 81.5 18.5

6.4 73.5 26.5

6.6 62.5 37.5

6.8 51.0 49.0

7.0 39.0 61.0

7.2 28.0 72.0

7.4 19.0 81.0

7.6 13.0 87.0

7.8 8.5 91.5

8.0 5.3 94.7

. 1955, , 138.

G. Gomori,

２．Tris-HCl Buffer A. 0.1M Tris (Tris(hydroxymethyl)aminomethane); MW 121.14）12.1g/L H2O B. 0.1M HCl (Hydrochloric Acid); Dilute commercial concentrated hydrochloric acid to 1/120 with deionized water. Mix 50mL of solution A and indicated volume of solution B and adjust the final volume to 100mL with deionized water. Adjust the final pH using a sensitive pH meter. pH (25ºC) HCl (mL)

7.2 44.7

7.4 42.0

7.5 40.3

7.6 38.5

7.8 34.5

8.0 29.2

8.2 22.9

8.4 17.2

8.5 14.7

8.6 12.4

8.8 8.5

9.0 8.4 8.1

9.1 8.5 8.2

9.2 8.6 8.3

9.3 8.7 8.4

Temperature dependency of the pH of Tris buffer 4℃ 25℃ 37℃

8.1 7.5 7.2

8.2 7.6 7.3

8.3 7.7 7.4

8.4 7.8 7.5

8.5 7.9 7.6

8.6 8.0 7.7

8.7 8.1 7.8

J. Sambrook, D. W. Russell, 2001, Vol.3, p. A1.2.

8.8 8.2 7.9

8.9 8.3 8.0

9.4 8.8 8.5

3rd. ed, Cold Spring Harbor Laboratory Press, New York,

３．Acetate Buffer A. 0.1M AcOH (Acetic Acid), 5.8mL/L B. 0.1M NaOAc (Sodium Acetate, anhydrous; FW 82.03) 8.2g /L H2O or (Sodium Acetate Trihydrate; FW 136.08) 13.6g/L H2O Mix solution A and B in the proportions indicated shown below, then adjust the final volume to 100mL with deionized water. Adjust the final pH using a sensitive pH meter. pH (25ºC) AcOH (mL) NaOAc (mL)

3.6 46.3 3.7

4.0 41.0 9.0

4.4 30.5 19.5

4.8 20.0 30.0

5.0 14.8 35.2

5.2 10.5 39.5

5.6 4.8 45.2


335

■Visualizing Reagents for Thin-Layer Chromatography1,2) Reagent

Product Code / Recipe

Treatment

Spot Color

I0604 (place some crystals in a chamber)

Place the plate in the chamber.

Brown

General organic compounds

Sulfuric Acid

Dilute with water (50∼98%)

Spray the solution and heat the plate at 110∼130℃

Brown ∼ Black


Phosphomolybdic Acid

P1484; The prepared solution may be diluted with ethanol 2∼4 fold.

Spray the solution and heat the plate at 110℃

Green to brown spot on yellow background


-Anisaldehyde

A1674


Depends on the compound: violet, gray, blue, green


Ceric Ammonium Molybdate

C1794


Ninhydrin

N0094 (Spray) N0719 (Solution)


Dragendorff’ s Reagent

p-Dimethylamino-

General organic compounds Pink ∼ yellow

Amino acids, primary, secondary amines

(Solution A) Dissolve 1.7g Spray the solution. bismuth(III) nitrate, 20g tartaric acid in 80mL water; (Solution B) Dissolve 16g potassium iodide in 40mL water; (Stock Solution) Mix equal parts of A and B; (Spray Solution) Dissolve 10g tartaric acid in 50mL water and add 10mL to the stock solution.

Orange

Tertiary amines, quaternary ammonium salts (alkaloids)

Dissolve D0645 or D1495 1g in ethanol 50mL and conc. HCl 50mL.

Spray the solution and warm the plate

Yellow

Amines

D2968

Spray the solution.

Reddish orange

Aldehydes, Ketones

Bromocresol Green B2401

Spray the solution.

Yellow spots on green to blue background

Carboxylic acids, Sulfonic Acids

benzaldehyde 2,4-Dinitrophenylhydrazine

Spray the solution. (Stock Solution) Dissolve 0.1g P0603 in 100mL water; (Spray Solution) Mix 1mL of the stock solution to the mixture of 100mL acetone-water (4:1 v/v) 3)

Primuline

1)

2006,

Pale blue to yellow Lipids under UV light

, 15.

2) H. Jork, W. Funk, W. Fishcer, & H. Wimmer, in

, ed. by H. Jork,

Wiley, New York, 1989, Vol. 1A; W. Funk, W. Fischer, H. Wimmer, H. Jork, in , ed. by H. Jork, Wiley, New York, 1994, Vol. 1B. 3) T. White, S. Bursten, D. Federighi, R. A. Lewis, E. Nudelman,

. 1998,


336

Target Compounds

Iodine

, 109.

■Solvent Strength in Chromatography Solvent Hexane Cyclohexane Diisopropyl Ether Toluene Diethyl Ether Dichloromethane Tetrahydrofuran Acetone

Strength Parameter εº 0.01 0.04 0.28 0.29 0.38 0.40 0.45 0.56

Solvent Dioxane Ethyl Acetate Acetonitrile Pyridine 2-Propanol Ethanol Methanol Acetic Acid

Strength Parameter εº 0.56 0.58 0.65 0.71 0.82 0.88 0.95 »1

º is an adsorption free energy of the solvent, is the gas constant, is εº = Δ º/2.3/ S：where, Δ thermodynamic temperature. s is an area of the solvent molecule around the absorbent. The values are obtained in absorption chromatography by using alumina. L. R. Snyder, in

, Marcel Dekker, 1968.


337

Pressure-Temperature Nomograph

●

How to calculate the bp under atmospheric pressure from bp under reduced pressure ①

Connect a degree on the line C and its corresponding bp on the line A under reduced pressure using a straight line. ② An intersection found by step ① on the line B serves as an approximate bp in atmospheric pressure. *This nomograph applies to nonassociated solvent. Since the bp obtained from this nomograph is an approximate value, it is not an exact bp. Reference：Science of Petroleum, Vol.II. p.1281 (1938).


338

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茨城県キシダ化学㈱つくば営業所伊勢久㈱つくば営業所㈱テービック東海ケミー㈱筑波営業所

300-0326 300-1231 300-2307 300-2406

稲敷郡阿見町大字星の里13-2 牛久市猪子町字原992-532 つくばみらい市板橋3060-9 つくばみらい市福岡2504-1

029-833-6011 029-870-1111 0297-58-3406 0297-52-4817


340

関東地区・東京地区岩井化学薬品㈱筑波支店中山商事㈱筑波営業所㈱タナカつくば営業所純正化学㈱筑波営業所片山化学工業㈱筑波営業所筑波家田化学㈱不二化学薬品㈱つくば営業所茨城半井化学㈱中山商事㈱下館営業所東海ケミー㈱中山商事㈱水戸営業所伊勢久㈱鹿島営業所中山商事㈱鹿島営業所東海ケミー㈱鹿島営業所中山商事㈱東海ケミー㈱北部営業所

300-2635 300-2651 300-3261 304-0031 305-0005 305-0821 305-0041 305-0074 308-0113 311-4165 312-0063 314-0115 314-0121 314-0252 317-0075 319-1418

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栃木県アズサイエンス㈱北関東支店中山商事㈱栃木営業所

321-0901 322-0026

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0286-61-5616 0289-60-7871

群馬県高信化学㈱㈲共愛テクノサイエンス家田ケミカル㈱群馬営業所㈲共栄化学

370-0072 370-0073 371-0846 376-0023

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千葉県㈱薬研創栄科学㈱薬研社柏営業東海ケミー㈱東葛営業㈱メディセ伊勢久㈱千葉営業京葉ケミー広島和光㈱千葉営業純正化学㈱千葉営業

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260-0843 262-0006 277-0831 277-0873 279-0024 290-0046 290-0056 290-0056 299-0242

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101-0032 101-0032 101-0036 101-0041

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化学品㈱東京支学薬品化学


341

東京地区・関東地区金剛薬品㈱東京支店㈱イトーキヨス薬品㈱眞光化学㈱ナカライテスク㈱東京営業所家田化学薬品㈱栄光科学㈱関東化学㈱国産化学㈱岩井化学薬品㈱和光純薬工業㈱東京支店昭和化学㈱米山薬品工業㈱東京支店中野化学㈱久木田薬品工業㈱中外薬品工業㈱日化産商事㈱山田化学薬品㈱東新化成㈱不二化学薬品㈱東京営業所㈱高長㈱藤本理化家田化学㈱（本郷）㈲山本薬品商会理科研㈱東京支店㈱カーク東京営業所㈱十條合成化学研究所日進化成㈱日理化学㈱㈱宮川商店新陽化成㈱㈱ミカミキシダ化学㈱東京支店アズサイエンス㈱東京営業所広島和光㈱東京営業所西尾工業㈱東光化成㈱正晃㈱東京支店東都化学工業㈱宮田化学㈱㈲高橋藤吉商店東邦薬品㈱宮崎化学薬品㈱東京試薬販売㈱北辰化学㈱㈲勝見化学片山化学工業㈱東京営業所㈱高長多摩営業所㈱日栄東海尾崎理化㈱多摩営業所

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千代田区神田錦町1丁目5番地中央区日本橋馬喰町1-6-3吉野第一ビル8階中央区日本橋浜町3-34-8 中央区日本橋本石町4-5-6 中央区日本橋本石町4-2-16 日本橋本石町トーセイビル中央区日本橋室町4-3-4オフィス家田室町中央区日本橋室町4-6-7 中央区日本橋室町2-2-1室町東ビルディング中央区日本橋本町3-1-3 中央区日本橋本町3-2-10 中央区日本橋本町4-5-13 中央区日本橋本町4-3-8 中央区日本橋本町4-2-12 中央区日本橋本町4-13-10日本橋中野ビル中央区日本橋本町4-2-10 中央区日本橋本町4-6-2 中央区日本橋本町4-11-6 中央区日本橋本町3-2-14山一大野ビル5F 中央区日本橋本町4-5-15 中央区日本橋小伝馬町16-9 文京区本駒込5-1-4 文京区向丘1-9-22 文京区本郷2-9-4 文京区本郷1-8-18岡戸ビル文京区本郷3-44-2 文京区本郷4-37-17大間ビル1F 北区滝野川3-84-2 足立区千住河原町11-5 足立区扇2-2-8 墨田区石原4-17-7 墨田区錦糸1-4-3若山ビル墨田区東向島5-4-12 江東区新大橋2-11-8 江東区佐賀1-18-8佐賀町MDビル4F 品川区北品川5-8-26 品川区小山4-5-20 世田谷区新町2-34-2 新宿区若葉3-10-10正晃新宿ビル豊島区巣鴨3-39-4 豊島区上池袋2-8-14 豊島区千早1-17-8 板橋区本町36-8 板橋区小豆沢3-1-30 板橋区桜川2-24-1 練馬区豊玉中3-10-7 練馬区大泉町1-48-14 武蔵野市吉祥寺本町1-31-11 KSビル706号室国立市富士見台3-22-7 小平市小川東町4-6-7 八王子市長沼町200-6

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神奈川県ナカライテスク㈱神奈川営業所理科研㈱神奈川営業所尾崎理化㈱横浜営業所理科研㈱鶴見営業所横浜家田化学㈱純正化学㈱横浜営業所伊勢久㈱神奈川営業所

222-0033 226-0025 226-0028 230-0033 230-0051 242-0029 243-0018

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342

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243-0812 252-0153 254-0002

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343

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601-8343 604-0854 604-0855 606-8171 607-8225 610-0343

京都市南区吉祥院稲葉町31-1 京都市中京区二条通烏丸東入仁王門町21 京都市中京区二条通烏丸西入東玉屋町498 京都市左京区一乗寺西水干町17 京都市山科区勧修寺西北出町10 京田辺市大住池ノ端66-5

075-661-3591 075-231-2248 075-251-1723 075-711-7117 075-593-4711 0774-65-2521

大阪府㈱アズバイオ不二化学薬品㈱キシダ化学㈱林純薬工業㈱和光純薬工業㈱米山薬品工業㈱大阪営業課片山化学工業㈱三栄化工㈱重松貿易㈱関東化学㈱大阪支店㈱関薬双葉化学薬品㈱太洋㈱

530-0043 530-0044 540-0029 540-0037 540-8605 541-0045 541-0045 541-0045 541-0047 541-0048 550-0003 550-0025 554-0024

大阪市北区天満3-5-8 大阪市北区東天満2-6-11 大阪市中央区本町橋3-1 大阪市中央区内平野町3-2-12 大阪市中央区道修町3-1-2 大阪市中央区道修町2-3-11 大阪市中央区道修町2-5-10 大阪市中央区道修町1-3-6 大阪市中央区淡路町2-2-5 大阪市中央区瓦町2-5-1 大阪市西区京町堀1-12-30 大阪市西区九条南4-13-18 大阪市此花区島屋4-3-24

06-6351-5351 06-6358-0981 06-6946-8062 06-6910-7338 06-6203-3748 06-6231-3555 06-6201-3391 06-6231-1964 06-6231-6146 06-6231-1672 06-6445-0215 06-6583-2834 06-6465-0573


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近畿地区・中国地区㈱ダイトー片山化学工業㈱池田営業所ナカライテスク㈱大阪営業所八洲薬品㈱不二化学薬品㈱高槻営業所八洲薬品㈱京阪奈営業所佐々木化学薬品㈱東大阪営業所八洲薬品㈱堺営業所竹内化学㈱大阪営業所

555-0025 563-0024 564-0015 567-0085 569-0063 574-0057 581-0056 592-8333 598-0002

大阪市西淀川区姫里2-2-22 池田市鉢塚1-9-14 吹田市幸町23-1 茨木市彩都あさぎ7-7-18彩都バイオヒルズセンター内高槻市南庄所町1-5 大東市新田西町3-10 八尾市南太子堂4-3-11 堺市西区浜寺石津町西1-4-20 泉佐野市中庄809-18

06-4808-8038 072-763-1920 06-6381-3621 072-640-1265 072-671-1080 072-870-2711 0729-94-0061 072-244-1368 0724-61-0052

兵庫県広瀬化学薬品㈱㈱多次商店不二化学薬品㈱尼崎営業所㈱シマヤ広瀬化学薬品㈱兵庫西支店播磨薬品㈱

650-0046 653-0015 661-0962 672-8075 674-0074 675-0025

神戸市中央区港島中町2-2-2 神戸市長田区菅原通2-4 尼崎市額田町3-1 姫路市飾磨区思案橋60番地明石市魚住町清水字井桶田加古川市尾上町養田1575

078-303-3807 078-575-7985 06-6499-3191 0792-34-1001 078-942-2511 0794-24-2536

和歌山県竹内化学八洲薬品㈱和歌山営業㈱ダイトー和歌山営業竹内化学㈱紀南営業

㈱所所所

640-8131 640-8303 640-8324 646-0011

和歌山市弁財天丁63 和歌山市鳴神746-3 和歌山市吹屋町3-36-1 田辺市新庄町東跡之浦2744-74

073-424-2321 073-473-5951 073-433-8648 0739-26-0315

鳥取県鳥取サイエンス㈱㈲友田大洋堂鳥取営業所㈱林薬品

680-0841 680-0862 683-0003

鳥取市吉方温泉3-110 鳥取市雲山147-4 米子市皆生3-11-3

0857-23-5651 0857-22-4156 0859-33-3061

島根県㈱宮㈲友

品堂

690-0017 690-0047

松江市西津田1-5-29 松江市嫁島町13-34

0852-21-0279 0852-24-3456

岡山県広島和光㈱岡山営業所高塚ライフサイエンス㈱岡山薬品工業㈱片山化学工業㈱岡山営業所

700-0971 700-8577 701-2155 703-8236

岡山市北区野田5-11-31 岡山市北区今1-3-9 岡山市北区中原551 岡山市中区国富1-11-3

086-241-0771 086-241-5221 086-275-0666 086-271-6511

広島県広島和光㈱福山営業所山本薬品㈱米山薬品工業㈱広島営業所広島和光㈱広島営業所広島和光㈱東広島営業所中国ケミー㈱

721-0926 730-0805 733-0007 735-0024 739-0046 739-0263

福山市大門町4-16-43 広島市中区十日市町1-4-29 広島市西区大宮3-7-4 安芸郡府中町緑ケ丘6-40 東広島市鏡山3-12-26ハナヤマビル101号東広島市志和流通1番85

084-943-2720 082-291-8931 082-537-0290 082-285-6225 0824-31-3511 0824-33-5152

山口県広島和光㈱岩国営業所キシダ化学㈱山陽営業所田中藍㈱徳山営業所広島和光㈱徳山営業所広島和光㈱防府営業所中国ケミー㈱小郡営業所正晃㈱山口営業所広島和光㈱宇部営業所片山化学工業㈱山口営業所

740-0024 745-0062 745-0074 745-0801 747-0825 754-0001 754-0015 755-0008 755-0028

岩国市旭町2-12-29 周南市月丘町3-11 周南市今宿町4-17 周南市久米字沖角田3039-1 防府市新田66-2 山口市小郡上郷2296-15 山口市小郡大江町7-12 宇部市明神町3-3-26 宇部市東本町1-2-30

0827-22-0683 0834-22-3177 0834-31-6331 0834-25-1230 0835-24-5432 083-973-0913 083-972-0215 0836-34-3331 0836-21-9196

田田

大

薬洋


345

四国地区・九州地区・沖縄地区徳島県四国八洲薬品㈱㈱阿波化成片山化学工業㈱徳島営業所四国理科㈱徳島営業所

770-0873 771-0138 771-1151 771-1201

徳島市東沖洲2-17 徳島市川内町平石流通団地76番徳島市応神町古川字戎子野137-11 板野郡藍住町奥野字山畑39-3

088-664-6321 088-665-6565 088-666-3711 088-693-4660

香川県増田薬品㈱四国八洲薬品㈱高松営業所

760-0020 761-0301

高松市錦町1-13-21 高松市林町148-19

087-851-0631 087-815-1111

愛媛県四国八洲薬品㈱松山営業所荒木薬品㈱

791-1102 792-0011

松山市来住町1445-1 新居浜市西原町2-7-7

089-960-0260 0897-33-3853

高知県四国八洲薬品㈱高知営業所篠原化学薬品㈱日進商事㈱

780-0082 780-0084 780-0901

高知市南川添21-13 高知市南御座9-41 高知市上町5-6-15

088-884-8881 088-882-5000 088-822-3141

福岡県㈱三和正晃㈱北九州営業所ナカライテスク㈱福岡営業所キシダ化学㈱西日本営業所正晃㈱㈱三和福岡営業所サンケイ化学薬品㈱正晃㈱久留米営業所

804-0082 805-0071 812-0013 813-0034 813-0062 813-0062 815-0082 839-0815

北九州市戸畑区新池2-5-42 北九州市八幡東区東田1-6-5 福岡市博多区博多駅東3-12-1 福岡市東区多ノ津4-1-28 福岡市東区松島3-34-33 福岡市東区松島6-8-4 福岡市南区大楠2-6-24 久留米市山川沓形町3-30

093-871-4821 093-671-8006 092-474-2341 092-622-0422 092-621-8199 092-626-2333 092-531-2735 0942-45-1331

佐賀県正晃㈱佐賀営業所林純薬工業㈱九州営業所

840-0857 849-0305

佐賀市鍋島町八戸1843 小城市牛津町上砥川1641-17

0952-22-7841 0952-51-5777

長崎県三和化工薬品㈱正晃㈱長崎営業所

850-0875 859-0401

長崎市栄町4-13 諫早市多良見町化屋1781-1

095-821-2563 0957-49-2780

熊本県堤㈱ケ

㈱仁

860-0083 862-0967

熊本市北区大窪2-8-6 熊本市南区流通団地1-44-2

096-356-8711 096-377-2277

大分県㈲春日薬局正晃㈱大分営業所

870-0005 870-0921

大分市王子北町1-5 大分市萩原4-7-5

097-536-1177 0975-58-0025

宮崎県宝来メデック㈱宮崎支店旭化成コマース㈱南九州営業所

880-0916 882-0845

宮崎市恒久字草葉974-6 延岡市安賀多町3-4

0985-53-3611 0982-33-2933

鹿児島県正晃㈱鹿児島営業所宝来メデック㈱

891-0115 891-0123

鹿児島市東開町3-23 鹿児島市卸本町5-29

099-260-7133 099-260-2445

沖縄県正晃

901-1117

島尻郡南風原町津嘉山1582

098-888-3666

化ミ

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General Information

試薬のご購入，ご使用時の注意

■ Methods of Shipment

■ 取扱い

Unless specified otherwise, shipments are made at our discretion, and generally made by air parcel post where permitted by regulations. When special packaging or shipping is requested or required by regulations, the charges for these services will be added to the invoice.

試薬・化学薬品を使用する方は，化学的知識のある専門家に限られます。それ以外の方のご使用はお避けください。製品ラベル上に「毒物及び劇物取締法」，「消防法」，「労働安全衛生法」に基づく表示や，その他の危険性・有害性に関する事項を可能な限り表示しました。これらの表示に十分注意してご使用ください。試薬・化学薬品には危険性・有害性の知見が十分に得られていないものが数多くあります。したがって，危険性・有害性に関する表示がない場合，その試薬・化学薬品に危険性・有害性がないという事を意味するものではありません。また，たとえ表示がある場合であっても，その試薬・化学薬品の全ての危険性・有害性を示しているとは限りません。ご使用の際には安全面に十分注意し，開封，保管から廃棄に至るまで責任ある管理をお願いいたします。

■ Bulk Orders and Custom Synthesis Prices for bulk quantities and custom synthesis are available on request. Please contact us for information on the availability of bulk chemicals and new chemicals not listed here. (Please refer to the back cover or page 339 for a list of our local TCI offices and contact information.)

■ Return Shipment Return shipment cannot be accepted without prior authorization and unless made in compliance with proper shipment procedures. All claims for damage or shortage must be filed within 10 days of receipt.

■ Product Liability All products described in this catalog are for research purpose only. They are in no way to be used for food, drug, household or any other application. The hazards, physiological and toxicological properties of most chemicals have not yet been fully investigated and/or determined. Therefore, all chemicals should be handled with the utmost caution when used, stored or during disposal. All of our chemicals should be handled only by individuals familiar with their potential hazards and who have been fully trained in proper safety, laboratory and chemical handling procedures. Tokyo Chemical Industry Co., Ltd. (TCI) is not liable for damage to any person, persons or property resulting from incorrect handling, storage, usage or disposal of our products. TCI is not responsible for conditions and actions which are beyond our control. All products are supplied solely on the condition the customer alone accepts responsibility for damages resulting from any such incident or incidents.

■ Chemical Hazards Many products in this catalog have been made on the research basis only. Their chemical, physiological and toxicological properties and hazards may not have been fully investigated or determined. When known, Merck Index, Chemical Abstract and RTECS Numbers are provided for each chemical. TCI does not accept any responsibility for this information's correctness, completeness, or that it may fully provide all hazardous properties of each chemical. Chemicals may be extremely toxic or otherwise hazardous. The absence of warning for these conditions cannot and should not be interpreted as an indication of safety. All products should be handled only by individuals familiar with their potential hazards and who have been fully trained in proper safety, laboratory, and chemical handling procedures. For additional assistance, please refer to the back cover for a list of our local TCI offices and contact information.

■ 用途の範囲本カタログに収録した化学薬品は，試薬であり，試験・研究用のみに使用するものです。不適当な使用が予測される場合，注文をお断りすることが法により義務づけられています。弊社試薬には，「化学物質の審査及び製造等の規制に関する法律」および「労働安全衛生法（化学物質の有害性調査制度）」により既存化学物質として登録されていない新規化学物質が数多くあります。新規化学物質を試験・研究以外の用途に利用される場合には，使用される数量の多少にかかわらず新規化学物質としての届出の義務が生じます。その必要がある場合には，速やかに弊社営業部または化成品部へご連絡ください。試験・研究の目的で利用される場合には必要ありません。本カタログに収録した試薬・化学薬品は，医薬品，医薬部外品，化粧品，農薬，殺虫剤，食品添加物，家庭用化学薬品など，試験・研究以外の用途に使用することはできません。誤った使用による事故，保障については，当社は一切の責任を負いません。弊社は，出荷された製品の使用，販売に関して，その製品自身や他製品との併用からあるいは何らかの工程操作において，日本国内や外国の特許に抵触しないということを保証いたしません。

■ カタログ記載内容の変更本カタログに掲載されている製品およびその価格は，カタログ発行時のものです。原料事情や品質改善などのさまざまな理由により，やむを得ず品目の削除や価格，品質内容，製品等級の変更などを予告なしに行う場合があります。あらかじめご了承ください。製造ロットにより，製品ラベルの表示内容などがカタログ表示と異なる場合があります。最新情報は，ホームページをご覧ください。 (http://www.TCIchemicals.com/)

■ ご注文ご注文方法，お問い合わせにつきましては表紙裏をご覧ください。本カタログに掲載した試薬は，常時在庫してプロンプトデリバリーをモットーといたしておりますが，やむを得ない事情により品切れの場合はしばらくの猶予をお願いいたします。試薬・化学薬品は，特殊な性質を有しているものが数多くあり，品質管理上ご返品はご容赦願います。

■ MSDS 化学物質のより安全な取扱いの推進を目的とし，「製品安全データシート：Material Safety Data Sheet（MSDS）」の作成と提供に努めています。弊社ホームページにて公開しておりますのでご利用ください。


347

Reagents for Glyco Chemistry & Biology 4th Edition Not for Sale Fourth Edition : July 2013 Publisher TOKYO CHEMICAL INDUSTRY CO., LTD. 東京化成工業株式会社東京化成販売株式会社 4-10-2, Nihonbashi-Honcho, Chuo-Ku, Tokyo 103-0023, Japan 〒 103-0023 東京都中央区日本橋本町 4-10-2

Editor

TOKYO CHEMICAL INDUSTRY CO., LTD. Technical Information Management Department

東京化成工業株式会社学術部 ©2013 Tokyo Chemical Industry Co., Ltd. Reproduction forbidden without permission. Printed in Japan

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