Table II contains results of ab initio calculations for the benzyl radical. The ground and .... A two-fold potential is seen to exist with barriers of 13.0 and 17.2 cm-1 ,.
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Salvation Effects on Reactive Intermediatesi with Ar, N,,, CH 4, C H,, and C3Hz
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the Benzyl Radical and Its Clusters
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R. Disselkamp and E. R. Bernstein 13a TYPE OF REPORT
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transition region, electronic states, van der Waal modes, transition-energies, ionization eneray ABSTRACT (Continue on reverse if necessary and identify by block number) L I
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18.SUBJECT TERMS (Continue on reverse if necessary and identify by block rnjmberI mass resolved excitation spectra, red shifts, electronic
~vibronic coupling
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TECHNICAL REPORT #82 Solvation Effects on Reactive Intermediates: the Benzyl Radical and Its Clusters with Ar, N2 , CH 4 , C2 H 6, and C3H 8 by R. Disselkamp and E. R. Bernstein Accepted by Journal of Chemical Physics
Department of Chemistry Colorado State University Fort Collins, Colorado 80523
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This document has been approved for public release and sale; its distribution is unlimited
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ABSTRACT Mass resolved excitation spectra are presented for the benzyl radical and its clusters with Ar, N2 , CH 4 , C2 H6 , and C3 H8 . The cluster spectra exhibit small red shifts (< 50 cm-1) relative to the unclustered benzyl radical for the DI(12A2) (-- D0(1 2 B2) and D2(22B2)
