Supplement

4 downloads 171 Views 53KB Size Report
under dark condition in function of time at ozone concentrationO): 3ppm, ... 3,0. 3, 5 m a ss fo rm e d. (m g. ) reaction time (h). A. Figure 1S. Net et al., 2009. 0. 1. 2.
Supplemental electronic Material to

Heterogeneous ozonation kinetics of 4-phenoxyphenol in presence of photosensitizer S. Net, L. Nieto-Gligorovski, S. Gligorovski* and H. Wortham

Figure captions (1S to 9S): Figure 1S: Representative maleic acid formed during ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration): 1ppm, ): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4-CB in function of time at ozone concentration ): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm Figure 2S: Representative fumaric acid formed during ozonolysis of 4-PP under solar light illumination of the silica surface in presence of 4-CB in function of time at ozone concentration): 500ppb, ): 1ppm, ): 3ppm, ): 6ppm Figure 3S: Representative hydroquinone formed during ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration): 250ppm, ): 500ppb, ): 1ppm, ): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4CB in function of time at ozone concentration): 60ppm, ): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm Figure 4S: Representative catechol formed during ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration): 250ppm, ): 500ppb, ): 1ppm, ): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4CB in function of time at ozone concentration): 60ppm, ): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm Figure 5S: Representative benzoic acid formed during ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration): 500ppb, ): 1ppm, ): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4-CB in function of time at ozone concentration): 60ppm, ): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm Figure 6S: Representative 4-hydroxybenzoic acid formed during ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4-CB in function of time at

ozone concentration): 60ppm, ): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm Figure 7S: Representative 4,4’-dioxyphenol formed during ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration ): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4CB in function of time at ozone concentration): 60ppm, ): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm Figure

8S:

Representative

2-(4-Phenoxyphenoxy)-4-phenoxyphenol

formed

during

ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4-CB in function of time at ozone concentration ): 60ppm, ): 250ppb, ): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm Figure

9S:

Representative

4-[4-(4-Phenoxyphenoxy)phenoxy]phenol

formed

during

ozonolysis of 4-PP. A) under dark condition in function of time at ozone concentration): 500ppb, ): 1ppm, ): 3ppm, ): 6ppm and B) under solar light illumination of the silica surface in presence of 4-CB in function of time at ozone concentration): 500ppb, ): 1ppm, ): 3ppm and ): 6ppm 2-(4-Phenoxyphenoxy)-4-phenoxyphenol or 4-[4-(4-Phenoxyphenoxy)phenoxy]phenol

3,5

A

3,0

mass formed (mg)

2,5 2,0 1,5 1,0 0,5 0,0

0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 1S

Net et al., 2009 1,4

mass formed (mg)

B 1,2

1,0

0,8

0,6

0,4

0,2

0,0 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 1S

Net et al., 2009

0,12

mass formed (mg)

0,10

0,08

0,06

0,04

0,02

0,00 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 2S

Net et al., 2009 10

A

mass formed (mg)

8

6

4

2

0

0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 3S

Net et al., 2009

2,5

B

mass formed (mg)

2,0

1,5

1,0

0,5

0,0 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 3S

Net et al., 2009 1,2

A mass formed (mg)

1,0

0,8

0,6

0,4

0,2

0,0

0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 4S

Net et al., 2009

0,4

B

mass formed (mg)

0,3

0,2

0,1

0,0

0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 4S

Net et al., 2009

0,18

A 0,16

mass formed (mg)

0,14

0,12

0,10

0,08

0,06

0,04 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 5S

Net et al., 2009

0,7

B

mass formed (mg)

0,6

0,5

0,4

0,3

0,2

0,1

0,0 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 5S

Net et al., 2009 0,064

A mass formed (mg)

0,062

0,060

0,058

0,056

0,054 1

2

3

4

5

6

7

8

9

reaction time (h) Figure 6S

Net et al., 2009

0,5

B mass formed (mg)

0,4

0,3

0,2

0,1

0,0 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 6S

Net et al., 2009

3,0

A

mass formed (mg)

2,5

2,0

1,5

1,0

0,5

0,0 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 7S

Net et al., 2009

3,5

B mass formed (mg)

3,0

2,5

2,0

1,5

1,0

0,5

0,0 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 7S

Net et al., 2009 25

Normalised MS intensity (%)

A 20

15

10

5

0

0

1

2

3

4

5

6

7

8

9

reaction time (h)

Figure 8S

Net et al., 2009

120

Normalised MS intensity (%)

B 100

80

60

40

20

0 0

1

2

3

4

5

6

7

8

9

reaction time (h)

Figure 8S

Net et al., 2009

14

A

Normalised MS intensity (%)

12 10 8 6 4 2 0

0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 9S

Net et al., 2009

120

Normalised MS intensity (%)

B 100

80

60

40

20 0

1

2

3

4

5

6

7

8

9

reaction time (h) Figure 9S

Net et al., 2009