Supplementary Information for

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Terpyridyl – Naphthalene Diimide Complex. Duraisamy Kumaresan, Kristi Lebkowsky and Russell H. Schmehl ([email protected]). Tulane University, New ...
Supplementary Information for :

Photoinduced Charge Separation and Recombination in Solution and in Gels of a Pt(II) Terpyridyl – Naphthalene Diimide Complex

Duraisamy Kumaresan, Kristi Lebkowsky and Russell H. Schmehl ([email protected]) Tulane University, New Orleans, LA

I.

ESI Mass Spectral Data [(ND-tpy)PtCl]+

II.

Cyclic Voltammetry of [(ND-tpy)PtCl]+ in CH3CN

III.

SEM images of dried gels.

I. ESI-TOF spectra were acquired using a Bruker MicroTOF mass spectrometer. Assignment of the complex was based upon the exact mass analysis and the quality of the isotope distribution.

II. Reductive cyclic voltammetry data. Data obtained with for a degassed DMF solution containing tetrabutylammonium hexafluorophosphate as supporting electrolyte. Potentials shown are not accurate. Separate voltammograms were obtained for the complex with ferrocene as an internal reference; potentials were then corrected to those having a SCE reference.

III. SEM images obtained for dried gels. NOTE : EDX data clearly show presence of Pt and Cl in the dried gels.