Waste Processing and Recycling in Mineral and

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increased from 8.4% to 27.3o/o, to the disadvantage of Ni-Cd bafteries that decreased from 63.8 to ..... recycling as cobaltite in new batteries, with yield of 100%.
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40th ANNUAL CONFERENCE OF METALLURGISTS OF CIM

AUGUST 26 -29,2OOI,TORONTO, ONTARTO,CANADA WASTE PROCEEDINGSOF THE FOURTH INTERNATIONAL SYMPOSTUMON PROCESSINGAND RECYCLING IN MINERAL A}{D METALLURGICAL INDUSTRIES

Waste Processingand Recycling in Mineral and Metallurgical Industries IV

Editors S.R.Rao McGill UniversitY Montreal,Quebec,Canada

L.M. Arnaratunga LaurentianUniversitY Sudbury,Ontario,Canada

P.D.Kondos Centrede technlogieNoranda PointeClaire,Quebec,Canada

G.G.Richards ComincoLimited Trail, British Columbia,Canada

N. Kuyucak GolderAssociatesLimited Ottawa,Ontario,Canada

J.A.Kozinski McGill UniversitY Montreal,Quebec,Canada

Symposium Organized by Mineral Sciencesand Engineering, Hydrometallurglt, \on-ferrous py.ometallurgy, Iron and Steel and Light Metals Sections of the Metallurgical Society, and the Environmental Societyof The Canadian Instituîe of Mining, Metallurgt and Petroleum

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Electrolytic cobalt recoveryfrom lithium-ion batteries

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Mauro Pasquali and Carla LuPi "La Sapíenza" Dip. ICMMPM - Università di Roma Via Eudossiana 18 0A184 Roma Italy clupí@metal I . ing. uniroma I . it

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i5580, ABSTRACT from The studiedprocessdealsu.ith cobalt electrolyticrecoveryfrom Li-ion'batteries by means of both galvanostaticand potentiostatic electrowinning. The use of guluunortaticconditionsallows to obtain a good Co metal deposit,while potentiostatic óonditionsprovide a cobaltdepletionin the electrolyte.

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The last operation is very interesting becausethe produced Co powd-er is transformedat lod .C in Co:oa precursorwith LizCo: for the Lithium Cobalt oxide cathodematerial.In this casewe havenot only a recoveryof Co but alsoa true recycleof the cathodeactivepaste.

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